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    • 21. 发明授权
    • Semiconductor process for forming stress absorbent shallow trench isolation structures
    • 用于形成应力吸收性浅沟槽隔离结构的半导体工艺
    • US07442621B2
    • 2008-10-28
    • US10996319
    • 2004-11-22
    • Marius K. OrlowskiMark C. FoisyOlubunmi O. Adetutu
    • Marius K. OrlowskiMark C. FoisyOlubunmi O. Adetutu
    • H01L21/76
    • H01L29/7842H01L21/76224H01L21/76229H01L21/823807H01L21/823878
    • A semiconductor fabrication process includes patterning a hard mask over a semiconductor substrate to expose an isolation region and forming a trench in the isolation region. A flowable dielectric is deposited in the trench to partially fill the trench and a capping dielectric is deposited overlying the first oxide to fill the trench. The substrate may be a silicon on insulator (SOI) substrate including a buried oxide (BOX) layer and the trench may extend partially into the BOX layer. The flowable dielectric may be a spin deposited flowable oxide or a CVD BPSG oxide. The flowable dielectric isolation structure provides a buffer that prevents stress induced on one side of the isolation structure from creating stress on the other side of the structure. Thus, for example, compressive stress created by forming silicon germanium on silicon in PMOS regions does not create compressive stress in NMOS regions.
    • 半导体制造工艺包括在半导体衬底上图案化硬掩模以暴露隔离区域并在隔离区域中形成沟槽。 在沟槽中沉积可流动电介质以部分地填充沟槽,并且覆盖覆盖第一氧化物的覆盖电介质以填充沟槽。 衬底可以是包括掩埋氧化物(BOX)层的绝缘体上硅(SOI)衬底,并且沟槽可以部分地延伸到BOX层中。 可流动电介质可以是自旋沉积的可流动氧化物或CVD BPSG氧化物。 可流动介电隔离结构提供了缓冲器,其防止在隔离结构的一侧上引起的应力在结构的另一侧上产生应力。 因此,例如,通过在PMOS区域中的硅上形成硅锗产生的压缩应力在NMOS区域中不产生压应力。
    • 23. 发明授权
    • ALD gate electrode
    • ALD栅电极
    • US07303983B2
    • 2007-12-04
    • US11331763
    • 2006-01-13
    • Dina H. TriyosoOlubunmi O. AdetutuJames K. Schaeffer
    • Dina H. TriyosoOlubunmi O. AdetutuJames K. Schaeffer
    • H01L21/3205
    • H01L21/28088H01L29/4966H01L29/517H01L29/665H01L29/6656H01L29/6659
    • A semiconductor process and apparatus fabricate a metal gate electrode by forming a first conductive layer (22) over a gate dielectric layer (11), forming a transition layer (32) over the first conductive layer using an atomic layer deposition process in which an amorphizing material is increasingly added as the transition layer is formed, forming a capping conductive layer (44) over the transition layer, and then selectively etching the capping conductive layer, transition layer, and first conductive layer, resulting in the formation of an etched gate stack (52). By forming the transition layer (32) with an atomic layer deposition process in which the amorphizing material (such as silicon, carbon, or nitrogen) is increasingly added, the transition layer (32) is constructed having a lower region (e.g., 31, 33) with a polycrystalline structure and an upper region (e.g., 37, 39) with an amorphous structure that blocks silicon diffusion.
    • 一种半导体工艺和装置,通过在栅介质层(11)上形成第一导电层(22)制造金属栅电极,在第一导电层上形成过渡层(32),使用原子层沉积工艺,其中非晶化 随着形成过渡层,材料越来越多地加入,在过渡层上形成覆盖导电层(44),然后选择性地蚀刻覆盖导电层,过渡层和第一导电层,从而形成蚀刻栅叠层 (52)。 通过用原子层沉积工艺形成过渡层(32),其中非晶化材料(例如硅,碳或氮)越来越多地被加入,过渡层(32)被构造成具有较低的区域(例如,31, 33)和具有阻挡硅扩散的非晶结构的上部区域(例如,37,39)。
    • 24. 发明授权
    • Semiconductor device with low resistance contacts
    • 具有低电阻触点的半导体器件
    • US07179700B2
    • 2007-02-20
    • US10895553
    • 2004-07-21
    • Olubunmi O. AdetutuWilliam J. Taylor, Jr.
    • Olubunmi O. AdetutuWilliam J. Taylor, Jr.
    • H01L21/8238
    • H01L21/28518H01L21/26506H01L21/28044H01L21/28052H01L21/823814H01L21/823835H01L29/456
    • An N channel transistor and a P channel transistor have their source/drains contacts with different suicides to provide for low resistance contacts. The silicides are chosen to provide good matching of the work functions. The P-type source/drain contacts of the P channel transistors have a silicide that is close to the P work function of 5.2 electron volts, and the N-type source/drain contacts of the N channel transistors have a silicide that is close to the N work function of 4.1 electron volts. This provides for a lower resistance at the interface between these source/drain contact regions and the corresponding silicide. These suicides with differing work functions are achieved with implants as needed. For example, for N-type source/drain contacts and a base metal of cobalt, titanium, or nickel, the implanted material is platinum and/or iridium. For the P-type, the implanted material is erbium, yttrium, dysprosium, gadolinium, hafnium, or holmium.
    • N沟道晶体管和P沟道晶体管的源极/漏极接触不同的自杀,以提供低电阻触点。 选择硅化物以提供工作功能的良好匹配。 P沟道晶体管的P型源极/漏极触点具有接近5.2电子伏特的P功函数的硅化物,并且N沟道晶体管的N型源极/漏极触点具有接近于 4.1电子伏特的N工作功能。 这提供了在这些源极/漏极接触区域和相应的硅化物之间的界面处的较低电阻。 具有不同工作功能的这些自杀根据需要用植入物实现。 例如,对于N型源极/漏极触点和钴,钛或镍的母体金属,植入的材料是铂和/或铱。 对于P型,植入的材料是铒,钇,镝,钆,铪或钬。
    • 26. 发明授权
    • Reverse ALD
    • 反向ALD
    • US08404594B2
    • 2013-03-26
    • US11139765
    • 2005-05-27
    • Dina H. TriyosoOlubunmi O. Adetutu
    • Dina H. TriyosoOlubunmi O. Adetutu
    • C23F1/00H01L21/461H01L21/302B44C1/22
    • H01L21/0228H01L21/02142H01L21/02175H01L21/265H01L21/31111H01L21/31116H01L21/31122H01L21/3141H01L21/31645H01L21/823462H01L21/823857H01L29/513H01L29/517H01L29/518H01L29/78
    • A semiconductor process and apparatus includes forming first and second gate electrodes (151, 161) by forming the first gate electrode (151) over a first high-k gate dielectric (121) and forming the second gate electrode (161) over at least a second high-k gate dielectric (122) different from the first gate dielectric (121). Either or both of the high-k gate dielectric layers (121, 122) may be formed by depositing and selectively etching an initial layer of high-k dielectric material (e.g., 14). As deposited, the initial layer (14) has an exposed surface (18) and an initial predetermined crystalline structure. An exposed thin surface layer (20) of the initial layer (14) is prepared for etching by modifying the initial crystalline structure in the exposed thin surface layer. The modified crystalline structure in the exposed thin surface layer may be removed by applying a selective etch, such as HF or HCl.
    • 半导体工艺和装置包括通过在第一高k栅极电介质(121)上形成第一栅电极(151)并且形成第二栅极电极(161)至少形成第一栅极电极(151,161) 与第一栅极电介质(121)不同的第二高k栅极电介质(122)。 可以通过沉积和选择性蚀刻高k电介质材料的初始层(例如14)来形成高k栅极电介质层(121,122)之一或两者。 沉积时,初始层(14)具有暴露表面(18)和初始预定晶体结构。 通过改变暴露的薄表面层中的初始晶体结构,准备初始层(14)的暴露的薄表面层(20)用于蚀刻。 暴露的薄表面层中的改性晶体结构可以通过施加选择性蚀刻如HF或HCl来去除。
    • 29. 发明授权
    • Method for removing metal foot during high-k dielectric/metal gate etching
    • 在高k电介质/金属栅极蚀刻期间去除金属脚的方法
    • US07579282B2
    • 2009-08-25
    • US11331786
    • 2006-01-13
    • Shahid RaufOlubunmi O. AdetutuEric D. LuckowskiPeter L. G. Ventzek
    • Shahid RaufOlubunmi O. AdetutuEric D. LuckowskiPeter L. G. Ventzek
    • H01L21/285H01L21/3065
    • H01L21/02071H01L21/28088H01L21/32136H01L21/32137H01L21/32139H01L29/4966H01L29/517H01L29/518
    • A metal layer etch process deposits, patterns and anisotropically etches a polysilicon layer (24) down to an underlying metal layer (22) to form an etched polysilicon structure (54) with polymer layers (50, 52) formed on its sidewall surfaces. The polymer layer (50, 52) are removed to expose an additional surface area (60, 62) of the metal layer (22), and dielectric layers (80, 82) are formed on the sidewall surfaces of the etched polysilicon structure (54). Next, the metal layer (22) is plasma etched to form an etched metal layer (95) with substantially vertical sidewall surfaces (97, 99) by simultaneously charging the dielectric layers (80, 82) to change plasma ion trajectories near the dielectric layers (80, 82) so that plasma ions (92, 94) impact the sidewall surfaces (97, 99) in a more perpendicular angle to enhance etching of the sidewall surfaces (97, 99) of the etched metal layer (95).
    • 金属层蚀刻工艺沉积,图案和各向异性地将多晶硅层(24)向下蚀刻到下面的金属层(22)以形成蚀刻的多晶硅结构(54),其上形成有在其侧壁表面上的聚合物层(50,52)。 去除聚合物层(50,52)以暴露金属层(22)的另外的表面区域(60,62),并且在蚀刻的多晶硅结构(54)的侧壁表面上形成介电层(80,82) )。 接下来,通过同时对电介质层(80,82)充电以改变电介质层附近的等离子体离子轨迹,等离子体蚀刻金属层(22)以形成具有基本上垂直的侧壁表面(97,99)的蚀刻金属层(95) (80,82),使得等离子体离子(92,94)以更垂直的角度冲击侧壁表面(97,99)以增强蚀刻金属层(95)的侧壁表面(97,99)的蚀刻。