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21. 发明申请

US20080275280A1 Method of Preparing an Alkyl Aromatic Product with Phosphorus-Treated Zeolite Catalyst 有权
标题翻译：用磷处理的沸石催化剂制备烷基芳族化合物的方法
公开(公告)号：US20080275280A1
公开(公告)日：2008-11-06
申请号：US12054788
申请日：2008-03-25
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
IPC分类号： C07C2/66
CPC分类号： B01J29/40 , B01J2229/18 , B01J2229/37 , B01J2229/42 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A zeolite catalyst is prepared by treating a zeolite with a phosphorus compound to form a phosphorus-treated zeolite. The phosphorus-treated zeolite is heated to a temperature of about 300° C. or higher and combined with an inorganic oxide binder material to form a zeolite-binder mixture. The zeolite-binder mixture is heated to a temperature of about 400° C. or higher to form a bound zeolite catalyst. The bound zeolite may exhibit at least two 31P MAS NMR peaks with maxima at from about 0 to about −55 ppm, with at least one peak having a maximum at from about −40 to about −50 ppm. Zeolites containing 10-oxygen ring pores that have been prepared in such a way may be used in aromatic alkylation by contacting the bound zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：通过用磷化合物处理沸石以形成磷处理的沸石来制备沸石催化剂。将磷处理的沸石加热至约300℃或更高的温度，并与无机氧化物粘合剂材料组合以形成沸石 - 粘合剂混合物。将沸石 - 粘合剂混合物加热至约400℃或更高的温度以形成结合的沸石催化剂。结合的沸石可以显示至少两个具有约0至约-55ppm的最大值的31 P MAS NMR峰，其中至少一个峰在约-40至约-50ppm处具有最大值。含有以这种方式制备的10-氧环孔的沸石可以通过使结合的沸石催化剂与适于芳族烷基化的反应条件下的芳族化合物和烷基化剂的芳族烷基化进料接触而用于芳族烷基化。

22. 发明授权

US07399727B2 Zeolite catalyst and method 有权
标题翻译：沸石催化剂和方法
公开(公告)号：US07399727B2
公开(公告)日：2008-07-15
申请号：US11136877
申请日：2005-05-25
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
IPC分类号： B01J29/04
CPC分类号： C07C2/66 , B01J29/40 , B01J35/002 , B01J2229/12 , B01J2229/18 , B01J2229/37 , B01J2229/40 , C07C2/864 , C07C2529/40 , C10G2300/1096 , C10G2400/30 , Y02P20/52 , C07C15/08
摘要： A catalyst is formed from a phosphorus-containing ZSM-5-type zeolite. The ZSM-5-type zeolite has a silica/alumina molar ratio of at least 200. The phosphorus-containing ZSM-5-type zeolite also has a phosphorus content of at least 8% by weight of zeolite and has multiple phosphorus species exhibited by at least two 31P MAS NMR peaks with maxima at from about 0 to about −50 ppm. The catalyst may be used in aromatic alkylation by contacting the catalyst with a feed of an aromatic hydrocarbon and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：由含磷ZSM-5型沸石形成催化剂。 ZSM-5型沸石的二氧化硅/氧化铝摩尔比至少为200.含磷ZSM-5型沸石的磷含量至少为沸石重量的8％，具有多种磷类，至少两个具有约0至约-50ppm的最大值的31 P MAS NMR峰。催化剂可以通过在适于芳族烷基化的反应条件下使催化剂与芳族烃和烷基化剂的进料接触而用于芳族烷基化。

23. 发明授权

US07368410B2 Zeolite catalyst and method of preparing and use of zeolite catalyst 有权
标题翻译：沸石催化剂及沸石催化剂的制备与应用
公开(公告)号：US07368410B2
公开(公告)日：2008-05-06
申请号：US11195970
申请日：2005-08-03
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
IPC分类号： B01J29/06
CPC分类号： B01J29/40 , B01J2229/18 , B01J2229/37 , B01J2229/42 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A zeolite catalyst is prepared by treating a zeolite with a phosphorus compound to form a phosphorus-treated zeolite. The phosphorus-treated zeolite is heated to a temperature of about 300° C. or higher and combined with an inorganic oxide binder material to form a zeolite-binder mixture. The zeolite-binder mixture is heated to a temperature of about 400° C. or higher to form a bound zeolite catalyst. The bound zeolite may exhibit at least two 31P MAS NMR peaks with maxima at from about 0 to about −55 ppm, with at least one peak having a maximum at from about −40 to about −50 ppm. Zeolites containing 10-oxygen ring pores that have been prepared in such a way may be used in aromatic alkylation by contacting the bound zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：通过用磷化合物处理沸石以形成磷处理的沸石来制备沸石催化剂。将磷处理的沸石加热至约300℃或更高的温度，并与无机氧化物粘合剂材料组合以形成沸石 - 粘合剂混合物。将沸石 - 粘合剂混合物加热至约400℃或更高的温度以形成结合的沸石催化剂。结合的沸石可以显示至少两个具有约0至约-55ppm的最大值的31 P MAS NMR峰，其中至少一个峰在约-40至约-50ppm处具有最大值。含有以这种方式制备的10-氧环孔的沸石可以通过使结合的沸石催化剂与适于芳族烷基化的反应条件下的芳族化合物和烷基化剂的芳族烷基化进料接触而用于芳族烷基化。

24. 发明申请

US20090036723A1 Method of Preparing a Xylene Product 有权
标题翻译：二甲苯制品的制备方法
公开(公告)号：US20090036723A1
公开(公告)日：2009-02-05
申请号：US11876259
申请日：2007-10-22
申请人： Ashim Kumar Ghosh , Gopalakrishnan Juttu , Pamela Harvey , Neeta Kulkarni
发明人： Ashim Kumar Ghosh , Gopalakrishnan Juttu , Pamela Harvey , Neeta Kulkarni
IPC分类号： C07C2/68
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A method of modifying a zeolite catalyst to increase para-xylene selectivity of the zeolite catalyst in toluene methylation reactions is provided. The method includes forming a slurry of a ZSM-5-type zeolite and an aqueous solution of a phosphorus compound. Water is removed from the slurry to provide a non-steamed, phosphorus treated ZSM-5 zeolite catalyst without deposition of phosphorus onto the catalyst by organophosphorus vapor deposition. The resulting non-steamed, phosphorus treated ZSM-5 zeolite catalyst has a pore volume of from 0.2 ml/g or less and provides greater than 80% para-xylene selectivity of mixed xylenes when used in toluene methylation.
摘要翻译：提供了一种改进沸石催化剂以提高沸石催化剂在甲苯甲基化反应中的对二甲苯选择性的方法。该方法包括形成ZSM-5型沸石的浆料和磷化合物的水溶液。从浆液中除去水，以提供不经蒸煮的磷处理的ZSM-5沸石催化剂，而不通过有机磷气相沉积将磷沉积在催化剂上。所得非蒸馏磷处理的ZSM-5沸石催化剂的孔体积为0.2ml / g或更低，当用于甲苯甲基化时，其混合二甲苯的对二甲苯选择性大于80％。

25. 发明申请

US20080305945A1 Method of Making a Phosphorus-Modified Zeolite Catalyst 有权
标题翻译：制备磷改性沸石催化剂的方法
公开(公告)号：US20080305945A1
公开(公告)日：2008-12-11
申请号：US12142184
申请日：2008-06-19
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey
IPC分类号： B01J29/85
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A catalyst is formed from a phosphorus-containing ZSM-5-type zeolite. The ZSM-5-type zeolite has a silica/alumina molar ratio of at least 200. The phosphorus-containing ZSM-5-type zeolite also has a phosphorus content of at least 8% by weight of zeolite and has multiple phosphorus species exhibited by at least two 31P MAS NMR peaks with maxima at from about 0 to about −50 ppm. The catalyst may be used in aromatic alkylation by contacting the catalyst with a feed of an aromatic hydrocarbon and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：由含磷ZSM-5型沸石形成催化剂。 ZSM-5型沸石的二氧化硅/氧化铝摩尔比至少为200.含磷ZSM-5型沸石的磷含量至少为沸石重量的8％，具有多种磷类，至少两个具有约0至约-50ppm的最大值的31P MAS NMR峰。催化剂可以通过在适于芳族烷基化的反应条件下使催化剂与芳族烃和烷基化剂的进料接触而用于芳族烷基化。

26. 发明授权

US07304194B2 Hydrothermal treatment of phosphorus-modified zeolite catalysts 有权
标题翻译：磷改性沸石催化剂的水热处理
公开(公告)号：US07304194B2
公开(公告)日：2007-12-04
申请号：US11122919
申请日：2005-05-05
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey , Roncalli J. Twomey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Harvey , Roncalli J. Twomey
IPC分类号： C07C2/64 , C07C2/66 , C07C2/68
CPC分类号： C07C2/66 , B01J29/40 , B01J2229/18 , B01J2229/36 , Y02P20/52 , C07C15/08
摘要： A method of treating a ZSM-5-type zeolite catalyst is carried out by treating a ZSM-5 zeolite catalyst having a silica/alumina mole ratio of at least about 200 with a phosphorus compound. The phosphorus-treated ZSM-5 zeolite catalyst is calcined and steamed. Steaming of the catalyst is carried out at a temperature of less than about 300° C. The phosphorus-treated ZSM-5 zeolite catalyst has less than 0.05% by weight of the catalyst of any other element other than phosphorus provided from any treatment of the ZSM-5 zeolite with a compound containing said other element. The catalyst may be used in aromatic alkylation by contacting the catalyst with feed of an aromatic hydrocarbon and an alkylating agent within a reactor under reactor conditions suitable for aromatic alkylation. Water cofeed may be introduced water into the reactor during the aromatic alkylation reaction.
摘要翻译：通过用磷化合物处理具有至少约200的二氧化硅/氧化铝摩尔比的ZSM-5沸石催化剂来进行处理ZSM-5型沸石催化剂的方法。磷处理的ZSM-5沸石催化剂被煅烧和蒸煮。催化剂的蒸汽在小于约300℃的温度下进行。磷处理的ZSM-5沸石催化剂具有小于0.05重量％的任何除了磷的任何其它元素的催化剂 ZSM-5沸石与含有所述其它元素的化合物。催化剂可以通过在适于芳族烷基化的反应器条件下在反应器内使催化剂与芳族烃和烷基化剂的进料接触而用于芳族烷基化。在芳香族烷基化反应期间，可以将水共进料引入反应器中。

27. 发明申请

US20100113850A1 Stable Shape-Selective Catalyst for Aromatic Alkylation and Methods of Using and Preparing 有权
标题翻译：用于芳族烷基化的稳定形状选择性催化剂及其使用和制备方法
公开(公告)号：US20100113850A1
公开(公告)日：2010-05-06
申请号：US12263689
申请日：2008-11-03
申请人： Ashim Kumar Ghosh , Neeta Kulkarni
发明人： Ashim Kumar Ghosh , Neeta Kulkarni
IPC分类号： C07C2/00 , B01J29/06 , B01J29/072 , B01J29/068
CPC分类号： B01J29/44 , B01J29/40 , B01J29/46 , B01J37/28 , B01J2229/18 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C2/66 , C07C2529/44 , C07C15/02
摘要： A catalyst and method of forming a catalyst for use in aromatic alkylation involves treating a zeolite, which may be a ZSM-5 zeolite, with a phosphorus-containing compound. The phosphorus-treated zeolite is combined with a binder material. The bound phosphorus-treated zeolite is treated with an aqueous solution of a hydrogenating metal compound by contacting the bound phosphorus-treated zeolite with the aqueous solution and separating the aqueous solution from the bound phosphorus-treated zeolite to form a hydrogenating-metal-containing zeolite catalyst. The catalyst may be used in preparing an alkyl aromatic product by contacting a hydrogenating-metal-containing zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：形成用于芳族烷基化的催化剂的催化剂和方法包括用含磷化合物处理可以是ZSM-5沸石的沸石。磷处理的沸石与粘合剂材料组合。通过使结合的磷处理的沸石与水溶液接触，将结合的磷处理的沸石用氢化金属化合物的水溶液处理，并将水溶液与结合的磷处理沸石分离以形成含氢化金属的沸石催化剂。通过使含氢化金属的沸石催化剂与芳族化合物和烷基化剂的芳族烷基化进料在适于芳族烷基化的反应条件下接触，催化剂可用于制备烷基芳族化合物。

28. 发明申请

US20160362349A1 STABLE CONVERSION OF ALKYL HALIDE TO OLEFINS 审中-公开
标题翻译：烷基化合物对烯烃的稳定转化
公开(公告)号：US20160362349A1
公开(公告)日：2016-12-15
申请号：US15120780
申请日：2015-06-30
申请人： Ashim Kumar GHOSH , Neeta KULKARNI , Mike MIER , SABIC GLOBAL TECHNOLOGIES B.V.
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Mike Mier
IPC分类号： C07C1/30 , B01J35/10 , B01J37/28 , B01J29/85
CPC分类号： C07C1/30 , B01J29/85 , B01J35/002 , B01J35/1019 , B01J37/28 , B01J2229/186 , C07C1/26 , C07C2529/85 , Y02P20/52 , C07C11/02 , C07C11/04 , C07C11/06
摘要： Disclosed are stable catalysts, and methods for their use, that are capable of producing an olefin from an alkyl halide. The catalysts include a phosphorus-treated silicoalummophosphate (SAPO) having a structure of X/SAPO or X/Z-SAPO, where X includes a non-framework phosphorus and Z is one or more elements from Groups 2A, 3A, IVB, VIB, VIIB, VIII, IB of the Periodic Table, or compounds thereof comprised in the SAPO framework.
摘要翻译：公开了能够从烷基卤生产烯烃的稳定的催化剂及其使用方法。催化剂包括具有X / SAPO或X / Z-SAPO结构的磷处理的磷硅酸钠（SAPO），其中X包括非骨架磷，Z是来自2A，3A，IVB，VIB， VIIB，VIII，IB，或其化合物包含在SAPO框架中。

29. 发明申请

US20140046109A1 METHOD OF MAKING A CATALYST AND CATALYST MADE THEREBY 有权
标题翻译：制备催化剂和催化剂的方法
公开(公告)号：US20140046109A1
公开(公告)日：2014-02-13
申请号：US13570731
申请日：2012-08-09
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Lawyer Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Lawyer Harvey
IPC分类号： B01J37/28 , B01J29/40 , B01J29/89 , C07C2/66
CPC分类号： B01J29/44 , B01J29/40 , B01J29/89 , B01J35/0006 , B01J37/0009 , B01J37/04 , B01J37/16 , B01J37/18 , B01J2229/186 , B01J2229/37 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/22 , C07C2529/44 , C07C2529/67 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： In an embodiment, a method of forming a catalyst can comprises: treating a detemplated pentasil zeolite material with a phosphorus-containing compound to form a phosphorus treated zeolite; combining a hydrogenating material, the phosphorus treated zeolite, and a binder material to form a mixture; forming the mixture into a shaped body, wherein the mixture is formed into the shaped body without the mixture being heat-treated; and calcining the shaped body to form the catalyst. Combining the hydrogenating material with the phosphorus treated zeolite and the binder material occurs prior to forming of the shaped body.
摘要翻译：在一个实施方案中，一种形成催化剂的方法可以包括：用含磷化合物处理一个经过测定的pentasil沸石材料以形成磷处理的沸石; 组合氢化材料，磷处理的沸石和粘合剂材料以形成混合物; 将所述混合物形成成形体，其中所述混合物形成为所述成形体，而不对所述混合物进行热处理; 并煅烧成形体以形成催化剂。在形成成形体之前，将氢化材料与磷处理的沸石和粘合剂材料组合。

30. 发明授权

US09314779B2 Method of making a catalyst and catalyst made thereby 有权
标题翻译：由此制备催化剂和催化剂的方法
公开(公告)号：US09314779B2
公开(公告)日：2016-04-19
申请号：US13570731
申请日：2012-08-09
申请人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Lawyer Harvey
发明人： Ashim Kumar Ghosh , Neeta Kulkarni , Pamela Lawyer Harvey
IPC分类号： B01J29/06 , C07C2/66 , B01J29/44 , B01J37/04 , B01J37/18 , C07C2/86 , B01J37/16 , B01J35/00 , B01J29/40 , B01J29/89 , B01J37/00
CPC分类号： B01J29/44 , B01J29/40 , B01J29/89 , B01J35/0006 , B01J37/0009 , B01J37/04 , B01J37/16 , B01J37/18 , B01J2229/186 , B01J2229/37 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/22 , C07C2529/44 , C07C2529/67 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： In an embodiment, a method of forming a catalyst can comprises: treating a detemplated pentasil zeolite material with a phosphorus-containing compound to form a phosphorus treated zeolite; combining a hydrogenating material, the phosphorus treated zeolite, and a binder material to form a mixture; forming the mixture into a shaped body, wherein the mixture is formed into the shaped body without the mixture being heat-treated; and calcining the shaped body to form the catalyst. Combining the hydrogenating material with the phosphorus treated zeolite and the binder material occurs prior to forming of the shaped body.
摘要翻译：在一个实施方案中，一种形成催化剂的方法可以包括：用含磷化合物处理一个经过测定的pentasil沸石材料以形成磷处理的沸石; 组合氢化材料，磷处理的沸石和粘合剂材料以形成混合物; 将所述混合物形成成形体，其中所述混合物形成为所述成形体，而不对所述混合物进行热处理; 并煅烧成形体以形成催化剂。在形成成形体之前，将氢化材料与磷处理的沸石和粘合剂材料组合。

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