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21. 发明授权

US08198206B2 Ink for producing catalyst layers 有权
标题翻译：用于生产催化剂层的油墨
公开(公告)号：US08198206B2
公开(公告)日：2012-06-12
申请号：US12987956
申请日：2011-01-10
申请人： Walter Behl , Marco Lopez
发明人： Walter Behl , Marco Lopez
IPC分类号： H01M4/02 , H01M4/36 , H01M4/88 , H01M4/90 , H01M4/92 , H01M4/94 , B01J21/18 , B01J23/40 , B01J23/74
CPC分类号： H01M4/92 , H01M4/8807 , H01M4/881 , H01M4/8828 , H01M4/926 , H01M8/1004
摘要： The invention relates to an ink for producing catalyst layers for electrochemical devices. The ink comprises catalyst materials, ionomer material, water and at least one organic solvent. The organic solvent belongs to the class of tertiary alcohols and/or the class of aliphatic diketones and bears functional groups which are stable to oxidative degradation in the ink. This prevents formation of decomposition products in the ink. The ink of the invention displays a high storage stability and is used for producing catalyst-coated substrates for electrochemical devices, in particular fuel cells (PEMFCs, DMFCs).
摘要翻译：本发明涉及一种用于生产电化学装置的催化剂层的油墨。油墨包含催化剂材料，离聚物材料，水和至少一种有机溶剂。有机溶剂属于叔醇类和/或脂族二酮类，并具有对油墨中的氧化降解稳定的官能团。这防止在油墨中形成分解产物。本发明的油墨显示出高的储存稳定性，并且用于生产用于电化学装置，特别是燃料电池（PEMFC，DMFC）的催化剂涂覆的基材。

22. 发明申请

US20110166009A1 Ink For Producing Catalyst Layers 有权
标题翻译：用于生产催化剂层的油墨
公开(公告)号：US20110166009A1
公开(公告)日：2011-07-07
申请号：US12987956
申请日：2011-01-10
申请人： Walter Behl , Marco Lopez
发明人： Walter Behl , Marco Lopez
IPC分类号： B01J31/06
CPC分类号： H01M4/92 , H01M4/8807 , H01M4/881 , H01M4/8828 , H01M4/926 , H01M8/1004
摘要： The invention relates to an ink for producing catalyst layers for electrochemical devices. The ink comprises catalyst materials, ionomer material, water and at least one organic solvent. The organic solvent belongs to the class of tertiary alcohols and/or the class of aliphatic diketones and bears functional groups which are stable to oxidative degradation in the ink. This prevents formation of decomposition products in the ink. The ink of the invention displays a high storage stability and is used for producing catalyst-coated substrates for electrochemical devices, in particular fuel cells (PEMFCs, DMFCs).
摘要翻译：本发明涉及一种用于生产电化学装置的催化剂层的油墨。油墨包含催化剂材料，离聚物材料，水和至少一种有机溶剂。有机溶剂属于叔醇类和/或脂族二酮类，并具有对油墨中的氧化降解稳定的官能团。这防止在油墨中形成分解产物。本发明的油墨显示出高的储存稳定性，并且用于生产用于电化学装置，特别是燃料电池（PEMFC，DMFC）的催化剂涂覆的基材。

23. 发明授权

US07906452B2 Ink for producing catalyst layers 有权
标题翻译：用于生产催化剂层的油墨
公开(公告)号：US07906452B2
公开(公告)日：2011-03-15
申请号：US11909767
申请日：2006-03-25
申请人： Walter Behl , Marco Lopez
发明人： Walter Behl , Marco Lopez
IPC分类号： B01J23/40 , B01J23/74 , B01J31/00 , B01J21/18 , B01J23/00 , H01M4/02 , H01M4/36 , H01M4/92 , H01M4/94 , H01M4/90
CPC分类号： H01M4/92 , H01M4/8807 , H01M4/881 , H01M4/8828 , H01M4/926 , H01M8/1004
摘要： The invention relates to an ink for producing catalyst layers for electrochemical devices. The ink comprises catalyst material, ionomer material, water and at least one organic solvent. The organic solvent belongs to the class of tertiary alcohol's and/or the class of aliphatic diketones and bears functional groups which are stable to oxidative degradation in the ink. This prevents formation of decomposition products in the ink. The ink of the invention displays a high storage stability and is used for producing catalyst-coated substrates for electrochemical devices, in particular fuel cells (PEMFCs, DMFCs).
摘要翻译：本发明涉及一种用于生产电化学装置的催化剂层的油墨。油墨包含催化剂材料，离聚物材料，水和至少一种有机溶剂。有机溶剂属于叔醇类和/或脂族二酮类，并具有对油墨中的氧化降解稳定的官能团。这防止在油墨中形成分解产物。本发明的油墨显示出高的储存稳定性，并且用于生产用于电化学装置，特别是燃料电池（PEMFC，DMFC）的催化剂涂覆的基材。

24. 发明申请

US20080064771A1 Process for Recycling Fuel Cell Components Containing Precious Metals 失效
标题翻译：回收利用含有贵金属的燃料电池组件的方法
公开(公告)号：US20080064771A1
公开(公告)日：2008-03-13
申请号：US11574199
申请日：2005-08-31
申请人： Joachim Koehler , Ralf Zuber , Matthias Binder , Volker Baenisch , Marco Lopez
发明人： Joachim Koehler , Ralf Zuber , Matthias Binder , Volker Baenisch , Marco Lopez
IPC分类号： C08J11/04 , C22B11/00 , C22B7/00
CPC分类号： H01M8/008 , B01D11/0203 , C08J11/08 , C08J2327/12 , C22B7/009 , C22B11/046 , C22B11/048 , H01M2008/1095 , Y02P10/214 , Y02P20/544 , Y02P20/582 , Y02W30/701 , Y02W30/86
摘要： The invention relates to a process for recycling fuel cell components containing fluorine-containing and precious metal-containing constituents: in this process, the fluorine-containing constituents are separated off from the precious metal-containing constituents by treatment with a medium present in the supercritical state. Preference is given to using water as supercritical medium. After the fluorine-containing constituents have been separated off, the precious metal-containing residues can be recovered in a recycling process without harmful fluorine or hydrogen fluoride emissions. The fluorine-containing constituents can likewise be recovered. The process is used in the recovery of precious metals and/or fluorine-containing constituents from membrane fuel cells, electrolysis cells, batteries, sensors and other electrochemical devices.
摘要翻译：本发明涉及一种用于再循环含有含氟和含贵金属成分的燃料电池组件的方法：在该方法中，通过用存在于超临界中的介质处理含氟成分与贵金属成分分离州。优先使用水作为超临界介质。含氟成分被分离后，含有贵金属的残留物可以在循环过程中回收，而不会有有害的氟或氟化氢排放。含氟成分同样可以回收。该方法用于从膜燃料电池，电解槽，电池，传感器和其它电化学装置回收贵金属和/或含氟成分。

25. 发明申请

US20060177727A1 Gas diffuser substrate containing catalysts for fuel cells, in addition to a method for the production thereof 审中-公开
标题翻译：含有用于燃料电池的催化剂的气体扩散器基板，以及其生产方法
公开(公告)号：US20060177727A1
公开(公告)日：2006-08-10
申请号：US10541173
申请日：2003-12-23
申请人： Karsten Ruth , Karl-Anton Starz , Marco Lopez
发明人： Karsten Ruth , Karl-Anton Starz , Marco Lopez
IPC分类号： H01M4/94 , H01M4/96 , H01M4/88
CPC分类号： H01M4/92 , H01M4/926 , H01M8/0668 , H01M8/1007 , H01M8/1011 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： The invention relates to a catalyst-containing gas diffusion layer for fuel cells, in particular low-temperature fuel cells, e.g. PEMFCs and DMFCs. The gas diffusion layer is used on the anode side of the fuel cell and contains catalyst components which effect removal of carbon monoxide (in the PEMFC) or oxidation of methanol (in the DMFC). The catalyst components are produced directly in the porous substrate material from suitable precursor compounds by heat treatment and are distributed uniformly over the entire volume of the gas diffusion layer. As a result, the catalyst components have a particularly high activity. Furthermore, a process for producing a catalyst-containing gas diffusion layer is described. The gas diffusion layers are used in membrane-electrode units (MEUs) for low-temperature fuel cells, in particular for PEM fuel cells operated using a CO-containing reformate gas. They can also be used in direct methanol fuel cells (DMFCs).
摘要翻译：本发明涉及一种用于燃料电池的含催化剂的气体扩散层，特别是低温燃料电池。 PEMFCs和DMFCs。气体扩散层用于燃料电池的阳极侧，并含有能够除去一氧化碳（在PEMFC中）或氧化甲醇（在DMFC中）的催化剂成分。催化剂组分通过热处理从合适的前体化合物直接制备在多孔基材中，并均匀分布在气体扩散层的整个体积上。结果，催化剂组分具有特别高的活性。另外，对含有催化剂的气体扩散层的制造方法进行说明。气体扩散层用于低温燃料电池的膜 - 电极单元（MEU），特别是用于使用含CO重整气体操作的PEM燃料电池。它们也可用于直接甲醇燃料电池（DMFC）。

26. 发明授权

US08691717B2 Core/shell-type catalyst particles and methods for their preparation 有权
标题翻译：核/壳型催化剂颗粒及其制备方法
公开(公告)号：US08691717B2
公开(公告)日：2014-04-08
申请号：US13557103
申请日：2012-07-24
申请人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stéphanie Chevalliot
发明人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stéphanie Chevalliot
IPC分类号： H01M4/02 , H01M4/36 , H01M4/88 , H01M4/90 , H01M4/92 , H01M4/94 , B01J21/18 , B01J23/00 , B01J23/40 , B01J23/74 , B32B5/16 , B32B9/00 , B32B15/02 , B32B17/02 , B32B19/00 , B32B21/02 , B32B23/02 , B32B27/02
CPC分类号： B22F1/025 , B22F1/0018 , B22F2998/00 , B82Y30/00 , H01M4/8605 , H01M4/8842 , H01M4/921 , H01M4/926 , H01M8/1007 , Y10T29/49345 , Y10T428/2991 , B22F9/24
摘要： The invention discloses core/shell, type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt˜based shell reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要翻译：本发明公开了包含Mcore / Mshell结构的核/壳型催化剂颗粒，其中Mcore =内颗粒核和Mshell =外颗粒壳，其中催化剂颗粒的介质直径（dcore +壳）在20至100的范围内 nm，优选在20〜50nm的范围内。外壳的厚度（tshell）为所述催化剂颗粒的内颗粒芯的直径的约5至20％，优选包含至少3个原子层。核/壳型催化剂颗粒，特别是包含基于Pt的壳的颗粒显示高的比活性。催化剂颗粒优选负载在合适的载体材料如炭黑上，并用作燃料电池的电催化剂。

27. 发明申请

US20110114578A1 UNIVERSAL PRODUCT DISPLAY 审中-公开
标题翻译：通用产品展示
公开(公告)号：US20110114578A1
公开(公告)日：2011-05-19
申请号：US12703554
申请日：2010-02-10
申请人： Richard Jacobs , Lance Kaiser , Marco Lopez
发明人： Richard Jacobs , Lance Kaiser , Marco Lopez
IPC分类号： A47F7/00
CPC分类号： A47F5/005 , A47F1/12 , A47F5/137
摘要： A universal cooler product display generally used for displaying any of various products, such as dairy products inside a store cooler, includes an adjustable frame supporting adjustable shelves having HDPE trays that allow products to slide forward under gravity and a drainage system to dispose of unwanted liquids.
摘要翻译：通常用于显示各种产品的通用冷却器产品显示器，例如商店冷却器内的乳制品，包括可调节框架，其支撑具有HDPE托盘的可调节架，其允许产品在重力作用下向前滑动，并且排水系统处理不需要的液体。

28. 发明授权

US07713910B2 Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权
标题翻译：制备贵金属合金催化剂的方法及其制备的催化剂
公开(公告)号：US07713910B2
公开(公告)日：2010-05-11
申请号：US10977579
申请日：2004-10-29
申请人： Dan V. Goia , Marco Lopez , Tapan Kumar Sau , Mihaela-Ortansa Jitianu
发明人： Dan V. Goia , Marco Lopez , Tapan Kumar Sau , Mihaela-Ortansa Jitianu
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译：本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。该方法基于使用多元醇溶剂作为反应介质，并且包括在存在载体材料的情况下的两步还原过程。在第一步骤中，第一金属（M1 =过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃来活化。在第二步中，第二金属（M2 =贵金属;例如 Pt，Pd，Au及其混合物），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。由于这种两步法，发生均匀的还原，导致贵金属具有高度合金化和小于3nm的微晶尺寸的金属基催化剂。由于高合金化，晶格常数降低。根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC），直接甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂的电极催化剂。

29. 发明申请

US20100086832A1 CORE / SHELL-TYPE CATALYST PARTICLES AND METHODS FOR THEIR PREPARATION 有权
标题翻译：核/壳型催化剂颗粒及其制备方法
公开(公告)号：US20100086832A1
公开(公告)日：2010-04-08
申请号：US12438978
申请日：2007-08-27
申请人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stephanie Chevalliot
发明人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stephanie Chevalliot
IPC分类号： B01J23/56 , H01M4/38 , B01J23/42 , B01J27/20
CPC分类号： B22F1/025 , B22F1/0018 , B22F2998/00 , B82Y30/00 , H01M4/8605 , H01M4/8842 , H01M4/921 , H01M4/926 , H01M8/1007 , Y10T29/49345 , Y10T428/2991 , B22F9/24
摘要： The invention discloses core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt-based shell, reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要翻译：本发明公开了包含Mcore / Mshell结构的核/壳型催化剂颗粒，其中Mcore =内颗粒核和Mshell =外颗粒壳，其中催化剂颗粒（dcore +壳）的介质直径在20至100nm的范围内，优选在20〜50nm的范围内。外壳的厚度（tshell）为所述催化剂颗粒的内颗粒芯的直径的约5至20％，优选包含至少3个原子层。核/壳型催化剂颗粒，特别是包含Pt基壳的颗粒显示高的比活性。催化剂颗粒优选负载在合适的载体材料如炭黑上，并用作燃料电池的电催化剂。

30. 发明申请

US20090214624A1 TOPICAL NITRIC OXIDE DONOR DEVICES AND METHODS FOR THEIR THERAPEUTIC USE 审中-公开
标题翻译：主题氮氧化物掺合物及其治疗方法
公开(公告)号：US20090214624A1
公开(公告)日：2009-08-27
申请号：US11719894
申请日：2005-11-29
申请人： Daniel J. Smith , Marco Lopez , Patricio Lopez-Jaramillo
发明人： Daniel J. Smith , Marco Lopez , Patricio Lopez-Jaramillo
IPC分类号： A61K9/70 , A61K33/00 , A61P9/00
CPC分类号： A61K9/7084
摘要： The present invention is related to topical nitric oxide delivery systems, and to using the same for mitigating or remediating various disease states The present invention is also related to using topical nitric oxide delivery systems for enhancing blood flow.
摘要翻译：本发明涉及局部一氧化氮递送系统，并且用于减轻或补救各种疾病状态本发明还涉及使用局部一氧化氮递送系统来增强血流量。

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