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21. 发明授权

US5849666A N-substituted hydrazinophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulations 失效
标题翻译： N-取代的肼基苯基磺酰脲，其制备方法及其作为除草剂和植物生长规则的用途
公开(公告)号：US5849666A
公开(公告)日：1998-12-15
申请号：US562043
申请日：1995-11-22
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D251/16 , A01N47/36 , C07C311/39 , C07D239/42 , C07D251/46 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , C07D239/64 , A01N43/54 , C07D403/12
CPC分类号： C07D521/00 , A01N47/36
摘要： N-substituted hydrazinophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators Compounds of the formula (I) or salts thereof ##STR1## in which R.sup.1 to R.sup.6, W, Q, X, Y and Z are defined as in formula (I) as claimed in claim 1, are suitable as herbicides and plant growth regulators. The compounds (I) are prepared by processes analogous to known processes (cf. claim 5), in some cases via novel intermediates of the formula (II) ##STR2##
摘要翻译： N-取代的肼基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途式（I）化合物或其盐其中R 1至R 6，W，Q，X，Y和Z为如权利要求1所述的式（I）所定义，适合作为除草剂和植物生长调节剂。化合物（I）通过类似于已知方法（参见权利要求5）的方法制备，在一些情况下通过式（II）的新型中间体制备（II）

22. 发明授权

US5747421A Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators 失效
标题翻译：甲酰氨基苯基磺酰脲，制备方法和用作除草剂和植物生长调节剂
公开(公告)号：US5747421A
公开(公告)日：1998-05-05
申请号：US453978
申请日：1995-05-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D251/16 , A01N47/36 , C07D239/42 , C07D251/46 , C07D251/50 , C07D405/12 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Formylaminophenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) ##STR1## in which R.sup.1 is H, a substituted or unsubstituted hydrocarbon radical or an unsubstituted or substituted heterocyclic radical, R.sup.2 is H, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, R.sup.3 is halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, (C.sub.1 -C.sub.6)-haloalkyl, (C.sub.1 -C.sub.6)-haloalkoxy, NO.sub.2, CN, NH.sub.2, (C.sub.1 -C.sub.4) -mono- or dialkylamino, each independently of other radicals R.sup.3 if n is 2 or 3, n is 0, 1, 2 or 3, W is an oxygen atom or a sulfur atom, X and Y independently of one another are halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy or (C.sub.1 -C.sub.6)-alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)-alkoxy and (C.sub.1 -C.sub.4)-alkylthio, or are (C.sub.3 -C.sub.6)-cycloalkyl, (C.sub.2 -C.sub.6)-alkenyl, (C.sub.2 -C.sub.6)-alkynyl, (C.sub.2 -C.sub.6)-alkenyloxy, (C.sub.2 -C.sub.6)-alkynyloxy, mono- or di�(C.sub.1 -C.sub.4 -alkyl)!amino, and Z is CH or N, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared by processes analogous to known processes whereby some novel intermediates of formula (II) are used.
摘要翻译：甲酰氨基苯基磺酰脲其制备方法及其作为除草剂和植物生长调节剂的用途式（I）取代烃基或未取代或取代的杂环基的化合物，R2是H，（C1-C6） - 烷基或（C1-C6） - 烷氧基，R 3为卤素，（C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基，（C 1 -C 6） - 卤代烷基，（C 1 -C 6） - 卤代烷氧基，NO 2，CN，NH 2，（C 1 -C 4）单或二烷基氨基，如果n为2或3，各自独立地为其它基团，n为0,1,2或3，W为氧原子或硫原子，X和Y彼此独立地为卤素，（C1 （C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基或（C 1 -C 6） - 烷硫基，三个最后提到的基团中的每一个是未取代的或被一个或多个选自卤素，（C1- 或（C 1 -C 6） - 烷硫基，或者是（C 3 -C 6） - 环烷基，（C 2 -C 6） - 烯基，（C 2 -C 6） - 炔基，（C 2 -C 6） - 炔基氧基，（C 2 -C 6） C6） - 炔氧基，单或二[（C1-C4烷基）]氨基，Z为CH或N，适合作为除草剂和植物生长调节剂。化合物（I）可以通过类似于已知方法的方法制备，由此使用一些新的式（II）中间体。

23. 发明授权

US07078369B2 Phenylsulfonyl ureas, process for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：苯磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US07078369B2
公开(公告)日：2006-07-18
申请号：US10659201
申请日：2003-09-09
申请人： Hansjörg Dietrich , Christian Waldraff , Lothar Willms , Hermann Bieringer , Christopher Rosinger , Felix Thürwächter , Thomas Auler
发明人： Hansjörg Dietrich , Christian Waldraff , Lothar Willms , Hermann Bieringer , Christopher Rosinger , Felix Thürwächter , Thomas Auler
IPC分类号： C07D251/42 , C07D251/48 , C07D251/52 , A01N43/68 , A01N47/36
CPC分类号： C07D521/00 , A01N47/36 , C07C311/16 , C07C311/39 , C07D207/32 , C07D239/42 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/46 , C07D295/155 , C07D403/12
摘要： Phenylsulfonyl ureas are disclosed for controlling harmful plants in crops of useful plants. Also disclosed are processes for the preparation of phenylsulfonyl ureas, and their use as herbicides and plant growth regulators.
摘要翻译：公开了苯磺酰脲用于控制有用植物作物中的有害植物。还公开了制备苯磺酰脲的方法及其作为除草剂和植物生长调节剂的用途。

24. 发明授权

US06410482B1 (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
标题翻译：（Het）芳基磺酰脲具有氨基功能，它们的表现及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06410482B1
公开(公告)日：2002-06-25
申请号：US08855251
申请日：1997-05-13
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D40112
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),
摘要翻译：（Het）具有亚氨基功能的芳基磺酰脲，它们的制备及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中A是通过直接连接到基团SO 2上的（杂）芳族或杂环桥或通过O，S，NH，CH 2或通过烷基化NH或烷基化亚甲基，B是具有亚氨基的片段N = CN，N = CS，N = CO或N = CC的基团，其通过所述片段的氮原子之一R = H或脂族基，W = O或S和X，Y和Z如权利要求1中所定义，适合作为除草剂和植物生长调节剂。通过式（XII）的新型中间体（参见权利要求6和10）类似于已知方法进行制备，

25. 发明授权

US06331506B1 Disubstituted methylidene hydrazinophenyl sulfonylureas, process for their production and their use as herbicides and plant growth regulators 失效
标题翻译：二取代亚甲基肼基苯基磺酰脲，其生产方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06331506B1
公开(公告)日：2001-12-18
申请号：US09142961
申请日：1998-09-16
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D23948
CPC分类号： C07D521/00 , A01N47/36
摘要： Disubstituted methylidenehydrazinophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which R1 to R6, W, X, Y, Z are as defined in claim 1 and the group R2R3C is a carbon atom which is subsituted by at least one electron-withdrawing radical R2 or R3 are suitable as herbicides and plant growth regulators. They can be prepared in accordance with known processes via intermediates, some of which are novel.
摘要翻译：二取代亚甲基肼基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中R 1至R 6，W，X，Y，Z如权利要求1所定义，R 2 R 3 C为碳由至少一个吸电子基团R2或R3取代的原子适合作为除草剂和植物生长调节剂。它们可以根据已知方法通过中间体制备，其中一些是新颖的。

26. 发明授权

US06239071B1 2,4-diamino-1,3,5-triazines, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译： 2,4-二氨基-1,3,5-三嗪，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06239071B1
公开(公告)日：2001-05-29
申请号：US08701360
申请日：1996-08-22
申请人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Hermann Bieringer , Klaus Bauer , Christopher Rosinger
发明人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Hermann Bieringer , Klaus Bauer , Christopher Rosinger
IPC分类号： A01N4368
CPC分类号： C07D251/18
摘要： Compounds of the formula (I) and their salts in which R1 is optionally substituted (C1-C6)alkyl or optionally substituted phenyl, A is an optionally substituted hydrocarbon diradical and R2, R3, R4, R5, X and n are as defined in claim 1, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared according to processes as claimed in claim 6 by means of intermediates which are novel in some cases, e.g. of the formula (IV) as claimed in claim 10.
摘要翻译：式（I）化合物及其盐，其中R 1为任选取代的（C 1 -C 6）烷基或任意取代的苯基，A为任选取代的烃基，R 2，R 3，R 4，R 5，X和n如权利要求1所定义，适合作为除草剂和植物生长调节剂。化合物（I）可以根据权利要求6所述的方法，通过中间体制备，所述中间体在一些情况下是新的，例如。权利要求10所述的式（IV）化合物。

27. 发明授权

US5861357A 5-acylamino-2-alkoxycarbonylphenylsulfonylureas as selective herbicides 失效
标题翻译：作为选择性除草剂的5-酰基氨基-2-烷氧基羰基苯基磺酰脲
公开(公告)号：US5861357A
公开(公告)日：1999-01-19
申请号：US757372
申请日：1996-11-27
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N47/36 , C07D521/00 , A01N43/20 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula (I) ##STR1## in which R.sup.1 to R.sup.5, X, W, n and Z are defined as in claim 1 are particularly suitable for use as selective herbicides in crops of useful plants.
摘要翻译：其中R1至R5，X，W，n和Z如权利要求1中所定义的式（I）化合物（I）特别适合用作有用植物作物中的选择性除草剂。

28. 发明授权

US07414011B2 Phenylsulfonyl ureas, process for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：苯磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US07414011B2
公开(公告)日：2008-08-19
申请号：US11224153
申请日：2005-09-12
申请人： Hansjörg Dietrich , Christian Waldraff , Lothar Willms , Hermann Bieringer , Christopher Rosinger , Felix Thürwächter , Thomas Auler
发明人： Hansjörg Dietrich , Christian Waldraff , Lothar Willms , Hermann Bieringer , Christopher Rosinger , Felix Thürwächter , Thomas Auler
IPC分类号： C07D239/42 , C07D239/46 , C07D239/47 , A01N43/54 , A01N43/66 , C07D251/42 , C07D251/22 , C07D251/26
CPC分类号： C07D521/00 , A01N47/36 , C07C311/16 , C07C311/39 , C07D207/32 , C07D239/42 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/46 , C07D295/155 , C07D403/12
摘要： Disclosed are compounds of the formula (I) or salts thereof in which R1, R2, R3, R4, I, R5, Q, R4, W, X, Y, V and Z, are as defined in the specification, which are suitable for use as herbicides or plant growth regulators. Also disclosed are processes for preparing the compounds of formula (I) or salts thereof.
摘要翻译：公开了式（I）化合物或其盐，其中R 1，R 2，R 3，R 4， I，R 5，Q，R 4，W，X，Y，V和Z如本说明书中所定义，适用于作为除草剂或植物生长调节剂。还公开了制备式（I）化合物或其盐的方法。

29. 发明授权

US06884758B2 2,4-Diamino-1,3,5-triazines, their preparation, and their use as herbicides and plant growth regulators 失效
标题翻译： 2,4-二氨基-1,3,5-三嗪，它们的制备及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06884758B2
公开(公告)日：2005-04-26
申请号：US10227760
申请日：2002-08-26
申请人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Thomas Auler , Hermann Bieringer , Christopher Rosinger
发明人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Thomas Auler , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N43/68 , C07C211/27 , C07C279/26 , C07D251/18 , C07D403/12 , C07D405/12 , C07D405/14 , C07D407/12 , C07D413/12 , C07D417/12 , C07D521/00 , C07D251/44 , A01N43/66 , C07D251/48 , C07D251/52
CPC分类号： C07D231/12 , A01N43/68 , C07D233/56 , C07D249/08 , C07D251/18 , C07D407/12 , C07D413/12 , C07D417/12
摘要： The invention is in the technical field of the crop protection agents, such as herbicides and plant growth regulators, in particular of the herbicides for the selective control of harmful plants in crops of useful plants.
摘要翻译：本发明属于作物保护剂的技术领域，例如除草剂和植物生长调节剂，特别是用于有选择地控制有用植物作物中有害植物的除草剂。

30. 发明授权

US06228808B1 Carbamoylphenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：氨基甲酰基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06228808B1
公开(公告)日：2001-05-08
申请号：US09182763
申请日：1998-10-30
申请人： Heinz Kehne , Lothar Willms , Christian Waldraff , Hansjörg Dietrich , Hermann Bieringer , Christopher Rosinger , Thomas Auler
发明人： Heinz Kehne , Lothar Willms , Christian Waldraff , Hansjörg Dietrich , Hermann Bieringer , Christopher Rosinger , Thomas Auler
IPC分类号： A01N4354
CPC分类号： C07D275/06 , C07C311/16 , C07D521/00
摘要： Compounds of the formula (I) or salts thereof in which R1, R3=H, (subst.) hydrocarbon radical (HC) or (subst.) heterocyclyl which, including substituents, have 1-30 carbon atoms, R2=R0—Q0—, in which R0=H, (subst.) HC or (subst.) heterocyclyl radical, in each case having 1-30 carbon atoms including substituents, and Q0=a direct bond or —O—, —SO2-, —NH—, —N[(C1-C6)alkyl]-, —CO—, —CO—NH— or —O—CO—NH—; R4=H, halogen, NO2, CN, (C1-C4)alkyl, (C1-C4)alkoxy, [(C1-C4)alkyl]carbonyl or [(C1-C4)alkoxy]carbonyl, where each of the last four radicals may be halogenated; R5=H or (C1-C4)alkyl; Q=O or NR*; R*=H. (C1-C4)alkyl, (C3-C4)alkenyl or (C3-C4)alkynyl, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, W=O or S; X,Y=H, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alkylthio, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, or mono- or di[(C1-C4)alkyl]amino, (C3-C4)cycloalkyl, (C2-C5)alkenyl, (C2-C5)alkynyl, (C2-C5)alkenyloxy or (C2-C5)alkynyloxy, Z=CH or N, are suitable as herbicides or plant growth regulators, for example for controlling harmful plants in crop plants, including transgenic crop plants. They can be prepared by processes according to claim 6, via intermediates, some of which are novel.
摘要翻译：式（I）化合物或其盐，其中R 1，R 3 = H，（取代）烃基（HC）或（取代）杂环基，其包括取代基，具有1-30个碳原子，R 2 = R 0 -Q 0-，其中R 0 = H，（低级）HC或（取代）杂环基，在每种情况下具有包含取代基的1-30个碳原子，Q 0 =直接键或-O-，-SO 2 - ， - NH-， -N [（C 1 -C 6）烷基] - ， - CO - ， - CO-NH-或-O-CO-NH-; R4 = H，卤素，NO2，CN，（C1-C4）烷基，（C1-C4）烷氧基，[（C1-C4）烷基]羰基或[（C1-C4）烷氧基]羰基，自由基可以被卤化; R5 = H或（C1-C4）烷基; Q = O或NR *; R * = H。（C 1 -C 4）烷基，（C 3 -C 4）烯基或（C 3 -C 4）炔基，其中最后三个基团中的每一个可以被卤素，（C 1 -C 4）烷氧基和/或（C 1 -C 4）烷硫基取代， W = O或S; X，Y = H，卤素，（C1-C4）烷基，（C1-C4）烷氧基，（C1-C4）烷硫基，其中最后三个基团中的每一个可以被卤素，（C 1 -C 4）烷氧基和/ 或（C 1 -C 4）烷硫基或单或二[（C 1 -C 4）烷基]氨基，（C 3 -C 4）环烷基，（C 2 -C 5）烯基，（C 2 -C 5）炔基，（C 2 -C 5）或（C 2 -C 5）炔氧基Z = CH或N适合作为除草剂或植物生长调节剂，例如用于控制作物植物（包括转基因作物植物）中的有害植物。它们可以通过根据权利要求6的方法通过中间体制备，其中一些是新颖的。

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