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    • 28. 发明授权
    • Foam structures of ethylenic polymer material having enhanced toughness
and elasticity and process for making
    • 具有增强的韧性和弹性的乙烯聚合物材料的泡沫结构和制备方法
    • US5369136A
    • 1994-11-29
    • US226150
    • 1994-04-11
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • C08J9/14C08J9/18
    • C08J9/14C08J2323/16Y10S526/943
    • Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form. Further disclosed is a process for making an article of the foam beads.
    • 公开了一种含烯属聚合物材料的乙烯聚合物泡沫结构。 烯属聚合物材料包含基本上线性的乙烯性聚合物,其具有:a)熔体流动比,I10 / I2,= 5.63; b)分子量分布,Mw / Mn,由方程式Mw / Mn定义(I10 / I2)-4.63; 和c)在具有大约相同的I2和Mw / Mn的线性烯烃聚合物的表面熔融断裂开始时,表面熔融断裂开始时的临界剪切速率比临界剪切速率大至少50%。 泡沫结构具有类似于由常规LLDPE形成的那些的韧性和弹性,而没有与这些结构相关联的差的尺寸稳定性和泡沫质量。 泡沫结构的泡沫质量与常规LDPE制成的泡沫质量相似,但具有增强的韧性和弹性。 进一步公开的是制造上述泡沫结构并使其成泡沫珠形式的方法。 进一步公开的是制造泡沫珠的制品的方法。
    • 29. 发明授权
    • Foam structures of ethylenic polymer material having enhanced toughness
and elasticity and process for making
    • 具有增强的韧性和弹性的乙烯聚合物材料的泡沫结构和制备方法
    • US5340840A
    • 1994-08-23
    • US54330
    • 1993-04-28
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • C08J9/14C08J9/18
    • C08J9/14C08J2323/16Y10S526/943
    • Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, I.sub.10 I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form. Further disclosed is a process for making an article of the foam beads.
    • 公开了一种含烯属聚合物材料的乙烯聚合物泡沫结构。 烯属聚合物材料包含基本上线性的乙烯类聚合物,其具有:a)熔体流动比,I10I2,≥5.63; b)分子量分布,Mw / Mn,由方程式Mw / Mn定义(I10 / I2)-4.63; 和c)在具有大约相同的I2和Mw / Mn的线性烯烃聚合物的表面熔融断裂开始时,表面熔融断裂开始时的临界剪切速率比临界剪切速率大至少50%。 泡沫结构具有类似于由常规LLDPE形成的那些的韧性和弹性,而没有与这些结构相关联的差的尺寸稳定性和泡沫质量。 泡沫结构的泡沫质量与常规LDPE制成的泡沫质量相似,但具有增强的韧性和弹性。 进一步公开的是制造上述泡沫结构并使其成泡沫珠形式的方法。 进一步公开的是制造泡沫珠的制品的方法。