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    • 24. 发明授权
    • Emulsion-char method for making fine ceramic powders
    • 用于制造精细陶瓷粉末的乳液 - 焦炭方法
    • US4749664A
    • 1988-06-07
    • US947117
    • 1986-12-29
    • Sidney D. RossGaleb H. MaherClinton E. Hutchins
    • Sidney D. RossGaleb H. MaherClinton E. Hutchins
    • C01B13/32C01G23/00C01G25/00C01G33/00C01G45/02C04B35/626C04B35/00C01B13/14
    • C01B13/328C01G23/006C01G25/00C01G33/00C01G45/02C04B35/626C01P2004/32C01P2004/52C01P2004/61C01P2004/62
    • Water soluble precursors of ceramic compounds are emulsified in an organic fluid containing an organic surfactant. The emulsion is subsequently mildly heated at a pressure of about 0.05 atmospheres to remove the free water from the emulsion droplets. The resulting sludge consists of particles deriving from the dehydrated emulsion droplets. These particles may only be bound by the surfactant, all or most of the original organic fluid having been boiling off under low pressure. This sludge is then heated in a standard air atmosphere to char the surfactant, which char is to maintain the separation between the dried droplet-derived particles to prevent forming sintered or fused agglomerates thereof. With continued heating the transient char is subsequently burned off and the particles are calcined to controllably and simply produce a fine ceramic powder of spherical particles having a narrow size distribution and an average size in the particularly useful range of 0.1 micron to 1.0 micron.
    • 陶瓷化合物的水溶性前体在含有机表面活性剂的有机流体中乳化。 随后在约0.05大气压的压力下温和地加热乳液以从乳液液滴中除去游离水。 所得污泥由衍生自脱水乳液液滴的颗粒组成。 这些颗粒只能通过表面活性剂结合,所有或大部分原始有机流体在低压下已经沸腾。 然后将该污泥在标准空气气氛中加热以使表面活性剂成为焦炭,以保持干燥的液滴衍生的颗粒之间的分离,以防止形成其烧结或熔融附聚物。 随着持续加热,随后烧掉瞬时焦炭,并且颗粒被煅烧以可控地并且简单地产生具有窄尺寸分布和在0.1微米至1.0微米特别有用范围内的平均尺寸的球形颗粒的细陶瓷粉末。