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21. 发明授权

US4942215A Thermosetting liquid composition containing a polyepoxide and a tricarboxylic isocyanurate 失效
标题翻译：含有聚环氧化物和三羧酸异氰脲酸酯的热固性液体组合物
公开(公告)号：US4942215A
公开(公告)日：1990-07-17
申请号：US273358
申请日：1988-11-18
申请人： Alberto Greco , Luigi Raisa
发明人： Alberto Greco , Luigi Raisa
IPC分类号： C08G59/20 , C08G59/42
CPC分类号： C08G59/4238 , C08G59/42
摘要： A thermosetting liquid moulding composition comprising:(a) a polyepoxide containing at least two epoxide groups per molecule;(b) a tricarboxylic acid definable by the general formula: ##STR1## where: R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description; and(c) a diacarboxylic acid anhydride.This composition can be transformed by liquid moulding into manufactured articles particularly useful in the electrical sector.

22. 发明授权

US4778838A Stabilizer compounds and process for their preparation 失效
标题翻译：稳定剂化合物及其制备方法
公开(公告)号：US4778838A
公开(公告)日：1988-10-18
申请号：US45066
申请日：1987-05-01
申请人： Alberto Greco , Carlo Busetto
发明人： Alberto Greco , Carlo Busetto
IPC分类号： C09K15/32 , C07F9/59 , C07F9/6574 , C08K5/54 , C08K5/544 , C08L101/00 , C08K5/34 , C07D211/46 , C07F7/02
CPC分类号： C07F9/65746 , C07F9/592 , C07F9/65744 , C08K5/5406
摘要： Siliconic compounds, stabilizer for organic polymers, containing in their molecule the aromatic phosphite or phosphonite function and the sterically hindered aminic function, are obtained by making a 2,2,6,6-tetramethyl-piperidinyl-4-oxyalkylene-.gamma.-alkyl-di(alkyloxy)silane, an aliphatic glycol, an aromatic phosphite, phosphonite or diphosphite and possibly an aliphatic mono-hydroxy alcohol interact with each other.
摘要翻译：通过制备2,2,6,6-四甲基 - 哌啶基-4-氧亚烷基-γ-烷基 - 亚烷基 - 取代基来获得在其分子中含有芳族亚磷酸酯或亚膦酸酯官能团和空间位阻胺官能团的有机聚合物的稳定剂，二（烷氧基）硅烷，脂族二醇，芳族亚磷酸酯，亚膦酸酯或二亚磷酸酯和可能的脂族单羟基醇相互作用。

23. 发明授权

US4194992A Method for the polymerization of olefines and means suitable thereto 失效
标题翻译：烯烃聚合方法和适合的方法
公开(公告)号：US4194992A
公开(公告)日：1980-03-25
申请号：US926518
申请日：1978-07-20
申请人： Margherita Corbellini , Alberto Greco
发明人： Margherita Corbellini , Alberto Greco
IPC分类号： C01G31/00 , C01G37/00 , C01G45/00 , C01G49/00 , C08F10/00 , C08F4/64 , C08F4/68
CPC分类号： C08F10/00 , C01G31/006 , C01G37/006 , C01G45/00 , C01G49/009 , C01P2006/10 , C01P2006/60
摘要： A novel catalyst system for the polymerization or copolymerization as the case may be, of alpha-olefines is disclosed, which comprises a cocatalyst which is an aluminum-organic compound and a catalyst proper which is obtained by reacting metal vapors (such as vapors of Mg, Al, Ti, V, Cr, Mn, Fe or their alloys) with Ti or V compounds, a halogen donor and a hydrocarbonaceous inert diluent being possibly present. Another aspect of the invention is the conduct of the polymerization, or copolymerization, run proper. Numerous examples of practical application of the catalyst preparation and use are given and the advantages of the novel approach shown.
摘要翻译：公开了用于α-烯烃聚合或共聚的新型催化剂体系，其包括作为铝 - 有机化合物和催化剂的助催化剂，其通过使金属蒸气（例如Mg的蒸气），Al，Ti，V，Cr，Mn，Fe或其合金）与Ti或V化合物，卤素供体和烃惰性稀释剂可能存在。本发明的另一方面是进行聚合或共聚合适合。给出了催化剂制备和使用的实际应用的许多实例，并示出了新颖方法的优点。

24. 发明授权

US06512086B2 Process for preparation of organosilicon compositions 失效
标题翻译：有机硅组合物的制备方法
公开(公告)号：US06512086B2
公开(公告)日：2003-01-28
申请号：US09910957
申请日：2001-07-24
申请人： Alberto Greco , Antonio Ausilio , Enrico Pozzi
发明人： Alberto Greco , Antonio Ausilio , Enrico Pozzi
IPC分类号： C08J300
CPC分类号： C08G65/336 , C08G18/6715 , C08G18/837 , C08G65/33348
摘要： Process for the preparation of fluid organosilicon compounds usable in adhesive, coating and sealant formulations is described. The process includes the synthesis of organosilicon prepolymer compositions starting from unsaturated polyurethanes obtained in turn from unsaturated monoalcohol polyethers and diisocyanates with a controlled NCO/OH ratio, to which chlorosilanes are added in the presence of methyl or ethyl orthoformates. These organosilicon compositions are able to cross-link through silicon-alkoxy end groups of the type:
摘要翻译：描述了可用于粘合剂，涂料和密封剂制剂的流体有机硅化合物的制备方法。该方法包括从不饱和聚氨酯开始合成有机硅预聚物组合物，其中不饱和聚氨酯依次由不饱和一元醇聚醚和具有受控NCO / OH比的二异氰酸酯制备，在原甲酸甲酯或乙酸乙酯存在下加入氯硅烷。这些有机硅组合物能够通过以下类型的硅 - 烷氧基端基交联：

25. 发明授权

US5847069A Process for the preparation of polycarbonate copolyether polyols 失效
标题翻译：制备聚碳酸酯共聚醚多元醇的方法
公开(公告)号：US5847069A
公开(公告)日：1998-12-08
申请号：US818899
申请日：1997-03-17
申请人： Alberto Greco
发明人： Alberto Greco
IPC分类号： C08G65/32 , C08G18/44 , C08G64/18 , C08G64/30 , C08G64/00
CPC分类号： C08G64/183 , C08G18/44 , C08G64/305
摘要： A process is described for the preparation of polycarbonate polyether polyols characterized in that dimethylcarbonate (DMC) and one or more polyether diols are reacted at a ratio DMC/polyether diols of between 0.5 and 1.35, at a temperature of between 130.degree. and 175.degree. C. and in the presence of a catalyst consisting of an oxide, a carbonate or an alcoholate of a metal of the first or second group or a salt or organometallic compound of a metal belonging to the third or fourth or fifth group at a concentration of between 0.0001 and 0.01%.
摘要翻译：描述了一种制备聚碳酸酯聚醚多元醇的方法，其特征在于在130-175℃的温度下，二甲基碳酸酯（DMC）和一种或多种聚醚二醇以DMC /聚醚二醇的比例在0.5和1.35之间反应并且在由第一或第二组的金属的氧化物，碳酸盐或醇化物或属于第三或第四或第五组的金属的盐或有机金属化合物的催化剂的存在下， 0.0001和0.01％。

26. 发明授权

US5795952A Two-stage process for the preparation of polycarbonate copolyether diols 失效
标题翻译：用于制备聚碳酸酯共聚醚二醇的两阶段方法
公开(公告)号：US5795952A
公开(公告)日：1998-08-18
申请号：US818939
申请日：1997-03-17
申请人： Alberto Greco
发明人： Alberto Greco
IPC分类号： B01J23/02 , C07B61/00 , C07C68/06 , C07C69/96 , C08G18/44 , C08G64/18 , C08G64/30 , C08G64/32 , C08G64/00
CPC分类号： C08G64/305 , C08G18/44 , C08G64/183
摘要： A process for the preparation of polycarbonate copolyether diols comprising two successive reaction stages wherein in the first stage the precursor, bisdimethylcarbonate of polyether diols is synthesized by reacting, in a reactor equipped with a distillation column, one or more polyetherglycols with dimethyl carbonate, in the presence of a basic catalyst selected from the group consisting of an oxide, a hydroxide, a carbonate and an alcoholate of a metal belonging to the group of alkaline or earth-alkaline metals and in the second stage, the precursor, after being freed from the catalyst and excess dimethylcarbonate, is converted to polycarbonate copolyether diols by transesterification reaction with polyetherglycols in the presence of a solvent and an organometallic catalyst selected from compounds of tin, lead, titanium, zirconium and antimonium, said polycarbonate polyether diols having utility as additives in the field of polyurethane end-products, thermoelastomers, paints and adhesives.
摘要翻译：一种制备聚碳酸酯共聚醚二醇的方法，包括两个连续的反应阶段，其中在第一阶段中，聚醚二醇的前体，双二甲基碳酸酯通过在装有蒸馏塔的反应器中与一种或多种聚醚二醇与碳酸二甲酯反应合成，存在选自属于碱金属或碱土金属组的金属的氧化物，氢氧化物，碳酸盐和醇化物的碱性催化剂，并且在第二阶段中，所述前体在从催化剂和过量的二甲基碳酸酯通过在溶剂和选自锡，铅，钛，锆和锑的化合物的有机金属催化剂的存在下与聚醚二醇进行酯交换反应而转化为聚碳酸酯共聚醚二醇，所述聚碳酸酯聚醚二醇可用作添加剂聚氨酯最终产品领域，热弹性体，涂料和粘合剂活塞

27. 发明授权

US5288839A Diol-terminated polycarbonates 失效
标题翻译：二醇封端的聚碳酸酯
公开(公告)号：US5288839A
公开(公告)日：1994-02-22
申请号：US944908
申请日：1992-09-15
申请人： Alberto Greco
发明人： Alberto Greco
IPC分类号： C08G18/10 , C08G18/42 , C08G18/44 , C08G18/67 , C08G18/81 , C08G64/00 , C08G64/02 , C08G64/16 , C08G64/18 , C08G64/20 , C08G64/30 , C09J175/00 , C09J175/04 , C09J175/16 , C09K3/10
CPC分类号： C09J175/16 , C08G18/10 , C08G18/44 , C08G18/672 , C08G18/8175 , C08G64/0208 , C08G64/1608 , C08G64/183 , C09J175/04
摘要： Diol-polycarbonates having the general formulaHO--(Ri--O--CO--O).sub.x ----(R.sub.2 --O--CO--O--).sub.y --R.sub.3 --OH (I)where R.sub.1, R.sub.2, R.sub.3, X and Y have the meaning specified in the text, are used in the synthesis of prepolymers which in turn can be used in reactive adhesive and/or sealing formulations of the hygro-, photo- or thermosetting type, and the procedure for their preparation. The sealing compositions deriving from these diolterminated-polycarbonates are mainly used in transport industry, in the textile and wood industry, for cellular products and in the bookbinding industry.
摘要翻译：具有通式HO-（R 1 -O-CO-O）x - （R 2 -O-CO-O-）y -R 3 -OH（I））的二醇 - 聚碳酸酯，其中R1，R2，R3，X和Y具有本文中指定的含义用于预聚物的合成，预聚物又可用于湿热，光或热固型的反应性粘合剂和/或密封配方，以及其制备方法。来自这些二醇封端的聚碳酸酯的密封组合物主要用于运输工业，纺织和木材工业，蜂窝产品和装订行业。

28. 发明授权

US5234995A Method of crosslinking moisture curable systems with oxazolidinic silane and siloxanes 失效
标题翻译：用恶唑烷基硅烷和硅氧烷交联湿气固化体系的方法
公开(公告)号：US5234995A
公开(公告)日：1993-08-10
申请号：US785451
申请日：1991-10-31
申请人： Alberto Greco
发明人： Alberto Greco
IPC分类号： C07F7/08 , C07F7/21 , C08G18/10 , C08G59/50 , C08G77/388 , C08K5/544
CPC分类号： C08K5/5442 , C07F7/0812 , C07F7/0854 , C07F7/0896 , C07F7/21 , C08G18/10 , C08G59/504 , C08G59/5046 , C08G77/388
摘要： New silanes containing at least two oxazolidinic moieties can be defined by means of the general formula: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 have the meaning as reported in the specification, and each one of A.sub.1, A.sub.2 and A.sub.3 represents from 0 to a plurality of siloxane radicals--SiO--and are better defined in the text of the specification.These compounds are useful as crosslinking agents for moisture-hardening systems based on polyisocyanates, of acrylate polymers and of polyepoxides in compositions for coatings, sealants and adhesive agents.
摘要翻译：含有至少两个恶唑烷基部分的新硅烷可以通过以下通式来定义：其中X1，X2，X3和X4具有说明书中报道的含义，A1，A2和A3中的每一个表示0至多个硅氧烷基-SiO-，并且在说明书的文本中更好地定义。这些化合物可用作基于多异氰酸酯，丙烯酸酯聚合物和聚环氧化物在用于涂料，密封剂和粘合剂的组合物中的湿固化体系的交联剂。

29. 发明授权

US4990578A Polyol-polycarbonates and process for preparing them 失效
标题翻译：多元醇 - 聚碳酸酯及其制备方法
公开(公告)号：US4990578A
公开(公告)日：1991-02-05
申请号：US367557
申请日：1989-06-19
申请人： Alberto Greco , Gabriele Lugli
发明人： Alberto Greco , Gabriele Lugli
IPC分类号： C08G63/02 , C08G18/44 , C08G64/00 , C08G64/02 , C08G64/42 , C09D163/00 , C09D169/00
CPC分类号： C09D169/00 , C08G18/44 , C08G64/0241 , C09D163/00
摘要： Polyol-polycarbonates having a molecular weight comprising within the range from 750 to 2500, endowed with good rheologic characteristics and having a low glass transition temperature (Tg), are obtained by means of the reaction, under transesterification conditions, of(a) an organic carbonate;(b) a saturated alifatic .alpha.,.omega.-glycol; and(c) tris-(hydroxyethyl)-isocyanurate.These polyol-polycarbonates are useful as bases for paints in combination with polyisocyanates.Furthermore, the polyol-polycarbonates can be reacted with bicarboxy acids, or with cyclic anhydrides in order to yield the corresponding products with carboxy end groups which are useful as bases for paints in combination with melaminic or epoxy resins.

30. 发明授权

US4203866A Chemical compositions based on titanium trihalides and methods for their production and use 失效
标题翻译：基于三卤化钛的化学成分及其生产和使用方法
公开(公告)号：US4203866A
公开(公告)日：1980-05-20
申请号：US915998
申请日：1978-06-16
申请人： Margherita Corbellini , Alberto Greco , Mirko Osellame
发明人： Margherita Corbellini , Alberto Greco , Mirko Osellame
IPC分类号： C08F4/00 , C01G1/06 , C01G23/00 , C01G31/00 , C08F4/60 , C08F4/62 , C08F4/639 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C01G1/06 , C01G23/002 , C01G31/006 , C01P2006/10 , C01P2006/22 , C01P2006/60 , Y10S526/907
摘要： For the polymerization of ethylene, as such or with one or more alpha-olefins, a novel catalyst composition is described, which gives a high yield of polymer per weight unit of catalyst. Such compositions are prepared from a titanium compound in which the valency of Ti is 3 or more, said compound being reacted with the vapors of one or more metals of the group consisting of Al, Cr, Mn, V, Ti, Zr, Mo, Zn and Ca in the presence of a halogen donor which is preferably an organic halide, certain inorganic halides being capable of being used provided that the halide metal has at least two degrees of valency. The composition is used in association with an aluminium hydrocarbyl halide. Yields as high as 30,000 grams of polymer per gram of elemental Ti can be obtained.
摘要翻译：对于乙烯聚合，如此或与一种或多种α-烯烃的聚合，描述了一种新的催化剂组合物，其给出了每单位重量单位催化剂的高产率的聚合物。这种组合物由Ti化合价为3以上的钛化合物制备，所述化合物与一种或多种Al，Cr，Mn，V，Ti，Zr，Mo， Zn和Ca在优选有机卤化物的卤素供体存在下，某些无机卤化物能够被使用，条件是卤化物金属具有至少两个化合价。该组合物与铝烃基卤化物结合使用。可以获得每克元素Ti产生高达30,000克聚合物。

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