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21. 发明授权

US6103106A Desulfurization and ring opening of petroleum streams 有权
标题翻译：石油流的脱硫和开环
公开(公告)号：US6103106A
公开(公告)日：2000-08-15
申请号：US326843
申请日：1999-06-07
申请人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
发明人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
IPC分类号： C10G45/10 , C10G65/04 , C10G65/08 , C10G67/06 , C10G45/00
CPC分类号： C10G67/06 , C10G45/10 , C10G65/04 , C10G65/043 , C10G65/08
摘要： A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.
摘要翻译：多重稠环杂环有机硫化合物的加氢脱硫（HDS）和存在于石油和石油化工流中的环化合物的开环方法。该方法在氢气，一种或多种贵金属催化剂和硫化氢吸附剂材料的存在下进行。

22. 发明授权

US09487714B2 Hydrocracking process selective for improved distillate and improved lube yield and properties 有权
公开(公告)号：US09487714B2
公开(公告)日：2016-11-08
申请号：US14011061
申请日：2013-08-27
申请人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
发明人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
IPC分类号： C10G47/18 , C10G49/04 , C10G65/10 , C10G65/12
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

23. 发明授权

US09458367B2 Low temperature transport and storage of amine gas treatment solutions 有权
标题翻译：低温运输和储存胺气处理溶液
公开(公告)号：US09458367B2
公开(公告)日：2016-10-04
申请号：US13793298
申请日：2013-03-11
申请人： Michael Siskin , Robert Basil Fedich , Michel Daage
发明人： Michael Siskin , Robert Basil Fedich , Michel Daage
IPC分类号： C09K3/00 , B01D53/14
CPC分类号： C09K3/00 , B01D53/1468 , B01D53/1493 , B01D2252/103 , B01D2252/2023 , B01D2252/2025 , B01D2252/204 , B01D2252/504 , B01D2252/60 , Y10T137/0391
摘要： A liquid aminoether acid gas absorbent which is subject to freezing in a cold climatic zone though which the aminoether is to be shipped is rendered freeze-resistant by mixing the aminoether with water prior to transport through the cold climatic zone; the aminoether/water mixture typically contains 10 to 40 weight percent water, based on the weight of the aminoether. The aminoether/water mixture can also be stored in the cold climatic zone without being externally maintained at a temperature above the inherent freezing point of the aminoether.
摘要翻译：在运输氨基醚的寒冷气候区域内要冷冻的液体氨基醚酸吸收剂在通过冷气候区域运输之前通过混合氨基醚与水而变成抗冻性; 基于氨基醚的重量，氨基醚/水混合物通常含有10至40重量％的水。氨基醚/水混合物也可以储存在寒冷气候区，而不会外部保持在高于氨基醚固有凝固点的温度。

24. 发明授权

US09221725B2 Production of lubricant base oils from biomass 有权
标题翻译：从生物质生产润滑油基础油
公开(公告)号：US09221725B2
公开(公告)日：2015-12-29
申请号：US13917743
申请日：2013-06-14
申请人： Virginia M. Roberts , Michel Daage , Paul D. Oldenburg , Suzzy C. Ho , Kun Wang , Bradley R. Fingland
发明人： Virginia M. Roberts , Michel Daage , Paul D. Oldenburg , Suzzy C. Ho , Kun Wang , Bradley R. Fingland
IPC分类号： C07C1/00 , C07C1/207 , C10G29/22 , C10G3/00 , C11C3/00 , B01J21/12 , B01J23/02 , B01J23/10
CPC分类号： C07C1/2076 , B01J21/12 , B01J23/02 , B01J23/10 , C10G3/44 , C10G3/50 , C10G29/22 , C10G2300/1014 , C10G2300/1018 , C10G2400/10 , C11C3/00 , Y02E50/13 , Y02P30/20
摘要： Methods are provided for processing glycerides to form lubricant boiling range molecules in a single reactor and/or a single reaction zone. The glycerides are exposed to catalysts that are stable under the conditions present in the reaction zones during conversion of glycerides to fatty ketones via a coupling reaction in the presence of a first catalyst, and the subsequent deoxygenation and isomerization of the ketones in the presence of a second dewaxing catalyst. The glyceride-containing feedstock can further include free fatty acids or fatty acid derivatives that can also be used for formation of ketones and subsequent deoxygenation and isomerization. In some configuration, the processing can occur in a single reaction zone containing mixed beds of the first and second catalyst. Such configurations can be used to control the ratio of diesel boiling range molecules versus lubricant boiling range molecules generated by the methods.
摘要翻译：提供了用于处理甘油酯以在单个反应器和/或单个反应区中形成润滑剂沸程分子的方法。将甘油酯暴露于在第一催化剂存在下通过偶联反应将甘油酯转化成脂肪酮的反应区中存在的条件下稳定的催化剂，以及随后在存在下的酮的脱氧和异构化第二脱蜡催化剂。含甘油酯的原料还可以包括游离脂肪酸或脂肪酸衍生物，其还可用于形成酮和随后的脱氧和异构化。在一些配置中，处理可以发生在包含第一和第二催化剂的混合床的单个反应区中。这种配置可用于控制柴油沸程分子与通过该方法产生的润滑剂沸程分子的比例。

25. 发明授权

US08992764B2 Integrated hydrocracking and dewaxing of hydrocarbons 有权
标题翻译：烃的综合加氢裂化和脱蜡
公开(公告)号：US08992764B2
公开(公告)日：2015-03-31
申请号：US13169409
申请日：2011-06-27
申请人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
发明人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
IPC分类号： C10G73/38 , C10G73/44 , C10G45/02 , C10G45/64 , C10G47/16 , C10G7/00 , C10G49/22 , C10G65/12 , C10G65/04 , B01J29/74 , B01J35/02
CPC分类号： C10G67/02 , B01J29/7461 , B01J35/026 , B01J2229/36 , B01J2229/42 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10 , C10L1/08 , C10L2200/0446 , C10L2270/026 , C10L2290/543 , C10M101/02
摘要： An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.
摘要翻译：提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。在更高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。酸性饲料可以输送到催化脱蜡步骤，而不会分离硫和氮污染物。一体化方法包括在酸性条件下进料的初始脱蜡，脱蜡进料的任选加氢裂化和分离以形成第一柴油产物和塔底馏分。然后将底部馏分暴露于额外的加氢裂化和脱蜡以形成第二柴油产品和任选的润滑剂基础油产品。或者，可以将原料加氢处理，分馏，脱蜡，然后进行加氢裂化，以形成任选适合用作润滑剂基础油的柴油燃料和脱蜡加氢裂化塔底馏分。

26. 发明授权

US08962701B2 Integrated bioprocessing for fuel production 有权
公开(公告)号：US08962701B2
公开(公告)日：2015-02-24
申请号：US13326017
申请日：2011-12-14
申请人： Paul D. Oldenburg , Michel Daage , Virginia M. Roberts , Paul J. Berlowitz , David C. Long , James R. Bielenberg
发明人： Paul D. Oldenburg , Michel Daage , Virginia M. Roberts , Paul J. Berlowitz , David C. Long , James R. Bielenberg
IPC分类号： C07C27/00 , C07C51/43 , C07C1/00
CPC分类号： C07C29/1518 , C10G2/32 , C10J2300/0916 , C10J2300/1659 , C10J2300/1665 , C10J2300/1681 , C10K1/005 , C10K3/04 , C11B1/04 , C11B1/10 , C11C3/003 , C12P7/6463 , Y02E50/18 , Y02E50/343 , Y02P20/125 , Y02P20/145 , Y02P20/582 , C07C31/04
摘要： Systems and methods are provided for enhancing the integration of processes for recovering products from algae-derived biomass. The enhanced process integration allows for increased use of input streams and other reagents that are derived from renewable sources. This increases the overall renewable character of the products extracted from the algae-derived biomass. The process integration can include exchange of input streams or energy between an algae processing system and a system for processing non-algal biomass. One example of improving process integration is using oxygenates that are generated in a renewable manner as a reagent for enhancing the algae processing system.

27. 发明授权

US08557106B2 Hydrocracking process selective for improved distillate and improved lube yield and properties 有权
标题翻译：加氢裂化过程选择性改善馏出物和改善润滑油产量和性能
公开(公告)号：US08557106B2
公开(公告)日：2013-10-15
申请号：US13237361
申请日：2011-09-20
申请人： William J. Novak , Robert A. Bradway , Stuart S. Shih , Timothy L. Hilbert , Michel Daage
发明人： William J. Novak , Robert A. Bradway , Stuart S. Shih , Timothy L. Hilbert , Michel Daage
IPC分类号： C10G47/02 , C10G45/62 , C10G45/64 , C10G45/12
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.
摘要翻译：本发明涉及一种包含进料流加氢裂化的方法，其中转化馏分可表现出相对较高的馏出物产物产率和维持或改善的馏出物燃料性质，而未转化的馏分可表现出在润滑剂区域特别有用的改进的性能。在该加氢裂化过程中，相对于转化的馏出物燃料和未转化的润滑剂，可以有利于减少或最小化汽油燃料应用的转化/未转化产物的产率。可以选择催化剂和条件以帮助实现或优化所需的产物产率和/或性能。

28. 发明授权

US08487148B2 Hydrothermal treatment of biomass with heterogeneous catalyst 有权
标题翻译：用非均相催化剂水热处理生物质
公开(公告)号：US08487148B2
公开(公告)日：2013-07-16
申请号：US13285519
申请日：2011-10-31
申请人： Virginia M. Roberts , Michel Daage , Paul D. Oldenburg , James R. Bielenberg , Paul J. Berlowitz , David C. Long , Halou Oumar-Mahamat
发明人： Virginia M. Roberts , Michel Daage , Paul D. Oldenburg , James R. Bielenberg , Paul J. Berlowitz , David C. Long , Halou Oumar-Mahamat
IPC分类号： C10M169/04
CPC分类号： C10G3/42 , C10G3/47 , C10G3/48 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/301 , C10G2300/4018 , C10J2300/0916 , Y02P20/145 , Y02P30/20
摘要： Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment can be performed in the presence of heterogeneous catalyst particles that can optionally include a catalyst metal or metal salt. The presence of the heterogeneous catalyst can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.
摘要翻译：基于生物质的饲料在水热处理条件下进行处理，例如产生烃液体产物和固体部分。水热处理可以在可任选地包括催化剂金属或金属盐的非均相催化剂颗粒的存在下进行。非均相催化剂的存在可以改变由水热处理产生的烃产物的性质。

29. 发明授权

US06753286B2 Supported catalyst regeneration 有权
标题翻译：负载催化剂再生
公开(公告)号：US06753286B2
公开(公告)日：2004-06-22
申请号：US10059917
申请日：2002-01-29
申请人： Janet Renee Clark , Russell John Koveal , Michel Daage
发明人： Janet Renee Clark , Russell John Koveal , Michel Daage
IPC分类号： B01J3862
CPC分类号： C10G2/33 , B01J23/94 , B01J23/96 , B01J38/10 , B01J38/58 , B01J38/62 , B01J38/70 , B01J2038/005 , C10G2/332 , C10G2/333
摘要： There is provided a process for renewing the activity of used, supported metal catalysts for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons comprising decreasing the hydrocarbon content of the catalyst, impregnating said catalyst under an non-oxidative atmosphere with a solution at least one weak organic acid, preferably a mono- or di-carboxylic acid, to the point where it has absorbed a volume of said solution equal to at least about 10% of its calculated pore volume, oxidizing the catalyst with a gaseous oxidant in the presence of the impregnating solution and activating the catalyst by reduction with hydrogen at elevated temperatures. Optionally, the catalyst is calcined after the oxidation step, and passivated after the activation step. A preferred means of decreasing the hydrocarbon content of the catalyst is contacting it with a hydrogen-containing gas at elevated temperatures.
摘要翻译：提供了一种用于更新用于一氧化碳氢化的用过的负载金属催化剂以形成烃的混合物的活性的方法，包括降低催化剂的烃含量，在非氧化性气氛下用至少一种溶液浸渍所述催化剂一种弱有机酸，优选单羧酸或二羧酸，其吸收一定体积的所述溶液等于其计算的孔体积的至少约10％，在存在下用气态氧化剂氧化催化剂的浸渍溶液，并通过在升高的温度下用氢还原来活化催化剂。任选地，在氧化步骤之后煅烧催化剂，并在活化步骤后钝化。降低催化剂的烃含量的优选方法是在升高的温度下将其与含氢气体接触。

30. 发明授权

US5841013A Aromatics hydrogenation with a new class of metal oxides 失效
标题翻译：芳烃氢化与一类新型的金属氧化物
公开(公告)号：US5841013A
公开(公告)日：1998-11-24
申请号：US857605
申请日：1997-05-16
申请人： Teh Chung Ho , Charles Ralph Symon , Viktor Buchholz , Michel Daage
发明人： Teh Chung Ho , Charles Ralph Symon , Viktor Buchholz , Michel Daage
IPC分类号： B01J23/28 , B01J23/30 , B01J23/88 , B01J37/08 , C07C5/10 , C10G45/50 , B01J31/00
CPC分类号： B01J23/883 , B01J23/28 , B01J23/30 , B01J23/88 , B01J23/8898 , B01J37/086 , C07C5/10 , C10G45/50 , B01J23/8878 , C07C2531/22
摘要： The present invention is directed toward a hydrogenation process using a highly active aromatics hydrogenation catalyst. The catalyst is prepared by decomposing a catalyst precursor selected from the group consisting of metal amine molybdates, metal amine tungstates and mixtures thereof, wherein said metal amine catalyst precursor has the general formula ML (Mo.sub.y W.sub.1-y O.sub.4).sub.a where M is Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu and Zn; L is one or more neutral nitrogen-containing ligands at least one of which is a chelating polydentate ligand; 0.ltoreq.y.ltoreq.1; and a=1 for non-chromium containing catalysts and wherein 0.5.ltoreq.a.ltoreq.3 for chromium containing catalysts, at a temperature of about 200.degree. C. to about 400.degree. C. in an inert atmosphere; then reducing at a temperature of about 300.degree. C. to about 450.degree. C. said metal amine catalyst precursor to form a mixed metal oxide catalyst of the formula ML(Mo.sub.y W.sub.1-y O.sub.b).sub.a where M, L and y are as above and b
摘要翻译：本发明涉及使用高活性芳烃加氢催化剂的氢化方法。催化剂是通过分解选自钼酸金属胺，钨酸金属胺及其混合物的催化剂前体制备的，其中所述金属胺催化剂前体具有通式ML（MoyW1-yO4）a，其中M是Cr和/或一种或多种选自Mn，Fe，Co，Ni，Cu和Zn的二价助催化剂金属; L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 0

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