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    • 22. 发明申请
    • Aliphatic gasoline component and process to prepare said gasoline component
    • 脂肪族汽油组分和制备所述汽油组分的方法
    • US20070215519A1
    • 2007-09-20
    • US11597312
    • 2005-05-25
    • Jan Lodewijk Maria Dierickx
    • Jan Lodewijk Maria Dierickx
    • C10L1/04
    • C10G57/005C10G2/332C10G11/02C10G55/06C10G63/04C10G2300/1022C10G2300/202C10G2300/305C10G2300/4006C10G2300/80C10G2400/02C10L1/06Y10S208/95
    • An aliphatic gasoline component comprising more than 90 wt % of a mixture of trimethyl substituted compounds and monomethyl substituted compounds in a weight ratio of trimethyl to monomethyl compounds of at least 0.03 and wherein the compounds may be paraffins and olefins. The invention is also directed to a process to prepare an aliphatic gasoline component by (a) contacting a Fischer-Tropsch synthesis product with a catalyst system comprising a catalyst, which catalyst comprises an acidic matrix and a large pore molecular sieve in a riser reactor at a temperature of between 450 and 650° C. at a contact time of between 1 and 10 seconds and at a catalyst to oil ratio of between 2 and 20 k.g/kg, (b) isolating from the product of step (a) a gasoline fraction and a fraction comprising iso-butane and isobutylene; (c) subjecting the iso-butane and the iso-butylene obtained in step (b) to an alkylation step to prepare a trimethyl substituted pentane, and (d) combining the gasoline fraction obtained in step (b) with the product rich in trimethyl substituted pentane as obtained in step (c).
    • 一种脂族汽油组分,其包含超过90重量%的三甲基取代的化合物和单甲基取代的化合物的三甲基与单甲基化合物的重量比为至少0.03的混合物,并且其中所述化合物可以是链烷烃和烯烃。 本发明还涉及通过以下方法制备脂肪族汽油组分的方法:(a)将费 - 托合成产物与包含催化剂的催化剂体系接触,催化剂在催化剂中包含酸性基质和大孔分子筛 温度为450-650℃,接触时间为1至10秒,催化剂与油之比为2-20kg / kg,(b)从步骤(a)的产物中分离汽油 馏分和包含异丁烷和异丁烯的馏分; (c)将步骤(b)中获得的异丁烷和异丁烯经烷基化步骤制备三甲基取代戊烷,和(d)将步骤(b)中获得的汽油馏分与富含三甲基 在步骤(c)中获得的取代戊烷。