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21. 发明授权

US5141976A Mixtures of polyarylene sulphides, nitroarylmethylidene ketones, glass fibers and optionally other fillers 失效
标题翻译：聚氨酯硫化物，硝基甲基纤维酮，玻璃纤维和可选择的其他填料的混合物
公开(公告)号：US5141976A
公开(公告)日：1992-08-25
申请号：US740116
申请日：1991-08-05
申请人： Burkhard Kohler , Wolfgang Russeler , Joachim Doring , Hans-Detlef Heinz
发明人： Burkhard Kohler , Wolfgang Russeler , Joachim Doring , Hans-Detlef Heinz
IPC分类号： C08K5/32 , C08K7/14 , C08K9/04 , C08L81/02 , H05K1/03
CPC分类号： C08K5/32 , C08K7/14 , H05K1/0333 , H05K1/0373
摘要： This invention relates to mixtures of polyarylene sulphides, nitroarylmethylidene ketones, glass fibers and optionally other fillers. The mixtures are distinguished by good mechanical properties.
摘要翻译：本发明涉及聚亚芳基硫醚，硝基芳基亚甲基酮，玻璃纤维和任选的其它填料的混合物。混合物的特征在于良好的机械性能。

22. 发明授权

US5102929A Mixtures of polyarylene sulphides, glass fibres and heterocyclic nitroaryloxy compounds 失效
标题翻译：聚苯硫醚，玻璃纤维和杂环硝基化合物的混合物
公开(公告)号：US5102929A
公开(公告)日：1992-04-07
申请号：US667341
申请日：1991-03-11
申请人： Burkhard Kohler , Walter Uerdingen , Klaus Kraft , Hans-Detlef Heinz , Wolfgang Wehnert
发明人： Burkhard Kohler , Walter Uerdingen , Klaus Kraft , Hans-Detlef Heinz , Wolfgang Wehnert
IPC分类号： C08K5/32 , C08K5/34 , C08K5/3492 , C08K5/35 , C08K5/46 , C08K5/47 , C08L81/02
CPC分类号： C08K5/35 , C08K5/3492 , C08K5/47
摘要： The invention relates to mixtures of polyarylene sulphides, heterocyclic nitryoaryloxy compounds and optionally other additives. The mixtures are distinguished by good mechanical properties.
摘要翻译：本发明涉及聚亚芳基硫醚，杂环氮杂芳氧基化合物和任选的其它添加剂的混合物。混合物的特征在于良好的机械性能。

23. 发明授权

US5264479A Lactam melts having increased viscosity and their use 失效
标题翻译：内酰胺熔化粘度增加及其用途
公开(公告)号：US5264479A
公开(公告)日：1993-11-23
申请号：US49640
申请日：1993-04-20
申请人： Hans-Detlef Heinz , Friedrich Fahnler
发明人： Hans-Detlef Heinz , Friedrich Fahnler
IPC分类号： C08L77/00 , C08L77/02 , C08F212/34 , C07D223/10 , C07D225/02
CPC分类号： C08L77/02 , C08L77/00
摘要： The invention relates to lactam mixtures which give lactam melts having increased viscosity, to their production and to their use, preferably in the activated anionic polymerization of lactams (to cast polyamides). According to the invention, certain unsaturated aromatic vinyl compound/diene block copolymers (B) which dissolve in the lactam melt are added to the lactam (melt)s (A) in quantities of 1 to 15% by weight, a component (C) which is compatible with the diene block copolymers (B) and which dissolves completely or partly in the lactam melt optionally being added as an additional component. The block copolymers (B) used contain 10 to 85% by weight aromatic vinyl units and 15 to 90% by weight diene units. The block copolymers (B) may even be partly hydrogenated, epoxidized or grafted.The preferred lactam is .epsilon.-caprolactam.Lactam melts of increased viscosity are particularly suitable for taking up reinforcing materials and fillers (D) and for the production of filled cast polyamides.The invention also relates to the use of lactam melts thus thickened, more particularly lactam melts containing fillers/reinforcing materials, in a process for the production of polyamides and also to corresponding polyamide moldings, more particularly by the anionically activated casting process.
摘要翻译：本发明涉及内酰胺混合物，该内酰胺混合物具有增加的粘度，其生产和使用的内酰胺熔体，优选在内酰胺（至浇铸聚酰胺）的活化的阴离子聚合中。根据本发明，将溶解在内酰胺熔体中的某些不饱和芳香族乙烯基化合物/二烯嵌段共聚物（B）以1〜15重量％的量添加到内酰胺（熔融体）（A）中，成分（C）其与二烯嵌段共聚物（B）相容并且完全或部分地溶解在内酰胺熔体中，任选地作为另外的组分加入。使用的嵌段共聚物（B）含有10至85重量％的芳族乙烯基单元和15至90重量％的二烯单元。嵌段共聚物（B）甚至可以部分氢化，环氧化或接枝。优选的内酰胺是ε-己内酰胺。增加粘度的内酰胺熔体特别适用于吸收增强材料和填料（D）和用于生产填充浇铸聚酰胺。本发明还涉及在制备聚酰胺的方法中以及相应的聚酰胺模制品，特别是阴离子活化的浇铸方法中使用由此增稠的内酰胺熔体，更特别是含有填料/增强材料的内酰胺熔体。

24. 发明授权

US5219908A PAS with reduced flash formation and good mechanical properties 失效
标题翻译： PAS具有减少的闪蒸形成和良好的机械性能
公开(公告)号：US5219908A
公开(公告)日：1993-06-15
申请号：US836400
申请日：1992-02-18
申请人： Burkhard Kohler , Bahman Sarabi , Sabine Dorf , Hans-Detlef Heinz , Friedrich Jonas
发明人： Burkhard Kohler , Bahman Sarabi , Sabine Dorf , Hans-Detlef Heinz , Friedrich Jonas
IPC分类号： C08K3/00 , C08K5/32 , C08K5/41 , C08L25/18 , C08L61/06 , C08L81/02 , H05K1/03
CPC分类号： C08L81/02 , C08L25/18 , C08L61/06 , H05K1/0333 , H05K1/0373
摘要： This invention relates to polyarylene sulphides (PAS) containing certain nitro compounds with reduced flash formation.
摘要翻译：本发明涉及含有某些具有减少闪蒸形成的硝基化合物的聚亚芳基硫醚（PAS）。

25. 发明授权

US5128401A Polyamide molding compounds 失效
标题翻译：聚酰胺模塑化合物
公开(公告)号：US5128401A
公开(公告)日：1992-07-07
申请号：US642877
申请日：1991-01-18
申请人： Hans-Detlef Heinz , Aziz El-Sayed , Werner Kloker , Ralf Dujardin
发明人： Hans-Detlef Heinz , Aziz El-Sayed , Werner Kloker , Ralf Dujardin
IPC分类号： C08K5/13 , C08L77/00 , C08L81/02 , D01F6/76 , D01F6/90
CPC分类号： C08K5/13 , C08L77/00
摘要： A polymeric molding compositon based on aliphatic polyamides contains as additives polyarylene sulfides and polyphenolic compounds free from tertiary alkyl group ortho to the phenolic-OH groups is useful in producing molded articles such as films, fibers and shaped objects.
摘要翻译：基于脂族聚酰胺的聚合物模塑组合物包含作为添加剂的聚亚芳基硫化物和不含酚-OH基团的叔烷基的多酚化合物可用于生产模制品如膜，纤维和成形物。

26. 发明授权

US5071905A Mixtures of polyarylene sulfides, glass fibers and silanes containing nitro groups 失效
标题翻译：聚氨酯硫化物，玻璃纤维和含有NITRO组的硅烷的混合物
公开(公告)号：US5071905A
公开(公告)日：1991-12-10
申请号：US603226
申请日：1990-10-25
申请人： Burkhard Kohler , Hans-Detlef Heinz , Hans-Joachim Traenckner , William Bushong
发明人： Burkhard Kohler , Hans-Detlef Heinz , Hans-Joachim Traenckner , William Bushong
IPC分类号： C08J5/04 , C08K5/544 , C08K7/14 , C08L81/02
CPC分类号： C08K5/544
摘要： The invention relates to mixtures of polyarylene sulfides, glass fibers and silanes containing nitro groups which are distinguished by good mechanical properties (for example relatively high flexural strength or outer fiber strain).
摘要翻译：本发明涉及聚亚芳基硫化物，玻璃纤维和含有硝基的硅烷的混合物，其特征在于具有良好的机械性能（例如相对高的弯曲强度或外部纤维应变）。

27. 发明授权

US5068311A High molecular weight (co)polyamide from diamino-alcohol 失效
标题翻译：来自二氨基醇的高分子量（共）聚酰胺
公开(公告)号：US5068311A
公开(公告)日：1991-11-26
申请号：US538780
申请日：1990-06-15
申请人： Klaus Horn , Hans-Detlef Heinz , Peter-Rolf Muller , Ralf Dujardin
发明人： Klaus Horn , Hans-Detlef Heinz , Peter-Rolf Muller , Ralf Dujardin
IPC分类号： C08G69/04 , C08G69/06 , C08G69/16 , C08G69/28 , C08G69/36 , C08G69/44
CPC分类号： C08G69/16 , C08G69/06 , C08G69/28 , C08G69/36
摘要： The invention relates to high molecular weight thermoplastically deformable branched aliphatic polyamides prepared by polycondensation of lactams and/or polyamide-forming diamine/dicarboxylic acid reaction mixtures and/or amino acids in the presence of small amounts of specific diamino-alcohols and approximately equivalent amounts of polycarboxylic acids (preferably dicarboxylic acids), and to a process for their preparation, which is distinguished by considerably shortened polycondensation times, without crosslinked products being formed. If appropriate, the process additionally utilizes a solid phase after-condensation, in which rapid further condensation to products which are indeed branched but are soluble in m-cresol and have an increased melt viscosity takes place.
摘要翻译：本发明涉及通过在少量特定二氨基醇存在下内酰胺和/或形成聚酰胺的二胺/二羧酸反应混合物和/或氨基酸进行缩聚而制备的高分子量热塑性可变支化脂族聚酰胺和大约等量的多元羧酸（优选二羧酸），以及它们的制备方法，其特征在于显着缩短缩聚时间，没有形成交联产物。如果合适，该方法另外使用固相缩合后，其中快速进一步冷凝到确实是支化但可溶于间甲酚并且具有增加的熔体粘度的产物。

28. 发明授权

US07211701B2 Preparation of trimethylolpropane 有权
标题翻译：三羟甲基丙烷的制备
公开(公告)号：US07211701B2
公开(公告)日：2007-05-01
申请号：US10322962
申请日：2002-12-18
申请人： Dirk Müller , Paul Wagner , Brian Schwegler , Ulrich Notheis , Ralph Armbrust , Hans-Detlef Heinz , Alexander Wagner
发明人： Dirk Müller , Paul Wagner , Brian Schwegler , Ulrich Notheis , Ralph Armbrust , Hans-Detlef Heinz , Alexander Wagner
IPC分类号： C07C31/22 , C07C29/38
CPC分类号： B01D3/141 , C07C29/38 , C07C29/80 , C07C31/22
摘要： The present invention relates to a process for preparing trimethylolpropane having a low APHA color number.
摘要翻译：本发明涉及一种具有低APHA色数的三羟甲基丙烷的制备方法。

29. 发明授权

US5286809A Thermoplastic moulding compounds 失效
标题翻译：热塑性模塑料
公开(公告)号：US5286809A
公开(公告)日：1994-02-15
申请号：US803616
申请日：1991-12-09
申请人： Hans-Detlef Heinz , Burkhard Kohler
发明人： Hans-Detlef Heinz , Burkhard Kohler
IPC分类号： C08G75/02 , C08G75/06 , C08L67/00 , C08L67/02 , C08L77/00 , C08L81/02 , C08F283/04
CPC分类号： C08L81/02 , C08L67/00 , C08L77/00
摘要： This invention relates to thermoplastic moulding compounds based on polyamides and/or polyesters and special functionally modified polyarylene sulphides and optionally conventional additives and to their preparation and their use.
摘要翻译：本发明涉及基于聚酰胺和/或聚酯和特定的官能改性的聚亚芳基硫醚和任选的常规添加剂的热塑性模塑组合物的制备及其用途。

30. 发明授权

US5250619A Process for the preparation of high molecular weight polyamides 失效
标题翻译：制备高分子量聚酰胺的方法
公开(公告)号：US5250619A
公开(公告)日：1993-10-05
申请号：US553261
申请日：1990-07-16
申请人： Hans-Detlef Heinz , Helmut Schulte , Hans-Josef Buysch
发明人： Hans-Detlef Heinz , Helmut Schulte , Hans-Josef Buysch
IPC分类号： C08J3/12 , C08G69/16 , C08G69/20 , C08G69/30 , C08G69/36 , C08G69/46 , C08K5/524 , C08K7/02 , C08L77/00 , D01F6/60
CPC分类号： C08G69/30
摘要： This invention relates to a process for the preparation of particulate, high molecular weight polyamides, to the particulate, high molecular weight polyamides prepared by this process, to the use of these polyamides for the production of moulded bodies, especially by extrusion or blow moulding, and to the articles produced from the polyamides according to the invention. The process is characterized in that polyamides are mixed with concentrates of certain compounds containing phosphorus and worked up into granulates and these granulates are converted into high molecular weight products by solid phase after-condensation.
摘要翻译：本发明涉及一种通过该方法制备的颗粒状高分子量聚酰胺与通过该方法制备的颗粒状高分子量聚酰胺的方法，涉及使用这些聚酰胺来生产成型体，特别是通过挤出或吹塑成型，以及由根据本发明的聚酰胺生产的制品。该方法的特征在于将聚酰胺与某些含磷化合物的浓缩物混合并处理成颗粒，并将这些颗粒通过固相冷凝后转化为高分子量产物。

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