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    • 24. 发明授权
    • Water-dilutable lacquer binders for chemically resistant coatings
    • 用于耐化学腐蚀涂层的水稀释漆粘合剂
    • US4276210A
    • 1981-06-30
    • US95963
    • 1979-11-20
    • Peter HohleinJochen Schoeps
    • Peter HohleinJochen Schoeps
    • C08L33/00C08L33/02C08L33/04C08L61/20C09D125/00C09D133/04C09D133/06
    • C09D125/00C09D133/066C08L61/20
    • A water-dilutable lacquer binder comprising a mixture of A. 20 to 94% by weight of a copolymer consisting of copolymerized units of (a) 30 to 65% by weight of an aromatic vinyl or isopropenyl compound having 8 to 14 carbon atoms or of a methacrylic acid alkyl ester having 1 to 4 carbon atoms in the alcohol component, or any mixture thereof; (b) 10 to 30% by weight of at least one acrylic acid alkyl ester having 1 to 8 carbon atoms in the alcohol component; (c) 1 to 20% by weight of maleic acid, fumaric acid, itaconic acid or their semi-esters having 1 to 8 carbon atoms in the alcohol component, (meth)acrylic acid or any mixture of the aforesaid monomers; (d) 5 to 20% by weight of at least one hydroxyalkyl ester of (meth) acrylic acid having 2 to 4 carbon atoms in the alkyl group or glycidyl (meth)acrylate or any mixture of the aforesaid monomers; and (e) 10 to 30% by weight of N-methylol (meth)acrylic acid amide or N-methoxymethyl(meth)acrylic acid amide or any mixture thereof; B. 1 to 40% by weight of a saturated lactam, and C. 5 to 40% by weight of an aminoplast resin; wherein 30 to 100% of the number of carboxyl groups of component A. (c) incorporated in the copolymer have been neutralized by ammonia or monoamines or polyamines.
    • 一种水可稀释的漆结合剂,其包含A.20至94重量%的共聚物的混合物,该共聚物由(a)30至65重量%的具有8至14个碳原子的芳族乙烯基或异丙烯基化合物或 在醇组分中具有1至4个碳原子的甲基丙烯酸烷基酯或其任何混合物; (b)10至30重量%的至少一种在醇组分中具有1至8个碳原子的丙烯酸烷基酯; (c)1至20重量%的马来酸,富马酸,衣康酸或其在醇组分中具有1至8个碳原子的半酯,(甲基)丙烯酸或上述单体的任何混合物; (d)5〜20重量%的烷基或(甲基)丙烯酸缩水甘油酯中的至少一种具有2〜4个碳原子的(甲基)丙烯酸的羟烷基酯或上述单体的任意混合物; 和(e)10-30重量%的N-羟甲基(甲基)丙烯酸酰胺或N-甲氧基甲基(甲基)丙烯酸酰胺或其任何混合物; B. 1至40重量%的饱和内酰胺和5至40重量%的氨基塑料树脂; 其中加入到共聚物中的组分A(c)的羧基数目的30-100%已被氨或单胺或多胺中和。
    • 25. 发明授权
    • Cross-linkable lacquer binder containing saturated lactam
    • 含有饱和内酰胺的可交联的漆粘合剂
    • US4255530A
    • 1981-03-10
    • US95976
    • 1979-11-20
    • Peter HohleinJochen Schoeps
    • Peter HohleinJochen Schoeps
    • C08L33/00C08G18/62C08L33/02C08L33/04C08L57/00C09D125/00C09D133/06C08L33/08
    • C09D125/00C08G18/622C09D133/064Y10T428/31935
    • A binder composition which comprises (A) from 99 to 50% by weight of copolymer consisting of copolymerized units of (a) from 5 to 90% by weight of at least one aliphatic (meth)acrylate containing from 1 to 8 carbon atoms in the alcohol moiety; (b) from 0 to 60% by weight of at least one aromatic vinyl or isopropylene compound containing from 8 to 14 carbon atoms; (c) from 1 to 40% by weight of at least one comonomer selected from (I) at least one mono (meth)acrylate of an alcohol containing from 2 to 8 carbon atoms and having from 2 to 4 hydroxyl groups; and/or (II) at least one maleic acid semi-ester corresponding to the following general formula ##STR1## wherein R.sub.1 represents hydrogen or methyl; and R.sub.2 represents hydrogen, methyl, ethyl, propyl, i-propyl or phenyl; and (d) from 0 to 60% by weight of at least one other olefinically unsaturated comonomer; and (B) from 1 to 50% by weight of a saturated lactam.
    • 一种粘合剂组合物,其包含(A)99至50重量%的由(a)5-90重量%的至少一种含有1-8个碳原子的脂族(甲基)丙烯酸酯的共聚单元组成的共聚物, 醇部分; (b)0至60重量%的至少一种含有8至14个碳原子的芳族乙烯基或异丙烯化合物; (c)1至40重量%的至少一种选自(I)至少一种含有2至8个碳原子并具有2至4个羟基的醇的单(甲基)丙烯酸酯的共聚单体; 和/或(II)至少一种对应于下列通式的其中R 1表示氢或甲基的马来酸半酯; 并且R 2表示氢,甲基,乙基,丙基,异丙基或苯基; 和(d)0至60重量%的至少一种其它烯属不饱和共聚单体; 和(B)1至50重量%的饱和内酰胺。
    • 30. 发明授权
    • Powder mixtures for matt polycarbonate molding compounds
    • 用于哑光聚碳酸酯模塑料的粉末混合物
    • US5484846A
    • 1996-01-16
    • US349451
    • 1994-11-30
    • Dieter WittmanJochen SchoepsHorst BeicherKarl-Erwin PiejkoKurt Weirauch
    • Dieter WittmanJochen SchoepsHorst BeicherKarl-Erwin PiejkoKurt Weirauch
    • C08L21/02C08L21/00C08L51/04C08L55/02C08L57/00C08L67/00C08L67/02C08L69/00
    • C08L51/04C08L69/00C08L69/005C08L21/00C08L57/00C08L67/02
    • Thermoplastic molding compounds containingA. 10 to 99 parts by weight polycarbonate or polyester carbonateB. 0 to 90 parts by weight of a rubber-free resin compatible or partly compatible with component A.,C. 0 to 90 parts by weight of a rubber-modified resin compatible or partly compatible with component A.,D. 0.5 to 10 parts by weight, based on 100 parts by weight of A+B+C, of a rubber component having a glass transition temperature below 0.degree. C. which is incompatible with component A,characterized in that component D is used in the form of a powder mixture D* produced froma. 1 to 50 parts by weight of an ungrafted particulate rubber component having a glass transition temperature below 0.degree. C. and an average particle diameter d.sub.50 of 0.05 to 5 .mu.m in latex form andb. 50 to 99 parts by weight of component B, component C or a mixture of components B and C in latex form,the components mentioned under a. and b. initially being mixed with one another as latices and then being worked up together to form a powder mixture D*.
    • 含有A.10-99重量份聚碳酸酯或聚碳酸酯B的热塑性成型化合物B.0-90重量份与组分A,C相容或部分相容的无橡胶树脂。0至90重量份橡胶 与A组分相容或部分相容的树脂D.以0.5至10重量份,基于100重量份的A + B + C,玻璃化转变温度低于0℃的橡胶组分为 与组分A不相容,其特征在于组分D以由a制备的粉末混合物D *的形式使用。 1至50重量份的玻璃化转变温度低于0℃的未接枝的颗粒状橡胶组分和胶乳形式的平均粒径d50为0.05-5μm,b。 50至99重量份的组分B,组分C或胶乳形式的组分B和C的混合物,a。下提及的组分。 和b。 最初彼此混合作为胶乳,然后一起处理以形成粉末混合物D *。