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    • 26. 发明授权
    • Method for the separation of ruthenium from noble metal solutions
    • 从贵金属溶液中分离钌的方法
    • US06475448B2
    • 2002-11-05
    • US09753291
    • 2001-01-02
    • Matthias GrehlHorst MeyerDieter Schäfer
    • Matthias GrehlHorst MeyerDieter Schäfer
    • C22B1100
    • C01G55/004C22B3/44C22B11/00Y02P10/234
    • Ruthenium is separated from noble metal solutions, by: a) heating a noble metal solution containing ruthenium to a temperature of T=+50° C. to T=+65° C., the H+ concentration and Cl− concentration are greater than 1 mol/l each; b) addition of chlorate, the resulting suspension/solution having a temperature of T=+50° C. to T=+65° C., heating the suspension solution to T=+80° C. to T=+90° C. and passing a carrier gas through the suspension/solution and capturing the resultant ruthenium tetroxide; c) addition of bromate at a pH of 1 to 3, the resultant suspension/solution having a temperature T=+60° C. to T=+95° C., and passing a carrier gas through the suspension solution and capturing the resultant ruthenium tetroxide.
    • 钌通过以下方式与贵金属溶液分离:a)将含有钌的贵金属溶液加热至T = + 50℃的温度至T = + 65℃,H +浓度和Cl-浓度大于1 mol / l; b)加入氯酸盐,所得到的悬浮液/溶液的温度为T = + 50℃至T = + 65℃,将悬浮液加热至T = + 80℃至T = + 90℃,并使载气通过悬浮液/溶液并捕获所得的四氧化钌; c)在1至3的pH下加入溴酸盐,所得悬浮液/溶液的温度为T = + 60℃ 至T = + 95℃,并使载气通过悬浮液并捕获所得的四氧化钌。