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    • 21. 发明授权
    • Process for co-producing 1,1,1,2-tetrafluoroethane pentafluoroethane and
1,1,1-trifluoroethane
    • 共1,1,1,2-四氟乙烷五氟乙烷和1,1,1-三氟乙烷共生产方法
    • US5659094A
    • 1997-08-19
    • US591705
    • 1996-01-25
    • Hoon Sik KimByung Gwon LeeHonggon KimMoon Jo Chung
    • Hoon Sik KimByung Gwon LeeHonggon KimMoon Jo Chung
    • B01J23/26B01J27/12B01J27/132B01J27/138C07B61/00C07C17/20C07C17/21C07C17/23C07C19/08
    • C07C17/21B01J27/132B01J27/138C07C17/206C07C17/23
    • A process for co-production of 1,1,1,2-tetrafluoroethane (HFC-134a;CF.sub.3 CH.sub.2 F), pentafluoroethane (HFC-125; CF.sub.3 CHF.sub.2) and 1,1,1 -trifluoroethane (HFC-143a; CF.sub.3 CH.sub.3) by a two-step gaseous reaction comprising the steps of a) reacting 1,1,1-trifluoro-2-chloroethane (CFCH.sub.2 Cl, HCFC-133a) with HF in a first reactor to prepare 1,1,1,2-tetrafluoroethane (HFC-134a; CF.sub.3 CH.sub.2 F), pentafluoroethane (HFC-125; CF.sub.3 CHF.sub.2) and 1,1,1-trifluoroethane (HFC-143a; CF.sub.3 CH.sub.3); b) adding trichloroethylene (TCE:CCl.sub.2 CHCl) to the reaction product of step a) in a second reactor to prepare HCFC-133a; separating HCl, HFC-134a, HFC-125 and HFC-143a from the reaction product of step b) and recycling HCFC-133a to the first reactor, and the stages being performed in the presence of fluorization catalyst obtained by calcining a reaction product which is obtained by reacting ethanol with a mixture of calcium fluoride(CaF.sub.2) with an aqueous solution of chromium trioxide, zinc chloride and ferrous chloride is provided.
    • 一种通过两个共同生产1,1,1,2-四氟乙烷(HFC-134a; CF3CH2F),五氟乙烷(HFC-125; CF3CHF2)和1,1,1-三氟乙烷(HFC-143a; CF3CH3)的方法 包括以下步骤:a)在第一反应器中使1,1,1-三氟-2-氯乙烷(CFCH2Cl,HCFC-133a)与HF反应制备1,1,1,2-四氟乙烷(HFC-134a ; CF 3 CH 2 F),五氟乙烷(HFC-125; CF 3 CHF 2)和1,1,1-三氟乙烷(HFC-143a; CF 3 CH 3); b)在第二反应器中将三氯乙烯(TCE:CCl 2 CHCl)加入到步骤a)的反应产物中以制备HCFC-133a; 从步骤b)的反应产物中分离出HCl,HFC-134a,HFC-125和HFC-143a,并将HCFC-133a再循环到第一反应器中,这些阶段在通过煅烧反应产物得到的氟化催化剂存在下进行, 通过乙醇与氟化钙(CaF 2)与三氧化铬的水溶液,氯化锌和氯化亚铁的混合物反应获得。