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    • 23. 发明申请
    • COATING COMPOSITION, PROCESS FOR PRODUCING THE COMPOSITION, AND LAMINATE HAVING A HARD COAT LAYER
    • 涂料组合物,生产组合物的方法和具有硬层的层压材料
    • US20110244244A1
    • 2011-10-06
    • US13131741
    • 2010-01-12
    • Shunichiro NakatsukasaKatsuhiro Mori
    • Shunichiro NakatsukasaKatsuhiro Mori
    • C09D183/06C08K13/02C09D183/14G02B1/10
    • C09D183/06C08G77/14C08K3/22C09D7/61C09D183/04C09D183/14G02B1/105G02B1/14Y10T428/31511
    • To provide a coating composition capable of forming a hard coat layer having excellent transparency and scratch resistance on the surface of an optical resin substrate such as a plastic lens, and exhibiting long-term storage stability.[Means for Solution] The coating composition comprises (A) a fine particulate composite metal oxide, (B′) a hydrolyzed product obtained by the hydrolysis of (B) a hydrolyzable organosilicon compound containing (B1) an organosilicon compound that has an epoxy group, such as γ-glycidoxypropyltrimethoxysilane, (C) water, (D1) a low-boiling lowly viscous alcohol having not more than 3 carbon atoms, such as methanol or ethanol, (D2) a low-boiling highly viscous alcohol such as t-butanol, (D3) a high-boiling organic solvent having a boiling point of 150° C. to 200° C., such as diacetone alcohol, and (E) a curing catalyst such as tris(2,4-pentanedionato)aluminum(III), the mass ratio (D1/C) of the component (D1) and the component (C) being in a range of 1.80 to 7.00, the mass ratio (D2/C) of the component (D2) and the component (C) being in a range of 0.24 to 2.50, and the mass ratio (D3/C) of the component (D3) and the component (C) being in a range of 1.10 to 4.40.
    • 提供能够形成在诸如塑料透镜的光学树脂基材的表面上具有优异的透明性和耐划伤性的硬涂层的涂料组合物,并且具有长期的储存稳定性。 [解决方案]涂料组合物包含(A)细颗粒复合金属氧化物,(B')通过水解(B)含有(B1)具有环氧基的有机硅化合物的可水解有机硅化合物得到的水解产物 ,例如γ-环氧丙氧基丙基三甲氧基硅烷,(C)水,(D1)甲醇或乙醇等不超过3个碳原子的低沸点低粘度醇,(D2)低沸点高粘度醇, 丁醇,(D3)沸点为150℃〜200℃的高沸点有机溶剂,例如双丙酮醇,(E)固化催化剂如三(2,4-戊二酮)铝( III),成分(D1)和成分(C)的质量比(D1 / C)在1.80〜7.00的范围内,成分(D2)和成分(D)的质量比(D2 / C)在0.24〜2.50的范围内,成分(D3)和成分(C)的质量比(D3 / C)在1.10〜4.40的范围内。
    • 24. 发明申请
    • Photochromic Optical Element
    • 光致变色光学元件
    • US20100233485A1
    • 2010-09-16
    • US12223116
    • 2007-01-19
    • Katsuhiro MoriYuichiro KawabataIkumi KawaguchiHironobu Nagoh
    • Katsuhiro MoriYuichiro KawabataIkumi KawaguchiHironobu Nagoh
    • B32B9/04G02B1/10B05D5/06B29D11/00
    • G02B5/23C09K9/02C09K2211/1011C09K2211/1033C09K2211/1088G02B1/105G02B1/113G02B1/14Y10T428/256Y10T428/257Y10T428/259Y10T428/263Y10T428/264Y10T428/265Y10T428/31511Y10T428/31663Y10T428/31667
    • [Problems] To prevent or reduce the problem wherein color development and fading in expected color tones do not occur in an optical element that includes a photochromic coat layer containing alkylamino group-containing photochromic compounds and/or dialkylamino group-containing photochromic compounds in a high concentration and a hard coat layer formed on the photochromic coat layer.[Means for Solving Problems] A photochromic optical element comprising an optical substrate, a photochromic coat layer, and a hard coat layer that are laminated in this order, wherein (I) the photochromic coat layer comprising an alkylamino group-containing photochromic compound and/or a dialkylamino group-containing photochromic compound in a total amount of 0.1 to 10.0% by mass, and (II) the hard coat layer is obtained by curing a hard coat agent comprising metal oxide fine particles and an organosilicon compound, the hard coat agent containing as the organosilicon compound at least one selected from the group consisting of a tetraalkoxy silane, a methyl trialkoxy silane, and partial hydrolysates thereof in an amount of 10 to 60% by mass based on the total mass of the metal oxide fine particles and the organosilicon compound (with the proviso that, when the organosilicon compound is a partial hydrolysate of a partially hydrolyzable organosilicon compound, the mass of the organosilicon compound in the above total mass is the mass of the partially hydrolyzable organosilicon compound).
    • [问题]为了防止或减少在包含含有含有含有烷基氨基的光致变色化合物和/或含二烷基氨基的光致变色化合物的光致变色涂层的光学元件中不发生预期色调的显色和褪色的问题, 浓度和形成在光致变色涂层上的硬涂层。 解决问题的手段一种光致变色光学元件,其包含依次层叠的光学基板,光致变色涂层和硬涂层,其中(I)含有含烷基氨基的光致变色化合物的光致变色涂层和/ 或含有二烷基氨基的光致变色化合物,总量为0.1〜10.0质量%,(II)硬涂层通过固化包含金属氧化物微粒和有机硅化合物的硬涂层而获得,硬涂层 作为有机硅化合物,以金属氧化物微粒的总质量为基准,含有10〜60质量%的选自四烷氧基硅烷,甲基三烷氧基硅烷及其部分水解物的至少一种, 有机硅化合物(条件是当有机硅化合物是部分可水解的有机硅化合物的部分水解产物时,有机硅化合物的质量 在上述总质量中的n化合物是部分可水解的有机硅化合物的质量)。
    • 25. 发明授权
    • Curable composition
    • 可固化组合物
    • US07763693B2
    • 2010-07-27
    • US10567790
    • 2004-08-11
    • Hironobu NagohJunji MomodaKatsuhiro Mori
    • Hironobu NagohJunji MomodaKatsuhiro Mori
    • C08F118/02C08F20/10C08F130/08C08G63/48
    • C09D175/16C08F283/12C08G59/3209C08K5/0041C08K5/1545C08L33/14C08L83/04C08F220/32C08L83/00
    • A curable composition comprising (1) 0.1 to 20 parts by weight of a silicon compound having a silanol group or a functional group for forming a silanol group upon hydrolysis and no radically polymerizable group, such as γ-glycidoxypropyltrimethoxysilane, (2) 100 parts by weight of radically polymerizable monomers and (3) 0.01 to 20 parts by weight of a photochromic compound, wherein the radically polymerizable monomers include a radically polymerizable monomer having an epoxy group in the molecule, such as glycidyl methacrylate. This curable composition is capable of forming a photochromic coating layer which shows excellent photochromic properties such as high color development density and fast fading rate, is free from the dissolution of the photochromic compound, exhibits high adhesion to a substrate through a simple pre-treatment and has excellent hard coating applicability.
    • 一种可固化组合物,其包含(1)水解时形成硅烷醇基或硅烷醇基官能团的硅化合物0.1〜20重量份,γ-环氧丙氧基丙基三甲氧基硅烷等无自由基聚合性基团,(2)100份 自由基聚合性单体的重量和(3)0.01〜20重量份的光致变色化合物,其中可自由基聚合的单体包括分子中具有环氧基的自由基聚合性单体,如甲基丙烯酸缩水甘油酯。 该固化性组合物能够形成光显色性优异的光致变色涂层,如显色性高,褪色速度快,没​​有光致变色化合物的溶解,通过简单的预处理表现出对基材的高附着性, 具有优异的硬涂层适用性。
    • 26. 发明申请
    • Coating composition and optical article
    • 涂料组合物和光学制品
    • US20060071203A1
    • 2006-04-06
    • US10529462
    • 2003-12-04
    • Katsuhiro MoriJunji Momoda
    • Katsuhiro MoriJunji Momoda
    • G02B5/23G02B5/22
    • C09K9/02C09D4/00C08F230/08
    • There is provided a coating composition which can be applied to a substrate such as a plastic lens so as to form a photochromic coating layer having good photochromic properties and excellent adhesion to the substrate on the surface of the substrate. This composition comprises, for example, as monomer components, 0.1 to 20 wt % of monomer having a group which produces a silanol group through hydrolysis such as γ-methacryloyloxypropyltrimethoxysilane and 0.1 to 50 wt % of monomer having at least one oxycarbonyl group in a molecule. The composition can further contain a maleimide compound as a monomer component and further desirably contains an amine compound.
    • 提供了可以应用于诸如塑料透镜的基材的涂料组合物,以形成具有良好的光致变色性能和对基材表面上的基材的优异粘附性的光致变色涂层。 该组合物包含例如单体成分,0.1〜20重量%的具有通过水解产生硅烷醇基的基团如γ-甲基丙烯酰氧基丙基三甲氧基硅烷和0.1〜50重量%的分子中具有至少一个氧羰基的单体的单体 。 该组合物还可以含有作为单体成分的马来酰亚胺化合物,进一步优选含有胺化合物。
    • 29. 发明授权
    • Gas turbine cogeneration apparatus for the production of domestic heat
and power
    • 用于生产国内热能和动力的燃气轮机加热装置
    • US5148670A
    • 1992-09-22
    • US727381
    • 1991-07-05
    • Peter H. BirchToshiyuki KondoKatsuhiro Mori
    • Peter H. BirchToshiyuki KondoKatsuhiro Mori
    • F02C3/00F02C6/00F02C6/04F02C6/18F02C7/08F02C7/26
    • F02C6/006F02C7/08F02C7/26Y02E20/14
    • An apparatus for the domestic cogeneration of heat and electrical energy utilizing an inverted Brayton cycle gas turbine, a combustion chamber, an electrical generator and a compressor. Combustion air is preheated in a heat exchanger by gaseous combustion gases or exhaust gases exiting from the turbine. The combustion air is supplied at substantially atmospheric pressure to the combustion chamber where fuel is burned. The cooled gaseous combustion gases exiting from the heat exchanger are then fed to the compressor where they are recompressed to atmospheric pressure, and are finally used to heat the working fluid of a domestic heating system before being exhausted to the atmosphere. The apparatus can also include an acoustically and thermally insulated housing, an electric air blower for start-up, an engine ignition device, a frequency converter which conditions the electric generator output for connection to the main supply and a control system which is cooled by the engine intake air and which detects thermal and electrical demand and adjusts the engine power accordingly.
    • 一种利用倒置布雷顿循环燃气轮机,燃烧室,发电机和压缩机进行国内热电联产的装置。 燃烧空气在热交换器中由气体燃烧气体或从涡轮机排出的排气预热。 燃烧空气以基本大气压供应到燃烧燃烧的燃烧室。 然后将从热交换器排出的冷却的气态燃烧气体送入压缩机,在压缩机中将其再次压缩至大气压力,最后用于在排气到大气之前加热家用加热系统的工作流体。 该装置还可以包括隔热隔热的壳体,用于启动的电动鼓风机,发动机点火装置,调节用于连接主电源的发电机输出的变频器和由主电源冷却的控制系统 发动机进气,并检测热和电力需求,并相应地调整发动机功率。