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21. 发明授权

US08772419B2 Polyester films with low thermal expansion and methods for manufacturing the same 有权
标题翻译：低热膨胀的聚酯薄膜及其制造方法
公开(公告)号：US08772419B2
公开(公告)日：2014-07-08
申请号：US13494660
申请日：2012-06-12
申请人： Li-Cheng Jheng , Jrjeng Ruan , Ming-Tsong Leu , Kuo-Chen Shih , Jyh-Horng Wu , Cheng-Hsing Fan
发明人： Li-Cheng Jheng , Jrjeng Ruan , Ming-Tsong Leu , Kuo-Chen Shih , Jyh-Horng Wu , Cheng-Hsing Fan
IPC分类号： C08L67/03 , C08G63/189
CPC分类号： B29C47/92 , B29C47/0004 , B29C47/0021 , B29C47/0057 , B29C55/143 , B29C55/16 , B29C2947/9258 , B29C2947/92704 , B29K2267/00 , B29K2995/0012 , B29K2995/0053 , C08G63/189 , C08G63/199 , C08J5/18 , C08J2367/02 , C08J2467/02 , C08L67/02 , C08L2205/02
摘要： Disclosed is a method for manufacturing a polyester film with low thermal expansion. 95 wt % to 55 wt % of crystalline polyester and 5 wt % to 45 wt % of amorphous polyester are mixed. The blend is then melt extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a heat-setting procedure.
摘要翻译：公开了一种低热膨胀聚酯薄膜的制造方法。 95重量％至55重量％的结晶聚酯和5重量％至45重量％的无定形聚酯混合。然后将共混物熔融挤出以形成片材。然后将片材双轴拉伸得到薄膜。然后用热定形步骤处理双轴拉伸的薄膜。

22. 发明申请

US20120090408A1 METHOD FOR MANUFACTURING PIEZORESISTIVE MATERIAL, PIEZORESISTIVE COMPOSITION AND PRESSURE SENSOR DEVICE 有权
标题翻译：制造复合材料的方法，PIEZORESISTIVE COMPOSITION和压力传感器装置
公开(公告)号：US20120090408A1
公开(公告)日：2012-04-19
申请号：US13273604
申请日：2011-10-14
申请人： Li-Cheng Jheng , Wen-Yang Chang , Kuo-Chen Shih , Yi-Lun Hsu
发明人： Li-Cheng Jheng , Wen-Yang Chang , Kuo-Chen Shih , Yi-Lun Hsu
IPC分类号： G01L1/18 , H01B1/24
CPC分类号： G01L1/18 , H01B1/24
摘要： A method for manufacturing a piezoresistive material, a piezoresistive composition and a pressure sensor device are provided. The piezoresistive composition includes a conductive carbon material, a solvent, a dispersive agent, an unsaturated polyester and a crosslinking agent. The conductive carbon material is selected from a group consisting of multi-wall nanotube, single-wall carbon nanotube, carbon nanocapsule, graphene, graphite nanoflake, carbon black, and a combination thereof. The solvent is selected from a group consisting of ethyl acetate, butyl acetate, hexane, propylene glycol mono-methyl ether acetate and a combination thereof. The dispersive agent includes block polymer solution with functional groups providing the affinity. The unsaturated polyester is selected from a group consisting of an ortho-phthalic type unsaturated polyester, an iso-phthalic type unsaturated polyester, and a combination thereof. The crosslinking agent is selected from a group consisting of ethyl methyl ketone peroxide, cyclohexanone diperoxide, dibenzoyl peroxide, tert-butyl peroxybenzoate and a combination thereof.
摘要翻译：提供一种制造压阻材料的方法，压阻组合物和压力传感器装置。压电组合物包括导电碳材料，溶剂，分散剂，不饱和聚酯和交联剂。导电性碳材料选自多壁纳米管，单壁碳纳米管，碳纳米胶囊，石墨烯，石墨纳米片，炭黑及其组合。溶剂选自乙酸乙酯，乙酸丁酯，己烷，丙二醇单甲基醚乙酸酯及其组合。分散剂包括具有提供亲和性的官能团的嵌段聚合物溶液。不饱和聚酯选自邻苯二甲酸类不饱和聚酯，异邻苯二甲酸类不饱和聚酯及其组合。交联剂选自乙基甲基酮过氧化物，环己酮二过氧化物，过氧化二苯甲酰，过氧苯甲酸叔丁酯及其组合。

23. 发明授权

US07291680B1 Metal catalyst and hydrogenation method employing the same 有权
标题翻译：金属催化剂和采用其的氢化方法
公开(公告)号：US07291680B1
公开(公告)日：2007-11-06
申请号：US11600176
申请日：2006-11-16
申请人： Kuo-Chen Shih , Hung-Yu Chen , Tsai-Tien Su
发明人： Kuo-Chen Shih , Hung-Yu Chen , Tsai-Tien Su
IPC分类号： C08C19/02 , C08F8/42
CPC分类号： B01J31/1805 , B01J31/1895 , B01J31/2208 , B01J31/2234 , B01J31/226 , B01J31/24 , B01J31/2404 , B01J2231/645 , B01J2531/821 , B01J2531/827
摘要： A metal catalyst for hydrogenating unsaturated carbon-carbon bonds of copolymer is provided. The metal catalyst is a bimetallic complex comprising iridium and ruthenium. The metal catalyst has a formula comprising M1aM2bXm(L1)n, wherein the M1 is iridium, M2 is ruthenium; X is hydrogen, chlorine, bromine, iodine or pseudo halide; L1 is phosphine, bisphosphine, arsane or organic with nitrogen, sulfur and oxygen.
摘要翻译：提供了用于氢化共聚物的不饱和碳 - 碳键的金属催化剂。金属催化剂是包含铱和钌的双金属络合物。金属催化剂具有包含M 1，M 2，M 2，（L 1）n N，其中M 1是铱，M 2是钌; X是氢，氯，溴，碘或假卤化物; 膦1，膦，双膦，阿烷或有机氮，硫和氧。

24. 发明授权

US07132491B2 Chain transfer reagent, free radical polymerization employing the same and resulting polymers 有权
标题翻译：链转移试剂，使用其的自由基聚合和得到的聚合物
公开(公告)号：US07132491B2
公开(公告)日：2006-11-07
申请号：US10842141
申请日：2004-05-10
申请人： Yih-Hsing Lo , Kuo-Chen Shih , Yi-Chun Chen , Mei-Hua Wang , Fong Yee Hsu , Ming-Siao Hsiao
发明人： Yih-Hsing Lo , Kuo-Chen Shih , Yi-Chun Chen , Mei-Hua Wang , Fong Yee Hsu , Ming-Siao Hsiao
IPC分类号： C08F20/54 , C08F2/38
CPC分类号： C08F2/38 , C08F4/00
摘要： Organometallic reversible addition-fragmentation chain transfer reagents (RAFT reagents), processes of free radical polymerization employing the same and polymers with low polydispersity index obtained thereby. The process includes polymerizing at least one monomer with at least one initiator and at least one organometallic RAFT reagent to obtain polymers having terminal organometallic functional groups with low polydispersity index. In addition, the terminal organometallic functional group may be removed by subjecting the obtained polymer to elimination to provide the corresponding organic polymers.
摘要翻译：有机金属可逆加成 - 断裂链转移试剂（RAFT试剂），使用该方法的自由基聚合方法和由此获得的具有低多分散指数的聚合物。该方法包括使至少一种单体与至少一种引发剂和至少一种有机金属RAFT试剂聚合，得到具有低多分散指数的末端有机金属官能团的聚合物。此外，可以通过使所得聚合物进行消除以提供相应的有机聚合物来除去末端有机金属官能团。

25. 发明申请

US20050096440A1 Chain transfer reagent, free radical polymerization employing the same and resulting polymers 有权
标题翻译：链转移试剂，使用其的自由基聚合和得到的聚合物
公开(公告)号：US20050096440A1
公开(公告)日：2005-05-05
申请号：US10842141
申请日：2004-05-10
申请人： Yih-Hsing Lo , Kuo-Chen Shih , Yi-Chun Chen , Mei-Hua Wang , Fong-Yee Hsu , Ming-Siao Hsiao
发明人： Yih-Hsing Lo , Kuo-Chen Shih , Yi-Chun Chen , Mei-Hua Wang , Fong-Yee Hsu , Ming-Siao Hsiao
IPC分类号： C08F2/38 , C08F4/00 , C08F4/06
CPC分类号： C08F2/38 , C08F4/00
摘要： Organometallic reversible addition-fragmentation chain transfer reagents (RAFT reagents), processes of free radical polymerization employing the same and polymers with low polydispersity index obtained thereby. The process includes polymerizing at least one monomer with at least one initiator and at least one organometallic RAFT reagent to obtain polymers having terminal organometallic functional groups with low polydispersity index. In addition, the terminal organometallic functional group may be removed by subjecting the obtained polymer to elimination to provide the corresponding organic polymers.
摘要翻译：有机金属可逆加成 - 断裂链转移试剂（RAFT试剂），使用该方法的自由基聚合方法和由此获得的具有低多分散指数的聚合物。该方法包括使至少一种单体与至少一种引发剂和至少一种有机金属RAFT试剂聚合，得到具有低多分散指数的末端有机金属官能团的聚合物。此外，可以通过使所得聚合物进行消除以提供相应的有机聚合物来除去末端有机金属官能团。

26. 发明申请

US20050032997A1 Low polydispersity resin, and preparation thereof 审中-公开
标题翻译：低分散性树脂及其制备方法
公开(公告)号：US20050032997A1
公开(公告)日：2005-02-10
申请号：US10714052
申请日：2003-11-14
申请人： Ting-Yu Lee , Choa-Ying Yu , Meei-Yu Hsu , Shian-Jy Wang , Ching Ting , Kuo-Chen Shih
发明人： Ting-Yu Lee , Choa-Ying Yu , Meei-Yu Hsu , Shian-Jy Wang , Ching Ting , Kuo-Chen Shih
IPC分类号： C08F2/00 , C08F2/38 , C08F220/10
CPC分类号： C08F220/10 , C08F2/38
摘要： A resin with low polydispersity index and a process for preparing the same. The process includes polymerizing at least one monomer with an initiator and a chain transfer reagent, wherein the monomer is an acrylate monomer having at least one ethylenically unsaturated bonds or norbornene derivatives. Furthermore, a photoresist composition containing the resin composition according to the present invention can increase pattern resolution in lithography process.
摘要翻译：低分散指数的树脂及其制备方法。该方法包括使至少一种单体与引发剂和链转移试剂聚合，其中单体是具有至少一个烯属不饱和键或降冰片烯衍生物的丙烯酸酯单体。此外，含有本发明的树脂组合物的光致抗蚀剂组合物可以提高光刻工艺中的图案分辨率。

27. 发明授权

US06395928B1 Rhodium-catalyzed carbonylation using non-acetate lithium, sodium and potassium inorganic salts as promoters to produce carboxylic acids 失效
标题翻译：铑催化羰基化使用非乙酸锂，钠和钾无机盐作为助催化剂生产羧酸
公开(公告)号：US06395928B1
公开(公告)日：2002-05-28
申请号：US09482174
申请日：2000-01-12
申请人： Kuo-Chen Shih , Shu-Hei Wang , Tsu-Tseng Weng , Kou-Suein Ai
发明人： Kuo-Chen Shih , Shu-Hei Wang , Tsu-Tseng Weng , Kou-Suein Ai
IPC分类号： C07C5112
CPC分类号： C07C51/12 , C07C53/08
摘要： The present invention relates to an improved process for producing an organic carboxylic acid having (n+1) carbon atoms by reacting an alcohol having n carbon atoms with carbon monoxide in the presence of a rhodium catalyst system. More particularly, the present invention relates to carbonylation of alcohol such as methanol catalyzed by a rhodium system to produce acetic acid. The characteristic of the present invention is the addition of a catalyst stabilizer in the reaction medium to avoid or to alleviate the precipitation of the catalyst in the liquid phase. The catalyst as used herein is a an inorganic salt of alkaline metal having the following formula (A): XnMm (A) X=Li+, Na+, K+; M=CO3−2, HCO3−, PO4−3, HPO4−2, H2PO4−, SO4−2, HSO4−, C2O4−2, HC2O4−, B(C6Y5)4−1; Y=H, F or CF3.
摘要翻译：本发明涉及通过在铑催化剂体系的存在下使具有n个碳原子的醇与一氧化碳反应制备具有（n + 1）个碳原子的有机羧酸的改进方法。更具体地说，本发明涉及通过铑体系催化的醇如甲醇的羰基化以产生乙酸。本发明的特征是在反应介质中加入催化剂稳定剂以避免或减轻催化剂在液相中的沉淀。本文所用的催化剂是具有下式（A）的碱金属的无机盐：X = Li +，Na +，K +; M = CO 3 -2，HCO 3 - ，PO 4 3-，HPO 4 -2，H 2 PO 4 - ，SO 4 -2，HSO4-，C2O4-2，HC2O4-，B（C6Y5）4-1; Y = H，F或CF3。

28. 发明授权

US06346644B1 Process for producing carboxylic acid 有权
标题翻译：制备羧酸的方法
公开(公告)号：US06346644B1
公开(公告)日：2002-02-12
申请号：US09482173
申请日：2000-01-12
申请人： Kuo-Chen Shih , Shu-Hei Wang , Tsu-Tseng Weng , Kou-Suein Ai
发明人： Kuo-Chen Shih , Shu-Hei Wang , Tsu-Tseng Weng , Kou-Suein Ai
IPC分类号： C07C5112
CPC分类号： C07C51/12 , C07C53/08
摘要： The present invention relates to an improved process for producing an organic carboxylic acid having (n+1) carbon atoms by reacting an alcohol having n carbon atoms with carbon monoxide in the presence of a rhodium catalyst system. More particularly, the present invention relates to carbonylation of alcohol such as methanol catalyzed by a rhodium system to produce acetic acid. The characteristic of the present invention is the addition of a catalyst stabilizer in the reaction medium to avoid or to alleviate the precipitation of the catalyst in the liquid phase. The catalyst stabilizer as used herein is a pyridine derivative having substituent(s) of such as (CH2)mCOOR or (CH2)mSO3R (R═H or hydrocarbons; m=0-6).
摘要翻译：本发明涉及通过在铑催化剂体系的存在下使具有n个碳原子的醇与一氧化碳反应制备具有（n + 1）个碳原子的有机羧酸的改进方法。更具体地说，本发明涉及通过铑体系催化的醇如甲醇的羰基化以产生乙酸。本发明的特征是在反应介质中加入催化剂稳定剂以避免或减轻催化剂在液相中的沉淀。本文所用的催化剂稳定剂是具有（CH 2）m COOR或（CH 2）m SO 3 R（R = H或烃; m = 0-6）取代基的吡啶衍生物。

29. 发明授权

US5859268A Process for the synthesis of .alpha., .beta.-unsaturated esters 失效
标题翻译：合成α，β-不饱和酯的方法
公开(公告)号：US5859268A
公开(公告)日：1999-01-12
申请号：US826946
申请日：1997-04-08
申请人： Robert J. Angelici , Kuo-Chen Shih
发明人： Robert J. Angelici , Kuo-Chen Shih
IPC分类号： C07C67/333 , C07C51/347 , C07C69/74 , C11C1/00
CPC分类号： C07C67/333
摘要： The present invention provides a process for the synthesis of an .alpha.,.beta.-unsaturated ester from a mono-olefin-ester using Fe(CO).sub.5.
摘要翻译：本发明提供了使用Fe（CO）5从单烯烃酯合成α，β-不饱和酯的方法。

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