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    • 23. 发明申请
    • PROPYLENE COMPOSITION WITH HIGH STIFFNESS AND IMPACT STRENGTH
    • 丙烯组合物具有高强度和抗冲击强度
    • US20110229670A1
    • 2011-09-22
    • US13129511
    • 2010-02-04
    • Markus GahleitnerBo MalmKlaus BernreitnerJuliane Braun
    • Markus GahleitnerBo MalmKlaus BernreitnerJuliane Braun
    • C08L23/14C08L23/12C08K3/34C08K3/40C08K7/14B32B1/02B32B1/08
    • C08F10/00C08F10/06C08F110/06C08F4/6543C08F4/6492C08F4/651C08F210/16C08F2500/04C08F2500/19C08F2500/12C08F2500/11C08F2500/20C08F2500/24
    • The present invention is directed to a polypropylene composition comprising a propylene homo- or copolymer (A) with a polydispersity index (PI), determined according ISO 6721-1, of at least 5.8 Pa−1; and an inorganic filler (B) in an amount from 2.0 to 20 parts per weight based on 100 parts per weight of (A)+(B); The present invention is furthermore directed to a polypropylene composition comprising a propylene homo- or copolymer (A); and an inorganic filler (B); whereby the following relation is fulfilled (80F+1700) MPa≦T wherein F are the parts per weight of component (B) based on 100 parts per weight of the total amount of (A)+(B). T is the tensile modulus in MPa, determined according to ISO 527-2, of the polypropylene composition measured on a test specimen prepared by injection molding according to ISO 1873-2. The present invention is also directed to a process for the production of the polypropylene compositions according to the invention and to an article made of the polypropylene compositions according to the invention.The present invention is furthermore directed to the use of the polypropylene compositions according to the invention for the production of pipes, car components, appliance housings, transport containers.
    • 本发明涉及一种聚丙烯组合物,其包含根据ISO 6721-1测定的至少5.8Pa-1的具有多分散指数(PI)的丙烯均聚物或共聚物(A) 和每100重量份(A)+(B))为2.0〜20重量份的无机填料(B)。 本发明还涉及包含丙烯均聚物或共聚物(A)的聚丙烯组合物; 和无机填料(B); 由此满足以下关系(80F + 1700)MPa< NlE; T其中F是基于(A)+(B)的总量的每100重量份的组分(B)的重量份数。 T是根据ISO 527-2测定的根据ISO 1873-2通过注射成型制备的试样上测量的聚丙烯组合物的拉伸弹性模量(MPa)。 本发明还涉及一种生产根据本发明的聚丙烯组合物和由本发明的聚丙烯组合物制成的制品的方法。 本发明还涉及根据本发明的聚丙烯组合物用于生产管道,汽车部件,电器外壳,运输容器的用途。
    • 25. 发明申请
    • PROPYLENE RANDOM COPOLYMER AND PROCESS FOR THE PRODUCTION THEREOF
    • 丙烯无规共聚物及其生产方法
    • US20080027197A1
    • 2008-01-31
    • US11836644
    • 2007-08-09
    • Pirjo JaaskelainenNorbert HafnerPaivi PitkanenMarkus GahleitnerOlli TuominenWilfried Toltsch
    • Pirjo JaaskelainenNorbert HafnerPaivi PitkanenMarkus GahleitnerOlli TuominenWilfried Toltsch
    • C08F297/08C08F210/06
    • C08F297/083C08F10/00C08F210/06C08F210/16C08F297/08C08F4/6465C08F2/001C08F2500/12C08F2500/26C08F2500/17
    • The present invention relates to a process for preparing a propylene random copolymer comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerisation of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a propylene random copolymer prepared by copolymerisation of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerisation of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5.m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fibre or of a pipe.
    • 本发明涉及一种制备丙烯无规共聚物的方法,其包括丙烯与共聚单体的聚合,所述共聚单体是乙烯或包含至少四个碳原子的α-烯烃,在多级方法的催化剂存在下,包括聚合 丙烯与第一反应区中的共聚单体包括至少一个浆料反应器以产生第一聚合产物,将所述第一产物转移到包含至少一个气相反应器的第二反应区和丙烯与所述气相反应器中的共聚单体聚合 在所述第一聚合产物存在下,其中气相反应器中的温度高于浆料反应器中的至少10℃,并且可通过该方法获得的聚合物。 此外,本发明涉及通过丙烯与共聚单体共聚制备的丙烯无规共聚物,其中根据TREF法测定的共聚单体的分布是多峰的,优选双峰的,丙烯与共聚单体共聚制备的丙烯无规共聚物,其中, 共聚物具有根据TREF法测定的洗脱间隔为50℃以上,通过丙烯与共聚单体共聚制备的丙烯无规共聚物,其中无规共聚物是单峰聚合物,并且通过TREF方法测定的洗脱间隔 由方程Y <= 4.5.m + 16给出,其中Y是以℃计的洗脱间隔,m是共聚物中乙烯的百分比。 以及使用这种共聚物来制造纤维或管子的通过吹塑或注射成型的制品的薄膜,制品。