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    • 21. 发明申请
    • Fungicidal Mixtures
    • 杀菌混合物
    • US20080045414A1
    • 2008-02-21
    • US11793899
    • 2005-12-21
    • Markus GewehrReinhard StierlMatthias NiedenbruckUdo Hunger
    • Markus GewehrReinhard StierlMatthias NiedenbruckUdo Hunger
    • A01N43/40A01N43/54A01P3/00
    • A01N43/80A01N2300/00
    • Fungicidal mixtures, comprising as active components 1) the isoxazole derivative of the formula I, and 2) at least one active compound II selected from the group of the azoles, strobilurins, carboxamides, heterocyclic compounds, carbamates, guanidines, antibiotics, nitrophenyl derivatives, sulfur-containing heterocyclyl compounds, organometallic compounds, organophosphorus compounds, organochlorine compounds, inorganic active compounds, cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine, in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compound I with active compounds II, the use of the compound I with active compounds II for preparing such mixtures and compositions comprising these mixtures.
    • 包含作为活性组分的杀真菌混合物1)式I的异恶唑衍生物,和2)至少一种选自唑类,嗜球半胱氨酸,羧酰胺,杂环化合物,氨基甲酸酯,胍,抗生素,硝基苯基衍生物的活性化合物II, 混合有效量的含硫杂环化合物,有机金属化合物,有机磷化合物,有机氯化合物,无机活性化合物,cyflufenamid,cymoxanil,dimethirimol,ethirimol,furalaxyl,metrafenone和螺螺胺,使用化合物I 使用活性化合物II,使用化合物I与活性化合物II制备这种混合物和包含这些混合物的组合物。
    • 28. 发明申请
    • Use Of Menadione
    • US20080039320A1
    • 2008-02-14
    • US11791464
    • 2005-11-24
    • Harald KohleReinhard StierlRandall GoldFelix GorthJohn-Bryan SpeakmanPeter DomboMartin SemarDieter StrobelMatthias NiedenbruckHans Bestman
    • Harald KohleReinhard StierlRandall GoldFelix GorthJohn-Bryan SpeakmanPeter DomboMartin SemarDieter StrobelMatthias NiedenbruckHans Bestman
    • A01N35/06A01C1/06A01N43/40A01N43/56A01N43/84A01P3/00A01N43/653A01N43/50A01N25/00
    • A01N35/06A01N2300/00
    • The use of menadione or one of its plant-compatible acid addition salts for enhancing the activity of agrochemicals against phytopathogenic fungi, mixtures of menadione and at least one active compound selected from the following groups: A) azoles, such as cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, hexaconazole, imazalil, metconazole, myclobutanil, penconazole, prochloraz, prothioconazole, tebuconazole, triadimefon, triadimenol, triflumizole; B) strobilurins, such as azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin; C) acylalanines, such as benalaxyl, metalaxyl, mefenoxam, ofurace, oxadixyl; D) amine derivatives, such as spiroxamine; E) anilinopyrimidines, such as pyrimethanil, mepanipyrim or cyprodinil; F) dicarboximides, such as iprodione, procymidone, vinclozolin; G) cinnamides and analogs, such as dimethomorph, flumetover or flumorph; H) dithiocarbamates, such as ferbam, nabam, maneb, metam, metiram, propineb, polycarbamate, thiram, ziram, zineb; I) heterocylic compounds, such as benomyl, boscalid, carbendazim, dithianon, famoxadone, fenamidone, picobenzamid, proquinazid, quinoxyfen, thiophanate-methyl, triforine, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide or thiophene derivatives of the formula II; K) sulfur and copper fungicides, such as Bordeaux mixture, copper acetate, copper oxychloride, basic copper sulfate; L) nitrophenyl derivatives, such as dinocap; M) phenylpyrroles, such as fenpiclonil or fludioxonil; N) sulfenic acid derivatives, such as captafol, dichlofluanid, tolylfluanid; 0) other fungicides selected from the group consisting of benthiavalicarb, chlorothalonil, cyflufenamid, diclofluanid, diethofencarb, ethaboxam, fenhexamid, fluazinam, iprovalicarb, metrafenone, zoxamide; oxime ether derivatives of the formula III, phenylamidine derivatives of the formula IV, compounds of the formula V, where in the formulae III to V the substituents are defined according to the description; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of menadione with active compounds from groups A) to O) and compositions comprising these mixtures.
    • 29. 发明申请
    • Fungicidal 5-Hydroxypyrazolines, Method for Producing the Same and Agents Comprising the Same
    • 杀真菌剂5-羟基吡唑啉,其制备方法及其制剂
    • US20080194405A1
    • 2008-08-14
    • US11915989
    • 2006-05-24
    • Markus GewehrJochen DietzThomas GroteAndreas GypserMatthias Niedenbruck
    • Markus GewehrJochen DietzThomas GroteAndreas GypserMatthias Niedenbruck
    • A01N43/56C07D231/08A01P3/00
    • A01N43/56
    • The present invention relates to novel 5-hydroxypyrazolines of the formula I in which the substituents are as defined below: B is phenyl, naphthyl or 5- or 6-membered hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; A is C═O, C═S or SO2; R1 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R2 is alkyl, haloalkyl, alkenyl, haloalkyl, alkynyl, haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered hetaryl or heterocyclyl which contains one to four heteroatoms from the group consisting of O, N and S; R3 is hydrogen, nitro, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, haloalkynyl or NR′2, where R′ independently of one another are hydrogen or alkyl; R4 is hydrogen, halogen, nitro, cyano, NR′2, alkyl, haloalkyl, COOR′ or 5- or 6-membered hetaryl or heterocyclyl; where the variables mentioned above may be substituted according to the description; processes for their preparation, their use for controlling harmful fungi and compositions comprising them.
    • 本发明涉及式I的新的5-羟基吡唑啉,其中取代基如下所定义:B是苯基,萘基或5-或6-元杂芳基,其含有一至四个由O,N和 S; A是C-O,C-S或SO 2。 R 1是烷基,卤代烷基,烯基,卤代烯基,炔基或卤代炔基,环烷基,环烯基,环炔基,苯基,5-或6-元杂环基或杂芳基,其含有一至四个 O,N和S; R 2是烷基,卤代烷基,烯基,卤代烷基,炔基,卤代炔基,环烷基,环烯基,环炔基,苯基,5-或6-元杂芳基或杂环基,其含有一至四个 O,N和S; R 3是氢,硝基,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烯基,卤代烯基,炔基,卤代炔基或NR'2,其中R'彼此独立地 是氢或烷基; R 4是氢,卤素,硝基,氰基,NR'2,烷基,卤代烷基,COOR'或5-或6-元杂芳基或杂环基; 其中上述变量可以根据描述被替代; 其制备方法,它们用于控制有害真菌的用途和包含它们的组合物。
    • 30. 发明申请
    • Bicyclic 5-Hydroxypyrazolines, Method For Producing the Same and Agents Comprising the Same
    • 双环5-羟基吡唑啉,其制备方法和包含其的试剂
    • US20080227840A1
    • 2008-09-18
    • US11916201
    • 2006-05-24
    • Markus GewehrJochen DietzThomas GroteAndreas GypserMatthias Niedenbruck
    • Markus GewehrJochen DietzThomas GroteAndreas GypserMatthias Niedenbruck
    • A01N43/56C07D231/54A01N25/26A01P3/00
    • C07D401/12A01N43/56C07D231/56
    • Bicyclic 5-hydroxypyrazolines of the formula I in which the substituents are as defined below: B is phenyl, naphthyl or 5- or 6-membered hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; A is C═O, C═S or SO2; R1 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R2 together with R1 or R4 is C3-C4-alkylene or C3-C4-alkenylene, which groups may be defined according to the description, R3 is hydrogen, nitro, cyano, NR″2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl or haloalkynyl, where R″ independently of one another are hydrogen or alkyl; R4 is hydrogen, halogen, nitro, cyano, NR″2, alkyl, haloalkyl, COOR″, hetaryl or heterocyclyl; where the variables mentioned above may be substituted according to the description; processes for their preparation, their use for controlling harmful fungi and compositions comprising them.
    • 其中取代基如下定义的式I的双环5-羟基吡唑啉:B是含有一至四个由O,N和S组成的组的杂原子的苯基,萘基或5-或6-元杂芳基; A是C-O,C-S或SO 2。 R 1是烷基,卤代烷基,烯基,卤代烯基,炔基或卤代炔基,环烷基,环烯基,环炔基,苯基,5-或6-元杂环基或杂芳基,其含有一至四个 O,N和S; R 2与R 1或R 4一起是C 3 -C 4烷基, - 亚烷基或C 3 -C 4 - 亚烯基,这些基团可以根据描述定义,R 3是氢,硝基,氰基 ,NR“2,烷基,卤代烷基,烷氧基,卤代烷氧基,烯基,卤代烯基,炔基或卤代炔基,其中R”彼此独立地是氢或烷基; R 4是氢,卤素,硝基,氰基,NR“2,烷基,卤代烷基,COOR”,杂芳基或杂环基; 其中上述变量可以根据描述被替代; 其制备方法,它们用于控制有害真菌的用途和包含它们的组合物。