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    • 26. 发明授权
    • Novel herbicidally active n-phenyl-azoles
    • 新型除草活性的n-苯基 - 唑类
    • US5049181A
    • 1991-09-17
    • US440007
    • 1989-11-21
    • Georg PissiotasHans MoserHans-Georg Brunner
    • Georg PissiotasHans MoserHans-Georg Brunner
    • A01N43/90C07D231/12C07D231/22C07D231/56C07D401/12C07D403/12C07D405/12C07D409/12C07D417/12C07D471/04C07D487/04C07D521/00
    • C07D249/08C07D231/12C07D231/56C07D233/56C07D401/12C07D403/12C07D405/12C07D409/12C07D417/12C07D471/04C07D487/04
    • The invention relates to novel phenyl substituted pyrazoles, 4,5,6,7-tetrahydro-indazoles, 2,4,5,6-tetrahydro-cyclopenta[c]pyrazoles, octahydroimidazo[1,5-a]pyridin-1,3-diones, hexahydro-1H-pyrrolo[1,2-c]-imidazol-1,3-diones, hexahydro-1H-1,2,4-triazolo[1,2-a]pyridazin-1,3-diones and tetrahydro-1H,5H-pyrazolo[1,2-a][1,2,4]triazol-1,3-diones which have phenyl-substituted in the 2-position, herbicidal activity. It furthermore relates to agrochemical compositions, which contain these compounds, to their use for controlling undesirable plant-growth and for processes for the preparation of the compounds according to this invention.The novel N-Phenyl-azoles correspond to the formula I ##STR1## R.sup.1 is hydrogen or halogen; R.sup.2 is halogen;A is a straight-chain or branched C.sub.1 -C.sub.4 -alkylene chain;n is zero or 1;Q is --S(O).sub.m --R.sup.3 ; di-C.sub.1 -C.sub.4 -alkylamino; a 5- or 6-membered heterocyclus, that is bound via a carbon or nitrogen atom and which contains 1 to 3 hetero-atoms selected from the group consisting of N, O and S, which heterocycles can be fused to a benzene ring and mono- or disubstituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -haloalkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -haloalkoxy, C.sub.1 -C.sub.3 -dialkylamino, hydroxy or carboxyl;R.sup.3 is C.sub.1 -C.sub.10 -alkyl; ##STR2## m is zero, 1 or 2; R.sup.4 is C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy;p is zero 1, 2, or 3;X is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl;Y is C.sub.1 -C.sub.4 -alkyl; orX and Y form together a --(CH.sub.2).sub.q -chain, which is optionally mono- or disubstituted by methyl;q is three or four; andZ is halogen, methyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio; under inclusion of the salts of these azoles with acids, bases and complex-building substances.
    • 本发明涉及新的苯基取代的吡唑,4,5,6,7-四氢 - 吲唑,2,4,5,6-四氢 - 环戊二烯并[c]吡唑,八氢咪唑并[1,5-a]吡啶-1,3 六氢-1H-吡咯并[1,2-c] - 咪唑-1,3-二酮,六氢-1H-1,2,4-三唑并[1,2-a]哒嗪-1,3-二酮和 四氢-1H,5H-吡唑并[1,2-a] [1,2,4]三唑-1,3-二酮,其具有2位的苯基取代,除草活性。 此外,它还涉及含有这些化合物的农药组合物,其用于控制​​不期望的植物生长和根据本发明的化合物的制备方法。 新型N-苯基 - 吡咯对应于式I(I)其中R1是氢或卤素; R2是卤素; A是直链或支链的C 1 -C 4 - 亚烷基链; n为零或1; Q是-S(O)m -R 3; 二-C 1 -C 4烷基氨基; 通过碳或氮原子结合并含有1至3个选自N,O和S的杂原子的5-或6-元杂环,该杂环可以与苯环稠合并且单 或被卤素,C 1 -C 4 - 烷基,C 1 -C 3 - 卤代烷基,C 1 -C 3 - 烷氧基,C 1 -C 3 - 卤代烷氧基,C 1 -C 3 - 二烷基氨基,羟基或羧基二取代; R3是C1-C10-烷基; m是零,1或2; R4是C1-C4-烷基,卤素或C1-C4-烷氧基; p为零1,2或3; X是氢,卤素或C 1 -C 4 - 烷基; Y是C 1 -C 4 - 烷基; 或X和Y一起形成 - (CH 2)q链,其任选被甲基单或二取代; q是三四个; Z为卤素,甲基,C 1 -C 6 - 烷氧基或C 1 -C 6 - 烷硫基; 在这些唑类的盐类与酸,碱和复合物构成物质之间。
    • 27. 发明授权
    • Herbicidally active derivatives of N-phenyl-3,4,5,6-tetrahydrophthalimide
    • N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺的除草活性衍生物
    • US4824476A
    • 1989-04-25
    • US874765
    • 1986-06-16
    • Georg PissiotasBeat Bohner
    • Georg PissiotasBeat Bohner
    • A01N37/32A01N37/36A01N37/50A01N41/08A01N43/28A01N43/32A01N53/04C07D209/48C07D405/10C07D405/12C07D409/12A01N43/38
    • C07D209/48A01N37/32A01N37/36A01N37/50A01N41/08A01N43/28A01N43/32C07D405/10C07D405/12C07D409/12
    • Novel derivatives of N-phenyl-3,4,5,6-tetrahydrophthalimide of the formula I given below have good pre- and post-emergence, selective-herbicidal properties, and they furthermore regulate and inhibit plant growth. The compounds correspond to the formula I ##STR1## wherein R is C.sub.1 -C.sub.3 -alkyl,n is zero, one or two,R.sub.1 and R.sub.2 independently of one another are each hydrogen or halogen,R.sub.3 l is hydrogen, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl or a radical --CH.sub.2 YR.sub.4,R.sub.4 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkynyl, C.sub.3 -C.sub.7 -cycloalkyl, benzyl or phenyl,Z is oxygen, or an oxime radical .dbd.N--O--Q, and the grouping --C(R.sub.3).dbd.Z can also be a ketal radical, andQ is hydrogen, a C.sub.1 -C.sub.10 -alkyl radical, a C.sub.3 -C.sub.8 -alkenyl radical or a C.sub.3 -C.sub.8 -alkynyl radical, a C.sub.3 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.7 -cycloalkenyl radical, a phenyl-C.sub.1 -C.sub.4 -alkyl group, a carbamoyl radical, a carbonic or thiocarbonic acid radical, a C.sub.1 -C.sub.4 -alkylsulfonyl radical, a metal ion or a quaternized ammonium ion.
    • 下面给出的式I的N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺的新型衍生物具有良好的芽前和芽后,选择性除草性质,并且它们进一步调节和抑制植物生长。 化合物对应于式I(I)其中R是C 1 -C 3 - 烷基,n是0,1或2,R 1和R 2彼此独立地是氢或卤素,R 3是氢,氰基, C 1 -C 4 - 烷基,C 1 -C 4卤代烷基或基团-CH 2 YR 4,R 4是C 1 -C 4 - 烷基,C 3 -C 4 - 烯基,C 3 -C 4炔基,C 3 -C 7 - 环烷基,苄基或苯基,Z是氧 ,或肟基= NOQ,并且基团-C(R 3)= Z也可以是缩酮基,Q是氢,C 1 -C 10 - 烷基,C 3 -C 8 - 烯基或C 3 -C 8 - 炔基,C 3 -C 7 - 环烷基或C 3 -C 7 - 环烯基,苯基-C 1 -C 4 - 烷基,氨基甲酰基,碳或硫代碳酸基,C 1 -C 4烷基磺酰基,金属离子 或季铵化铵离子。