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21. 发明授权

US06830678B2 Process of desulphurizing gasoline comprising desulphurization of the heavy and intermediate fractions resulting from fractionation into at least three cuts 有权
$Process of desulphurizing gasoline comprising desulphurization of the heavy and intermediate fractions resulting from fractionation into at least three cuts$
标题翻译：包括脱硫汽油的方法，包括由分馏得到的重馏分和中间馏分脱硫至至少三个馏分
公开(公告)号：US06830678B2
公开(公告)日：2004-12-14
申请号：US09819949
申请日：2001-03-29
申请人： Blaise Didillon , Denis Uzio , Quentin Debuisschert , Jean-Luc Nocca
发明人： Blaise Didillon , Denis Uzio , Quentin Debuisschert , Jean-Luc Nocca
IPC分类号： C10G6506
CPC分类号： C10G65/00 , C10G69/00
摘要： The invention relates to a process of producing gasoline with a low sulphur content from a feedstock containing sulphur. This process comprises at least one step a1 of selectively hydrogenating the diolefins and acetylenic compounds, at least one separation of the gasoline (step b) obtained at step a1 into at least three fractions, at least one step c1 of treating the heavy gasoline separated at step b on a catalyst enabling the unsaturated sulphur compounds to be at least partially decomposed or hydrogenated and at least one step d to remove the sulphur and nitrogen from at least one intermediate fraction, followed by catalytic reforming.
摘要翻译：本发明涉及从含硫原料生产低硫含量的汽油的方法。该方法包括至少一个选择性氢化二烯烃和炔属化合物的步骤a1，至少一个步骤a1中获得的汽油（步骤b）分离成至少三个馏分，至少一个步骤c1处理在步骤b使得不饱和硫化合物至少部分分解或氢化并且至少一个步骤d从至少一个中间馏分中除去硫和氮，然后进行催化重整。

22. 发明授权

US06709639B1 Apparatus for purification of raw gasoline from catalytic cracking 有权
标题翻译：用于从催化裂化中净化原料汽油的装置
公开(公告)号：US06709639B1
公开(公告)日：2004-03-23
申请号：US09522179
申请日：2000-03-09
申请人： Thierry Chapus , Blaise Didillon , Christian Marcilly , Charles Cameron
发明人： Thierry Chapus , Blaise Didillon , Christian Marcilly , Charles Cameron
IPC分类号： B01J804
CPC分类号： C10G67/12 , C10G2400/02
摘要： An apparatus for the purification of catalytic cracking gasolines containing dienic and/or acetylenic impurities, and mercaptans, said apparatus comprising at least one selective hydrogenation reactor 3 containing at least one fixed catalyst bed, and having at least one line 1 for introducing a feed, at least one effluent outlet line, and a line supplying hydrogen to the reactor, said reactor being followed by at least one stabilization drum 4 connected to said effluent outlet line, the drum having at least one gas outlet line 5 and at least one stabilized effluent outlet line, and said effluent passing into at least one sweetening reactor 8 comprising at least one effluent inlet line 6 and at least one effluent outlet line, said reactor having close thereto at least one oxidizing agent supply line, said apparatus also comprising at least one drum 9 for degassing the effluent from the sweetening reactor 8, said drum 9 having at least one gas outlet line and at least one outlet line 11 for dedienized, stabilized and sweetened gasoline.
摘要翻译：一种用于纯化含有二烯和/或炔属杂质的催化裂解汽油的装置和硫醇，所述装置包括至少一个含有至少一个固定催化剂床的选择性氢化反应器3，并具有至少一条用于引入进料的管线1，至少一个流出物出口管线和向反应器供应氢气的管线，所述反应器后面连接有至少一个与所述流出物出口管线连接的稳定鼓筒，所述转鼓具有至少一个气体出口管线5和至少一个稳定的流出物出口管线，并且所述流出物进入至少一个甜味反应器8，其包含至少一个流出物入口管线6和至少一个流出物出口管线，所述反应器具有至少一个氧化剂供应管线，所述设备还包括至少一个鼓9用于对来自甜味反应器8的流出物进行脱气，所述滚筒9具有至少一个气体出口管线和至少一个出口管线11 用于发明，稳定和增甜的汽油。

23. 发明授权

US06315892B1 Catalytic hydroreforming process 失效
标题翻译：催化加氢成型工艺
公开(公告)号：US06315892B1
公开(公告)日：2001-11-13
申请号：US09688167
申请日：2000-10-16
申请人： Fabienne Le Peltier , Blaise Didillon , Patrick Sarrazin , Jean-Paul Boitiaux
发明人： Fabienne Le Peltier , Blaise Didillon , Patrick Sarrazin , Jean-Paul Boitiaux
IPC分类号： C10G35085
CPC分类号： B01J23/622 , B01J23/62 , B01J37/0205 , C10G35/09 , Y10S502/506 , Y10S502/513 , Y10S502/514
摘要： A process of hydroreforming in the presence of a catalyst containing at least one refractory inorganic carrier, platinum, possibly at least one metal from Group VIII (palladium, nickel, and ruthenium), a halogen or compound thereof, and at least one additional metal M selected from among germanium, tin, lead, gallium, indium, and thallium, process in which said metal M, in the form of at least one organic compound, is introduced in situ into the reactor where the hydrocarbon charge will then be treated or into a prereactor that is connected to said reactor.
摘要翻译：在含有至少一种难熔性无机载体的铂的催化剂存在下进行加氢反应的方法，铂，可能的至少一种来自第VIII族（钯，镍和钌）的金属，卤素或其化合物，以及至少一种另外的金属M 选自锗，锡，铅，镓，铟和铊的方法，其中将至少一种有机化合物形式的所述金属M原位引入反应器中，其中烃装料将被处理或进入连接到所述反应器的预反应器。

24. 发明授权

US06214890B1 Fischer-Tropsch synthesis process in the presence of a catalyst the metallic particles of which have a controlled size 有权
标题翻译：在其催化剂存在下的费 - 托合成方法，其金属颗粒具有受控的尺寸
公开(公告)号：US06214890B1
公开(公告)日：2001-04-10
申请号：US09373229
申请日：1999-08-12
申请人： Magalie Roy , Blaise Didillon , Denis Uzio , Catherine Verdon
发明人： Magalie Roy , Blaise Didillon , Denis Uzio , Catherine Verdon
IPC分类号： C07C2700
CPC分类号： B01J37/0211 , B01J23/75 , B01J35/0013 , B01J35/023 , C07C1/0425 , C07C1/0445 , C07C2523/75
摘要： The invention relates to a synthesis process for hydrocarbons using a mixture containing carbon monoxide and hydrogen, called Fischer-Tropsch synthesis in the presence of a catalyst comprising a support, at least one group VIII metal said process being characterized in that at least 80% of the group VIII metallic particles of the catalyst have a size comprised between D−(D.0.2) and D+(D.0.2), where D represents the average size of the metallic particles. The process can be used in a fixed-bed reactor of the catalyst or in a reactor operating in liquid phase of the catalyst.
摘要翻译：本发明涉及使用含有一氧化碳和氢气的混合物的烃的合成方法，在催化剂存在下，称为费 - 托合成，所述催化剂包含载体，至少一种第Ⅷ族金属，所述方法的特征在于至少80％催化剂的第VIII族金属颗粒的尺寸为D（D.0.2）和D +（D.0.2）之间，其中D表示金属颗粒的平均尺寸。该方法可用于催化剂的固定床反应器或在催化剂的液相中操作的反应器中。

25. 发明授权

US06187985B1 Process for dehydrogenating saturated aliphatic hydrocarbons to olefinic hydrocarbons 有权
标题翻译：将饱和脂肪烃脱氢成烯烃的方法
公开(公告)号：US06187985B1
公开(公告)日：2001-02-13
申请号：US09182660
申请日：1998-10-30
申请人： Fabienne Le Peltier , Blaise Didillon , Olivier Clause
发明人： Fabienne Le Peltier , Blaise Didillon , Olivier Clause
IPC分类号： C07C202
CPC分类号： C07C5/3335 , B01J23/622 , B01J37/0203 , C07C5/3337 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/62 , C07C11/02
摘要： A process for dehydrogenating C5-C22 aliphatic hydrocarbons to the corresponding olefinic hydrocarbons is carried out in the presence of a catalyst comprising at least one support, at least one metal from group VIII of the periodic table and at least one additional element M selected from the group formed by germanium, tin, lead, rhenium, gallium, indium, and thallium. The process is characterized in that the catalyst is prepared using a process in which said metal M is introduced in an aqueous solvent in the form of at least one organometallic compound comprising at least one carbon-M bond.
摘要翻译：将C5-C22脂族烃脱氢成相应的烯烃的方法是在催化剂存在下进行的，所述催化剂包含至少一种载体，至少一种来自元素周期表第VIII族的金属和至少一种选自由锗，锡，铅，铼，镓，铟和铊形成的组。该方法的特征在于，使用其中所述金属M以包含至少一个碳-M键的至少一种有机金属化合物的形式引入水性溶剂中的方法制备催化剂。

26. 发明授权

US5672801A Catalyst regeneration process and use of the catalyst in hydrocarbon conversion processes 失效
标题翻译：催化剂再生过程和催化剂在烃转化过程中的应用
公开(公告)号：US5672801A
公开(公告)日：1997-09-30
申请号：US692470
申请日：1996-08-06
申请人： Blaise Didillon
发明人： Blaise Didillon
IPC分类号： B01J23/96 , B01J38/44 , C07C5/32 , C07C5/333 , C07C5/41
CPC分类号： C07C5/417 , B01J23/96 , B01J38/44 , C07C5/324 , C07C5/325 , C07C5/3337 , C07C5/415 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/18 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/26 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/745 , C07C2523/755 , C07C2527/02 , C07C2527/057 , C07C2527/06 , C07C2527/14 , C07C2527/24 , Y02P20/584
摘要： The present invention concerns a regeneration process for a catalyst containing at least one metallic element selected from the group formed by platinum, palladium, ruthenium, rhodium, osmium, iridium and nickel, preferably platinum, on a refractory oxide based support, which has been deactivated by coke deposition. The regeneration process is characterised in that said regeneration consists of treatment with a gas containing at least chlorine and molecular oxygen, at a temperature between 20.degree. C. and 800.degree. C. and a total gas flow rate, expressed in litres of gas per hour and per gram of catalyst, of between 0.05 and 20. The process at least restores the initial catalytic properties of the catalyst.
摘要翻译：本发明涉及一种催化剂的再生方法，所述催化剂含有至少一种选自铂，钯，钌，铑，锇，铱和镍（优选铂）的金属元素，所述金属元素在难熔氧化物基载体上已被去活化通过焦炭沉积。再生方法的特征在于，所述再生包括在20℃至800℃之间的温度下用至少含有氯和分子氧的气体进行处理，总气体流速（以升每小时气体表示）和每克催化剂为0.05至20.该方法至少恢复催化剂的初始催化性能。

27. 发明授权

US5648576A Catalytic hydrogenation process and a catalyst for use in the process 失效
标题翻译：催化氢化方法和催化剂用于该方法
公开(公告)号：US5648576A
公开(公告)日：1997-07-15
申请号：US466685
申请日：1995-06-06
申请人： Canh Nguyen Than , Blaise Didillon , Patrick Sarrazin , Charles Cameron
发明人： Canh Nguyen Than , Blaise Didillon , Patrick Sarrazin , Charles Cameron
IPC分类号： B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/08 , C07B61/00 , C07C5/09 , C07C7/167 , C07C11/04 , C07C11/06 , B01J21/04
CPC分类号： C07C5/09 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/0006 , C07C7/167 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50 , C07C2523/66 , Y02P20/52
摘要： A process for the selective hydrogenation in the gas phase of acetylene compounds containing 2 or 3 carbon atoms to the corresponding ethylene compounds in the presence of a catalyst in the form of spherules or extradates containing an alumina support, 0.01-0.5% by weight palladium, 0.001 to 0.5% by weight of at least one group IB metal, preferably silver, and optionally at least one alkaline or alkaline-earth metal, the weight ratio of the group IB metal to palladium being 0.05:1 to 0.25:1, in which catalyst at least 80% of the palladium and at least 80% of the group IB element are present in a volume at a periphery of the catalyst defined between a spherical or cylindrical surface of radius r.sub.1 corresponding to the average spherule or extradate diameter and a spherical or cylindrical surface of radius r.sub.2 at least equal to 0.8r.sub.1.
摘要翻译：含有2或3个碳原子的乙炔化合物的气相中的选择性氢化到相应的乙烯化合物在催化剂存在下的催化剂的方法，所述催化剂是包含0.01-0.5重量％钯的氧化铝载体， 0.001至0.5重量％的至少一种IB族金属，优选银，以及任选的至少一种碱金属或碱土金属，IB族金属与钯的重量比为0.05:1至0.25:1，其中催化剂至少80％的钯和至少80％的IB族元素以体积计存在催化剂的外围，该体积定义在对应于平均球粒或引导体直径的半径r1的球形或圆柱形表面之间，或半径r2的圆柱形表面至少等于0.8r1。

28. 发明授权

US5475174A Process for the selective hydrogenation of compounds comprising endo and exocyclic unsaturations 失效
标题翻译：用于选择性氢化包含内环和外环不饱和化合物的方法
公开(公告)号：US5475174A
公开(公告)日：1995-12-12
申请号：US156777
申请日：1993-11-24
申请人： Christine Lucas , Jean-Pierre Candy , Jean-Marie Basset , Blaise Didillon , Jean-Paul Boitiaux
发明人： Christine Lucas , Jean-Pierre Candy , Jean-Marie Basset , Blaise Didillon , Jean-Paul Boitiaux
IPC分类号： B01J23/62 , C07B61/00 , C07C5/03 , C07C5/05 , C07C13/19
CPC分类号： C07C5/05 , B01J23/622 , C07C2101/14 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2523/755 , C07C2523/835
摘要： The invention concerns a process for the selective hydrogenation of polyunsaturated cyclic compounds comprising at least one endocyclic carbon-carbon double bond and at least one terminal exocyclic carbon-carbon double bond, said double bonds not being conjugated, to form a mixture essentially containing the saturated ring compound and comprising at least one terminal exocyclic double bond, the process being carried out in the presence of hydrogen under a pressure of from 1 to 10 MPa and at a temperature of from 0.degree. to 200.degree. C., and in the presence of a catalyst including a support and (a) from 0.1 to 5% by weight of at least one metal from group VIII (iridium, osmium, nickel, palladium, platinum and rhodium) and (b) from 0.01 to 15% by weight of at least one metal from group IVa (tin, germanium and lead), the molar ratio between metals of group VIII and group IVa being between 0.3 and 3. The process is used for the hydrogenation of 4-vinylcylcohexene to vinylcyclohexane.
摘要翻译：本发明涉及包含至少一个内环碳 - 碳双键和至少一个末端环外碳 - 碳双键的多不饱和环状化合物的选择性氢化的方法，所述双键不是共轭的，以形成基本上含有饱和的环化合物并且包含至少一个末端环外双键，该方法在氢气存在下，在1至10MPa的压力和0至200℃的温度下进行，并且在包含载体的催化剂和（a）0.1至5重量％的至少一种第VIII族金属（铱，锇，镍，钯，铂和铑）和（b）0.01至15重量％来自IVa族（锡，锗和铅）的至少一种金属，VIII族和IVa族金属之间的摩尔比在0.3和3之间。该方法用于将4-乙烯基环己烯氢化成乙烯基环己烷。

29. 发明授权

US5118884A Hydrogenation of citral 失效
标题翻译： CITRAL加氢
公开(公告)号：US5118884A
公开(公告)日：1992-06-02
申请号：US578113
申请日：1990-09-06
申请人： Blaise Didillon , Jean-Pierre Candy , Jean-Marie Bassett , Jean-Paul Bournonville
发明人： Blaise Didillon , Jean-Pierre Candy , Jean-Marie Bassett , Jean-Paul Bournonville
IPC分类号： B01J23/62 , C07B61/00 , C07C29/141 , C07C33/02
CPC分类号： C07C33/02 , C07C29/141
摘要： The invention concerns the production of a diolefinic unsaturated alcohol such as geraniol or nerol by the selective hydrogenation of citral. It is characterized by the use of a catalyst based on a metal from group VIII and based on a metal selected from the group made up of tin, germanium and lead, on preferably a silica carrier.
摘要翻译：本发明涉及通过柠檬醛的选择性氢化生产二烯属不饱和醇如香叶醇或橙花醇。其特征在于使用基于VIII族金属的催化剂，并且基于选自锡，锗和铅的金属，优选二氧化硅载体。

30. 发明授权

US06896795B2 Process for the production of gasolines with low sulfur contents 有权
标题翻译：生产低硫含量汽油的工艺
公开(公告)号：US06896795B2
公开(公告)日：2005-05-24
申请号：US10109850
申请日：2002-04-01
申请人： Blaise Didillon , Denis Uzio , Nathalie Marchal
发明人： Blaise Didillon , Denis Uzio , Nathalie Marchal
IPC分类号： B01J23/88 , C10G45/06 , C10G45/08 , C10G45/36 , C10G45/40 , C10G65/00 , C10G65/04 , C10G65/06 , C10G67/02 , C10G67/04 , C10G69/04 , C10G45/02
CPC分类号： B01J35/1019 , B01J23/755 , B01J23/882 , B01J35/08 , B01J35/1042 , C10G65/00 , C10G65/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/4093 , C10G2400/02
摘要： The invention relates to a process for the production of gasoline with a low sulfur content that comprises at least the following stages: a1) at least a selective hydrogenation of diolefins, a2) optionally at least one stage that is aimed at increasing the molecular weight of the light sulfur-containing products that are present in the gasoline, b) at least one separation of the gasoline that is obtained in stage a1 or a2 into two fractions: light gasoline and heavy gasoline, c) at least one treatment with heavy gasoline that is separated in stage b on a catalyst that makes it possible to decompose or to hydrogenate at least partially the unsaturated sulfur-containing compounds, d) at least one treatment of the heavy gasoline that is obtained in stage c, without eliminating the H2S that is formed during this stage, on a catalyst that makes it possible to decompose the sulfur-containing compounds and more preferably the linear and/or cyclic saturated compounds.
摘要翻译：本发明涉及一种生产低硫含量的汽油的方法，该方法至少包括以下阶段：a1）至少对二烯烃进行选择性氢化，a2）任选的至少一个阶段，目的在于提高分子量存在于汽油中的轻质含硫产物，b）在步骤a1或a2中获得的汽油至少一次分成两部分：轻质汽油和重质汽油，c）至少一种重质汽油处理，在阶段b中在催化剂上分离，使得可以至少部分地分解或氢化不饱和含硫化合物，d）在阶段c中获得的重汽油的至少一种处理，而不消除H 2 S 在这个阶段中形成的催化剂使得可以分解含硫化合物，更优选分解线性和/或环状饱和化合物。

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