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    • 25. 发明申请
    • Process for producing trans-1,4-cyclohexanedicarboxylic acid
    • 反式-1,4-环己烷二羧酸的制备方法
    • US20050014973A1
    • 2005-01-20
    • US10831156
    • 2004-04-26
    • Koetsu EndouHirofumi NakamuraShinichi Tanaka
    • Koetsu EndouHirofumi NakamuraShinichi Tanaka
    • C07C51/353C07C51/363C07C61/24
    • C07C51/353C07C51/363C07C2601/14C07C61/09
    • A subject for the invention is to obtain trans-1,4-cyclohexanedicarboxylic acid (t-CHDA) in a high concentration by efficiently isomerizing cis-1,4-cyclohexanedicarboxylic acid (c-CHDA) by a simple method. The invention provides: (1) a process for producing t-CHDA which comprises heating crude CHDA to 180° C. or higher in an inert atmosphere and causing the t-CHDA formed by isomerization to precipitate in the molten c-CHDA while holding the crude CHDA at a temperature in the range of not lower than 180° C. and less than the melting point of t-CHDA; (2) a process for producing t-CHDA, wherein crude CHDA which is powdery or granular is heat-treated at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA to thereby isomerize the cis isomer to the trans isomer while maintaining the powdery or granular state; (3) a process for producing t-CHDA, wherein crude CHDA is held at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA in an inert atmosphere while maintaining flowing to thereby obtain powdery or granular t-CHDA; and (4) a process for purifying crude CHDA in which crude CHDA obtained through the step of hydrogenating TPA or the like is heated in an atmosphere of an inert gas to volatilize and remove impurities.
    • 本发明的目的是通过简单的方法有效地使顺式-1,4-环己烷二羧酸(c-CHDA)异构化,以高浓度获得反式-1,4-环己烷二羧酸(t-CHDA)。 本发明提供:(1)一种生产t-CHDA的方法,其包括在惰性气氛中将粗CHDA加热至180℃或更高,并使通过异构化形成的t-CHDA在熔融的c-CHDA中沉淀,同时保持 原料CHDA在不低于180℃且小于t-CHDA的熔点的温度范围内; (2)生产t-CHDA的方法,其中将粉末状或粒状的粗CHDA在不低于c-CHDA的熔点并低于t-CHDA的熔点的温度下进行热处理,从而异构化 顺式异构体反式异构体,同时保持粉状或颗粒状态; (3)生产t-CHDA的方法,其中将粗CHDA保持在不低于c-CHDA的熔点并低于在惰性气氛中的t-CHDA的熔点的温度,同时保持流动,从而获得 粉状或颗粒状t-CHDA; (4)一种纯化粗制CHDA的方法,其中通过氢化TPA等步骤得到的粗CHDA在惰性气体气氛中加热,挥发除去杂质。
    • 27. 发明授权
    • Cu precipitation strengthened steel
    • 铜析出强化钢
    • US06558483B2
    • 2003-05-06
    • US09875146
    • 2001-06-07
    • Hirofumi NakamuraJun Furukawa
    • Hirofumi NakamuraJun Furukawa
    • C22C3816
    • C22C38/12C21D6/02C21D8/00C21D8/0226C21D8/0263C22C38/04C22C38/08C22C38/14C22C38/16C22C38/42C22C38/58C22C38/60
    • The Cu precipitation strengthened steel of the invention comprises, on the mass percent basis, C: 0.02-0.10%, Mn: 0.3-2.5%, Cu: 0.50-2.0%, Ni: 0.3-4.0% and Ti: 0.004-0.03% and further comprises Si: 0.01-0.4% and/or Al: 0.001-0.1%, with the contents of incidental impurities being P: not more than 0.025%, S: not more than 0.01%, N: not more than 0.006% and Se: not more than 0.005%, with the value of Pcm defined by the formula (1) given below being not more than 0.28. The steel material made of this Cu precipitation strengthened steel has good and stable CTOD toughness and is suited for use as a steel material for the construction of large industrial machines, ships, marine structures, line pipes, tanks, bridges and like welded structures. Pcm ⁢   =   ⁢ C ⁢   +   ⁢ Si 30 ⁢   +   ⁢ Mn 20 ⁢   +   ⁢ Cu 20 ⁢   +   ⁢ Ni 60 ⁢   +   ⁢ Cr 20 ⁢   +   ⁢ Mo 15 ⁢   +   ⁢ V 10 ⁢   +   ⁢ 5 ⁢   ⁢ B ( 1 ) In the above formula, C, Si, Mn, Cu, Ni, Cr, Mo, V and B respectively represent the contents (in mass percent) of the respective elements.
    • 本发明的Cu析出强化钢以质量%计含有C:0.02〜0.10%,Mn:0.3〜2.5%,Cu:0.50〜2.0%,Ni:0.3〜4.0%,Ti:0.004〜0.03% 并且进一步包含Si:0.01-0.4%和/或Al:0.001-0.1%,杂质含量为P:不大于0.025%,S:不大于0.01%,N:不大于0.006%,以及 Se:不大于0.005%,由下式(1)定义的Pcm值不大于0.28。 由该Cu析出强化钢制成的钢材具有良好稳定的CTOD韧性,适用于大型工业机械,船舶,船舶结构,管线管,水箱,桥梁等焊接结构的钢材的制造。 上述式C,Si,Mn,Cu,Ni,Cr,Mo,V和B分别表示各元素的含量(质量%)。