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21. 发明授权

US08741045B2 Ink composition, inkjet recording method, and colored material 失效
标题翻译：油墨组合物，喷墨记录方法和着色材料
公开(公告)号：US08741045B2
公开(公告)日：2014-06-03
申请号：US13806956
申请日：2011-06-24
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/02
CPC分类号： C09D11/328 , B41M5/5218 , C09B31/28 , C09B31/30 , C09B35/56 , C09B43/16 , C09B67/0055
摘要： An aqueous black ink composition which enables the formation of an excellent black recorded image having extremely high ozone gas resistance and a neutral and achromatic color. The ink composition comprises: a dye which includes at least one compound represented by specific formula (1) or at least one tautomer or salt of the compound; a dye which includes at least one compound represented by specific formula (3) or at least one tautomer or salt of the compound; and a dye which includes at least one compound represented by specific formula (4) or at least one tautomer or salt of the compound.
摘要翻译：一种黑色油墨组合物，其能够形成具有极高的耐臭氧气体性和中性和无色性的优异的黑色记录图像。油墨组合物包含：包含至少一种由特定式（1）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 包含至少一种由特定式（3）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 和包含至少一种由特定式（4）表示的化合物或该化合物的至少一种互变异构体或盐的染料。

22. 发明授权

US08167991B2 Trisazo compound, ink composition, recording method, and colored article 有权
标题翻译：三唑类化合物，油墨组合物，记录方法和有色制品
公开(公告)号：US08167991B2
公开(公告)日：2012-05-01
申请号：US12087426
申请日：2006-12-28
申请人： Takahiko Matsui , Yoshiyuki Dejima , Takashi Yoshimoto , Ryoutarou Morita , Koji Hirota
发明人： Takahiko Matsui , Yoshiyuki Dejima , Takashi Yoshimoto , Ryoutarou Morita , Koji Hirota
IPC分类号： C09D11/02 , C09B31/16
CPC分类号： C07D471/04 , C09B31/28 , C09D11/17 , C09D11/328
摘要： The present invention relates to a trisazo compound represented by the following formula (1) or a salt thereof, The formula (1) wherein, the group A is a substituted phenyl group, the group B and the group C are substituted para-phenylene groups, R1 represents a C1 to C4 alkyl group which may be substituted by a carboxy group, a phenyl group which may be substituted by a sulfo group, or a carboxy group, R2 represents a cyano group, a carbamoyl group or a carboxy group, each of R3 and R4 independently represents a hydrogen atom, a methyl group, a chlorine atom or a sulfo group, respectively and a water-based black ink composition containing said compound; said compound has high solubility in a medium where the main component is water, its aqueous solution having a high concentration and ink are stable when stored for a long period of time, black-recorded images with it can be provided where both light fastness and ozone gas fastness of the printed images are excellent.
摘要翻译：本发明涉及由下式（1）表示的三偶氮化合物或其盐。式（1）其中A组为取代苯基，B组和C组为取代的对亚苯基 R1表示可被羧基取代的C1〜C4烷基，可被磺基取代的苯基或羧基，R2表示氰基，氨基甲酰基或羧基，各自独立地表示 R 3和R 4分别独立地表示氢原子，甲基，氯原子或磺基，以及含有所述化合物的水性黑色油墨组合物。所述化合物在主要成分为水的介质中具有高溶解度，其浓度高的水溶液和长时间储存时的油墨稳定，可以提供具有耐光性和臭氧性的黑色记录图像印刷图像的耐气牢度优异。

23. 发明申请

US20100309246A1 TRISAZO COMPOUND, INK COMPOSITION, PRINTING METHOD AND COLORED PRODUCT 有权
标题翻译： TRISAZO化合物，墨水组合物，印刷方法和着色产品
公开(公告)号：US20100309246A1
公开(公告)日：2010-12-09
申请号：US12734655
申请日：2008-11-25
申请人： Koji Hirota , Takahiko Matsui , Takashi Yoshimoto , Shinsuke Shimizu
发明人： Koji Hirota , Takahiko Matsui , Takashi Yoshimoto , Shinsuke Shimizu
IPC分类号： B41J2/015 , C09B31/16
CPC分类号： C07D471/04 , B41M5/0023 , C09B31/28 , C09D11/328
摘要： The present invention relates to a trisazo compound represented by the following formula (1): (wherein, n represents 0 or 1, the group A represents a substituted heterocyclic group, R1 represents a C1-C4 alkyl group which may be substituted or the like, R2 represents a cyano group or the like, R3 and R4 each independently represent a hydrogen atom, a sulfo group or the like, R5 to R7 each independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, a C1-C4 alkoxy group which may be substituted or the like, respectively) or a salt thereof. Said trisazo compound or a salt thereof provides a coloring matter compound for black ink and an ink composition thereof where they have high solubility in medium where water is a principal component, their aqueous solution and ink having high concentration is stable even when stored for a long period of time, printed images therewith have very high density, no bronzing is caused on the images printed even with their high concentration solution, and they give black recorded images excellent in fastnesses, particularly in both light fastness and ozone gas fastness.
摘要翻译：本发明涉及由下式（1）表示的三偶氮化合物：其中，n表示0或1，A组代表取代的杂环基，R 1表示可被取代的C 1 -C 4烷基等，R 2表示氰基等，R 3和R 4各自独立地表示氢原子，磺基等，R 5〜R 7各自独立地表示氢原子，可以被取代的C 1〜C 4烷基，C 1 可以被取代的C 1-4烷氧基或类似物）或其盐。所述三偶氮化合物或其盐提供了黑色墨水的着色剂化合物及其油墨组合物，其中以水为主要成分的介质中它们具有高溶解度，即使长时间储存，其浓度高的水溶液和油墨也是稳定的时间段，印刷图像具有非常高的密度，即使在高浓度溶液下印刷图像也不会导致烫伤，并且它们具有耐光性优异的黑色记录图像，特别是耐光牢度和耐臭氧气体牢度。

24. 发明授权

US08815998B2 Modified natural rubber, production process for the same and rubber composition and tire prepared by using the same 有权
标题翻译：改性天然橡胶，生产工艺相同，橡胶组成和使用轮胎制备的轮胎
公开(公告)号：US08815998B2
公开(公告)日：2014-08-26
申请号：US13128429
申请日：2009-11-10
申请人： Takahiko Matsui
发明人： Takahiko Matsui
IPC分类号： C08L15/00 , C08C19/44 , C07C17/06
CPC分类号： C08C1/04 , B60C1/0016 , C08C1/02 , C08C19/38 , C08K3/013 , C08L15/00
摘要： After hydrolyzing a phospholipid bonded to a molecular end of a natural rubber, a compound having a polar group reacting with a hydroxyl group is condensed with a hydroxyl group contained in the phospholipid-hydrolyzed natural rubber to thereby obtain a modified natural rubber in which a polar group is present at a molecular end. The modified natural rubber thus obtained in which a polar group is present at a molecular end is used for a rubber component of a rubber composition, whereby a rubber composition in which carbon black and silica as fillers are bonded to the rubber component to enhance a reinforcing effect and which is excellent in a low hysteresis loss property and abrasion resistance to a large extent is obtained. An enzyme or an alkali is used for hydrolyzing the phospholipid, and a condensing agent is used for condensing the polar group-containing compound.
摘要翻译：在与天然橡胶的分子末端结合的磷脂水解后，将具有与羟基反应的极性基团的化合物与磷脂水解天然橡胶中所含的羟基缩合，得到极性的改性天然橡胶基团存在于分子末端。橡胶组合物的橡胶组分使用由此获得的极性基团在分子末端存在的改性天然橡胶，由此将作为填料的炭黑和二氧化硅作为填料的橡胶组合物结合到橡胶组分以增强强化并且获得了在很大程度上具有优异的低磁滞损耗特性和耐磨性。酶或碱用于水解磷脂，并使用缩合剂冷凝含极性基团的化合物。

25. 发明申请

US20130288019A1 INK COMPOSITION, INKJET RECORDING METHOD, AND COLORED MATERIAL 失效
标题翻译：墨水组合物，喷墨记录方法和彩色材料
公开(公告)号：US20130288019A1
公开(公告)日：2013-10-31
申请号：US13806956
申请日：2011-06-24
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/00
CPC分类号： C09D11/328 , B41M5/5218 , C09B31/28 , C09B31/30 , C09B35/56 , C09B43/16 , C09B67/0055
摘要： An aqueous black ink composition which enables the formation of an excellent black recorded image having extremely high ozone gas resistance and a neutral and achromatic color. The ink composition comprises: a dye which includes at least one compound represented by specific formula (1) or at least one tautomer or salt of the compound; a dye which includes at least one compound represented by specific formula (3) or at least one tautomer or salt of the compound; and a dye which includes at least one compound represented by specific formula (4) or at least one tautomer or salt of the compound.
摘要翻译：一种黑色油墨组合物，其能够形成具有极高的耐臭氧气体性和中性和无色性的优异的黑色记录图像。油墨组合物包含：包含至少一种由特定式（1）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 包含至少一种由特定式（3）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 和包含至少一种由特定式（4）表示的化合物或该化合物的至少一种互变异构体或盐的染料。

26. 发明申请

US20130101811A1 INK COMPOSITION, INKJET RECORDING METHOD AND COLORED BODY 有权
标题翻译：墨水组合物，喷墨记录方法和彩色体
公开(公告)号：US20130101811A1
公开(公告)日：2013-04-25
申请号：US13806981
申请日：2011-06-27
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D7/12
CPC分类号： C09D7/63 , B41M5/5218 , C09B67/0046 , C09B67/0055 , C09D11/17 , C09D11/328 , Y10T428/24802
摘要： A water-based black ink composition which exhibits a low intensity, colorless and neutral black color and provides a black recorded image the printed image of which has high density. The ink composition includes at least one compound represented by formula (1) or a salt thereof and an azo compound having λmax within the range of 550-660 nm. In the formula (1), R1 to R8 independently represent a hydrogen atom; a halogen atom; a sulfo group; a carboxy group; a sulfamoyl group; a carbamoyl group; a C1-C4 alykyl group; a C1-C4 alkoxy group; and a C1-C4 alkoxy group substituted with at least one group selected from a group consisting of a hydroxy group, a C1-C4 alkoxy group, a hydroxy C1-C4 alkoxy group, a sulfo group and a carboxy group. X represents a bivalent cross-linking group.
摘要翻译：一种水性黑色油墨组合物，其具有低强度，无色和中性黑色，并提供其印刷图像具有高密度的黑色记录图像。油墨组合物包含至少一种由式（1）表示的化合物或其盐和具有550-660nm范围内的兰姆巴的偶氮化合物。式（1）中，R 1〜R 8分别独立地表示氢原子。卤素原子; 磺基; 羧基; 氨磺酰基; 氨基甲酰基; C1-C4烷基; C1-C4烷氧基; 被选自羟基，C1-C4烷氧基，羟基C1-C4烷氧基，磺基和羧基中的至少一个基团取代的C1-C4烷氧基。 X表示二价交联基团。

27. 发明授权

US07901498B2 Trisazo compound, ink composition, printing method and colored product 有权
标题翻译：三唑烷化合物，油墨组合物，印刷方法和有色产品
公开(公告)号：US07901498B2
公开(公告)日：2011-03-08
申请号：US12734655
申请日：2008-11-25
申请人： Koji Hirota , Takahiko Matsui , Takashi Yoshimoto , Shinsuke Shimizu
发明人： Koji Hirota , Takahiko Matsui , Takashi Yoshimoto , Shinsuke Shimizu
IPC分类号： C09D11/02 , C09B31/16
CPC分类号： C07D471/04 , B41M5/0023 , C09B31/28 , C09D11/328
摘要： The present invention relates to a trisazo compound represented by the following formula (1): wherein, n represents 0 or 1, the group A represents a substituted heterocyclic group, R1 represents a C1-C4 alkyl group which may be substituted or the like, R2 represents a cyano group or the like, R3 and R4 each independently represent a hydrogen atom, a sulfo group or the like, R5 to R7 each independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, a C1-C4 alkoxy group which may be substituted or the like, respectively or salt thereof. Said trisazo compound or salt thereof provides a coloring matter compound for black ink and an ink composition thereof where they have high solubility in medium where water is a principal component, their aqueous solution and ink having high concentration is stable even when stored for a long period of time, printed images therewith have very high density, no bronzing is caused on the images printed even with their high concentration solution, and they give black recorded images excellent in fastness, particularly in both light fastness and ozone gas fastness.
摘要翻译：本发明涉及由下式（1）表示的三偶氮化合物：其中，n表示0或1，A组代表取代的杂环基，R 1表示可被取代的C 1 -C 4烷基等， R2表示氰基等，R3和R4各自独立地表示氢原子，磺基等，R5〜R7各自独立地表示氢原子，可以被取代的C1-C4烷基，C1- 分别为可被取代的C 4烷氧基或类似物或其盐。所述三偶氮化合物或其盐提供黑色墨水的着色剂化合物及其油墨组合物，其中以水为主要成分的介质中具有高溶解性，即使长期储存，其浓度高的水溶液和油墨也是稳定的的时间，印刷图像具有非常高的密度，即使在高浓度溶液下印刷的图像也不会导致烫伤，并且它们给出耐光性优异的黑色记录图像，特别是耐光牢度和耐臭氧气体牢度。

28. 发明申请

US20090062545A1 Trisazo Compound, Ink Composition, Recording Method, and Colored Article 有权
标题翻译：三唑类化合物，油墨组合物，记录方法和彩色制品
公开(公告)号：US20090062545A1
公开(公告)日：2009-03-05
申请号：US12087426
申请日：2006-12-28
申请人： Takahiko Matsui , Yoshiyuki Dejima , Takashi Yoshimoto , Ryoutarou Morita , Koji Hirota
发明人： Takahiko Matsui , Yoshiyuki Dejima , Takashi Yoshimoto , Ryoutarou Morita , Koji Hirota
IPC分类号： C07D471/04 , B05D5/00 , C09D11/02
CPC分类号： C07D471/04 , C09B31/28 , C09D11/17 , C09D11/328
摘要： The present invention relates to a trisazo compound represented by the following formula (1) or a salt thereof,The formula (1) (wherein, the group A is a substituted phenyl group, the group B and the group C are substituted para-phenylene groups, R1 represents a C1 to C4 alkyl group (which may be substituted by a carboxy group), a phenyl group (which may be substituted by a sulfo group), or a carboxy group, R2 represents a cyano group, a carbamoyl group or a carboxy group, each of R3 and R4 independently represents a hydrogen atom, a methyl group, a chlorine atom or a sulfo group, respectively) and a water-based black ink composition containing said compound; said compound has high solubility in a medium where the main component is water, its aqueous solution having a high concentration and ink are stable when stored for a long period of time, black-recorded images with it can be provided where both light fastness and ozone gas fastness of the printed images are excellent.
摘要翻译：本发明涉及由下式（1）表示的三偶氮化合物或其盐。式（1）（其中A为取代苯基，B为基团，C为取代对亚苯基基团，R 1表示C 1〜C 4烷基（可以被羧基取代），苯基（可以被磺基取代）或羧基，R 2表示氰基，氨基甲酰基或羧基，R 3和R 4分别独立地表示氢原子，甲基，氯原子或磺基）和含有所述化合物的水性黑色油墨组合物; 所述化合物在主要成分为水的介质中具有高溶解度，其浓度高的水溶液和长时间储存时的油墨稳定，可以提供具有耐光性和臭氧性的黑色记录图像印刷图像的耐气牢度优异。

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