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21. 发明授权

US4857616A Process for the preparation of polychloroprene 失效
标题翻译：制备聚氯丁二烯的方法
公开(公告)号：US4857616A
公开(公告)日：1989-08-15
申请号：US154936
申请日：1988-02-11
申请人： Rudiger Musch , Eberhard Muller , Gerhard Hohmann , Karl-Heinz Schabel
发明人： Rudiger Musch , Eberhard Muller , Gerhard Hohmann , Karl-Heinz Schabel
IPC分类号： C08F6/14 , C08C19/08 , C08F2/26 , C08F2/38 , C08F4/30 , C08F4/40 , C08F6/06 , C08F36/18
CPC分类号： C08C19/08 , C08F36/18
摘要： Storage-stable polychloroprene is obtained, by aqueous emulsion polymerization, using xanthogen disulphides as molecular weight regulators, when a peptizing agent is added after the end of the polymerization.
摘要翻译：当聚合结束后加入胶溶剂时，通过水乳液聚合获得储存稳定的聚氯丁二烯，使用黄原酸二硫化物作为分子量调节剂。

22. 发明授权

US4485216A Polychloroprene mixtures and the use thereof 失效
标题翻译：聚氯丁二烯混合物及其用途
公开(公告)号：US4485216A
公开(公告)日：1984-11-27
申请号：US529389
申请日：1983-09-06
申请人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Eberhard Muller
发明人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Eberhard Muller
IPC分类号： C08L33/00 , C08L7/00 , C08L11/00 , C08L21/00 , C08L33/04 , C08L27/22
CPC分类号： C08L11/00 , C08L2205/02
摘要： Solid polychloroprene mixtures consisting of sol and gel polymer, wherein the sol component consists of a copolymer of chloroprene and from 0.75 to 0.32% by weight of sulphur, based on the total quantity of unsaturated compounds of the sol polychloroprene, and the gel component consists of a copolymer of chloroprene, from 0.4 to 1.0% by weight of sulphur, based on the total quantity of unsaturated compounds of the gel polychloroprene and from 7.5.times.10.sup.-3 to 3.0.times.10.sup.-2 mols, based on 100 g of the total quantity of monomer of the gel polychloroprene, of a compound corresponding to the general formula ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or C.sub.1 -C.sub.4 alkyl group, and X represents a C.sub.2 -C.sub.10 alkylene group,are suitable for the production by extrusion and by calandering of rubber articles which may be subjected to high strains.
摘要翻译：由溶胶和凝胶聚合物组成的固体聚氯丁二烯混合物，其中溶胶组分由氯丁二烯和0.75至0.32重量％硫的共聚物组成，基于溶胶聚氯丁二烯的不饱和化合物的总量，凝胶组分由基于凝胶聚氯丁二烯的不饱和化合物的总量和基于100g单体总量的7.5×10 -3至3.0×10 -2摩尔的氯丁二烯共聚物，为0.4至1.0重量％的硫的凝胶聚氯丁二烯，其通式为：其中R1和R2各自表示氢原子或C1-C4烷基，X代表C2-C10亚烷基，适用于通过挤出和通过压缩可能经受高应变的橡胶制品。

23. 发明授权

US4482676A Production of sulfur-modified solid chloroprene rubbers 失效
标题翻译：生产硫改性固体氯丁橡胶
公开(公告)号：US4482676A
公开(公告)日：1984-11-13
申请号：US473697
申请日：1983-03-09
申请人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
发明人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
IPC分类号： C08F2/00 , C08F2/22 , C08F2/44 , C08F36/00 , C08F36/18 , C08L11/00 , C08L21/00 , C08L11/02
CPC分类号： C08F36/18 , C08L11/02 , C08L2205/02
摘要： Vulcanizable, elastomeric chloroprene/sulfur copolymers having viscosities of from 60 to 35 ME, strengths of greater than 20 MPa and sulfur contents of from about 0.3 to 0.45% by weight are obtained by polymerizing chloroprene in the presence of from 0.05 to 0.40% by weight of sulfur to form a latex I, polymerizing chloroprene in the presence of from 0.5 to 1.5% by weight of sulfur to form a latex II, mixing latices I and II, optionally together with other sulfur-modified polychloroprene latices, in a ratio of from 4:1 to 1:4 (based in each case on solids) and peptizing the mixture, followed by working up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要翻译：通过在0.05至0.40重量％的存在下聚合氯丁二烯，可获得粘度为60至35MW，强度大于20MPa，硫含量为约0.3至0.45重量％的可硫化的弹性体氯丁二烯/硫共聚物的硫以形成胶乳I，在0.5至1.5重量％的硫存在下聚合氯丁二烯以形成胶乳II，任选地将胶乳I和II与其它硫改性的聚氯丁二烯胶乳混合，其比例为 4：1至1：4（基于每种情况下为固体）和胶体化混合物，然后加工形成固体橡胶，所引用的百分比基于单体的量。

24. 发明授权

US4452947A Process for the production of sulphur-modified solid chloroprene rubbers 失效
标题翻译：生产硫改性固体氯丁橡胶的方法
公开(公告)号：US4452947A
公开(公告)日：1984-06-05
申请号：US496413
申请日：1983-05-20
申请人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
发明人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
IPC分类号： C08L7/00 , C08C1/00 , C08C19/08 , C08F2/00 , C08F2/44 , C08F8/50 , C08F36/00 , C08F36/18 , C08K3/00 , C08L11/00 , C08L21/00 , C08F8/00
CPC分类号： C08F36/18 , C08L11/02 , C08L2205/02
摘要： Vulcanisable, elastomeric chloroprene-sulphur copolymers having viscosities of from 60 to 35 MU, strengths of >20 MPa and sulphur contents of from about 0.5 to 0.7%, by weight, in the batch are obtained by polymerising chloroprene in the presence of from 0.10 to 0.35%, by weight, of sulphur to form a latex I, polymerising chloroprene in the presence of from 0.50 to 1.00% by weight, of sulphur to form a latex II, mixing latices I and II in a ratio of from 4:1 to 1:4 (based in each case on solids), optionally together with other sulphur-modified polychloroprene latices, the mixture is peptised and worked-up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要翻译：通过将氯丁二烯在0.10〜0.1重量％的存在下聚合，得到批次中粘度为60〜35MW，强度> 20MPa，硫含量为约0.5〜0.7％的可硫化弹性体氯丁二烯 - 硫共聚物 0.35重量％的硫以形成胶乳I，在0.50至1.00重量％的硫存在下聚合氯丁二烯以形成胶乳II，将胶乳I和II以4:1至4:1的比例混合 1：4（基于固体的每种情况），任选地与其它硫改性的聚氯丁二烯胶乳一起，对混合物进行胶溶和后处理以形成固体橡胶，所引用的百分比是基于单体的量。

25. 发明申请

US20060069196A1 AQUEOUS COMPOSITIONS BASED ON POLYCHLOROPRENE 有权
标题翻译：基于聚氯乙烯的水性组合物
公开(公告)号：US20060069196A1
公开(公告)日：2006-03-30
申请号：US10856916
申请日：2004-05-28
申请人： Stefan Grabowski , Volker Wege , Rudiger Musch , Knut Panskus , Thiemo Marx
发明人： Stefan Grabowski , Volker Wege , Rudiger Musch , Knut Panskus , Thiemo Marx
IPC分类号： C08K3/22
CPC分类号： B82Y30/00 , C01P2004/64 , C08K3/22 , C08L11/00 , C08L61/04 , C08L2666/14 , C09C1/043 , C09J11/04 , C09J111/00 , C08L11/02 , C08L2666/16
摘要： Water-containing compositions containing polychloroprene particles, zinc oxide particles having an average particle size of less than 150 nm and water. The compositions can be used as adhesives and/or sealants.
摘要翻译：含有聚氯丁二烯颗粒的含水组合物，平均粒径小于150nm的氧化锌颗粒和水。组合物可用作粘合剂和/或密封剂。

26. 发明申请

US20050143498A1 Aqueous adhesive dispersions 有权
标题翻译：水性粘合剂分散体
公开(公告)号：US20050143498A1
公开(公告)日：2005-06-30
申请号：US10825934
申请日：2004-04-16
申请人： Rudiger Musch , Christiane Oppenheimer-Stix , Knut Panskus , Renke Mottweiler , Norbert Schildan
发明人： Rudiger Musch , Christiane Oppenheimer-Stix , Knut Panskus , Renke Mottweiler , Norbert Schildan
IPC分类号： C09J11/04 , C08C1/02 , C08F6/14 , C08F36/18 , C09J11/08 , C09J111/00 , C09J111/02 , C08L3/00
CPC分类号： C09J111/02 , C08C1/02 , C08F36/18
摘要： Aqueous polymer dispersions based on polychloroprene, a process for their preparation and their use in adhesive formulations. The aqueous polymer dispersion is obtained by a) preparing an aqueous polychloroprene dispersion with a gel content of 0.1 wt. %-30 wt. %, based on the polymer, prepared by polymerization at 0° C.-70° C. of chloroprene and, optionally, ethylenically unsaturated monomers which can be copolymerized with chloroprene and b) subsequently storing the dispersion at temperatures of from 50° C.-110° C. until the gel content has risen by at least 10 wt. % to 1-60 wt. %, based on the polymer.
摘要翻译：基于聚氯丁二烯的聚合物水分散体，其制备方法及其在粘合剂配方中的应用。聚合物水分散体是通过以下步骤获得的：a）制备凝胶含量为0.1wt。％-30wt。％，基于聚合物，其通过在0℃-70℃下聚合氯丁二烯和任选的可与氯丁二烯共聚的烯属不饱和单体制备，和b）随后在50℃的温度下储存分散体 -110℃，直到凝胶含量增加至少10wt。％至1-60重量％％，基于聚合物。

27. 发明申请

US20050131109A1 Aqueous adhesive dispersions 有权
标题翻译：水性粘合剂分散体
公开(公告)号：US20050131109A1
公开(公告)日：2005-06-16
申请号：US10939803
申请日：2004-09-13
申请人： Wolfgang Arndt , Rudiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
发明人： Wolfgang Arndt , Rudiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
IPC分类号： C08G18/70 , C08K3/34 , C08K3/20
CPC分类号： C08G18/706 , C08G2170/80
摘要： An aqueous polymer dispersion that includes a) a polyurethane dispersion having an average particle size of 60 to 350 nm and b) an aqueous silicon dioxide dispersion having a particle diameter of the SiO2 particles of 20 to 400 nm. The dispersion is prepared by mixing the polyurethane dispersion (a) with the silicon dioxide dispersion (b). The aqueous polymer dispersion can be used in adhesive compositions, which can be used to bond substrates together, especially substrates that are structural components of shoes.
摘要翻译：一种含水聚合物分散体，其包括a）平均粒径为60至350nm的聚氨酯分散体和b）具有20-400nm的SiO 2颗粒的粒径的二氧化硅水分散体。通过将聚氨酯分散体（a）与二氧化硅分散体（b）混合来制备分散体。聚合物水分散体可用于粘合剂组合物中，粘合剂组合物可用于将基材粘合在一起，特别是作为鞋结构部件的基材。

28. 发明授权

US5889123A Polymer compounds and their use for the vulcanization of halogenated butyl rubbers with a low halogen content 失效
标题翻译：高分子化合物及其用于硫化卤素含量低的卤化丁基橡胶的用途
公开(公告)号：US5889123A
公开(公告)日：1999-03-30
申请号：US939423
申请日：1997-09-29
申请人： Rudiger Schubart , Rudiger Musch , Anthony Sumner , Stefan Kelbch
发明人： Rudiger Schubart , Rudiger Musch , Anthony Sumner , Stefan Kelbch
IPC分类号： C08J3/24 , B60C1/00 , C08K5/00 , C08K5/29 , C08K5/3442 , C08K5/378 , C08L21/00 , C08L23/28 , C08F14/00
CPC分类号： C08K5/3442 , B60C1/0008 , C08K5/0008 , C08K5/29 , C08L21/00 , C08L23/283
摘要： Compositions comprising new halogenated butyl rubbers with a defined, low content of halogen, a defined content of non-halogenated double bonds and a defined content of anti-agglomeration/vulcanisation control agents and containing polymer compounds comprising special amidines, mercapto or zinc mercapto compounds and polymers possess outstanding mechanical and physiological properties, so that they are suitable for the production of tyres, particularly tyre inner liners, tyre sidewalls and tyre treads.
摘要翻译：组合物包含具有限定的低含量卤素，定义的非卤化双键含量的新卤化丁基橡胶和限定含量的抗附聚/硫化控制剂并含有包含特殊脒基，巯基或锌巯基化合物的聚合物化合物和聚合物具有突出的机械和生理特性，因此它们适用于生产轮胎，特别是轮胎内衬，轮胎侧壁和轮胎胎面。

29. 发明授权

US5210152A Process for the vulcanization of polychloroprene 失效
标题翻译：聚氯乙烯聚合方法
公开(公告)号：US5210152A
公开(公告)日：1993-05-11
申请号：US624967
申请日：1990-12-10
申请人： Rudiger Musch , Rudiger Schubart
发明人： Rudiger Musch , Rudiger Schubart
IPC分类号： C08J3/24 , C08C19/30 , C08F8/00 , C08K5/29 , C08K5/3442 , C08L11/00 , C08L21/00
CPC分类号： C08K5/29 , C08K5/3442
摘要： The metal oxide vulcanization of polychloroprene in the presence of amidine compounds, but in the absence of magnesium oxide, leads to vulcanizates which are capable of withstanding high temperatures, even under dynamic stress.
摘要翻译：在脒化合物存在下，聚氯丁二烯的金属氧化物硫化，但是在不存在氧化镁的情况下，即使在动态应力下也能耐受高温的硫化胶。

30. 发明授权

US5187232A Rubber compounds of polychloroprene and hydrogenated nitrile rubber 失效
标题翻译：聚氯乙烯和氢化硅橡胶的橡胶化合物
公开(公告)号：US5187232A
公开(公告)日：1993-02-16
申请号：US594624
申请日：1990-10-09
申请人： Rudiger Musch , Joachim Thormer , Hartmuth Buding , Friedrich Leibbrandt
发明人： Rudiger Musch , Joachim Thormer , Hartmuth Buding , Friedrich Leibbrandt
IPC分类号： C08L11/00 , C08L15/00 , C08L21/00
CPC分类号： C08L11/00 , C08L15/005
摘要： Mixtures of polychloroprene and hydrogenated nitrile rubber give vulcanizates combining high modulus with a high dynamic stress absorption capacity.
摘要翻译：聚氯丁二烯和氢化丁腈橡胶的混合物得到结合高模量和高动态应力吸收能力的硫化胶。

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