会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 25. 发明授权
    • Radiation curable coating composition comprising an oligomer and a
copolymerizable ultra-violet absorber
    • 包含低聚物和可共聚紫外线吸收剂的可辐射固化涂料组合物
    • US4263366A
    • 1981-04-21
    • US079550
    • 1979-09-27
    • Donald H. LorenzBruce A. Gruber
    • Donald H. LorenzBruce A. Gruber
    • C08F20/36C09D4/00C09D133/00C08J3/28C08F2/48C08F20/68
    • C07C255/00C08F20/36C09D4/00Y10S525/92Y10T428/26Y10T428/3158
    • What is described herein is a radiation curable coating composition comprising:A. An oligomer of Formula I: ##STR1## wherein: R.sup.1 is hydrogen or methyl; andY is a divalent urethane residue; andB. a copolymerizable ultra-violet light absorber which is a copolymerizable (2-cyano-3,3-diphenylacryloxy) alkylene ethylenic ether of Formula IV: ##STR2## where (Ar).sub.1 and (Ar).sub.2 are aromatic carbocylic nuclei of the benzene and naphthalene series;X is alkylene, C.sub.2 -C.sub.17, unsubstituted or substituted;R is alkylene, C.sub.1 -C.sub.10, oxyalkylene, C.sub.1 -C.sub.10, alkyleneoxyalkylene, C.sub.1 -C.sub.10 or phenylene, C.sub.1 -C.sub.10, unsubstituted or substituted with hydroxy, andR' and R" are independently hydrogen or alkyl, C.sub.1 -C.sub.6.Preferably the coating composition contains a vinyl monomer, such as N-vinyl-2-pyrrolidone or an acrylic acid ester, which is copolymerizable with the oligomer.The process for curing the composition also is disclosed.
    • 本文描述的是可辐射固化的涂料组合物,其包含:A.式I的低聚物:其中:R 1是氢或甲基; Y为二价氨基甲酸酯残基; (IV)的共聚合(2-氰基-3,3-二苯基丙烯酰氧基)亚烷基乙烯醚,其中(Ar)1和(Ar)2是芳香族的)的共聚合的紫外光吸收剂 苯和萘系列的碳原子核; X是亚烷基,C 2 -C 17,未取代或取代的; R是亚烷基,C 1 -C 10,氧化烯,C 1 -C 10,亚烷氧基亚烷基,C 1 -C 10或亚苯基,未被取代或被羟基取代的C 1 -C 10,R'和R“独立地是氢或烷基,C 1 -C 6。 优选地,涂料组合物含有可与低聚物共聚的乙烯基单体,如N-乙烯基-2-吡咯烷酮或丙烯酸酯。 公开了固化组合物的方法。
    • 27. 发明授权
    • Method of making copolymerizable, ultraviolet light absorber
(2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters
    • 制备可共聚紫外光吸收剂(2-氰基-3,3-二苯基丙烯酰氧基)亚烷基丙烯酸酯的方法
    • US4207253A
    • 1980-06-10
    • US16134
    • 1979-03-01
    • Donald H. LorenzBruce A. Gruber
    • Donald H. LorenzBruce A. Gruber
    • C07C255/34C08F20/36C07C121/70
    • C07C255/00C08F20/36
    • This invention relates to a method of making in high yield light absorber compounds which are (2-cyano-3,3-diphenylacryloxy) alkylene acrylic acid esters having the formula: ##STR1## where (Ar).sub.1 and (Ar).sub.2 are aromatic carbocyclic nuclei of the benzene and naphthalene series and are independently selected from phenyl or phenyl substituted with alkyl, halo, alkoxy, carboxy, carbalkoxy, cyano, acetyl, benzoyl, phenyl, alkyl phenyl, phenoxy phenyl, alkyl substituted phenoxy, or alkoxy phenyl substituted phenyl, and naphthyl;X is alkylene, C.sub.2 -C.sub.17, unsubstituted or substituted with halo, cyano, alkyl, alkoxy, alkoxyalkyl, or alkoxyalkyleneoxy, C.sub.1 -C.sub.6 ; andY is copolymerizable radical selected from acryloyl, alkylacryloyl, acryloxyalkyl, acryloxyhydroxyalkyl and alkylacryloxyhydroxyalkyl, C.sub.3 -C.sub.12.The method comprises:(a) acylating a hydroxyalkylene cyanoacetate with an acylating agent to form an acylated intermediate whose hydroxy radical is protected by an acyl group which is convertible to hydroxy by hydrolysis,(b) condensing the acyl intermediate with a benzophenone,(c) hydrolyzing the condensed compound to form the corresponding condensed hydroxy compound; and,(d) esterifying the hydroxy compound with an acryloyl halide or an acrylic acid to provide the desired product.
    • 本发明涉及制备具有下式的(2-氰基-3,3-二苯基丙烯酰氧基)亚烷基丙烯酸酯的高收率光吸收剂化合物的方法,其中(Ar)1和(Ar)2是芳族的 苯和萘系列的碳环核独立地选自苯基或被烷基,卤素,烷氧基,羧基,烷氧基,氰基,乙酰基,苯甲酰基,苯基,烷基苯基,苯氧基苯基,烷基取代的苯氧基或烷氧基苯基取代的苯基 苯基和萘基; X是亚烷基,未被取代或被卤素,氰基,烷基,烷氧基,烷氧基烷基或烷氧基亚烷氧基取代的C 1 -C 6烷基,C 1 -C 6烷基, 并且Y是选自丙烯酰基,烷基丙烯酰基,丙烯酰氧基烷基,丙烯酰氧基羟基烷基和烷基丙烯酰氧基羟基烷基,C 3 -C 12的共聚基。 该方法包括:(a)用酰化剂酰化氰基乙酸羟基亚烷基酯,形成酰化中间体,其羟基被可通过水解转化为羟基的酰基保护,(b)将酰基中间体与二苯甲酮缩合,(c )水解缩合的化合物以形成相应的缩合羟基化合物; 和(d)用丙烯酰卤或丙烯酸酯化羟基化合物以提供所需产物。