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21. 发明授权

US5731478A Process for preparing alkanediols 失效
标题翻译：制备烷二醇的方法
公开(公告)号：US5731478A
公开(公告)日：1998-03-24
申请号：US729971
申请日：1996-10-15
申请人： Lynn Henry Slaugh , Paul Richard Weider , Joseph Broun Powell , Juan Pedro Arhancet
发明人： Lynn Henry Slaugh , Paul Richard Weider , Joseph Broun Powell , Juan Pedro Arhancet
IPC分类号： C07C29/141 , C07C45/58 , C07C47/62 , C07C27/00 , C07C27/04 , C07C45/00
CPC分类号： C07C29/141 , C07C45/58
摘要： An alkanediol such as 1,3-propanediol is prepared in a process which involves reacting an alkylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of a non-phosphine-ligated cobalt or rhodium catalyst and a manganese porphyrine promoter to produce an intermediate product mixture containing a hydroxyalkanal in an amount less than 15 wt %; extracting the hydroxyalkanal from the intermediate product mixture into an aqueous liquid at a temperature less than about 100.degree. C. and separating the aqueous phase containing hydroxyalkanal from the organic phase containing cobalt catalyst; hydrogenating the hydroxyalkanal in the aqueous phase to an alkanediol; and recovering the alkanediol. The process enables the production of an alkanediol such as 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand with the cobalt or rhodium catalyst.
摘要翻译：在一种方法中制备链烷二醇，例如在非磷化氢连接的钴或铑催化剂存在下使环氧烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中反应，锰卟吩促进剂，以产生含有小于15重量％的量的羟基卡那定的中间产物混合物; 在低于约100℃的温度下将羟基卡那酸从中间产物混合物中提取成水性液体，并将含有羟基卡那的水相与含钴催化剂的有机相分离; 将水相中的羟基卡那酸氢化成链烷二醇; 并回收链烷二醇。该方法能够以高产率和选择性生产链烷二醇如1,3-丙二醇，而不需要使用与钴或铑催化剂的膦配体。

22. 发明授权

US06753289B2 One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a phospholanoalkane ligand 失效
标题翻译：从环氧乙烷和合成气一步生产1,3-丙二醇与催化剂与磷酰烷配体
公开(公告)号：US06753289B2
公开(公告)日：2004-06-22
申请号：US10371462
申请日：2003-02-21
申请人： John Frederick Knifton , Talmadge Gail James , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell , Lynn Henry Slaugh
发明人： John Frederick Knifton , Talmadge Gail James , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell , Lynn Henry Slaugh
IPC分类号： B01J3100
CPC分类号： B01J31/2433 , B01J31/20 , B01J31/2208 , B01J2231/48 , B01J2531/0211 , B01J2531/0258 , B01J2531/821 , B01J2531/845
摘要： Disclosed is a novel class of modified ruthenium catalysts useful in the one step synthesis of 1,3-PDO comprising (a) a cobalt component comprising one or more non-ligated cobalt compounds; and (b) a ruthenium component comprising in major part a ruthenium carbonyl compound ligated with a phospholanoalkane ligand, solubilized in an ether solvent, that provides potential improvements in cost and performance in one step hydroformylation/hydrogenation. For example, cobalt-ruthenium-bidentate, bis(phospholano)alkane catalyst precursors in ether solvents provide good yields of 1,3-PDO in a one step synthesis.
摘要翻译：公开了一种新型的改性钌催化剂，其用于一步合成1,3-PDO，其包含（a）包含一种或多种非连接的钴化合物的钴组分; 和（b）主要部分包含与溶于醚溶剂中的磷酸烷烃配体连接的钌羰基化合物的钌组分，其在一步加氢甲酰化/氢化中提供成本和性能的潜在改进。例如，在醚溶剂中的钴 - 钌二齿，双（磷酸）烷烃催化剂前体在一步合成中提供了1,3-PDO的良好产率。

23. 发明授权

US06750373B2 One-step production of 1, 3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst 失效
标题翻译：一氧化碳和合成气用钴 - 铁催化剂一步法制备1,3-丙二醇
公开(公告)号：US06750373B2
公开(公告)日：2004-06-15
申请号：US10146675
申请日：2002-05-15
申请人： John Frederick Knifton , Talmadge Gail James , Lynn Henry Slaugh , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell
发明人： John Frederick Knifton , Talmadge Gail James , Lynn Henry Slaugh , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell
IPC分类号： C07C2700
CPC分类号： B01J31/24 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/20 , B01J31/28 , B01J2231/321 , B01J2231/48 , B01J2531/0241 , B01J2531/842 , B01J2531/845 , C07C29/16 , Y02P20/52 , C07C31/205
摘要： Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a lower cost alternative for the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, a catalyst containing cobalt carbonyl: iron carbonyl with no ligand, or a catalyst containing a cobalt carbonyl: octaethylporphine iron acetate provide moderate yields of 1,3-PDO in a one step synthesis under mild conditions.
摘要翻译：公开了一种新的催化剂组合物，其包含任选与选自N-杂环，膦或卟吩配体的配体络合的双金属Co-Fe催化剂，其为1,3-丙二醇的一步合成提供了较低成本的替代方案（ 1,3-PDO）和环氧乙烷和合成气。例如，在温和条件下，在一步合成中含有羰基羰基羰基，不含配体的羰基催化剂或含有羰基钴：八乙基卟吩乙酸铁的乙酸铁的催化剂提供了适量的1,3-PDO产率。

24. 发明授权

US06734332B1 Process for enriching cis or trans-isomers in an olefin stream 失效
标题翻译：在烯烃流中富集顺式或反式异构体的方法
公开(公告)号：US06734332B1
公开(公告)日：2004-05-11
申请号：US10325340
申请日：2002-12-19
申请人： Lynn Henry Slaugh , Robert Lawrence Blackbourn , Laura Bridget Palmer , Julie Michelle Freelin
发明人： Lynn Henry Slaugh , Robert Lawrence Blackbourn , Laura Bridget Palmer , Julie Michelle Freelin
IPC分类号： C07C7152
CPC分类号： C07C7/152 , C07C11/02
摘要： An olefin product rich in cis- or trans-isomers can be produced by reacting the mixed olefin feedstock with an linear polyaromatic compound such as anthracene under heat, then separating the unreacted olefin enriched in cis-isomer. The remaining linear unreacted polyaromtic compound and the polyaromatic compound-olefin adduct can be heated to dissociate the adduct to linear polyaromatic compound and olefin stream enriched in trans-isomer.
摘要翻译：富含顺式或反式异构体的烯烃产物可以通过使混合烯烃原料与线性多芳族化合物如蒽在加热下反应，然后分离富含顺式异构体的未反应烯烃来制备。剩余的线性未反应多元化合物和多芳族化合物 - 烯烃加合物可被加热以将加合物解离成线性聚芳族化合物和富含反式异构体的烯烃物流。

25. 发明授权

US06706656B2 One step process for preparing a 1,3-diol 失效
标题翻译：一步法制备1,3-二醇
公开(公告)号：US06706656B2
公开(公告)日：2004-03-16
申请号：US10127957
申请日：2002-04-23
申请人： John Frederick Knifton , Lynn Henry Slaugh , Paul Richard Weider , Talmadge Gail James , Joseph Broun Powell , Kevin Dale Allen , Timothy Scott Williams
发明人： John Frederick Knifton , Lynn Henry Slaugh , Paul Richard Weider , Talmadge Gail James , Joseph Broun Powell , Kevin Dale Allen , Timothy Scott Williams
IPC分类号： B01J3100
CPC分类号： B01J31/2409 , B01J31/20 , B01J31/24 , B01J31/2414 , B01J31/248 , B01J2231/48 , B01J2531/821 , B01J2531/845 , C07C29/16 , Y02P20/52 , Y02P20/584 , C07C31/205
摘要： The invention provides a process for an improved oxirane hydroformylation catalyst, the improved oxirane hydroformylation catalyst, and a one step process for preparing a 1,3-diol in the presence of such a catalyst. One process for preparing the hydroformylation catalyst involves: a) forming a complex (A) by contacting a ruthenium(0) compound with a ditertiary phosphine ligand; and b) forming a complex (B) by subjecting complex (A) to a redox reaction with a cobalt(0) carbonyl compound. This catalyst is used in a one step hydroformylation process for preparing a 1,3-diol, comprising the reaction of an oxirane with syngas at hydroformylation conditions in an inert solvent in the presence of the above hydroformylation catalyst where recovery of product is preferably accomplished via phase separation of a diol rich phase from the bulk reaction liquor.
摘要翻译：本发明提供改进的环氧乙烷加氢甲酰化催化剂，改进的环氧乙烷加氢甲酰化催化剂的方法，以及在这种催化剂存在下制备1,3-二醇的一步法。制备加氢甲酰化催化剂的一个方法包括：a）通过使钌（O）化合物与二膦配体接触形成络合物（A）; 和b）通过使复合物（A）与羰基钴（O）化合物进行氧化还原反应形成络合物（B）。该催化剂用于制备1,3-二醇的一步加氢甲酰化方法，其包括在上述加氢甲酰化催化剂存在下，在惰性溶剂中，在加氢甲酰化条件下使环氧乙烷与合成气反应，其中产物的回收优选通过富二醇相与本体反应液相分离。

26. 发明授权

US06660892B2 Synthesis of aliphatic 1,3-diols utilizing reduced ligand concentration and water extraction 失效
标题翻译：利用配体浓度降低和水提取合成脂肪族1,3-二醇
公开(公告)号：US06660892B2
公开(公告)日：2003-12-09
申请号：US10360302
申请日：2003-02-07
申请人： Joseph Broun Powell , Paul Richard Weider , John Frederick Knifton , Kevin Dale Allen , Lynn Henry Slaugh , Juan Pedro Arhancet
发明人： Joseph Broun Powell , Paul Richard Weider , John Frederick Knifton , Kevin Dale Allen , Lynn Henry Slaugh , Juan Pedro Arhancet
IPC分类号： C07C2700
CPC分类号： B01J31/2471 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/20 , B01J31/24 , B01J31/28 , B01J2231/321 , B01J2531/025 , B01J2531/16 , B01J2531/80 , B01J2531/82 , B01J2531/821 , B01J2531/824 , B01J2531/828 , B01J2531/845 , C07C29/16 , Y02P20/584 , C07C31/205
摘要： This invention is a process for synthesizing aliphatic 1,3-diols in one step by hydroformylation and hydrogenation of oxirane, carbon monoxide, and hydrogen employing a catalyst comprising a cobalt carbonyl compound and a cocatalyst metal compound ligated with a ligand in a ligand to cocatalyst metal atom molar ratio in the range of 0.2:1.0 to 0.6:1.0, optionally in the presence of a promoter, where recovery of product is preferably accomplished via water extraction of a diol rich phase from the bulk reaction mixture. The process modifications can, particularly in combination, be beneficial with respect to product recovery, catalyst recycle, and overall economics of a one-step process for producing aliphatic 1,3-diols.
摘要翻译：本发明是通过使用包含羰基钴化合物的催化剂和与配位体中的配体连接的助催化剂金属化合物进行助催化剂的环氧乙烷，一氧化碳和氢气的加氢甲酰化和氢化来合成脂肪族1,3-二醇的方法金属原子摩尔比在0.2:1.0至0.6:1.0的范围内，任选地在助催化剂存在下，其中产物的回收优选通过从本体反应混合物中萃取富含二醇的相来完成。关于产物回收，催化剂再循环以及用于生产脂族1,3-二醇的一步法的总体经济性，方法修饰尤其可以组合地是有益的。

27. 发明授权

US06586643B2 One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand 失效
公开(公告)号：US06586643B2
公开(公告)日：2003-07-01
申请号：US10146590
申请日：2002-05-15
申请人： John Frederick Knifton , Talmadge Gail James , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell , Lynn Henry Slaugh , Timothy Williams
发明人： John Frederick Knifton , Talmadge Gail James , Kevin Dale Allen , Paul Richard Weider , Joseph Broun Powell , Lynn Henry Slaugh , Timothy Williams
IPC分类号： C07C2700
CPC分类号： C07C29/16 , B01J31/181 , B01J31/1815 , B01J31/183 , B01J31/20 , B01J31/28 , B01J2231/48 , B01J2531/0208 , B01J2531/025 , B01J2531/821 , B01J2531/845 , Y02P20/52 , C07C31/205
摘要： Disclosed is a new catalyst composition comprising a bimetallic Co—Ru catalyst complexed with a N-heterocylcic ligand that is effective, economical, and provides improvements in oxidative stability in the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, cobalt-ruthenium-2,2′-bipyrimidine, 2,2′-dipyridyl, or 2,4,6-tripridyl-s-triazine catalyst precursors in cyclic ether solvents, such as 1,3-dioxolane, 1,4-dioxolane, 1,4-dioxane, and 2-ethyl-2-methyl-1,3-dioxolane, provide good yields of 1,3-PDO in a one step synthesis.

28. 发明授权

US06576806B1 Process for separating C2-C3 olefins from industrial gases 失效
标题翻译：将C2-C3烯烃与工业气体分离的方法
公开(公告)号：US06576806B1
公开(公告)日：2003-06-10
申请号：US09467806
申请日：1999-12-20
申请人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
发明人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
IPC分类号： C07C7152
CPC分类号： C07C7/152
摘要： A process for treating a feedstock comprising olefins having an average carbon number ranging from 2-3.5, and non-olefinic compounds, said process comprising the following steps: a) contacting gaseous feedstock with a linear polyaromatic compound in a reaction zone under conditions effective to form a reaction mixture comprising linear polyaromatic compound-olefin adducts and unreacted gaseous feedstock; b) separating the olefin adducts from the unreacted gaseous feedstock; and c) dissociating the olefin adducts to form linear polyaromatic compounds and an olefin enriched composition comprising ethylene, propylene, or mixtures thereof; whereby the concentration of at least one of the olefins in said olefin enriched composition is enriched over the concentration of said at least one olefin present in the feedstock.
摘要翻译：一种处理包含平均碳数为2-3.5的烯烃和非烯烃化合物的原料的方法，所述方法包括以下步骤：a）在反应区中将气态原料与线性聚芳族化合物接触，形成包含直链多芳族化合物 - 烯烃加合物和未反应气态原料的反应混合物; b）从未反应的气态原料中分离烯烃加合物; 和c）解离所述烯烃加合物以形成线性聚芳族化合物和包含乙烯，丙烯或其混合物的烯烃富集组合物;由此所述富含烯烃的组合物中的至少一种烯烃的浓度超过所述至少一种烯烃存在于原料中。

29. 发明授权

US06545192B2 Process for separating olefins from saturated hydrocarbons 失效
标题翻译：从饱和烃分离烯烃的方法
公开(公告)号：US06545192B2
公开(公告)日：2003-04-08
申请号：US09309417
申请日：1999-05-11
申请人： Lynn Henry Slaugh , Laurent Alain Fenouil , Howard Lam-Ho Fong
发明人： Lynn Henry Slaugh , Laurent Alain Fenouil , Howard Lam-Ho Fong
IPC分类号： C07C7148
CPC分类号： C07C11/02 , C07C1/04 , C07C7/152 , C10G2/32
摘要： A process for separating and isolating olefins from saturated hydrocarbons, preferably in a Fischer Tropsch stream, by adducting the olefins with a linear polyaromatic compound and separating the adducts from the remainder, which comprises saturated hydrocarbons.
摘要翻译：通过将烯烃与线性多芳族化合物加成并将其与包含饱和烃的其余部分分离出的加合物，从饱和烃，优选在费托料流中分离和分离烯烃的方法。

30. 发明授权

US06211423B1 Process for separating saturated compounds from olefins 失效
标题翻译：从烯烃中分离饱和化合物的方法
公开(公告)号：US06211423B1
公开(公告)日：2001-04-03
申请号：US09379223
申请日：1999-08-23
申请人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
发明人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
IPC分类号： C07C700
CPC分类号： C07C11/02 , C07C1/0485 , C07C7/152
摘要： There is provided a process for separating olefins from saturated hydrocarbons in a feedstock containing saturated hydrocarbons, internal olefins, and alpha olefins characterized by steps of selectively forming of olefin-linear polyaromatic compound adducts and steps of dissociation of these adducts.
摘要翻译：提供了一种在含有饱和烃，内烯烃和α烯烃的原料中从饱和烃中分离烯烃的方法，其特征在于选择性地形成烯烃线性多芳族化合物加合物和这些加合物解离步骤。

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