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21. 发明授权

US07321014B2 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US07321014B2
公开(公告)日：2008-01-22
申请号：US11025249
申请日：2004-12-29
申请人： Katherine Glasgow , Brian Mullen , Paul D. Sybert
发明人： Katherine Glasgow , Brian Mullen , Paul D. Sybert
IPC分类号： C08L69/00 , C08L83/10
CPC分类号： C08L83/10 , C08G63/64 , C08G77/445 , C08G77/448
摘要： A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.
摘要翻译：公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。还公开了形成由组合物形成的组合物和制品的方法。

22. 发明申请

US20050004406A1 Process for the synthesis of bisphenol 有权
标题翻译：合成双酚的方法
公开(公告)号：US20050004406A1
公开(公告)日：2005-01-06
申请号：US10612101
申请日：2003-07-01
申请人： Brian Carvill , Katherine Glasgow , Michael Roland
发明人： Brian Carvill , Katherine Glasgow , Michael Roland
IPC分类号： C07C37/20 , C07C39/16 , C08G64/20 , C07C29/10 , C07C35/04
CPC分类号： C07C37/20 , C08G64/20 , C07C39/16
摘要： A process for the production of a bisphenol comprises reacting a feed comprising a phenol, a ketone and water in the presence of an ion exchange resin catalyst to produce an effluent; determining the para-para bisphenol selectivity of the reaction; and adjusting the concentration of the water in the feed based upon the para-para bisphenol selectivity in the effluent.
摘要翻译：制备双酚的方法包括在离子交换树脂催化剂存在下使包含苯酚，酮和水的进料反应以产生流出物; 确定反应的对位双酚选择性; 并且基于流出物中对位双酚选择性调节进料中的水的浓度。

23. 发明授权

US07812078B2 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US07812078B2
公开(公告)日：2010-10-12
申请号：US11263325
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： C08K5/42
CPC分类号： C08J3/226 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprises a polycarbonate, and an aromatic sulfonate compound of formula (Y)m—Ar—(Z—S(O)2—X)n wherein each X is independently a substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C1-C20 arylalkyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C7-C40 alkylaryl; Z is —O—, or substituted or unsubstituted —(O—C1-20—)w—O—, wherein w is 1 to 20; Ar is a C6-C62 aromatic group; m is 0-3 and n is 3-6; and each Y is independently C1-C20 alkyl, substituted C1-C20 alkyl, C6-C20 aryl, C1-C8 alkyl-substituted C6-C20 aryl, halogen, nitro, C1-C20 alkoxycarbonyl, C1-C20 alkoxy, or C1-C20 acyl, and further wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, aromatic sulfonate compound, and an effective amount of each of a mold-release agent and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：热塑性组合物包含聚碳酸酯和式（Y）m-Ar-（Z-S（O）2-X）n的芳族磺酸盐化合物，其中每个X独立地为取代或未取代的C 1 -C 20烷基，取代或未取代的 C 1 -C 20芳烷基，取代或未取代的C 6 -C 20芳基或取代或未取代的C 7 -C 40烷基芳基; Z是-O-或取代或未取代的 - （O-C 1-20 - ）w -O-，其中w是1至20; Ar为C6-C62芳族基团; m为0-3，n为3-6; 并且每个Y独立地为C 1 -C 20烷基，取代的C 1 -C 20烷基，C 6 -C 20芳基，C 1 -C 8烷基取代的C 6 -C 20芳基，卤素，硝基，C 1 -C 20烷氧基羰基，C 1 -C 20烷氧基或C 1 -C 20 酰基，并且其中由曝露于总γ辐射之后，由聚碳酸酯，芳族磺酸盐化合物和有效量的脱模剂和抗氧化剂组成的厚度为3.2±0.12毫米的模塑制品剂量为83kGy，当根据ASTM D1925-70测量时，与未曝光的模制品相比，黄度指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

24. 发明授权

US07649039B2 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US07649039B2
公开(公告)日：2010-01-19
申请号：US11263372
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： C08K5/42
CPC分类号： C08K5/0008 , C08J3/226 , C08J2369/00 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprising a polycarbonate, and an aromatic sulfonate compound of formula: Ar1—S(O)2—O—L—O—S(O)2—Ar1 wherein each Ar1 is each independently a substituted or unsubstituted C6-20 aryl group, and L is a branched, substituted or unsubstituted divalent aliphatic hydrocarbon, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯和下式的芳族磺酸盐化合物：Ar1-S（O）2 -OROS（O）2 -Ar1，其中各Ar1各自独立地为取代或未取代的C6-20芳基，L为支链的，取代的或未取代的二价脂族烃，其中由聚碳酸酯，芳族磺酸盐化合物和有效量的脂肪族二醇，脱模剂和抗氧化剂在暴露于83kGy的总伽马辐射剂量之后，当根据ASTM D1925-70测量时，与未曝光的模塑制品相比，黄色指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

25. 发明授权

US07432327B2 Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same 有权
标题翻译：包含聚硅氧烷 - 聚碳酸酯共聚物，由其制成的制品的透明聚合物组合物及其制备方法
公开(公告)号：US07432327B2
公开(公告)日：2008-10-07
申请号：US11026362
申请日：2004-12-30
申请人： Katherine Glasgow , Naresh Alle
发明人： Katherine Glasgow , Naresh Alle
IPC分类号： C08L83/10
CPC分类号： C08L83/10 , C08L25/12 , C08L69/00 , C08L2666/06 , C08L2666/02 , C08L2666/04
摘要： A composition made from a transparent polysiloxane-polycarbonate copolymer and styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, the composition being transparent. A thin-walled article may be made from such a composition. A transparent composition made by combining a transparent polysiloxane-polycarbonate copolymer with styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, to produce a transparent composition. An article made by forming a transparent composition comprising a transparent polysiloxane-polycarbonate copolymer, styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate into an article.
摘要翻译：由透明聚硅氧烷 - 聚碳酸酯共聚物和苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯制成的组合物是透明的。薄壁制品可以由这种组合物制成。通过将透明聚硅氧烷 - 聚碳酸酯共聚物与苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯组合来制备透明组合物以制备透明组合物。通过将包含透明聚硅氧烷 - 聚碳酸酯共聚物，苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯的透明组合物形成制品制成的制品。

26. 发明申请

US20070100021A1 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US20070100021A1
公开(公告)日：2007-05-03
申请号：US11263372
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： G21F1/10
CPC分类号： C08K5/0008 , C08J3/226 , C08J2369/00 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprising a polycarbonate, and an aromatic sulfonate compound of formula: Ar1—S(O)2—O-L-O—S(O)2—Ar1 wherein each Ar1 is each independently a substituted or unsubstituted C6-20 aryl group, and L is a branched, substituted or unsubstituted divalent aliphatic hydrocarbon, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯和下式的芳香族磺酸酯化合物：＆lt;？in-line-formula description =“In-line formula”end =“lead”？> Ar < ）2-in-line-formula description =“In-line Formulas”end =“ 其中每个Ar 1各自独立地是取代或未取代的C 6-20芳基，L是支链，取代或未取代的二价脂族烃，其中由聚碳酸酯，芳族磺酸盐化合物和有效量的脂肪族二醇，脱模剂和抗氧化剂组成的厚度为3.2±0.12毫米的模制品在暴露于总伽马辐射之后剂量为83kGy，当根据ASTM D1925-70测量时，与未曝光的模制品相比，黄度指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

27. 发明授权

US07132575B2 Process for the synthesis of bisphenol 有权
标题翻译：合成双酚的方法
公开(公告)号：US07132575B2
公开(公告)日：2006-11-07
申请号：US10612101
申请日：2003-07-01
申请人： Brian Carvill , Katherine Glasgow , Michael Roland
发明人： Brian Carvill , Katherine Glasgow , Michael Roland
IPC分类号： C07C39/12 , C07C39/16
CPC分类号： C07C37/20 , C08G64/20 , C07C39/16
摘要： A process for the production of a bisphenol comprises reacting a feed comprising a phenol, a ketone and water in the presence of an ion exchange resin catalyst to produce an effluent; determining the para—para bisphenol selectivity of the reaction; and adjusting the concentration of the water in the feed based upon the para—para bisphenol selectivity in the effluent.
摘要翻译：制备双酚的方法包括在离子交换树脂催化剂存在下使包含苯酚，酮和水的进料反应以产生流出物; 确定反应的对位双酚选择性; 并且基于流出物中对位双酚选择性调节进料中的水的浓度。

28. 发明授权

US07112702B2 Process for the synthesis of bisphenol 有权
标题翻译：合成双酚的方法
公开(公告)号：US07112702B2
公开(公告)日：2006-09-26
申请号：US10248028
申请日：2002-12-12
申请人： Brian Carvill , Katherine Glasgow , Gurram Kishan , Ramesh Krishnamurti , Nilesh Kumar Parkash Kukalyekar , G. V. Ramanarayanan
发明人： Brian Carvill , Katherine Glasgow , Gurram Kishan , Ramesh Krishnamurti , Nilesh Kumar Parkash Kukalyekar , G. V. Ramanarayanan
IPC分类号： C07C39/16
CPC分类号： B01J31/0218 , B01J31/0237 , B01J31/0244 , B01J31/0271 , B01J31/08 , B01J2231/347 , C07C37/20 , C08G64/20 , Y02P20/582 , C07C39/16
摘要： A commercial scale continuous process for the production of a bisphenol comprising reacting a phenol and a ketone in the presence of a modified ion exchange resin catalyst, wherein said modified ion exchange resin comprises a crosslinked gellular acid functionalized polystyrene resin modified by neutralization of with a mercapto promoter.
摘要翻译：一种用于生产双酚的商业规模的连续方法，包括在改性离子交换树脂催化剂存在下使苯酚和酮反应，其中所述改性离子交换树脂包括通过用巯基中和形成的交联的聚乙烯醇交联聚乙烯树脂启动子。

29. 发明申请

US20060148986A1 Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same 有权
标题翻译：包含聚硅氧烷 - 聚碳酸酯共聚物，由其制成的制品的透明聚合物组合物及其制备方法
公开(公告)号：US20060148986A1
公开(公告)日：2006-07-06
申请号：US11026362
申请日：2004-12-30
申请人： Katherine Glasgow , Naresh Alle
发明人： Katherine Glasgow , Naresh Alle
IPC分类号： C08L83/10 , C08L69/00
CPC分类号： C08L83/10 , C08L25/12 , C08L69/00 , C08L2666/06 , C08L2666/02 , C08L2666/04
摘要： A composition made from a transparent polysiloxane-polycarbonate copolymer and styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, the composition being transparent. A thin-walled article may be made from such a composition. A transparent composition made by combining a transparent polysiloxane-polycarbonate copolymer with styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate, to produce a transparent composition. An article made by forming a transparent composition comprising a transparent polysiloxane-polycarbonate copolymer, styrene-acrylonitrile copolymer (SAN) and, optionally, polycarbonate into an article.
摘要翻译：由透明聚硅氧烷 - 聚碳酸酯共聚物和苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯制成的组合物是透明的。薄壁制品可以由这种组合物制成。通过将透明聚硅氧烷 - 聚碳酸酯共聚物与苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯组合来制备透明组合物以制备透明组合物。通过将包含透明聚硅氧烷 - 聚碳酸酯共聚物，苯乙烯 - 丙烯腈共聚物（SAN）和任选的聚碳酸酯的透明组合物形成制品制成的制品。

30. 发明申请

US20060142527A1 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US20060142527A1
公开(公告)日：2006-06-29
申请号：US11025249
申请日：2004-12-29
申请人： Katherine Glasgow , Brian Mullen , Paul Sybert
发明人： Katherine Glasgow , Brian Mullen , Paul Sybert
IPC分类号： C08G77/04 , C08G77/06 , C08L83/04
CPC分类号： C08L83/10 , C08G63/64 , C08G77/445 , C08G77/448
摘要： A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.
摘要翻译：公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。还公开了形成由组合物形成的组合物和制品的方法。

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