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21. 发明授权

US07960030B2 Free films made of cured organopolysiloxane resins, process for production thereof, and laminated films 有权
标题翻译：由固化的有机聚硅氧烷树脂制成的游离膜，其制造方法和层压膜
公开(公告)号：US07960030B2
公开(公告)日：2011-06-14
申请号：US11569104
申请日：2005-05-13
申请人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
发明人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
IPC分类号： B32B15/08 , B29C71/00 , C08F283/12 , C08J5/18
CPC分类号： C08J5/18 , C08G77/12 , C08G77/20 , C08G77/70 , C08J2383/04 , C08K3/22 , C08L83/04 , Y10T156/1158 , Y10T428/31663 , C08L83/00
摘要： A free-standing film comprising a cured organopolysiloxane resin obtained by conducting a cross-linking reaction between (A) an organopolysiloxane resin represented by the following average siloxane unit formula: [R1aR23-aSiO1/2]v[R3SiO3/2]w (1) or [R1aR23-aSiO1/2]x[R3SiO3/2]y[SiO4/2]z (2) (where R1 designates univalent hydrocarbon groups of one or more than one type selected from alkyl groups having 1 to 4 carbon atoms and univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; R2 designate alkenyl groups having 2 to 6 carbon atoms; R3 designates alkyl groups with 1 to 4 carbon atoms or univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; at least 50 mole % of R3 groups being phenyl groups; “a” is 0, 1, or 2; 0.8≦w
摘要翻译：通过在（A）由以下平均硅氧烷单元式：[R a R 23-a SiO 1/2/2] v [R 3 SiO 3/2] w（1）表示的有机聚硅氧烷树脂之间进行交联反应获得的固化的有机聚硅氧烷树脂，）或[R1aR23-aSiO1 / 2] x [R3SiO3 / 2] y [SiO4 / 2] z（2）（其中R1表示一个或多于一种选自具有1至4个碳原子的烷基的一价烃基，具有6至8个碳原子的单价芳族烃基; R 2表示具有2至6个碳原子的烯基; R 3表示具有1至4个碳原子的烷基或具有6至8个碳原子的单价芳族烃基;至少50摩尔％ R3为苯基;“a”为0,1或2;0.8≤n1E; w <1.0且v + w = 1; 0

22. 发明申请

US20110086989A1 Organopolysiloxane, Method of Manufacturing Thereof, Curable Silicone Composition, And Cured Product Thereof 有权
标题翻译：有机聚硅氧烷，其制造方法，可固化硅酮组合物及其固化产物
公开(公告)号：US20110086989A1
公开(公告)日：2011-04-14
申请号：US12935092
申请日：2009-03-11
申请人： Yoshitsugu Morita , Michitaka Suto
发明人： Yoshitsugu Morita , Michitaka Suto
IPC分类号： C08G77/38 , C07F7/08
CPC分类号： C08G77/50 , C08L83/14 , C08L83/00
摘要： A curable organopolysiloxane composition comprising: (A) an novel organopolysiloxane represented by the following average structural formula: R1aSiO(4-a)2 {wherein R1 represents a substituted or non-substituted monovalent hydrocarbon group, an alkoxy group, a hydroxyl group, or an organopolysiloxane residue of the following general formula: —X—(SiR2O)mSiR23 (wherein R2 are the same or different, substituted or unsubstituted monovalent hydrocarbon groups; X represents oxygen atoms or a bivalent hydrocarbon group; and ‘m’ is an integer equal to or greater than 1); however, at least one R1 in one molecule is the aforementioned organopolysiloxane residue, at least one R1 is a monovalent hydrocarbon group having aliphatic carbon-carbon double bonds, and ‘a’ is a positive number that satisfies the following condition: 0
摘要翻译：一种可固化的有机基聚硅氧烷组合物，其包含：（A）由以下平均结构式表示的新型有机聚硅氧烷：R1aSiO（4-a）2 {其中R1表示取代或未取代的单价烃基，烷氧基，羟基或具有以下通式的有机聚硅氧烷残基：-X-（SiR 2 O）m SiR 23（其中R 2相同或不同，取代或未取代的一价烃基; X代表氧原子或二价烃基;“m”是等于大于1）; 然而，一个分子中的至少一个R 1是上述有机聚硅氧烷残基，至少一个R 1是具有脂肪族碳 - 碳双键的一价烃基，'a'是满足以下条件的正数：0

23. 发明申请

US20080318067A1 Free Films Made Of Cured Organopolysiloxane Resins, Process For Production Thereof, And Laminated Films 有权
标题翻译：固化有机聚硅氧烷树脂，其生产工艺和层压薄膜制成的免费薄膜
公开(公告)号：US20080318067A1
公开(公告)日：2008-12-25
申请号：US11569104
申请日：2005-05-13
申请人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
发明人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
IPC分类号： B32B9/00 , C08G77/38 , B32B38/10
CPC分类号： C08J5/18 , C08G77/12 , C08G77/20 , C08G77/70 , C08J2383/04 , C08K3/22 , C08L83/04 , Y10T156/1158 , Y10T428/31663 , C08L83/00
摘要： A free-standing film comprising a cured organopolysiloxane resin obtained by conducting a cross-linking reaction between (A) an organopolysiloxane resin represented by the following average siloxane unit formula: [R1aR23-aSiO1/2]v[R3SiO3/2]w (1) or [R1aR23-aSiO1/2]x[R3SiO3/2]y[SiO4/2]z (2) (where R1 designates univalent hydrocarbon groups of one or more than one type selected from alkyl groups having 1 to 4 carbon atoms and univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; R2 designate alkenyl groups having 2 to 6 carbon atoms; R3 designates alkyl groups with 1 to 4 carbon atoms or univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; at least 50 mole % of R3 groups being phenyl groups; “a” is 0, 1, or 2; 0.8≦w
摘要翻译：通过在（A）由以下平均硅氧烷单元：[R1aR23-aSiO1 / 2] v [R3SiO3 / 2] w（1）表示的有机聚硅氧烷树脂之间进行交联反应获得的固化的有机聚硅氧烷树脂）或[R1aR23-aSiO1 / 2] x [R3SiO3 / 2] y [SiO4 / 2] z（2）（其中R1表示一个或多于一种选自具有1至4个碳原子的烷基的一价烃基，具有6至8个碳原子的一价芳族烃基; R 2表示具有2至6个碳原子的烯基; R 3表示具有1至4个碳原子的烷基或具有6至8个碳原子的单价芳族烃基;至少50摩尔％ R3为苯基;“a”为0,1或2; 0.8 <= w <1.0且v + w = 1; 0

24. 发明授权

US08263723B2 Organopolysiloxane, method of manufacturing thereof, curable silicone composition, and cured product thereof 有权
标题翻译：有机聚硅氧烷，其制造方法，可固化有机硅组合物及其固化产物
公开(公告)号：US08263723B2
公开(公告)日：2012-09-11
申请号：US12935092
申请日：2009-03-11
申请人： Yoshitsugu Morita , Michitaka Suto
发明人： Yoshitsugu Morita , Michitaka Suto
IPC分类号： C08G77/04 , C08G77/06 , C08G77/12 , C08G77/20 , C08G77/38
CPC分类号： C08G77/50 , C08L83/14 , C08L83/00
摘要： A curable organopolysiloxane composition comprising: (A) an novel organopolysiloxane represented by the following average structural formula: R1aSiO(4-a)/2 {wherein R1 represents a substituted or non-substituted monovalent hydrocarbon group, an alkoxy group, a hydroxyl group, or an organopolysiloxane residue of the following general formula: —X—(SiR2O)mSiR23 (wherein R2 are the same or different, substituted or unsubstituted monovalent hydrocarbon groups; X represents oxygen atoms or a bivalent hydrocarbon group; and ‘m’ is an integer equal to or greater than 1); however, at least one R1 in one molecule is the aforementioned organopolysiloxane residue, at least one R1 is a monovalent hydrocarbon group having aliphatic carbon-carbon double bonds, and ‘a’ is a positive number that satisfies the following condition: 0
摘要翻译：一种可固化的有机基聚硅氧烷组合物，其包含：（A）由以下平均结构式表示的新型有机聚硅氧烷：R1aSiO（4-a）/ 2 {其中R1表示取代或未取代的单价烃基，烷氧基，羟基，或下述通式的有机聚硅氧烷残基：-X-（SiR2O）mSiR23（其中R2相同或不同，取代或未取代的单价烃基; X表示氧原子或二价烃基;“m”为整数等于或大于1）; 然而，一个分子中的至少一个R 1是上述有机聚硅氧烷残基，至少一个R 1是具有脂肪族碳 - 碳双键的一价烃基，'a'是满足以下条件的正数：0

25. 发明申请

US20050227091A1 Polysiloxane film and process for producing the same 失效
标题翻译：聚硅氧烷薄膜及其制造方法
公开(公告)号：US20050227091A1
公开(公告)日：2005-10-13
申请号：US10516840
申请日：2003-06-05
申请人： Michitaka Suto , Dimitris Katsoulis , Nobuo Kushibiki
发明人： Michitaka Suto , Dimitris Katsoulis , Nobuo Kushibiki
IPC分类号： B32B9/04 , C08F2/46 , C08F4/80 , C08G77/42 , C08J5/18 , C08L83/04 , C08L83/07 , C23C26/00
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08J5/18 , C08J2383/04 , C09D183/04 , C23C26/00 , Y10T428/31663 , C08L83/00
摘要： The present invention relates to a film made from a cross-linked polysiloxane obtained by subjecting a polysiloxane that has a specific chemical structure and contains at least two unsaturated aliphatic hydrocarbon groups in one molecule and an organosilicon compound with at least two hydrogen atoms directly bonded to silicon atoms in one molecule to cross-linking reaction in the presence of a platinum-type catalyst. The film provided by the invention possesses superior heat-resistant properties, has excellent permeability for light in the visible wavelength range, is characterized by low birefringence, and demonstrates physical properties suitable for practical application. By forming an inorganic substance layer on the aforementioned polysiloxane, it is possible to use the laminated film of the invention, e.g., as a transparent electrode film.
摘要翻译：本发明涉及一种由交联聚硅氧烷制成的薄膜，其通过使具有特定化学结构并在一个分子中含有至少两个不饱和脂族烃基的聚硅氧烷和至少两个氢原子的有机硅化合物直接键合到一个分子中的硅原子在铂型催化剂存在下交联反应。本发明提供的薄膜具有优异的耐热性能，对可见光波长范围的光具有极好的透过性，其特征在于双折射低，并表现出适用于实际应用的物理性能。通过在上述聚硅氧烷上形成无机物质层，可以使用本发明的层压膜，例如作为透明电极膜。

26. 发明申请

US20090246499A1 Silicone Resin Film and Method of Preparing Same 审中-公开
标题翻译：硅树脂膜及其制备方法
公开(公告)号：US20090246499A1
公开(公告)日：2009-10-01
申请号：US12441586
申请日：2007-08-16
申请人： Dimitris Katsoulis , Elizabeth Mc Quiston , Michitaka Suto
发明人： Dimitris Katsoulis , Elizabeth Mc Quiston , Michitaka Suto
IPC分类号： B32B5/00 , B32B37/00
CPC分类号： C09D183/04 , C08L83/00
摘要： A method of preparing a silicone resin film comprising coating a first release liner with a filled silicone composition comprising a hydrosilylation-curable silicone composition and a flame retardant filler, applying a second release liner to the coated first release liner to form an assembly, compressing the assembly; and curing the silicone resin of the compressed assembly, wherein the silicone resin film has a thickness of from 1 to 500 μm; and a silicone resin film.
摘要翻译：一种制备有机硅树脂膜的方法，包括用填充的硅氧烷组合物涂覆第一释放衬垫，所述硅氧烷组合物包括可氢化硅烷化可固化的有机硅组合物和阻燃填料，将第二释放衬垫施加到涂覆的第一释放衬垫上以形成组件，部件; 并固化所述压缩组件的硅树脂，其中所述有机硅树脂膜的厚度为1至500μm; 和硅树脂膜。

27. 发明授权

US06252030B1 Hydrogenated octasilsesquioxane-vinyl group-containing copolymer and method for manufacture 失效
标题翻译：氢化八倍半硅氧烷 - 含乙烯基的共聚物及其制造方法
公开(公告)号：US06252030B1
公开(公告)日：2001-06-26
申请号：US09521558
申请日：2000-03-09
申请人： Gregg Alan Zank , Michitaka Suto
发明人： Gregg Alan Zank , Michitaka Suto
IPC分类号： C08G7712
CPC分类号： C08L83/04 , C08G77/045 , C08G77/12 , C08G77/20 , C08G77/50 , C08K5/56 , C08L83/00
摘要： A method for manufacturing an organic solvent-soluble hydrogenated octasilsesquioxane-vinyl group-containing compound copolymer comprising reacting 1 mol of (A) a hydrogenated octasilsesquioxane described by formula I with 0.2 to less than 3 mol of (B) a divinyl group-containing compound described by formula (2) CH2═CH—L—CH═CH2 Formula 2 where L is selected from the group consisting of (a) a divalent hydrocarbon group comprising 3 to 10 carbon atoms and (b) —(SiR2O)m—SiR2—, where each R is independently selected from the group consisting of alkyls comprising 1 to 6 carbon atoms and aryls comprising 6 to 9 carbon atoms and 1≦m≦10; in the presence of a hydrosilylation catalyst.
摘要翻译：一种制造有机溶剂可溶性氢化倍半硅氧烷 - 含乙烯基的化合物共聚物的方法，其包括使1摩尔式（A）式I所示的氢化倍半硅氧烷与0.2至小于3摩尔（B）所述的含二乙烯基化合物式（2）其中L选自（a）包含3至10个碳原子的二价烃基和（b） - （SiR 2 O）m -SiR 2 - ，其中每个R独立地选自的包含1至6个碳原子的烷基和包含6至9个碳原子的芳基和1 <= m <= 10; 在氢化硅烷化催化剂的存在下。

28. 发明授权

US6008310A Silicone release coating compositions 失效
标题翻译：硅酮脱模涂料组合物
公开(公告)号：US6008310A
公开(公告)日：1999-12-28
申请号：US28332
申请日：1998-02-24
申请人： Maki Itoh , Akihito Sakakibara-Saitoh , Michitaka Suto , Takateru Yamada
发明人： Maki Itoh , Akihito Sakakibara-Saitoh , Michitaka Suto , Takateru Yamada
IPC分类号： C08L83/00 , C08L83/04 , C08L83/05 , C08L83/07 , C09D183/04 , C09D183/07 , C08G77/12
CPC分类号： C08L83/04 , C09D183/04 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/70
摘要： This invention relates to a silicone release coating comprising (A) an organopolysiloxane having at least two crosslinkable carbon-carbon double bonds in each molecule, (B) an organopolysiloxane having at least two Si-bonded hydrogen atoms in each molecule, (C) a silylated polymethylsilsesquioxane and (D) platinum catalyst. The silicone release coating compositions of this invention can further comprise an inhibitor. The silicone release coating compositions of this invention do not decline in release resistance due to release paper aging or release liner aging.
摘要翻译：本发明涉及有机硅剥离涂层，其包含（A）在每个分子中具有至少两个可交联碳 - 碳双键的有机聚硅氧烷，（B）每个分子中具有至少两个与Si键合的氢原子的有机聚硅氧烷，（C）甲硅烷基化聚甲基倍半硅氧烷和（D）铂催化剂。本发明的有机硅剥离涂料组合物还可包含抑制剂。本发明的有机硅剥离涂料组合物由于剥离纸老化或脱模剂老化而不会降低耐剥离性。

29. 发明授权

US5939500A Hydrogen-functional silylated polymethylsilsesquioxane 失效
标题翻译：氢功能甲硅烷基化聚甲基倍半硅氧烷
公开(公告)号：US5939500A
公开(公告)日：1999-08-17
申请号：US27548
申请日：1998-02-23
申请人： Maki Itoh , Akihito Sakakibara-Saitoh , Michitaka Suto
发明人： Maki Itoh , Akihito Sakakibara-Saitoh , Michitaka Suto
IPC分类号： C08L83/05 , C08G77/06 , C08G77/12 , C08G77/14 , C08L83/04 , C08L83/06 , C08L83/07 , C08F283/12
CPC分类号： C08G77/12 , C08L83/04 , C08G77/16 , C08G77/20
摘要： A hydrogen-functional silylated polymethylsilsesquioxane that contains no more than 0.12 residual silanol per Si atom and is obtained by silylating the silanol in starting polymethylsilsesquioxane. The starting polymethylsilsesquioxane has a predetermined number average molecular weight, Mn, from 380 to 2,000 and is represented by the general formula(CH.sub.3 SiO.sub.3/2).sub.n (CH.sub.3 Si(OH)O.sub.2/2).sub.mwherein m and n are positive numbers that provide the predetermined Mn, with the proviso that the value of m/(m+n) is less than or equal to 0.152/(Mn.times.10.sup.-3)+0.10 and greater than or equal to 0.034/(Mn.times.10.sup.-3). The hydrogen-functional silylated polymethylsilsesquioxane has the formula(CH.sub.3 SiO.sub.3/2).sub.n (CH.sub.3 Si(OH)O.sub.2/2).sub.m-k (CH.sub.3 Si(OSiR.sup.1 R.sup.2 R.sup.3)O.sub.2/2).sub.kwherein k is a positive number smaller than m, (m-k/(m+n) is less than or equal to 0.12, and R.sup.1, R.sup.2, and R.sup.3 are each selected from substituted and unsubstituted monovalent hydrocarbon groups with the proviso that at least 1 of said R.sup.1, R.sup.2, and R.sup.3 is hydrogen.
摘要翻译：每个Si原子含有不超过0.12个残余硅烷醇的氢官能的甲硅烷基化的聚甲基倍半硅氧烷，并通过在起始的聚甲基倍半硅氧烷中硅烷化得到。起始聚甲基倍半硅氧烷具有预定的数均分子量Mn，为380-2,000，并由通式（CH 3 SiO 3/2）n（CH 3 Si（OH）O 2/2）m表示，其中+ E，uns m + EE和+ E，uns n + EE是提供预定Mn的正数，条件是+ E，uns m + EE /（+ E，uns m + EE ++ E，uns n + EE）的值小于或等于0.152 /（Mn×10-3）+0.10且大于或等于0.034 /（Mn×10-3）。氢官能的甲硅烷基化聚甲基倍半硅氧烷具有式（CH 3 SiO 3/2）n（CH 3 Si（OH）O 2/2）mk（CH 3 Si（OSiR 1 R 2）3 O 2）2其中+ E， E，uns m + EE，（+ E，uns m + EE - + E，uns k + EE /（+ E，uns m + EE ++ E，uns n + EE）小于或等于0.12， R 1，R 2和R 3各自选自取代和未取代的单价烃基，条件是所述R 1，R 2和R 3中的至少1个为氢。

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