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21. 发明授权

US07022420B1 Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same 失效
公开(公告)号：US07022420B1
公开(公告)日：2006-04-04
申请号：US10775579
申请日：2004-02-09
申请人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
发明人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
IPC分类号： B32B15/00
CPC分类号： C08F12/30 , B82Y30/00 , C07D487/22 , C08F4/00 , C08F12/24 , C08F12/28 , C08G73/0266 , C08L25/18 , G01N33/531 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958 , C08F4/80 , C08L2666/02
摘要： An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.

22. 发明授权

US07344751B2 Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same 失效
公开(公告)号：US07344751B2
公开(公告)日：2008-03-18
申请号：US11111570
申请日：2005-04-21
申请人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
发明人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
IPC分类号： B05D5/12 , C08F2/00 , C08F4/00 , B32B15/00 , C07D487/22
CPC分类号： C08F12/30 , B82Y30/00 , C07D487/22 , C08F4/00 , C08F12/24 , C08F12/28 , C08G73/0266 , C08L25/18 , G01N33/531 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958 , C08F4/80 , C08L2666/02
摘要： An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.

23. 发明授权

US07510739B2 Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same 失效
标题翻译：组装的血红蛋白，其形成方法和使用其聚合芳族单体的方法
公开(公告)号：US07510739B2
公开(公告)日：2009-03-31
申请号：US11111567
申请日：2005-04-21
申请人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
发明人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
IPC分类号： B05D5/12 , C08F2/00 , C08F4/00 , B32B15/00 , C07D487/22 , C08G73/06
CPC分类号： C08F12/30 , B82Y30/00 , C07D487/22 , C08F4/00 , C08F12/24 , C08F12/28 , C08G73/0266 , C08L25/18 , G01N33/531 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958 , C08F4/80 , C08L2666/02
摘要： An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.
摘要翻译：通过将沉积在一个或多个层中的带电衬底上的血红蛋白形成，所述层与一层或多层聚电解质，优选阳离子聚合物交替。在芳族单体聚合的方法中，将组装的血红素与单体和模板（优选阴离子聚合物）接触。在苯胺聚合的方法中，将苯胺磺化多壁碳纳米管，PEG血红素和反应引发剂分散在水中。

24. 发明授权

US07358327B2 Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same 失效
标题翻译：组装的血红蛋白，其形成方法和使用其聚合芳族单体的方法
公开(公告)号：US07358327B2
公开(公告)日：2008-04-15
申请号：US11111566
申请日：2005-04-21
申请人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
发明人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar , Michael Sennett
IPC分类号： C08F2/00 , C08F4/00 , B32B15/00 , C07D487/22
CPC分类号： C08F12/30 , B82Y30/00 , C07D487/22 , C08F4/00 , C08F12/24 , C08F12/28 , C08G73/0266 , C08L25/18 , G01N33/531 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958 , C08F4/80 , C08L2666/02
摘要： An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.
摘要翻译：通过将沉积在一个或多个层中的带电衬底上的血红蛋白形成，所述层与一层或多层聚电解质，优选阳离子聚合物交替。在芳族单体聚合的方法中，将组装的血红素与单体和模板（优选阴离子聚合物）接触。在苯胺聚合的方法中，将苯胺磺化多壁碳纳米管，PEG血红素和反应引发剂分散在水中。

25. 发明授权

US07186792B2 Methods for polymerization of electronic and photonic polymers 失效
标题翻译：电子和光子聚合物的聚合方法
公开(公告)号：US07186792B2
公开(公告)日：2007-03-06
申请号：US11120032
申请日：2005-05-02
申请人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar
发明人： Ferdinando Bruno , Lynne A. Samuelson , Ramaswamy Nagarajan , Jayant Kumar
IPC分类号： C08G73/06
CPC分类号： C07D487/22 , C08F4/00
摘要： A method for polymerizing electronic and photonic polymers, wherein an aromatic monomer is combined with a hematin catalyst derivatized with at least one non-proteinaceous amphipathic group, and a peroxide initiator, and employing a template, wherein the aromatic monomer aligns along the template and polymerizes to form a complex comprising the polymerized monomer and the template.
摘要翻译：一种用于聚合电子和光子聚合物的方法，其中芳族单体与用至少一种非蛋白质两亲性基团衍生的血红素催化剂和过氧化物引发剂结合，并使用模板，其中芳族单体沿模板对齐并聚合以形成包含聚合单体和模板的复合物。

26. 发明授权

US06569651B1 Enzymatic polymerization of anilines or phenols around a template 失效
标题翻译：苯胺或酚类在模板周围的酶聚合
公开(公告)号：US06569651B1
公开(公告)日：2003-05-27
申请号：US09334105
申请日：1999-06-16
申请人： Lynne A. Samuelson , Sukant K. Tripathy , Ferdinando Bruno , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Lynne A. Samuelson , Sukant K. Tripathy , Ferdinando Bruno , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
IPC分类号： C12P1300
CPC分类号： C12P13/001 , C12P7/22 , Y10S435/817 , Y10S977/898
摘要： The micelle contains multiple units, each of which contains a hydrophobic part and a hydrophilic part. A preferred unit is dodecyl benzene sulfonic acid. Borate-containing electrolytes include trifluoroborate, trimethylborate and hydrobis(pyridine)boron. Enzymes include peroxidases such as horseradish peroxidase or lignin peroxidase, and laccase. Monomers include unsubstituted and substituted anilines and unsubstituted and substituted phenols. A method is provided for enzymatic polymerization which includes (1) obtaining a reaction mixture including a monomer, a template, and an enzyme; and (2) incubating the reaction mixture for a time and under conditions sufficient for the monomer to align along the template and polymerize to form a polymer-template complex. The template can be a micelle, a borate-containing electrolyte, or lignin sulfonate. The polymer-template complex may be conductive, and possesses exceptional electrical and optical stability, water solubility, and processibility, and can be used in applications such as light-weight energy storage devices (e.g., rechargeable batteries), electrolytic capacitors, anti-static and anti-corrosive coatings for smart windows, and biological sensors.
摘要翻译：胶束含有多个单元，每个单元含有疏水部分和亲水部分。优选的单元是十二烷基苯磺酸。含硼酸盐的电解质包括三氟硼酸盐，硼酸三甲酯和氢化双（吡啶）硼。酶包括过氧化物酶如辣根过氧化物酶或木质素过氧化物酶，以及漆酶。单体包括未取代的和取代的苯胺和未取代的和取代的酚。提供了一种用于酶促聚合的方法，其包括（1）获得包含单体，模板和酶的反应混合物; 和（2）将反应混合物温育一段时间并在足以使单体沿着模板排列的聚合物形成聚合物 - 模板复合物的条件下。模板可以是胶束，含硼酸盐的电解质或木质素磺酸盐。聚合物 - 模板复合物可以是导电的，并且具有优异的电和光学稳定性，水溶性和可加工性，并且可以用于诸如轻量储能装置（例如可再充电电池），电解电容器，防静电以及智能窗户和生物传感器的防腐涂料。

27. 发明申请

US20130216480A1 AMPHIPHILIC POLYMERS AND METHODS OF USE THEREOF 审中-公开
标题翻译：聚合物及其使用方法
公开(公告)号：US20130216480A1
公开(公告)日：2013-08-22
申请号：US13610150
申请日：2012-09-11
申请人： Clark K. Colton , Arthur Watterson , Rajesh Kumar , Virinder S. Parmar , Robert Fisher , Jayant Kumar
发明人： Clark K. Colton , Arthur Watterson , Rajesh Kumar , Virinder S. Parmar , Robert Fisher , Jayant Kumar
IPC分类号： A61K49/12 , G01N33/574 , G01N33/50 , A61K51/06
CPC分类号： A61K49/126 , A61K9/51 , A61K31/785 , A61K38/10 , A61K47/593 , A61K47/60 , A61K47/6907 , A61K49/0002 , A61K49/0032 , A61K49/0041 , A61K49/0043 , A61K49/0054 , A61K49/0056 , A61K49/0082 , A61K49/14 , A61K49/1809 , A61K49/1818 , A61K51/06 , A61K51/1237 , B82Y5/00 , C08G63/668 , C08G63/672 , C08G63/6826 , C08G63/6854 , C08G63/914 , C08G69/40 , C08G73/028 , C08G2261/126 , C08L77/00 , C08L79/02 , G01N33/5091 , G01N33/57492
摘要： The present invention relates to amphiphilic polymers, and micelles and compositions comprising the same, and their use in a variety of biological settings, including imaging, targeting drugs, or a combination thereof for diagnostic and therapeutic purposes.
摘要翻译：本发明涉及两亲性聚合物，以及包含该两性聚合物的胶束和组合物，以及它们在各种生物学设置中的用途，包括成像，靶向药物或其组合用于诊断和治疗目的。

28. 发明授权

US08349991B2 Amphiphilic polymers and methods of use thereof 有权
标题翻译：两亲聚合物及其使用方法
公开(公告)号：US08349991B2
公开(公告)日：2013-01-08
申请号：US11405012
申请日：2006-04-17
申请人： Clark K. Colton , Arthur Watterson , Rajesh Kumar , Virinder S. Parmar , Robert Fisher , Jayant Kumar
发明人： Clark K. Colton , Arthur Watterson , Rajesh Kumar , Virinder S. Parmar , Robert Fisher , Jayant Kumar
IPC分类号： C08G63/06 , C08G63/12 , C08G69/08 , C08G75/00 , C08G63/00 , C08G67/00 , C08G69/00 , A61K47/30
CPC分类号： A61K49/126 , A61K9/51 , A61K31/785 , A61K38/10 , A61K47/593 , A61K47/60 , A61K47/6907 , A61K49/0002 , A61K49/0032 , A61K49/0041 , A61K49/0043 , A61K49/0054 , A61K49/0056 , A61K49/0082 , A61K49/14 , A61K49/1809 , A61K49/1818 , A61K51/06 , A61K51/1237 , B82Y5/00 , C08G63/668 , C08G63/672 , C08G63/6826 , C08G63/6854 , C08G63/914 , C08G69/40 , C08G73/028 , C08G2261/126 , C08L77/00 , C08L79/02 , G01N33/5091 , G01N33/57492
摘要： The present invention relates to amphiphilic polymers, and micelles and compositions comprising the same, and their use in a variety of biological settings, including imaging, targeting drugs, or a combination thereof for diagnostic and therapeutic purposes.
摘要翻译：本发明涉及两亲性聚合物，以及包含该两性聚合物的胶束和组合物，以及它们在各种生物学设置中的用途，包括成像，靶向药物或其组合用于诊断和治疗目的。

29. 发明授权

US07595074B2 Polymeric antioxidants 失效
标题翻译：聚合物抗氧化剂
公开(公告)号：US07595074B2
公开(公告)日：2009-09-29
申请号：US10761933
申请日：2004-01-21
申请人： Ashok L. Cholli , Vijayendra Kumar , Ashish Dhawan , Jayant Kumar , Virinder Singh Parmar , Lynne Ann Samuelson , Ferdinando F. Bruno
发明人： Ashok L. Cholli , Vijayendra Kumar , Ashish Dhawan , Jayant Kumar , Virinder Singh Parmar , Lynne Ann Samuelson , Ferdinando F. Bruno
IPC分类号： A23D7/00
CPC分类号： A23G3/36 , A23G4/06 , A23L3/3463 , A23L3/349 , A23L13/42 , C09K15/08 , C09K15/10 , C09K15/12 , C09K15/18 , C09K15/20 , C10M2207/026 , C10M2209/10 , C11B5/0035
摘要： A method of preparing a phenolic polymer comprising: a) protecting at least one hydroxyl group of a substituted or unsubstituted phenol represented by Structural Formula (XXIX), wherein: R11, R12, R13, R14 and R15 are independently —H, —OH, —NH, —SH, a substituted or unsubstituted alkyl or aryl group, a substituted or unsubstituted alkoxycarbonyl or aryloxycarbonyl group, a substituted or unsubstituted alkoxy group or a saturated or unsaturated carboxylic acid group; or R11, R12, R13, R14 or R15, in conjunction with an adjacent R11, R12, R13, R14 or R15, forms a substituted or unsubstituted alkylene dioxy group; provided that at least one of R11, R12, R13, R14 or R15 is a tert-butyl group 1-ethenyl-2-carboxylic acid or ester thereof, a substituted or unsubstituted alkylene dioxy group or a substituted or unsubstituted n-alkoxycarbonyl group, at least one of R11, R12, R13, R14 or R15 is a hydroxyl group, and at least one of R11, R12, R13, R14 and R15 is —H; with a protecting group, wherein thereby obtaining one or more protected hydroxyl groups; and b) polymerizing the substituted or unsubstituted phenol, thereby obtaining the phenolic polymer.
摘要翻译：一种制备酚醛聚合物的方法，包括：a）保护由结构式（XXIX）表示的取代或未取代的酚的至少一个羟基，其中：R 11，R 12，R 13，R 14和R 15独立地为-H，-OH， -NH，-SH，取代或未取代的烷基或芳基，取代或未取代的烷氧基羰基或芳氧基羰基，取代或未取代的烷氧基或饱和或不饱和羧酸基团; 或R11，R12，R13，R14或R15与相邻的R11，R12，R13，R14或R15结合形成取代或未取代的亚烷基二氧基; 条件是R11，R12，R13，R14或R15中的至少一个是叔丁基1-乙烯基-2-羧酸或其酯，取代或未取代的亚烷基二氧基或取代或未取代的正烷氧基羰基， R 11，R 12，R 13，R 14或R 15中的至少一个为羟基，R 11，R 12，R 13，R 14和R 15中的至少一个为-H; 与保护基，其中由此获得一个或多个被保护的羟基; 和b）使取代或未取代的苯酚聚合，由此得到酚类聚合物。

30. 发明申请

US20060269479A1 Amphiphilic polymers and methods of use thereof 有权
公开(公告)号：US20060269479A1
公开(公告)日：2006-11-30
申请号：US11405012
申请日：2006-04-17
申请人： Clark Colton , Arthur Watterson , Rajesh Kumar , Virinder Parmar , Robert Fisher , Jayant Kumar
发明人： Clark Colton , Arthur Watterson , Rajesh Kumar , Virinder Parmar , Robert Fisher , Jayant Kumar
IPC分类号： A61K51/00 , A61K38/19 , A61K38/22 , A61K31/785 , C08G63/91 , C08F20/00
CPC分类号： A61K49/126 , A61K9/51 , A61K31/785 , A61K38/10 , A61K47/593 , A61K47/60 , A61K47/6907 , A61K49/0002 , A61K49/0032 , A61K49/0041 , A61K49/0043 , A61K49/0054 , A61K49/0056 , A61K49/0082 , A61K49/14 , A61K49/1809 , A61K49/1818 , A61K51/06 , A61K51/1237 , B82Y5/00 , C08G63/668 , C08G63/672 , C08G63/6826 , C08G63/6854 , C08G63/914 , C08G69/40 , C08G73/028 , C08G2261/126 , C08L77/00 , C08L79/02 , G01N33/5091 , G01N33/57492
摘要： The present invention relates to amphiphilic polymers, and micelles and compositions comprising the same, and their use in a variety of biological settings, including imaging, targeting drugs, or a combination thereof for diagnostic and therapeutic purposes.

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