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21. 发明授权

US5981639A Stabilization of tin-coupled polymers 失效
标题翻译：锡偶合聚合物的稳定化
公开(公告)号：US5981639A
公开(公告)日：1999-11-09
申请号：US58572
申请日：1998-04-10
申请人： Wen-Liang Hsu , Adel Farhan Halasa
发明人： Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： C08C19/44 , C08K5/04 , C08K5/17 , C08K5/34 , C08K5/35 , C08K5/09
CPC分类号： C08C19/44 , C08K5/17 , C08K5/34
摘要： The process of this invention can be utilized to stabilize tin-coupled rubbery polymers. This process involves adding a chelating diamine or a sodium alkoxide to the rubbery polymer after the tin coupling has been carried out. This invention more specifically discloses a process for improving the stability of a tin-coupled rubbery polymer which comprises adding a sodium alkoxide to the tin-coupled rubbery polymer subsequent to the time at which the tin-coupled rubbery polymer is coupled. Sodium alkoxide is a representative example of a sodium alkoxide that can be used to stabilize the tin-coupled rubbery polymer.
摘要翻译：本发明的方法可用于稳定锡偶联的橡胶状聚合物。该方法包括在进行锡偶合之后向橡胶状聚合物中加入螯合二胺或醇钠。本发明更具体地公开了一种改进锡偶合橡胶状聚合物的稳定性的方法，该方法包括在锡偶合的橡胶状聚合物偶合的时间之后向锡偶联的橡胶状聚合物中加入醇钠。烷氧基钠是可用于稳定锡偶联橡胶状聚合物的烷醇钠的代表性实例。

22. 发明授权

US5859133A Tire tread compound 失效
标题翻译：轮胎胎面复合物
公开(公告)号：US5859133A
公开(公告)日：1999-01-12
申请号：US617234
申请日：1996-03-18
申请人： David John Zanzig , Adel Farhan Halasa , Wen-Liang Hsu , Paul Harry Sandstrom , Laurie Elizabeth Austin
发明人： David John Zanzig , Adel Farhan Halasa , Wen-Liang Hsu , Paul Harry Sandstrom , Laurie Elizabeth Austin
IPC分类号： B60C1/00 , C08L9/00 , C08L21/00 , C08L53/00 , C08L53/02 , C08F236/08 , C08F236/06
CPC分类号： C08L21/00 , B60C1/0016 , C08F297/04 , C08L53/00 , C08L9/00 , C08L9/06
摘要： The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100.degree. C. which is within the range of about 50 to about 140, and wherein the repeat units derived from isoprene and 1,3-butadiene in the isoprene-butadiene block are in essentially random order; and (b) a second rubber selected from the group consisting of high vinyl polybutadiene rubber, styrene-isoprene-butadiene rubber, solution styrene-butadiene rubber and emulsion styrene-butadiene rubber.
摘要翻译：本发明公开了一种具有外周胎面的充气轮胎，其中所述胎面是由（a）异戊二烯 - 丁二烯二嵌段橡胶组成的硫固化橡胶组合物，所述异戊二烯 - 丁二烯二嵌段橡胶由丁二烯嵌段和异戊二烯 - 丁二烯嵌段，其中所述丁二烯嵌段的数均分子量在约25,000至约350,000的范围内，其中所述异戊二烯 - 丁二烯嵌段的数均分子量在约25,000至约350,000的范围内，其中所述异戊二烯 - 丁二烯二嵌段橡胶具有在约-100℃至约-70℃范围内的基本上一个玻璃化转变温度，其中所述异戊二烯 - 丁二烯二嵌段聚合物在100℃下具有门尼ML-4粘度，其在约50至约140的范围内，并且其中衍生自异戊二烯和1,3-丁二烯的异戊二烯 - 丁二烯嵌段中的重复单元基本上为兰德呃订单和（b）选自高乙烯基聚丁二烯橡胶，苯乙烯 - 异戊二烯 - 丁二烯橡胶，溶剂苯乙烯 - 丁二烯橡胶和乳液丁苯橡胶的第二橡胶。

23. 发明授权

US5798408A Tire tread of coupled SIBR 失效
标题翻译：耦合SIBR轮胎胎面
公开(公告)号：US5798408A
公开(公告)日：1998-08-25
申请号：US811629
申请日：1997-03-05
申请人： David John Zanzig , Wen-Liang Hsu , Adel Farhan Halasa , Barry Allen Matrana
发明人： David John Zanzig , Wen-Liang Hsu , Adel Farhan Halasa , Barry Allen Matrana
IPC分类号： B60C1/00 , C08F236/10 , C08L9/00 , C08L53/00
CPC分类号： C08F236/10 , B60C1/0016 , C08L9/00 , C08K3/36 , C08L7/00 , C08L9/06 , Y10S156/91 , Y10T152/10495
摘要： This invention relates to a tire having a tread composed of quantitatively silica reinforced rubber composition, with a minor amount, if any, of carbon black where the tread elastomers are primarily composed of coupled styrene/isoprene/butadiene terpolymer with tin or silicon in combination with selected diene-based elastomers.
摘要翻译：本发明涉及一种具有由定量二氧化硅增强橡胶组合物构成的胎面的轮胎，其中少量（如果有的话）为炭黑，其中胎面弹性体主要由与锡或硅组合的苯乙烯/异戊二烯/丁二烯三元共聚物组合，选择的二烯基弹性体。

24. 发明授权

US5739182A Stabilization of tin-coupled polymers 失效
标题翻译：锡偶合聚合物的稳定化
公开(公告)号：US5739182A
公开(公告)日：1998-04-14
申请号：US791929
申请日：1997-01-31
申请人： Wen-Liang Hsu , Adel Farhan Halasa
发明人： Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： C08C19/44 , C08K5/04 , C08K5/17 , C08K5/34 , C08K5/35 , C08K5/3495
CPC分类号： C08K5/17 , C08C19/44 , C08K5/34
摘要： The process of this invention can be utilized to stabilize tin-coupled rubbery polymers. This process involves adding a chelating diamine to the rubbery polymer after the tin coupling has been carried out. This invention more specifically discloses a process for improving the stability of a tin-coupled rubbery polymer which comprises adding a tertiary chelating amine to the tin-coupled rubbery polymer subsequent to the time at which the tin-coupled rubbery polymer is coupled. The tertiary chelating amine will preferably be a tertiary chelating alkyl 1,2-ethylene diamine, such as N,N,N',N'-tetramethylethylenediamine.
摘要翻译：本发明的方法可用于稳定锡偶联的橡胶状聚合物。该方法包括在进行锡偶合之后将螯合二胺加入到橡胶状聚合物中。本发明更具体地公开了一种改进锡 - 偶联橡胶状聚合物稳定性的方法，该方法包括在锡 - 偶联的橡胶状聚合物偶合的时间之后向锡偶合的橡胶状聚合物中加入叔螯合胺。叔螯合胺优选为叔螯合烷基1,2-乙二胺，例如N，N，N'，N'-四甲基乙二胺。

25. 发明授权

US5679751A Solution polymerization process for synthesis of styrene-butadiene or styrene-isoprene rubber 失效
标题翻译：用于合成苯乙烯 - 丁二烯或苯乙烯 - 异戊二烯橡胶的溶液聚合方法
公开(公告)号：US5679751A
公开(公告)日：1997-10-21
申请号：US599542
申请日：1996-02-12
申请人： Adel Farhan Halasa , Laurie Elizabeth Austin , Wen-Liang Hsu , Bill Bud Gross
发明人： Adel Farhan Halasa , Laurie Elizabeth Austin , Wen-Liang Hsu , Bill Bud Gross
IPC分类号： B60C1/00 , C08F4/46 , C08F4/48 , C08F236/10
CPC分类号： B60C1/0016 , C08F236/10
摘要： The subject invention relates to a technique for synthesizing rubbery copolymers of styrene and butadiene and/or isoprene. These rubbers exhibit an excellent combination of properties for utilization in high performance tire tread rubber compounds. The subject invention specifically discloses a process for preparing a styrene-butadiene rubber (SBR) which comprises: copolymerizing from about 30 weight percent to about 55 weight percent styrene and from about 45 weight percent to about 70 weight percent 1,3-butadiene in an alkane solvent, such as hexane, at a temperature which is within the range of about -10.degree. C. to about 150.degree. C. in the presence of (a) an alkali metal alkoxide, and (b) an organolithium compound, wherein the molar ratio of the alkali metal alkoxide to the organolithium compound is within the range of about 0.01:1 to about 1:1. The subject invention further discloses a process for preparing a rubbery copolymer of styrene and isoprene having an excellent combination of properties for use in making tire treads by a solution polymerization process which comprises: copolymerizing from about 30 weight percent to about 55 weight percent styrene and from about 45 weight percent to about 70 weight percent isoprene in an alkane solvent at a temperature which is within the range of about -10.degree. C. to about 150.degree. C. in the presence of (a) an alkali metal alkoxide, and (b) an organolithium compound, wherein the molar ratio of the alkali metal alkoxide to the organolithium compound is within the range of about 0.01:1 to about 1:1.
摘要翻译：本发明涉及一种合成苯乙烯和丁二烯和/或异戊二烯橡胶共聚物的技术。这些橡胶在高性能轮胎胎面橡胶化合物中表现出优异的性能组合。本发明具体公开了一种制备苯乙烯 - 丁二烯橡胶（SBR）的方法，其包括：以约30重量％至约55重量％的苯乙烯和约45重量％至约70重量％的1,3-丁二烯的共聚合烷烃溶剂如己烷，在（a）碱金属醇盐存在下，在约-10℃至约150℃的温度范围内，和（b）有机锂化合物，其中，碱金属醇盐与有机锂化合物的摩尔比在约0.01:1至约1:1的范围内。本发明进一步公开了一种制备苯乙烯和异戊二烯的橡胶共聚物的方法，其具有通过溶液聚合方法制备轮胎胎面的优异的性能组合，其包括：共聚约30重量％至约55重量％的苯乙烯和在（a）碱金属醇盐存在下，在约-10℃至约150℃的温度下，在烷烃溶剂中约45重量％至约70重量％的异戊二烯，和（b ）有机锂化合物，其中碱金属醇盐与有机锂化合物的摩尔比在约0.01:1至约1:1的范围内。

26. 发明授权

US5677402A Process for preparing 3,4-polyisoprene rubber 失效
标题翻译：制备3,4-聚异戊二烯橡胶的方法
公开(公告)号：US5677402A
公开(公告)日：1997-10-14
申请号：US685762
申请日：1996-07-24
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08F4/48 , C08F136/06 , C08F136/08
CPC分类号： C08F136/08 , C08F136/06
摘要： This invention reveals an initiator system which is comprised of (a) a lithium initiator, (b) a sodium alkoxide and (c) a polar modifier; wherein the molar ratio of the sodium alkoxide to the lithium initiator is within the range of about 0.05:1 to about 3:1; and wherein the molar ratio of the polar modifier to the lithium initiator is within the range of about 0.25:1 to about 5:1. The subject invention also discloses a process for preparing 3,4-polyisoprene rubber which comprises polymerizing isoprene monomer with a lithium initiator at a temperature which is within the range of about 30.degree. C. to about 100.degree. C. in the presence of a sodium alkoxide and a polar modifier, wherein the molar ratio of the sodium alkoxide to the lithium initiator is within the range of about 0.05:1 to about 3:1; and wherein the molar ratio of the polar modifier to the lithium initiator is within the range of about 0.25:1 to about 5:1.
摘要翻译：本发明揭示了一种引发剂体系，其包括（a）锂引发剂，（b）醇钠和（c）极性改性剂; 其中所述醇钠与所述锂引发剂的摩尔比在约0.05:1至约3:1的范围内; 并且其中极性改性剂与锂引发剂的摩尔比在约0.25:1至约5:1的范围内。本发明还公开了一种制备3,4-聚异戊二烯橡胶的方法，该方法包括在钠存在下，在约30℃至约100℃的温度范围内用锂引发剂聚合异戊二烯单体醇盐和极性改性剂，其中烷氧基钠与锂引发剂的摩尔比在约0.05:1至约3:1的范围内; 并且其中极性改性剂与锂引发剂的摩尔比在约0.25:1至约5:1的范围内。

27. 发明授权

US5654384A Process for preparing high vinyl polbutadiene rubber 失效
标题翻译：制备高乙烯基聚丁二烯橡胶的方法
公开(公告)号：US5654384A
公开(公告)日：1997-08-05
申请号：US622272
申请日：1996-03-27
申请人： Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , Paul Harry Sandstrom , Steven Kristofer Henning , Danielle Lucas
发明人： Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , Paul Harry Sandstrom , Steven Kristofer Henning , Danielle Lucas
IPC分类号： B60C1/00 , C08F2/38 , C08F2/44 , C08F4/48 , C08F36/00 , C08F36/04 , C08F36/06 , C08F136/06 , C08L9/00 , C08L21/00
CPC分类号： C08F36/04 , C08F136/06 , C08L9/00 , C08K5/06 , C08K5/17 , Y10S152/905
摘要： This invention reveals a process for preparing high vinyl polybutadiene rubber which comprises polymerizing 1,3-butadiene monomer with a lithium initiator at a temperature which is within the range of about 5.degree. C. to about 100.degree. in the presence of a sodium alkoxide and a polar modifier, wherein the molar ratio of the sodium alkoxide to the polar modifier is within the range of about 0.1:1 to about 10:1; and wherein the molar ratio of the sodium alkoxide to the lithium initiator is within the range of about 0.05:1 to about 10:1.
摘要翻译：本发明揭示了一种制备高乙烯基聚丁二烯橡胶的方法，其包括在醇钠存在下，在约5℃至约100℃的温度范围内使锂引发剂聚合1,3-丁二烯单体，以及极性改性剂，其中烷氧基钠与极性改性剂的摩尔比在约0.1:1至约10:1的范围内; 并且其中所述醇钠与所述锂引发剂的摩尔比在约0.05:1至约10:1的范围内。

28. 发明授权

US09587060B2 Functionalized rubbery polymers 有权
标题翻译：官能化橡胶聚合物
公开(公告)号：US09587060B2
公开(公告)日：2017-03-07
申请号：US11603719
申请日：2006-11-22
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Jin-Ping Zhou , Teresa Diane Martter
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Jin-Ping Zhou , Teresa Diane Martter
IPC分类号： C08F236/10 , C08F236/12 , C08F212/08 , C08F212/14 , C08K5/548 , C08K3/36 , B60C1/00 , C07C211/27 , C07F7/10 , C08L21/00 , C08L97/00
CPC分类号： C08F236/12 , B60C1/0016 , C07C211/27 , C07F7/10 , C08F212/08 , C08F212/14 , C08F236/10 , C08K3/36 , C08K5/548 , C08L21/00 , C08L97/00 , C08L15/00 , C08F236/06 , C08L2666/26
摘要： This invention discloses a process for the synthesis of a rubbery polymer by emulsion polymerization that comprised polymerizing (1) a conjugated diolefin monomer and (2) a functionalized monomer having the structural formula: wherein the R1 groups can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 8 carbon atoms, wherein R2 represents a hydrogen atom or an alkyl group containing from 1 to about 8 carbon atoms, wherein R3 represents a hydrogen atom or an alkyl group containing from 1 to about 8 carbon atoms, and wherein R4 represents a hydrogen atom or an alkyl group containing from 1 to about 8 carbon atoms, with the proviso that if R3 represent an alkyl group then R4 represents a hydrogen atom, and with the proviso that R4 represents an alkyl group then R3 represents a hydrogen atom, wherein said polymerization is conducted in an aqueous medium, and wherein said polymerization is initiated with a free radical initiator.
摘要翻译：本发明公开了一种功能单体，其用于聚合物，橡胶组合物，轮胎以及制备这种橡胶组合物的方法。所述官能单体具有选自由以下组成的组的结构式：其中R 1基可以相同或不同，表示氢原子或含有1至8个碳原子的烷基，其中R 2表示氢原子或烷基含有1至8个碳原子的基团，其中R 3表示氢原子或含有1至8个碳原子的烷基，其中R 4表示氢原子或含有1至8个碳原子的烷基，条件是如果R 3表示烷基，则R 4表示氢原子，条件是R 4表示烷基，则R 3表示氢原子，并且其中R 5可以相同或不同，表示烷基含有1至8个碳原子的基团。

29. 发明申请

US20100043938A1 DENDRIMERS OF RUBBERY POLYMERS 失效
标题翻译：橡胶聚合物胶粘剂
公开(公告)号：US20100043938A1
公开(公告)日：2010-02-25
申请号：US12611807
申请日：2009-11-03
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas
IPC分类号： B60C1/00 , C08G77/06 , C08G79/12
CPC分类号： C08C19/44 , B60C1/0016 , C08G83/003 , C08L15/00 , C08L101/005 , Y10T152/10 , Y10T152/10495
摘要： This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated silicon containing compound to produce a polymer which is terminated with halogenated silicon moieties, wherein the halogenated silicon contain compound has at least four halogen atoms which are bonded directly to silicon atoms, wherein the ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated silicon containing compound is within the range of 2:n to (n-1):n, wherein n represents the number of halogen atoms that are bonded directly to silicon atoms in the halogenated silicon containing compound, wherein the halogenated silicon containing compound contains at least three halogen atoms which are bonded directly to a silicon atom; (b) reacting the polymer which is terminated with halogenated silicon moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy silyl moieties; and (c) allowing the polymer which is terminated with the hydroxy silyl moieties to couple under conditions sufficient to produce a dendrimer containing siloxane linkages. It has also be found that similar dendrimers having improved processability can be make utilizing halogenated tin containing compounds in stead of the halogenated silicon containing compound.
摘要翻译：本发明公开了一种用于合成橡胶状聚合物树枝状聚合物的方法，包括：（a）使锂封端的橡胶状聚合物与含卤化硅的化合物反应以制备用卤化硅部分封端的聚合物，其中卤化硅含有化合物在至少四个与硅原子直接键合的卤素原子，其中锂封端的橡胶状聚合物与含卤化硅化合物中的卤素原子的比例在2：n至（n-1）：n的范围内，其中n表示与卤代硅化合物中的硅原子直接键合的卤素原子数，其中含卤化硅的化合物含有至少三个与硅原子直接键合的卤素原子; （b）将用卤代硅部分封端的聚合物与摩尔过量的叔醇反应，以产生用羟基甲硅烷基部分封端的聚合物; 和（c）使在羟基甲硅烷基部分封端的聚合物在足以产生含有硅氧烷键的树枝状聚合物的条件下偶联。还可以发现，具有改进加工性能的类似树枝状大分子可以利用含卤化锡的化合物代替含卤化硅的化合物。

30. 发明申请

US20090156769A1 FUNCTIONALIZED MONOMERS AND FUNCTIONALIZED RUBBERY POLYMERS MADE THEREWITH 有权
标题翻译：功能性单体和功能性橡胶聚合物
公开(公告)号：US20090156769A1
公开(公告)日：2009-06-18
申请号：US11955453
申请日：2007-12-13
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Shingo Futamura , Joe Zhou , Chad Aaron Jasiunas
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Shingo Futamura , Joe Zhou , Chad Aaron Jasiunas
IPC分类号： C08F4/28 , C07C381/00 , C07F9/28 , C07F7/08 , C08F230/02 , C08F26/00 , C08F26/06
CPC分类号： C08F236/14 , C07C323/25 , C07F7/1804 , C07F9/5004 , C07F9/5031 , C08L19/006
摘要： Rubbery polymers can be formed having the general formula: R1R2N—(CH2)n—X—CH2—CHR3R4 wherein R1 and R2 are independently selected from a group consisting of alkyls, cycloalkyls, alkenyls, cycloalkenyls, aryls, phenyls, heterocycles, acyls, and silanes, or R1 in combination with R2 forms a heterocyclic ring; n is an integer from 1 to 20; X is selected from a group consisting of sulfur, a phosphorus moiety, and a silicon moiety; R3 and R4 are one of hydrogen, alkyls, alkenyls, and at least one of which includes reactive unsaturation such as an alkenyl group. Moreover, this invention discloses a process of making functionalized rubbery polymers from the functionalized monomers.
摘要翻译：可以形成具有以下通式的橡胶状聚合物：<？in-line-formula description =“In-line formula”end =“lead”？> R1R2N-（CH2）nX-CH2-CHR3R4 <？in-line-formula description 其中R 1和R 2独立地选自烷基，环烷基，烯基，环烯基，芳基，苯基，杂环，酰基和硅烷，或R 1与 R2形成杂环; n为1〜20的整数， X选自硫，磷部分和硅部分; R3和R4是氢，烷基，烯基之一，并且其中至少一个包括反应性不饱和键如烯基。此外，本发明公开了一种由官能化单体制备官能化橡胶聚合物的方法。

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