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21. 发明申请

US20100137540A1 Polymer and Surface-Treating Agent Containing the Polymer 有权
标题翻译：含聚合物的聚合物和表面处理剂
公开(公告)号：US20100137540A1
公开(公告)日：2010-06-03
申请号：US12531606
申请日：2008-03-21
申请人： Kenya Ito , Hisao Oikawa , Koji Ohguma , Mikio Yamahiro
发明人： Kenya Ito , Hisao Oikawa , Koji Ohguma , Mikio Yamahiro
IPC分类号： C08F230/08
CPC分类号： C08F290/148 , C08F283/12 , C08F290/06 , C08F290/068 , C08G77/04 , C08G77/24 , C09D143/04 , Y10T428/31855
摘要： A polymer and a treating agent (such as a surface-treating agent) are provided that have excellent characteristics in such properties as water repellency, oil repellency, antifouling property and charge controlling property. The polymer contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group, or contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group and a structural unit derived from organopolysiloxane having an addition polymerizable group. The treating agent contains the polymer. An article treated with the treating agent is also provided.
摘要翻译：提供聚合物和处理剂（例如表面处理剂），其具有防水性，拒油性，防污性和电荷控制性等性能优异的特性。聚合物含有衍生自具有加成聚合基团的氟代倍半硅氧烷的结构单元，或含有衍生自具有加聚性基团的氟代倍半硅氧烷的结构单元和衍生自具有加成聚合基团的有机聚硅氧烷的结构单元。处理剂含有聚合物。还提供了用处理剂处理的制品。

22. 发明授权

US08445613B2 Polymer and surface-treating agent containing the polymer 有权
标题翻译：含有聚合物的聚合物和表面处理剂
公开(公告)号：US08445613B2
公开(公告)日：2013-05-21
申请号：US12531606
申请日：2008-03-21
申请人： Kenya Ito , Hisao Oikawa , Koji Ohguma , Mikio Yamahiro
发明人： Kenya Ito , Hisao Oikawa , Koji Ohguma , Mikio Yamahiro
IPC分类号： C08F30/08
CPC分类号： C08F290/148 , C08F283/12 , C08F290/06 , C08F290/068 , C08G77/04 , C08G77/24 , C09D143/04 , Y10T428/31855
摘要： A polymer and a treating agent (such as a surface-treating agent) are provided that have excellent characteristics in such properties as water repellency, oil repellency, antifouling property and charge controlling property. The polymer contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group, or contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group and a structural unit derived from organopolysiloxane having an addition polymerizable group. The treating agent contains the polymer. An article treated with the treating agent is also provided.
摘要翻译：提供聚合物和处理剂（例如表面处理剂），其具有防水性，拒油性，防污性和电荷控制性等性能优异的特性。聚合物含有衍生自具有加成聚合基团的氟代倍半硅氧烷的结构单元，或含有衍生自具有加聚性基团的氟代倍半硅氧烷的结构单元和衍生自具有加成聚合基团的有机聚硅氧烷的结构单元。处理剂含有聚合物。还提供了用处理剂处理的制品。

23. 发明授权

US07989560B2 Fluorine-containing polymer and resin composition 有权
标题翻译：含氟聚合物和树脂组合物
公开(公告)号：US07989560B2
公开(公告)日：2011-08-02
申请号：US12519354
申请日：2007-12-17
申请人： Hisao Oikawa , Koji Ohguma , Kenya Ito , Mikio Yamahiro
发明人： Hisao Oikawa , Koji Ohguma , Kenya Ito , Mikio Yamahiro
IPC分类号： C08L43/04 , C08L75/04
CPC分类号： C08F283/12 , C08F290/00 , C08F290/06 , C08F290/068 , C08F290/14 , C08F290/148 , C08G77/385 , C08G77/442 , C08L55/00 , C09D155/00 , C08L2666/02
摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable functional monomer containing a group having active hydrogen, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer containing a group having active hydrogen.
摘要翻译：含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由含有具有活性氢的基团的加成聚合性官能单体衍生的结构单元C，并且任选地含有来自除了在分子中具有一个加成聚合官能团的氟代倍半硅氧烷以外的加聚性单体的结构单元D，具有加聚性官能团的有机聚硅氧烷和含有具有活性氢的基团的加成聚合性单体。

24. 发明申请

US20100063222A1 FLUORINE-CONTAINING POLYMER AND RESIN COMPOSITION 有权
标题翻译：含氟聚合物和树脂组合物
公开(公告)号：US20100063222A1
公开(公告)日：2010-03-11
申请号：US12519347
申请日：2007-12-17
申请人： Hisao Oikawa , Koji Ohguma , Kenya Ito , Minoru Nakayama , Shin Koga , Mikio Yamahiro , Hiroyuki Sato
发明人： Hisao Oikawa , Koji Ohguma , Kenya Ito , Minoru Nakayama , Shin Koga , Mikio Yamahiro , Hiroyuki Sato
IPC分类号： C08L83/06 , C08G77/04
CPC分类号： C08F290/06 , C08F283/12 , C08F290/068 , C08F290/14 , C08F290/148 , C08G77/04 , C08G77/24 , C08G77/385
摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable monomer and has a group having a polymerizable unsaturated bond on a side chain, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer having a functional group capable of introducing a group having a polymerizable unsaturated bond.
摘要翻译：含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由可加聚单体衍生的具有在侧链上具有可聚合不饱和键的基团的结构单元C，并且任选地含有衍生自具有一个可加聚可聚合的氟代倍半硅氧烷以外的可加聚单体的结构单元D 分子中的官能团，具有加聚性官能团的有机聚硅氧烷和具有能够引入具有聚合性不饱和键的基团的官能团的加成聚合性单体。

25. 发明授权

US07687593B2 Fluorinated polymer and polymer composition 有权
标题翻译：氟化聚合物和聚合物组成
公开(公告)号：US07687593B2
公开(公告)日：2010-03-30
申请号：US11528692
申请日：2006-09-28
申请人： Mikio Yamahiro , Koji Ohguma , Hisao Oikawa , Hisanobu Minamizawa , Hiroyuki Sato , Kenichi Watanabe
发明人： Mikio Yamahiro , Koji Ohguma , Hisao Oikawa , Hisanobu Minamizawa , Hiroyuki Sato , Kenichi Watanabe
IPC分类号： C08G77/12
CPC分类号： C08F214/18
摘要： Provided are: an addition polymer of fluorosilsesquioxane (a) having one addition polymerizable functional group or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and an addition polymerizable monomer (b); a coating film including the polymer or the copolymer; and an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and organopolysiloxane (c) having an addition polymerizable functional group, or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group, the organopolysiloxane (c) having an addition polymerizable functional group, and the addition polymerizable monomer (b).
摘要翻译：提供：具有一个可加聚官能团的氟倍半硅氧烷（a）的加成聚合物或具有一个可加聚官能团的氟代倍半硅氧烷（a）和可加聚单体（b）的加成共聚物; 包含聚合物或共聚物的涂膜; 和具有一个加成聚合官能团的氟代倍半硅氧烷（a）和具有加聚性官能团的有机聚硅氧烷（c）的加成共聚物，或具有一个可加成聚合官能团的氟代倍半硅氧烷（a）的加成共聚物，有机聚硅氧烷（c）具有可加成聚合的官能团和可加聚单体（b）。

26. 发明申请

US20070135602A1 Fluorinated polymer and polymer composition 有权
标题翻译：氟化聚合物和聚合物组成
公开(公告)号：US20070135602A1
公开(公告)日：2007-06-14
申请号：US11528692
申请日：2006-09-28
申请人： Mikio Yamahiro , Koji Ohguma , Hisao Oikawa , Hisanobu Minamizawa , Hiroyuki Sato , Kenichi Watanabe
发明人： Mikio Yamahiro , Koji Ohguma , Hisao Oikawa , Hisanobu Minamizawa , Hiroyuki Sato , Kenichi Watanabe
IPC分类号： C08F214/18
CPC分类号： C08F214/18
摘要： Provided are: an addition polymer of fluorosilsesquioxane (a) having one addition polymerizable functional group or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and an addition polymerizable monomer (b); a coating film including the polymer or the copolymer; and an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and organopolysiloxane (c) having an addition polymerizable functional group, or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group, the organopolysiloxane (c) having an addition polymerizable functional group, and the addition polymerizable monomer (b).
摘要翻译：提供：具有一个可加聚官能团的氟倍半硅氧烷（a）的加成聚合物或具有一个可加聚官能团的氟代倍半硅氧烷（a）和可加聚单体（b）的加成共聚物; 包含聚合物或共聚物的涂膜; 和具有一个加成聚合官能团的氟代倍半硅氧烷（a）和具有加聚性官能团的有机聚硅氧烷（c）的加成共聚物，或具有一个可加成聚合官能团的氟代倍半硅氧烷（a）的加成共聚物，有机聚硅氧烷（c）具有可加成聚合的官能团和可加聚单体（b）。

27. 发明申请

US20060089504A1 Silsesquioxane derivative having functional group 审中-公开
标题翻译：具有官能团的倍半硅氧烷衍生物
公开(公告)号：US20060089504A1
公开(公告)日：2006-04-27
申请号：US11294364
申请日：2005-12-06
申请人： Kenya Ito , Mikio Yamahiro , Kenichi Watanabe
发明人： Kenya Ito , Mikio Yamahiro , Kenichi Watanabe
IPC分类号： C07F7/10
CPC分类号： C08G77/06 , C08G77/045 , C08G77/38
摘要： A conventional silsesquioxane derivative has the problems that the functional groups are restricted and the chemical structure is not readily controlled and that it is expensive. The present inventors have developed a process for producing a silsesquioxane derivative at a high yield by a simple process in order to solve such problems. The novel silsesquioxane derivative according to the present invention is controlled in a structure thereof and has a functional group, which is excellent in reactivity with a target compound, to be modified. The present invention relates to a production process for a silsesquioxane derivative represented by Formula (2), characterized by using a silicon compound represented by Formula (1). In Formula (1) and Formula (2), R is a group selected from hydrogen, alkyl, aryl and arylalkyl; M is a monovalent alkaline metal atom; at least one of Y is a group represented by Formula (3), and the remainder of Y is hydrogen; R1 and R2 in Formula (3) represent the same group as defined for R; and Z is a functional group or a group having a functional group.
摘要翻译：常规的倍半硅氧烷衍生物存在官能团受限并且化学结构不容易控制并且昂贵的问题。为了解决这些问题，本发明人通过简单的工艺开发了高产率的倍半硅氧烷衍生物的制备方法。根据本发明的新型倍半硅氧烷衍生物在其结构中被控制，并且具有与待改性的目标化合物的反应性优异的官能团。本发明涉及由式（2）表示的倍半硅氧烷衍生物的制备方法，其特征在于使用由式（1）表示的硅化合物。在式（1）和式（2）中，R是选自氢，烷基，芳基和芳基烷基的基团; M是一价碱性金属原子; Y中的至少一个为由式（3）表示的基团，Y的其余部分为氢; 式（3）中的R 1和R 2代表与R所定义的相同的基团; Z为官能团或具有官能团的基团。

28. 发明授权

US07053167B2 Silsesquioxane derivative having functional group 有权
标题翻译：具有官能团的倍半硅氧烷衍生物
公开(公告)号：US07053167B2
公开(公告)日：2006-05-30
申请号：US10661536
申请日：2003-09-15
申请人： Kenya Ito , Mikio Yamahiro , Kenichi Watanabe
发明人： Kenya Ito , Mikio Yamahiro , Kenichi Watanabe
IPC分类号： C08G77/24
CPC分类号： C08G77/06 , C08G77/045 , C08G77/38
摘要： A conventional silsesquioxane derivative has the problems that the functional groups are restricted and the chemical structure is not readily controlled and that it is expensive. The present inventors have developed a process for producing a silsesquioxane derivative at a high yield by a simple process in order to solve such problems. The novel silsesquioxane derivative according to the present invention is controlled in a structure thereof and has a functional group, which is excellent in reactivity with a target compound, to be modified. The present invention relates to a production process for a silsesquioxane derivative represented by Formula (2), characterized by using a silicon compound represented by Formula (1). In Formula (1) and Formula (2), R is a group selected from hydrogen, alkyl, aryl and arylalkyl; M is a monovalent alkaline metal atom; at least one of Y is a group represented by Formula (3), and the remainder of Y is hydrogen; R1 and R2 in Formula (3) represent the same group as defined for R; and Z is a functional group or a group having a functional group
摘要翻译：常规的倍半硅氧烷衍生物存在官能团受限并且化学结构不容易控制并且昂贵的问题。为了解决这些问题，本发明人通过简单的工艺开发了高产率的倍半硅氧烷衍生物的制备方法。根据本发明的新型倍半硅氧烷衍生物在其结构中被控制，并且具有与待改性的目标化合物的反应性优异的官能团。本发明涉及由式（2）表示的倍半硅氧烷衍生物的制备方法，其特征在于使用由式（1）表示的硅化合物。在式（1）和式（2）中，R是选自氢，烷基，芳基和芳基烷基的基团; M是一价碱性金属原子; Y中的至少一个为由式（3）表示的基团，Y的其余部分为氢; 式（3）中的R 1和R 2代表与R所定义的相同的基团; Z为官能团或具有官能团的基团

29. 发明授权

US09751286B2 Weather-resistant multilayer film 有权
公开(公告)号：US09751286B2
公开(公告)日：2017-09-05
申请号：US14129990
申请日：2012-07-02
申请人： Akiko Yoda , Kenya Ito , Koji Ohguma , Mikio Yamahiro
发明人： Akiko Yoda , Kenya Ito , Koji Ohguma , Mikio Yamahiro
IPC分类号： B32B27/18 , B32B27/30 , B32B27/08 , B32B27/36
CPC分类号： B32B27/18 , B32B27/08 , B32B27/308 , B32B27/36 , B32B2307/40 , B32B2307/71 , B32B2307/712 , B32B2457/20 , Y10T428/24975 , Y10T428/31797 , Y10T428/31928
摘要： Provided is a multi-layered weather-resistant multilayer film that exhibits good substrate adhesion, wherein curing problems are avoided, bleed-out is minimized, yellowing is reduced, and weather-resistance is improved. The weather-resistant multilayer film 10 is provided with the following: a transparent film-like substrate C; a UV-absorbing resin layer B laminated on the substrate C and containing a UV absorber; and a first cured resin layer A laminated on the UV-absorbing resin layer B. The first cured resin layer A has a thickness of 1.0 to 10 μm. The UV-absorbing resin layer B has a thickness of 0.5 to 5 μm. The UV-absorbing resin layer B has an absorption wavelength of 200 to 500 nm.

30. 发明授权

US09375867B2 Transfer film for in-mold molding and method for producing same 有权
标题翻译：模内成型用转印膜及其制造方法
公开(公告)号：US09375867B2
公开(公告)日：2016-06-28
申请号：US14127964
申请日：2012-06-18
申请人： Kenya Ito , Koji Ohguma , Takuro Tanaka , Yuka Takahashi , Aki Kuromatsu , Mikio Yamahiro
发明人： Kenya Ito , Koji Ohguma , Takuro Tanaka , Yuka Takahashi , Aki Kuromatsu , Mikio Yamahiro
IPC分类号： B29C45/14 , B32B27/16 , B44C1/17 , B32B7/06 , B32B38/00
CPC分类号： B29C45/14688 , B29C45/14 , B29C45/14811 , B29C45/14827 , B32B7/06 , B32B27/16 , B32B38/0036 , B32B2270/00 , B32B2451/00 , B44C1/1729 , Y10T428/24851 , Y10T428/31511 , Y10T428/31515 , Y10T428/31551 , Y10T428/31554 , Y10T428/31598 , Y10T428/31663 , Y10T428/31946
摘要： Provided is a transfer film for in-mold molding which is superior in solvent resistance, heat resistance, durability, blocking resistance, and moldability, and is capable of suppressing the generation of gate flow, and also provided is a method for producing such a film. The film is provided with: a transfer layer (11) which is to be transferred to an in-mold molded body and which is to be cured when irradiated with active energy rays after the transfer; and a film shaped substrate (L0). The transfer layer (11) comprises an IMD layer (L2) laminated on the substrate (L0) and to be arranged on the outermost surface of the molded body after the in-mold molding. The IMD layer (L2) is constituted by a mixture composition containing at least one active-energy curable resin and at least one thermosetting resin.
摘要翻译：提供了一种模内成型用转印膜，其耐溶剂性，耐热性，耐久性，耐粘连性和成型性优异，并且能够抑制栅极流动的产生，并且还提供了制造这种膜的方法。膜设置有：转印层（11），其被转印到模内成型体中，并且在转印后用活性能量射线照射时被固化; 和薄膜状基板（L0）。转印层（11）包括层叠在基板（L0）上的IMD层（L2），并且在模内成型之后布置在成形体的最外表面上。 IMD层（L2）由含有至少一种活性能量固化树脂和至少一种热固性树脂的混合物组合物构成。

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