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    • 25. 发明授权
    • Polylactic acid fiber and manufacturing method thereof
    • 聚乳酸纤维及其制造方法
    • US08299148B2
    • 2012-10-30
    • US12439773
    • 2007-09-03
    • Midori IkegameTakaaki MatsudaShin To
    • Midori IkegameTakaaki MatsudaShin To
    • C07F9/6574
    • D01F6/92D01D5/084D01F1/10D01F6/625
    • An object of the present invention is to provide a fiber made of polylactic acid and having excellent strength, heat resistance and heat shrinkage resistance and a manufacturing method thereof. The present invention relates to the fiber is made of a composition which includes (i) poly(L-lactic acid) having a weight average molecular weight of 50,000 to 300,000 (component A), (ii) poly(D-lactic acid) having a weight average molecular weight of 50,000 to 300,000 (component B) and (iii) 0.01 to 5 parts by weight of a phosphate metal salt (component C) based on 100 parts by weight of the total of the components A and B and has a strength of 2.5 to 10 cN/dTex and a manufacturing method thereof.
    • 本发明的目的是提供一种由聚乳酸制成的纤维,具有优异的强度,耐热性和耐热收缩性及其制造方法。 纤维本发明涉及由以下组合物构成的纤维:(i)重均分子量为50,000〜300,000(成分A)的聚(L-乳酸),(ii)聚(D-乳酸) 基于100重量份的组分A和B的总量,重均分子量为50,000至300,000(组分B)和(iii)0.01至5重量份的磷酸盐金属盐(组分C),并且具有 强度为2.5〜10cN / dTex及其制造方法。
    • 30. 发明授权
    • Impact-resistant vinyl aromatic hydrocarbon resin
    • 耐冲击乙烯基芳烃树脂
    • US07557160B2
    • 2009-07-07
    • US11661182
    • 2004-08-31
    • Takaaki MatsudaToshinori Shiraki
    • Takaaki MatsudaToshinori Shiraki
    • C08L53/02C08L51/04
    • C08F287/00
    • An impact-resistant vinyl aromatic hydrocarbon resin, the hydrocarbon resin being produced by radical polymerization of 75 to 98 parts by mass of a vinyl aromatic hydrocarbon monomer (A-1) or a mixture of a vinyl aromatic hydrocarbon monomer and a monomer copolymerizable therewith (A-2) and 2 to 25 parts by mass of a modified block copolymer (B), wherein the component (B) comprises a base block copolymer (B-1) comprising conjugated diene monomer units and vinyl aromatic hydrocarbon monomer units and containing at least one polymer block of vinyl aromatic hydrocarbon monomer units (H), and a modifier group bonded thereto (B-2); and the component (B) has the following characteristics: (i) the content of the vinyl aromatic hydrocarbon monomer units is 12 to 50 mass %; (ii) the content of the polymer block (H) is 12 to 45 mass %; and (iii) the polymer block ratio (the mass % of the polymer block (H) based on the total mass of vinyl aromatic hydrocarbon monomer units contained in (B)) is more than 50 mass %.
    • 耐冲击乙烯基芳烃树脂,该烃树脂通过自由基聚合制得75〜98质量份的乙烯基芳香族烃单体(A-1)或乙烯基芳香族烃单体与可与其共聚的单体的混合物 A-2)和2〜25质量份改性嵌段共聚物(B),其中组分(B)包含含有共轭二烯单体单元和乙烯基芳烃单体单元的基础嵌段共聚物(B-1) 至少一个乙烯基芳烃单体单元(H)的聚合物嵌段和与其键合的改性基团(B-2); 组分(B)具有以下特性:(i)乙烯基芳烃单体单元的含量为12〜50质量% (ⅱ)聚合物嵌段(H)的含量为12〜45质量%。 和(iii)聚合物嵌段比(基于(B)中所含的乙烯基芳族烃单体单元的总质量)的聚合物嵌段(H)的质量%)大于50质量%。