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    • 24. 发明授权
    • Stabilization of polycarbonates having high heat distortion temperatures
    • 具有高热变形温度的聚碳酸酯的稳定化
    • US5668204A
    • 1997-09-16
    • US853670
    • 1992-03-19
    • Helmut-Martin MeierUwe WesteppeRolf DheinDieter FreitagDieter Constant
    • Helmut-Martin MeierUwe WesteppeRolf DheinDieter FreitagDieter Constant
    • C08K3/00C08K5/541C08K5/5419C08K5/549C08L69/00C08J5/10C08K5/54
    • C08K5/541C08K5/549C08L69/00
    • A thermoplastic molding composition containing an aromatic polycarbonate and a particular siloxane compound is disclosed. The composition which is based on a polycarbonate resin having bifunctional structural units corresponding to formula (Ia) ##STR1## wherein R.sup.1 and R.sup.2 denote, independently of one another, hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, or C.sub.7 -C.sub.12 -aralkyl,m is an integer from 4 to 7,R.sup.3 and R.sup.4 selected individually for each X, denote, independently of one another, hydrogen or C.sub.1 -C.sub.6 -alkyl, andX stands for carbon,under the condition that R.sup.3 and R.sup.4 are both alkyl groups on at least one X atom, andcontains from 0.001 to 1% by weight of at least one siloxane corresponding to formula (II) ##STR2## wherein R denotes hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.6 -C.sub.10 -aryl or C.sub.1 -C.sub.10 -alkoxy,B denotes R or A,r, s and t independently denote an integer from 0 to 200, or to formula (III) ##STR3## wherein R has the same meaning as in formula (II)u denotes an integer from 1 to 20, and v and w denote an integer from 0 to 20,and wherein the sum u+v+w is greater than 3, andA denotes a C.sub.1 -C.sub.20 -alkyl group or a C.sub.6 -C.sub.10 -aryl group is characterized in its improved heat distortion temperature and good aging properties.
    • 公开了一种含有芳族聚碳酸酯和特定的硅氧烷化合物的热塑性模塑组合物。 基于具有对应于式(Ia)的双功能结构单元的聚碳酸酯树脂的组合物(Ia)其中R 1和R 2彼此独立地表示氢,卤素,C 1 -C 8烷基,C 5 -C 6 - 环烷基 ,C 6 -C 10 - 芳基或C 7 -C 12 - 芳烷基,m是4至7的整数,每个X分别选择的R 3和R 4彼此独立地表示氢或C 1 -C 6烷基,X表示 对于碳,在R3和R4均为至少一个X原子上的烷基的情况下,并且含有0.001至1重量%的至少一种对应于式(II)的硅氧烷(II),其中R表示 氢,C 1 -C 20 - 烷基,C 6 -C 10 - 芳基或C 1 -C 10 - 烷氧基,B表示R或A,r,s和t独立地表示0至200的整数,或式(III) III)其中R具有与式(II)中相同的含义,u表示1至20的整数,v和w表示0至20的整数,其中和u + v + w大于3,并且 A表示C1-C 20烷基或C6-C10-芳基的特征在于其改进的热变形温度和良好的老化性能。
    • 30. 发明授权
    • Polysiloxane-polycarbonate block copolymers based on certain
dihydroxydiphenylcycloalkanes
    • 基于某些二羟基二苯基环烷烃的聚硅氧烷 - 聚碳酸酯嵌段共聚物
    • US5068302A
    • 1991-11-26
    • US564473
    • 1990-08-08
    • Peter HorlacherVolker SeriniDieter FreitagUlrich GrigoKarsten-Josef IdelUwe Westeppe
    • Peter HorlacherVolker SeriniDieter FreitagUlrich GrigoKarsten-Josef IdelUwe Westeppe
    • C08G64/00C08G64/18C08G77/42C08G77/448
    • C08G64/186C08G77/448
    • Polydiorganosiloxane-polycarbonate block copolymers based on dihydrodiphenylcycloalkanes corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl, preferably phenyl-C.sub.1-4 -alkyl, more especially benzyl,n=2 or 3 andthe substituents R.sup.5 independently of one another are hydrogen or C.sub.1-12 alkyl, with the proviso that at least one of the substituents R.sup.5 is not hydrogen,having an average molecular weight M.sub.w (weight average) in the range from 10,000 to 300,000 (as measured by ultracentrifugation or scattered light measurement) and a content of carbonate containing dihydroxydiphenylcycloalkanes of formula I and, optionally, other diphenols in co-condensed form of from 75% by weight of 99.0% by weight and a content of polydiorganosiloxane having a degree of polymerization Pn of 5 to 300 of from 25% by weight of 1% by weight.
    • 对应于式(I)的二氢二苯基环烷烃的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物其中R 1,R 2彼此独立地表示氢,卤素,优选氯或溴,C 1-8烷基,C 5-6环烷基,C 6 -10芳基和C7-12芳烷基,优选苯基-C1-4 - 烷基,更特别是苄基,n = 2或3,取代基R5彼此独立地为氢或C 1-12烷基,条件是至少一个 的取代基R5不是氢,平均分子量Mw(重均分子量)为10,000〜300,000(通过超速离心或散射光测定测定)和含有式I的二羟基二苯基环烷烃的碳酸酯的含量,以及任选的其它 共缩合形式的双酚75重量%为99.0重量%,聚二有机硅氧烷的聚合度Pn为5〜300的25重量%的1重量%的含量。