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21. 发明授权

US07235704B2 Process for preparing isobutene from tert-butanol 有权
标题翻译：从叔丁醇制备异丁烯的方法
公开(公告)号：US07235704B2
公开(公告)日：2007-06-26
申请号：US10868904
申请日：2004-06-17
申请人： Gerda Grund , Wilfried Bueschken , Dieter Reusch , Andreas Beckmann
发明人： Gerda Grund , Wilfried Bueschken , Dieter Reusch , Andreas Beckmann
IPC分类号： C07C1/00
CPC分类号： B01J8/0242 , B01J8/0005 , B01J8/06 , B01J19/0013 , B01J19/2475 , B01J2219/00006 , C07C1/24 , C07C2531/08 , C07C11/09
摘要： Isobutene is prepared by dissociating tert-butanol into isobutene and water over an acid ion-exchange resin arranged as a fixed bed in at least one reactor at a temperature of from 80 to 150° C. and at a pressure of from 5 to 25 bar to obtain a reaction mixture, separating the reaction mixture into isobutene, a by-product, water and at least one mixture of undissociated tert-butanol and water. The reactor is operated pseudo-isothermally, with a temperature difference between inflowing and outflowing streams of less than 15 K.
摘要翻译：异丁烯是通过在80至150℃的温度和5至25巴的压力下，在至少一个反应器中将叔丁醇离解成异丁烯和水，在酸性离子交换树脂上作为固定床排列的，以获得反应混合物，将反应混合物分离成异丁烯，副产物，水和至少一种未离解的叔丁醇和水的混合物。反应器假模拟运行，流入和流出之间的温度差小于15K。

22. 发明授权

US07179948B2 Process for preparing tert-butanol 有权
标题翻译：叔丁醇的制备方法
公开(公告)号：US07179948B2
公开(公告)日：2007-02-20
申请号：US10739086
申请日：2003-12-19
申请人： Bernhard Scholz , Franz Nierlich , Dieter Reusch , Silvia Santiago Fernandez , Andreas Beckmann , Wilfried Bueschken , Alfred Kaizik
发明人： Bernhard Scholz , Franz Nierlich , Dieter Reusch , Silvia Santiago Fernandez , Andreas Beckmann , Wilfried Bueschken , Alfred Kaizik
IPC分类号： C07C29/04 , C07C29/06 , C07C27/08
CPC分类号： C07C29/04 , C07C31/12
摘要： The invention relates to a process for preparing tert-butanol by reaction of a homogeneous mixture comprising water, tert-butanol and an isobutene-containing hydrocarbon mixture over an acidic ion-exchange resin at from 30 to 120° C., wherein the homogeneous mixture contains, at a proportion by mass of isobutene of above 10%, from 30 to 80% of the maximum amount of water made possible by the solubility of water in the mixture of tert-butanol and the isobutene-containing hydrocarbon mixture.
摘要翻译：本发明涉及一种通过酸性离子交换树脂在30〜120℃下由包含水，叔丁醇和含异丁烯的烃混合物的均匀混合物反应制备叔丁醇的方法，其中均匀混合物以大于10％的异丁烯的比例含有由水在叔丁醇和含异丁烯的烃混合物的混合物中的溶解度而产生的最大量的水的30至80％。

23. 发明授权

US06407295B1 Process for preparing higher oxo alcohols from olefin mixtures 失效
标题翻译：从烯烃混合物制备高级烯醇的方法
公开(公告)号：US06407295B1
公开(公告)日：2002-06-18
申请号：US09396402
申请日：1999-09-15
申请人： Alfred Kaizik , Bernhard Scholz , Walter Toetsch , Martin Trocha , Wilfried Bueschken , Franz Nierlich
发明人： Alfred Kaizik , Bernhard Scholz , Walter Toetsch , Martin Trocha , Wilfried Bueschken , Franz Nierlich
IPC分类号： C07C2916
CPC分类号： C07C31/125 , C07C29/141 , C07C45/50 , C07C47/02
摘要： The invention relates to a process for preparing higher oxo alcohols from mixtures of isomeric olefins having from 5 to 24 carbon atoms by hydroformylation in the presence of a catalyst at elevated temperature and at elevated pressure, in which the hydroformylation is carried out in one stage, the olefin conversion rate for one pass is restricted to from 40 to 90% to produce a reaction mixture, and the reaction mixture is selectively hydrogenated.
摘要翻译：本发明涉及一种通过在催化剂存在下在升高的温度和升高的压力下通过加氢甲酰化从具有5至24个碳原子的异构烯烃的混合物制备高级羰基合成醇的方法，其中加氢甲酰化在一个阶段中进行，一次通过的烯烃转化率限制在40〜90％，生成反应混合物，反应混合物选择性氢化。

24. 发明授权

US5756856A Process for the preparation of 2-ethylhexanal 失效
标题翻译： 2-乙基己醛的制备方法
公开(公告)号：US5756856A
公开(公告)日：1998-05-26
申请号：US668355
申请日：1996-06-26
申请人： Wilfried Bueschken , Juergen Hummel
发明人： Wilfried Bueschken , Juergen Hummel
IPC分类号： B01J23/44 , C07B61/00 , C07C45/62 , C07C47/02
CPC分类号： C07C45/62
摘要： The present invention relates to a process for the preparation of 2-ethylhexanal by catalytic hydrogenation of 2-ethylhex-2-enal, wherein the hydrogenation is carried out in a plurality of two or more series-connected loops, wherein each loop involves the use of one reactor, which comprises: (a) feeding 2-ethylhex-2-enal and hydrogen to an upper part of a reactor to catalytically hydrogenate said 2-ethylhex-2-enal to produce a hydrogenation product, (b) recycling a portion of said hydrogenation product back into said upper part of said reactor, (c) feeding the remainder of said hydrogenation product from said reactor to an upper part of a subsequent reactor wherein 2-ethylhex-2-enal is catalytically hydrogenated to produce a subsequent hydrogenation product, and wherein a portion of said subsequent hydrogenation product has been recycled and is fed with said remainder of said hydrogenation product to said upper part of said subsequent reactor, (d) repeating step (c) until the subsequent reactor is the last reactor, (e) recovering the remainder of said subsequent hydrogenation product from said last reactor, and (f) obtaining 2-ethylhexanal from the product of step (e).
摘要翻译：本发明涉及通过2-乙基己-2-烯醛的催化氢化制备2-乙基己醛的方法，其中氢化在多个两个或多个串联连接的环中进行，其中每个环包括使用的一个反应器，其包括：（a）将2-乙基己-2-烯醛和氢气加入到反应器的上部以催化氢化所述2-乙基己-2-烯醛以产生氢化产物，（b）将部分的所述氢化产物回到所述反应器的上部，（c）将剩余的所述氢化产物从所述反应器进料到后续反应器的上部，其中2-乙基己-2-烯醛被催化氢化以产生随后的氢化产物，并且其中所述后续氢化产物的一部分已经被再循环，并且将所述剩余的所述氢化产物进料到所述后续反应器的所述上部，（d）重复步骤（c）直到亚序列 t反应器是最后一个反应器，（e）从所述最后一个反应器回收剩余的所述后续氢化产物，和（f）从步骤（e）的产物得到2-乙基己醛。

25. 发明授权

US08461394B2 Process for preparing C5 aldehyde mixtures with a high n-pentanal content 有权
标题翻译：制备具有高正戊醛含量的C5醛混合物的方法
公开(公告)号：US08461394B2
公开(公告)日：2013-06-11
申请号：US12995800
申请日：2009-04-28
申请人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
发明人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
IPC分类号： C07C45/50
CPC分类号： B01J31/0237 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , C07C47/02
摘要： A process for preparing a C5 aldehyde mixture from a hydrocarbon mixture comprising at least one linear butene by terminal hydroformylation under isomerizing conditions, using a catalyst system comprising rhodium, a bisphosphite ligand, and an amine.
摘要翻译：一种通过使用包含铑，二亚磷酸酯配位体和胺的催化剂体系在异构化条件下通过末端加氢甲酰基化从包含至少一个直链丁烯的烃混合物制备C5醛混合物的方法。

26. 发明授权

US08431638B2 Citric ester mixtures and their use 失效
标题翻译：柠檬酸酯混合物及其用途
公开(公告)号：US08431638B2
公开(公告)日：2013-04-30
申请号：US12990225
申请日：2009-05-05
申请人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
发明人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
IPC分类号： C08K5/10
CPC分类号： C07C69/704 , C08K5/0016 , C08K5/11
摘要： The present invention relates to mixtures of citric esters of the formula I, in which each of R1, R2 and R3 is an aliphatic C5 or C9 moiety, wherein the average chain length of the aliphatic moieties in the mixture is in the range from greater than 5 to 7, and the average degree of branching of the aliphatic C9 moieties is in the range from 0.9 to 2.2. The present invention also relates to the use of the citric ester mixture as a plasticizer in plastics compositions.
摘要翻译：本发明涉及式I的柠檬酸酯的混合物，其中R 1，R 2和R 3各自为脂族C 5或C 9部分，其中混合物中脂族部分的平均链长在大于 5至7，并且脂族C 9部分的平均支化度在0.9至2.2的范围内。本发明还涉及柠檬酸酯混合物作为塑料组合物中的增塑剂的用途。

27. 发明申请

US20120116140A1 WORK-UP OF A 3-METHYL-1-BUTENE-CONTAINING MIXTURE 失效
标题翻译：一种含3-甲基-1-丁烯的混合物的研究
公开(公告)号：US20120116140A1
公开(公告)日：2012-05-10
申请号：US13375091
申请日：2010-04-29
申请人： Markus Winterberg , Alfred Kaizik , Armin Rix , Michael Grass , Wilfried Bueschken , Marc Becker
发明人： Markus Winterberg , Alfred Kaizik , Armin Rix , Michael Grass , Wilfried Bueschken , Marc Becker
IPC分类号： C07C5/00 , B01D3/36 , C07C7/04 , B01D3/14
CPC分类号： C07C7/04 , C07C1/24 , C07C7/06 , C07C11/10
摘要： The invention is a method for processing a mixture containing water, 3-methyl-1-butene and at least one other methylbutene. The method comprises primary distillation of the mixture, giving a gaseous primary overhead product containing methylbutene and water and a water-free primary bottom product containing 3-methyl-1-butene; condensation of the gaseous primary overhead product so as to give a condensate comprising a liquid aqueous phase and a liquid organic phase; separation of the condensate into a liquid aqueous phase and a liquid organic phase; discharge of the liquid aqueous phase; recirculation of the organic phase to the primary distillation; and finally secondary distillation of the water-free primary bottom product from the primary distillation so as to give a secondary overhead product comprising 3-methyl-1-butene and a secondary bottom product. The secondary overhead product obtained has a purity which enables it to be used directly as monomer or comonomer for preparing polymers or copolymers.
摘要翻译：本发明是一种处理含有水，3-甲基-1-丁烯和至少一种其它甲基丁烯的混合物的方法。该方法包括对该混合物进行一次蒸馏，得到含有甲基丁烯和水的气态初级塔顶馏出物和含有3-甲基-1-丁烯的无水初级底物产物; 气态一级塔顶产物的冷凝，以产生包含液态水相和液体有机相的冷凝物; 将冷凝物分离成液态水相和液体有机相; 液体水相的排出; 将有机相再循环至初级蒸馏; 最后从初级蒸馏二次蒸馏无水初级底部产物，得到包含3-甲基-1-丁烯和二级底部产物的二级塔顶产物。获得的二次塔顶产物具有使其能够直接用作制备聚合物或共聚物的单体或共聚单体的纯度。

28. 发明授权

US08143468B2 Process for preparing 3-methylbut-1-ene 有权
标题翻译： 3-甲基丁-1-烯的制备方法
公开(公告)号：US08143468B2
公开(公告)日：2012-03-27
申请号：US12300224
申请日：2007-05-11
申请人： Alfred Kaizik , Klaus-Diether Wiese , Dietrich Maschmeyer , Dieter Hess , Wilfried Bueschken , Franz Nierlich
发明人： Alfred Kaizik , Klaus-Diether Wiese , Dietrich Maschmeyer , Dieter Hess , Wilfried Bueschken , Franz Nierlich
IPC分类号： C08F110/08 , C07C5/27
CPC分类号： C07C1/24 , Y02P20/127 , C07C11/10
摘要： The present invention relates to the preparation of 3-methylbut-1-ene from a hydrocarbon stream I comprising isobutene by feeding a hydrocarbon stream II which comprises at least 70% by mass of isobutene in relation to the olefins present in the hydrocarbon stream and which has been obtained from hydrocarbon stream I or is identical to it to a process step for hydroformylation in which isobutene is hydroformylated in the presence of a rhodium catalyst, hydrogenating the aldehyde obtained from the hydroformylation of isobutene to the corresponding alcohol and preparing 3-methylbut-1-ene by water elimination from the alcohol.
摘要翻译：本发明涉及从包含异丁烯的烃流I中制备3-甲基丁-1-烯，该烃流包含相对于存在于烃流中的烯烃至少70质量％的异丁烯的烃流II，其中已经从烃流I获得或者与加氢甲酰化的方法步骤相同，其中异丁烯在铑催化剂的存在下被加氢甲酰化，氢化从异丁烯的加氢甲酰化得到的醛到相应的醇，并制备3-甲基丁酸， 1-ene由酒精消除水分。

29. 发明申请

US20110046283A1 CITRIC ESTER MIXTURES AND THEIR USE 失效
标题翻译： CITRIC ESTER MIXTURES及其使用
公开(公告)号：US20110046283A1
公开(公告)日：2011-02-24
申请号：US12990225
申请日：2009-05-05
申请人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
发明人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
IPC分类号： C08K5/12 , C08K5/11 , C09K3/00
CPC分类号： C07C69/704 , C08K5/0016 , C08K5/11
摘要： The present invention relates to mixtures of citric esters of the formula I, in which each of R1, R2 and R3 is an aliphatic C5 or C9 moiety, characterized in that the average chain length of the aliphatic moieties in the mixture is in the range from greater than 5 to 7, and the average degree of branching of the aliphatic C9 moieties is in the range from 0.9 to 2.2.The present invention also relates to the use of the citric ester mixture according to the invention as plasticizer in plastics compositions.The present invention also relates to a composition comprising the citric ester mixture according to the invention in a mixture with further components, comprising plasticizers from the group of the alkyl esters of aromatic polycarboxylic acids, of the cyclohexanepolycarboxylic acids, of benzoic acid or of adipic acid, and also to the use of this type of plasticizer composition in plastics compositions, in adhesives, in sealing compounds, in coatings, in paints, in plastisols or in inks. Plastics products produced from the plasticizers according to the invention can be, for example: profiles, gaskets, food packaging, foils, toys, medical items, roof sheeting, synthetic leather, floor coverings, underbody protection, coated textiles, wallpapers, cables and wire sheathing.
摘要翻译：本发明涉及式I的柠檬酸酯的混合物，其中R 1，R 2和R 3各自为脂族C 5或C 9部分，其特征在于混合物中脂族部分的平均链长在大于5至7，并且脂族C 9部分的平均支化度在0.9至2.2的范围内。本发明还涉及根据本发明的柠檬酸酯混合物在塑料组合物中作为增塑剂的用途。本发明还涉及包含根据本发明的柠檬酸酯混合物与其它组分的混合物的组合物，其包含来自芳族多元羧酸的烷基酯，环己烷多羧酸，苯甲酸或己二酸的增塑剂，以及在塑料组合物，粘合剂，密封化合物，涂料，涂料，增塑溶胶或油墨中使用这种类型的增塑剂组合物。根据本发明的由增塑剂生产的塑料产品可以是例如型材，垫圈，食品包装，箔，玩具，医疗用品，屋顶板，合成皮革，地板覆盖物，底部保护，涂布纺织品，壁纸，电缆和线护套

30. 发明授权

US07381838B2 Preparation of tertiary carboxylic acids 失效
标题翻译：叔羧酸的制备
公开(公告)号：US07381838B2
公开(公告)日：2008-06-03
申请号：US11071166
申请日：2005-03-04
申请人： Klaus-Diether Wiese , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Wilfried Bueschken
IPC分类号： C07C51/14 , C07C51/10
CPC分类号： B01J19/243 , B01J19/2415 , B01J2219/00033 , B01J2219/00103 , B01J2219/00108 , B01J2219/00243 , C07C51/14 , C07C53/126
摘要： Process for carrying out catalytic multiphase reactions in a tubular reactor, in which at least three reactants are present in three different phases, wherein the process is carried out in at least one tubular reactor, and the catalyst is present in a continuous phase, at least one reactant is present in this continuous phase, and at least two reactants are present dispersed in the continuous phase and the loading factor B of the tubular reactor is equal to or greater than 0.2. In particular, the multiphase reaction is a hydrocarboxylation of at least one olefin to a carboxylic acid.
摘要翻译：在管式反应器中进行催化多相反应的方法，其中至少三种反应物存在于三个不同的相中，其中该方法在至少一个管式反应器中进行，并且催化剂至少存在于连续相中在该连续相中存在一种反应物，并且至少两种反应物分散在连续相中，并且管式反应器的负载因子B等于或大于0.2。特别地，多相反应是至少一种烯烃与羧酸的加氢羧化反应。

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