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    • 26. 发明授权
    • IR absorber for laser-induced thermal dye transfer
    • 用于激光诱导热染料转移的IR吸收剂
    • US5256620A
    • 1993-10-26
    • US992233
    • 1992-12-17
    • Mitchell S. BurberryLee W. TuttMichael R. Detty
    • Mitchell S. BurberryLee W. TuttMichael R. Detty
    • B41M5/382B41M5/385B41M5/388B41M5/39B41M5/392B41M5/46B41M5/035B41M5/38
    • B41M5/465B41M5/392Y10S428/913Y10S428/914Y10S430/146
    • This invention relates to a dye donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer comprising an image dye in a binder and an infrared-absorbing material associated therewith, and wherein the infrared-absorbing material is a telluro- or seleno-squarylium dye having the following formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represents hydrogen or a substituted or unsubstituted alkyl, aryl or hetaryl group;R.sub.5 and R.sub.6 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino, or a substituted or unsubstituted alkyl, aryl or hetaryl group;X represents Se or Te; andY represents O, S, Se, Te, TeCl.sub.2 or TeBr.sub.2, with the proviso that when X and Y are both Se and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents t-butyl, then R.sub.5 and R.sub.6 cannot both be hydrogen at the same time; and with the second proviso that when X is Se and Y is O and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents t-butyl, then R.sub.5 and R.sub.6 cannot both be hydrogen at the same time.
    • 本发明涉及一种用于激光诱导的热染料转移的染料供体元件,其包括其上具有染料层的载体,所述染料层包含粘合剂中的图像染料和与其相关联的红外线吸收材料,并且其中所述红外线吸收材料是电泳 - 或具有下式的硒代方菁染料:其中:R 1,R 2,R 3和R 4各自独立地表示氢或取代或未取代的烷基,芳基或杂芳基; R 5和R 6各自独立地表示氢,卤素,氰基,烷氧基,芳氧基,酰氧基,芳氧基羰基,烷氧基羰基,磺酰基,氨基甲酰基,酰基,酰氨基,烷基氨基,芳基氨基或取代或未取代的烷基,芳基或杂芳基。 X表示Se或Te; Y表示O,S,Se,Te,TeCl 2或TeBr 2,条件是当X和Y均为Se和R1时,R2,R3和R4各自表示叔丁基,则R5和R6不能同时为氢 同时; 第二个条件是当X为Se且Y为O且R1,R2,R3和R4各自表示叔丁基时,则R5和R6不能同时为氢。
    • 27. 发明授权
    • Detecting cells using tellurapyrylium dihydroxides
    • 检测细胞使用二甲基二酰基二氢氧化物
    • US5082771A
    • 1992-01-21
    • US371958
    • 1989-06-27
    • Michael R. Detty
    • Michael R. Detty
    • C12Q1/04
    • C12Q1/04Y10S436/903
    • A process for detecting the presence of living cells suspended in an aqueous medium preferably at a nearly neutral pH, which comprises:(a) reducing a tellurapyrylium Te(IV) dihydroxide (TPDH) with cells, optionally while using a substituted benzoquinone electron transfer agent to assist the reduction, thereby producing a change in light absorbance and(b) sensing the change in absorbance to detect or quantify the presence of the cells.The light absorbance change comprises the appearance of a new spectral peak from the product formed by reduction of the Te(IV) dihydroxide. The new peak has a high extinction coefficient in the near infrared region of the electromagnetic spectrum, i.e., away from the spectral region where some biological components cause spectral interference. Consequently, detection methods provided by this invention have a high degree of sensitivity and are comparatively free from spectral interference caused by materials commonly present in biological materials.
    • 一种用于检测悬浮在含水介质中的活细胞存在的方法,优选在接近中性的pH下,该方法包括:(a)任选地在使用取代的苯醌电子转移剂的同时,用细胞还原碲化萘Te(IV)二氢氧化物(TPDH) 以帮助还原,从而产生光吸收的变化,和(b)感测吸光度的变化以检测或定量细胞的存在。 吸光度变化包括从通过还原Te(IV)二氢氧化物形成的产物出现新的光谱峰。 新的峰值在电磁光谱的近红外区域具有高消光系数,即远离其中一些生物成分引起光谱干扰的光谱区域。 因此,本发明提供的检测方法具有高度的灵敏度,并且相对没有由通常存在于生物材料中的材料引起的光谱干扰。