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21. 发明申请

US20060078700A1 Coated sheet materials and packages made therewith 有权
公开(公告)号：US20060078700A1
公开(公告)日：2006-04-13
申请号：US11282553
申请日：2005-11-18
申请人： Ioannis Bletsos , Michael Mikhael , Jose Rodriguez-Parada , Angelo Yializis
发明人： Ioannis Bletsos , Michael Mikhael , Jose Rodriguez-Parada , Angelo Yializis
IPC分类号： B60R21/16
CPC分类号： B65D65/42 , B32B5/022 , B32B27/06 , B32B2307/724 , B32B2333/04 , B32B2553/00 , B65D75/30 , D06N3/042 , Y10T428/1334 , Y10T428/1352 , Y10T428/1362 , Y10T428/31855
摘要： A coated porous sheet material comprising a gas permeable sheet material selected from the group consisting of flash spun plexifilamentary nonwoven sheet, spunbonded-film-spunbonded composite sheet, spun-laced polyester/wood pulp composite sheet and paper and a polymeric coating on at least one side thereof, wherein the permeability of the coated sheet material is substantially equivalent to the permeability of an equivalent sheet material without the coating. The coated porous sheet material is suitable for use in heat sealable packages.

22. 发明申请

US20050264179A1 Large-area electroluminescent light-emitting devices 审中-公开
标题翻译：大面积电致发光器件
公开(公告)号：US20050264179A1
公开(公告)日：2005-12-01
申请号：US11137823
申请日：2005-05-25
申请人： Michael Mikhael , Angelo Yializis
发明人： Michael Mikhael , Angelo Yializis
IPC分类号： B05D5/12 , H05B33/10 , H05B33/22
CPC分类号： H05B33/22 , H05B33/10
摘要： An electroluminescent light-emitting device is manufactured in a semi-continuous process using vapor deposition technology to reduce the thickness of the dielectric layers. The phosphor, dielectric and electrode layers are deposited sequentially on a flexible web substrate, preferably PET coated with conductive ITO, which is passed through the deposition sections on a continuous basis. By depositing the dielectric layers in vacuum, very thin layers are possible, which yields increased transparency and electrical capacitance. Accordingly the resulting multi-layer structure is suitable for the manufacture of large-area EL devices.
摘要翻译：采用蒸镀技术的半连续工艺制造电致发光发光器件，以减小电介质层的厚度。磷光体，介电层和电极层依次沉积在柔性幅材基材上，优选地涂覆有导电ITO的PET，其连续地通过沉积部分。通过在真空中沉积介电层，可以实现非常薄的层，这增加了透明度和电容。因此，所得到的多层结构适用于大面积EL器件的制造。

23. 发明授权

US06706412B2 Barrier film for limiting transmission of oxygen and moisture therethrough 失效
标题翻译：阻挡膜用于限制氧气和水分的透过
公开(公告)号：US06706412B2
公开(公告)日：2004-03-16
申请号：US09792196
申请日：2001-02-21
申请人： Angelo Yializis
发明人： Angelo Yializis
IPC分类号： B32B1508
CPC分类号： B05D1/60 , B05D3/144 , B05D3/147 , B32B27/00 , C23C14/20 , H01G4/20 , Y10T428/12569 , Y10T428/12576 , Y10T428/1462 , Y10T428/31515 , Y10T428/31533 , Y10T428/3154 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31855 , Y10T428/31935
摘要： A hybrid film, comprising a first polymer film having a plasma-treated surface and a second polymer film having first and second surfaces, with the first surface of the second polymer film being disposed along the first plasma-treated surface of the first polymer film, has superior thermal and mechanical properties that improve performance in a number of applications, including food packaging, thin film metallized and foil capacitors, metal evaporated magnetic tapes, flexible electrical cables, and decorative and optically variable films. One or more metal layers may be deposited on either the plasma-treated surface of the substrate and/or the radiation-cured acrylate polymer. A ceramic layer may be deposited on the radiation-cured acrylate polymer to provide an oxygen and moisture barrier film. The hybrid film is produced using a high speed, vacuum polymer deposition process that is capable of forming thin, uniform, high temperature, cross-linked acrylate polymers on specific thermoplastic or thermoset films. Radiation curing is employed to cross-link the acrylate monomer. The hybrid film can be produced in-line with the metallization or ceramic coating process, in the same vacuum chamber and with minimal additional cost.
摘要翻译：一种混合膜，包括具有等离子体处理表面的第一聚合物膜和具有第一和第二表面的第二聚合物膜，第二聚合物膜的第一表面沿着第一聚合物膜的第一等离子体处理表面设置，具有优异的热和机械性能，可在许多应用中提高性能，包括食品包装，薄膜金属化和箔电容器，金属蒸发磁带，柔性电缆以及装饰和光学可变膜。一个或多个金属层可以沉积在基板的等离子体处理的表面和/或辐射固化的丙烯酸酯聚合物上。可以将陶瓷层沉积在辐射固化的丙烯酸酯聚合物上以提供氧气和湿气阻挡膜。使用能够在特定热塑性或热固性膜上形成薄的，均匀的，高温的交联的丙烯酸酯聚合物的高速真空聚合物沉积工艺来制备混合膜。辐射固化用于交联丙烯酸酯单体。可以在相同的真空室中以与金属化或陶瓷涂覆方法一致的方式生产混合膜并以最小的额外成本。

24. 发明授权

US06287687B1 Structures and components thereof having a desired surface characteristic together with methods and apparatuses for producing the same 失效
标题翻译：具有期望的表面特性的结构及其组分及其制造方法和装置
公开(公告)号：US06287687B1
公开(公告)日：2001-09-11
申请号：US09307077
申请日：1999-05-07
申请人： Angelo Yializis , Richard E. Ellwanger , Michael G. Mikhael , Wolfgang Decker , C. Barry Johnson , Gale Shipley , Timothy D. O'Brien
发明人： Angelo Yializis , Richard E. Ellwanger , Michael G. Mikhael , Wolfgang Decker , C. Barry Johnson , Gale Shipley , Timothy D. O'Brien
IPC分类号： B32B702
CPC分类号： D06M14/32 , D06M10/025 , D06M14/26 , D06M2101/32 , Y10T428/2913 , Y10T428/2915 , Y10T428/2931 , Y10T428/2933 , Y10T428/2969
摘要： Methods and apparatus for plasma modifying a substrate are disclosed along with associated techniques for applying coatings to the substrate. Particular utility has been found using a hollow cathode to generate the plasma along with magnetic focusing means to focus the plasma at the surface of a substrate.
摘要翻译：公开了用于等离子体改性衬底的方法和装置以及用于将涂层施加到衬底的相关技术。已经发现使用空心阴极产生等离子体以及磁聚焦装置以将等离子体聚焦在基底表面的特别实用性。

25. 发明授权

US06040017A Formation of multilayered photonic polymer composites 有权
标题翻译：多层光子聚合物复合材料的形成
公开(公告)号：US06040017A
公开(公告)日：2000-03-21
申请号：US165999
申请日：1998-10-02
申请人： Michael G. Mikhael , Ali Boufelfel , Angelo Yializis
发明人： Michael G. Mikhael , Ali Boufelfel , Angelo Yializis
IPC分类号： B05D7/24 , C23C14/12 , G02F1/361 , G03G5/07 , C23C16/48
CPC分类号： B05D1/60 , C23C14/12 , G02F1/3615 , G03G5/07
摘要： The fabrication of linear and non-linear optical materials including photoconductive, photorefractive, and optical limiting polymer composite films from radiation curable homogeneous solutions or heterogeneous slurries via vacuum flash evaporation techniques is disclosed.
摘要翻译：公开了通过真空闪蒸蒸发技术制造包括由可辐射固化的均匀溶液或不均匀浆液的光导，光折射和光限制聚合物复合膜的线性和非线性光学材料。

26. 发明授权

US09558679B2 Ultra-bright passivated aluminum nano-flake pigments 有权
标题翻译：超亮度钝化铝纳米片状颜料
公开(公告)号：US09558679B2
公开(公告)日：2017-01-31
申请号：US14562437
申请日：2014-12-05
申请人： Michael G. Mikhael , Angelo Yializis
发明人： Michael G. Mikhael , Angelo Yializis
IPC分类号： C23C14/00 , G09C1/00 , B22F9/16 , C09C1/00 , C09D11/52 , H01B1/08 , B22F9/08 , C09D7/12
CPC分类号： G09C1/00 , B22F9/08 , B22F9/16 , C01P2004/20 , C01P2006/40 , C09C1/00 , C09D7/61 , C09D11/52 , C23C14/0005 , H01B1/08 , Y10T428/256
摘要： An organic release agent is vacuum deposited over a substrate and surface treated with a plasma or ion-beam source in a gas rich in oxygen-based functional groups to harden a very thin layer of the surface of the deposited layer in passivating environment. Aluminum is subsequently vacuum deposited onto the hardened release layer to form a very flat and specular thin film. The film is exposed to a plasma gas containing oxygen or nitrogen to passivate its surface. The resulting product is separated from the substrate, crushed to break up the film into aluminum flakes, and mixed in a solvent to separate the still extractable release layer from the aluminum flakes. The surface treatment of the release layer greatly reduces wrinkles in the flakes, improving the optical characteristics of the flakes. The passivation of the flake material virtually eliminates subsequent corrosion from exposure to moisture.
摘要翻译：将有机剥离剂真空沉积在基材上并用富含氧基官能团的气体中的等离子体或离子束源进行表面处理，以在钝化环境中硬化沉积层表面的非常薄的层。铝随后真空沉积在硬化的剥离层上以形成非常平坦和镜面的薄膜。该膜暴露于含有氧气或氮气的等离子体气体以钝化其表面。将所得产物与基材分离，粉碎以将薄膜分解成铝薄片，并在溶剂中混合以将可提取的脱模层与铝薄片分离。脱模层的表面处理大大减少了薄片的皱纹，提高了薄片的光学特性。薄片材料的钝化实际上消除了暴露于水分后的后续腐蚀。

27. 发明授权

US09082320B2 Ultra-bright passivated aluminum nano-flake pigments 有权
标题翻译：超亮度钝化铝纳米片状颜料
公开(公告)号：US09082320B2
公开(公告)日：2015-07-14
申请号：US11335039
申请日：2006-01-18
申请人： Michael G. Mikhael , Angelo Yializis
发明人： Michael G. Mikhael , Angelo Yializis
IPC分类号： C23C14/00 , G09C1/00 , B22F9/16 , C09D11/52 , H01B1/08
CPC分类号： G09C1/00 , B22F9/08 , B22F9/16 , C01P2004/20 , C01P2006/40 , C09C1/00 , C09D7/61 , C09D11/52 , C23C14/0005 , H01B1/08 , Y10T428/256
摘要： An organic release agent is vacuum deposited over a substrate and surface treated with a plasma or ion-beam source in a gas rich in oxygen-based functional groups to harden a very thin layer of the surface of the deposited layer in a passivating environment. Aluminum is subsequently vacuum deposited onto the hardened release layer to form a very flat and specular thin film. The film is exposed to a plasma gas containing oxygen or nitrogen to passivate its surface. The resulting product is separated from the substrate, crushed to brake up the film into aluminum flakes, and mixed in a solvent to separate the still extractable release layer from the aluminum flakes. The surface treatment of the release layer greatly reduces wrinkles in the flakes, improving the optical chracteristics of the flakes. The passivation of the flake material virtually eliminates subsequent corrosion from exposure to moisture.
摘要翻译：将有机剥离剂真空沉积在基材上并用富含氧基官能团的气体中的等离子体或离子束源进行表面处理，以在钝化环境中硬化沉积层表面的非常薄的层。铝随后真空沉积在硬化的剥离层上以形成非常平坦和镜面的薄膜。该膜暴露于含有氧气或氮气的等离子体气体以钝化其表面。将所得产物与基材分离，粉碎以将膜制成铝片，并在溶剂中混合以将可提取的脱模层与铝片分离。剥离层的表面处理大大减少了薄片的皱纹，提高了薄片的光学特性。薄片材料的钝化实际上消除了暴露于水分后的后续腐蚀。

28. 发明授权

US07807232B2 Inline passivation of vacuum-deposited aluminum on web substrate 有权
标题翻译：真空沉积的铝在网状基材上的在线钝化
公开(公告)号：US07807232B2
公开(公告)日：2010-10-05
申请号：US11586478
申请日：2006-10-25
申请人： Angelo Yializis , Michael Mikhael
发明人： Angelo Yializis , Michael Mikhael
IPC分类号： H05H1/24
CPC分类号： C23C14/022 , C23C14/20 , C23C14/562 , C23C14/5826 , C23C14/5853 , Y10T428/31678
摘要： In a continuous in-vacuum process for the manufacture of a film metallized with aluminum, the aluminum layer is exposed to a passivating agent, inline, immediately after deposition and prior to rewinding of the film onto a take-up roller. Passivation is carried out by plasma treatment in an oxidizing atmosphere (oxygen, nitrogen or others). The resulting product exhibits no peel-off problems during unwinding of the take-up roller and greatly improved corrosion resistance.
摘要翻译：在用于制造用铝金属化的膜的连续真空过程中，铝层在沉积之后并且在将膜重新卷绕到卷取辊上之前立即暴露于钝化剂。钝化通过在氧化气氛（氧气，氮气或其它）中等离子体处理进行。所得产品在卷取辊的卷绕过程中不会出现剥离问题，并且极大地改善了耐腐蚀性。

29. 发明授权

US07781034B2 Composite modular barrier structures and packages 有权
标题翻译：复合模块化屏障结构和封装
公开(公告)号：US07781034B2
公开(公告)日：2010-08-24
申请号：US10838701
申请日：2004-05-04
申请人： Angelo Yializis , Michael G. Mikhael
发明人： Angelo Yializis , Michael G. Mikhael
IPC分类号： B32B27/00 , B32B27/08 , B32B9/00 , B32B9/04 , B32B17/06
CPC分类号： H01L51/5237 , B32B7/02 , B32B27/06 , H01L51/524 , H01L51/5246 , H01L51/5256 , H01L51/5259 , H01L2251/5338 , Y10S977/712 , Y10S977/715 , Y10S977/779 , Y10T428/1321 , Y10T428/1334 , Y10T428/1352 , Y10T428/1372 , Y10T428/1379 , Y10T428/1383 , Y10T428/31504 , Y10T428/31507 , Y10T428/3154 , Y10T428/31551 , Y10T428/31598 , Y10T428/31601 , Y10T428/31667 , Y10T428/31678 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31971
摘要： A composite multi-layer barrier is produced by first vapor depositing a barrier under vacuum over a substrate and then depositing an additional barrier at atmospheric pressure in a preferably thermoplastic layer. The resulting multi-layer barrier is used to coat an article in a lamination process wherein the thermoplastic layer is fused onto itself and the surface of the article. The vacuum-deposited barrier may include of a first leveling polymer layer followed by an inorganic barrier material sputtered over the leveling layer and of an additional polymeric layer flash evaporated, deposited, and cured under vacuum. The thermoplastic polymeric layer is then deposited by extrusion, drawdown or roll coating at atmospheric pressure. The resulting multi-layer barrier may be stacked using the thermoplastic layer as bonding agent. Nano-particles may be included in the thermoplastic layer to improve barrier properties. A desiccant material may also be included or added as a separate layer.
摘要翻译：复合多层屏障是通过在衬底上真空下首先气相沉积阻挡层，然后在大气压下在优选热塑性层中沉积另外的阻挡层来产生的。所得到的多层屏障用于在层压过程中涂覆制品，其中热塑性层熔合到其本身和制品的表面上。真空沉积的屏障可以包括第一平整聚合物层，随后是在流平层上溅射的无机屏障材料，以及在真空下蒸发，沉积和固化的另外的聚合物层。然后通过在大气压下的挤出，拉伸或辊涂来沉积热塑性聚合物层。所得的多层阻挡层可以使用热塑性层作为粘合剂层叠。可以在热塑性层中包含纳米颗粒以改善阻隔性能。还可以包括或添加干燥剂材料作为单独的层。

30. 发明授权

US07557019B2 Electromagnetic treatment in atmospheric-plasma coating process 有权
标题翻译：大气等离子体涂层工艺中的电磁处理
公开(公告)号：US07557019B2
公开(公告)日：2009-07-07
申请号：US11633995
申请日：2006-12-05
申请人： Michael G. Mikhael , Angelo Yializis , Richard E. Ellwanger
发明人： Michael G. Mikhael , Angelo Yializis , Richard E. Ellwanger
IPC分类号： H01L21/20
CPC分类号： B05D1/62 , B05D1/60 , B05D3/0254 , B05D3/0263 , B05D3/06 , B05D3/067 , B05D3/068 , B05D3/142 , B05D3/147 , B05D5/083 , B05D7/04 , B05D2252/02 , C23C16/30 , C23C16/509 , D06M10/025 , D06M10/08 , D06M10/10 , D06M14/18 , D21H21/16 , D21H23/50 , H01J37/32009 , H01J37/32018 , H01J37/3244 , H01J37/32449 , H01J37/32532 , H01J37/32724 , H01J37/32825 , H01L21/312 , H05H1/2406 , H05H2001/2412
摘要： A plasma is produced in a treatment space (58) by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes (54,56) separated by a dielectric material (64), and a precursor material is introduced into the treatment space to coat a substrate film or web (14) by vapor deposition or atomized spraying at atmospheric pressure. The deposited precursor exposed to an electromagnetic field (AC, DC, or plasma) and then it is cured by electron-beam, infrared-light, visible-light, or ultraviolet-light radiation, as most appropriate for the particular material being deposited. Additional plasma post-treatment may be used to enhance the properties of the resulting coated products.
摘要翻译：在处理空间（58）中产生等离子体，通过在大气压下扩散等离子体气体并使其受到由电介质材料（64）分开的两个金属电极（54,56）产生的电场，前体材料是通过在大气压下气相沉积或雾化喷雾而引入处理空间以涂覆基底膜或网（14）。暴露于电磁场（AC，DC或等离子体）中的沉积的前驱物，然后通过电子束，红外光，可见光或紫外光辐射固化，最适合于沉积的特定材料。可以使用额外的等离子体后处理来增强所得涂覆产品的性能。

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