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    • 28. 发明授权
    • Coated cemented carbide endmill having hard-material-coated-layers excellent in adhesion
    • 涂层硬质合金立铣刀具有粘合性优异的硬质材料涂层
    • US06207262B1
    • 2001-03-27
    • US09145616
    • 1998-09-02
    • Hiroshi IchikawaShogo InadaAkira OsadaKatsuhiko SatoKazuhiro Kawano
    • Hiroshi IchikawaShogo InadaAkira OsadaKatsuhiko SatoKazuhiro Kawano
    • B32B1900
    • C23C30/005Y10T407/27Y10T428/24942Y10T428/24975Y10T428/252Y10T428/265
    • A coated cemented carbide endmill comprises a tungsten carbide based cemented carbide substrate comprising 5-20% Co as a binder phase forming component, optionally 0.1-2% of Cr and/or V as a binder phase forming component, optionally 0.1-5% of one or more of (Ti, Ta, Nb, Zr) C·N as a dispersed phase forming component, and the balance being WC as the dispersed phase forming component and inevitable impurities. The WC has a fine grained structure having an average grain size of 0.1-1.5 &mgr;m, the cemented carbide substrate has a reaction-created surface layer formed on the surface portion thereof which is formed by heating at high temperature and in which ComWnC is distributed over a thickness of 0.1-2 &mgr;m thereof, and further the substrate has coated layers composed of a Ti compound layer. Optionally, an Al2O3 layer is formed thereon with an average layer thickness of 0.5-4.5 &mgr;m, the Ti compound layer being composed of one or more layers of TiC, TiN, TiCN, TiCO, TiNO and TiCNO using MT-CVD and the Al2O3 layer is formed using MT-CVD or HT-CVD. The hard-material-coated layers of the endmill have excellent adhesion.
    • 涂覆的硬质合金立铣刀包括基于碳化钨的硬质合金基材,其包含5-20%的Co作为粘合剂相形成组分,任选地0.1-2%的Cr和/或V作为粘合剂相形成组分,任选地0.1-5%的 一种或多种(Ti,Ta,Nb,Zr)CN作为分散相形成组分,余量为作为分散相形成组分的WC和不可避免的杂质。 WC具有平均粒径为0.1〜1.5μm的细晶粒结构,硬质合金基板具有在其表面部分上形成的反应生成的表面层,其通过在高温下加热形成,并且其中ComWnC分布在 其厚度为0.1〜2μm,另外,基板具有由Ti化合物层构成的被覆层。 可选地,在其上形成平均层厚度为0.5-4.5μm的Al 2 O 3层,使用MT-CVD和Al 2 O 3层,Ti化合物层由TiC,TiN,TiCN,TiCO,TiNO和TiCNO的一层或多层组成 使用MT-CVD或HT-CVD形成。 端铣刀的硬质材料涂层具有优异的附着力。
    • 30. 发明授权
    • Process for producing cermet cutting tools having both longitudinal and
granular crystal structures
    • 具有纵向和粒状晶体结构的金属陶瓷切割工具的制造方法
    • US5589223A
    • 1996-12-31
    • US408691
    • 1995-03-21
    • Niro OdaniHironori YoshimuraAkira OsadaTetsuya TanakaSeiichirou Nakamura
    • Niro OdaniHironori YoshimuraAkira OsadaTetsuya TanakaSeiichirou Nakamura
    • C23C16/36C23C30/00C23C16/30
    • C23C16/36C23C30/005Y10T428/24975Y10T428/265
    • A cermet cutting tool, and process for producing the same, comprising a substrate formed from titanium carbo-nitride based cermet, and a hard coating layer of average thickness 0.5.about.20 .mu.m, formed onto the surface of the cermet substrate comprising a lower layer formed from at least one layer of a compound selected from the group consisting of titanium carbide (TiC), titanium nitride (TiN), titanium carbo-nitride (TiCN), titanium carbo-oxide (TiCO) and titanium carbo-oxi-nitride (TiCNO), and aluminum oxide (Al.sub.2 O.sub.3). Additionally, at least one of the layers comprising the hard coating layer is a titanium carbo-nitride layer, and at least one layer of this titanium carbo-nitride layer comprises a longitudinal growth crystal structure, and a further layer comprises a granular crystal structure. In the method of fabrication, chemical vapor deposition is performed using a reaction gas composed of 1.about.5% of TiCl.sub.4, 0.1.about.1% of CH.sub.3 CN, 0.about.25% of N.sub.2 with the remaining portion being composed of H.sub.2, under a reaction temperature of 800.degree..about.900.degree. C. and a reaction pressure of 30.about.200 Torr.
    • 一种金属陶瓷切削工具及其制造方法,包括由碳酸钛基金属陶瓷形成的基板和平均厚度为0.5μm的硬涂层,形成在金属陶瓷基板的表面上,该金属陶瓷基板包括下层 由选自碳化钛(TiC),氮化钛(TiN),碳氮化钛(TiCN),钛碳氧化物(TiCO)和钛碳氧化物氮化物(TiCO)的钛的化合物的至少一层形成, TiCNO)和氧化铝(Al 2 O 3)。 另外,包括硬涂层的层中的至少一层是钛碳氮化物层,并且该钛碳氮化物层的至少一层包含纵向生长晶体结构,另外的层包括颗粒状晶体结构。 在制造方法中,使用由1%的TiCl 4,0.1%的CH 3 CN,0.1%的CH 3 CN组成的反应气体,0%的N 2的剩余部分由H 2组成的反应气体在反应温度下进行化学气相沉积 800℃,反应压力为30℃,反应温度为200Torr。