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21. 发明申请

US20100058955A1 Hard Coat Layer-Forming Composition and Optical Lens 有权
标题翻译：硬涂层成型组合物和光学透镜
公开(公告)号：US20100058955A1
公开(公告)日：2010-03-11
申请号：US12090602
申请日：2006-10-17
申请人： Hirokazu Tanaka , Eiko Tanaka , Sachio Murai , Hideki Ito , Yoshifumi Miyano
发明人： Hirokazu Tanaka , Eiko Tanaka , Sachio Murai , Hideki Ito , Yoshifumi Miyano
IPC分类号： C07F7/18 , C09D5/00 , G02C7/02
CPC分类号： C09C1/0081 , B82Y30/00 , C01G23/002 , C01P2004/62 , C01P2004/64 , C08K3/22 , C08K2003/2241 , C09C1/0084 , C09D7/61 , C09D7/67 , C09D7/68 , C09D183/04 , G02B1/105 , G02B1/11 , G02B1/14 , C08K5/31
摘要： The hard coat layer-forming composition of this invention includes (A) composite oxide fine particles with a mean particle diameter of 1 to 200 nm, containing titanium, tin and optionally silicon, and with a rutile-type crystal structure, (B) an organosilicon compound represented by the formula R1aR2bSi(OR3)4−(a+b) and/or a hydrolyzate thereof, and (C) a cyanamide derivative compound. A hard coat layer formed from the composition not only is excellent in transparency, scratch resistance, adhesion property, weathering resistance, impact resistance, etc. but also can enjoy no coloration or little coloration, particularly in bluing or yellowing, upon exposure to or irradiation with ultraviolet rays, even if an antireflection film is provided.
摘要翻译：本发明的硬涂层组合物包含（A）平均粒径为1〜200nm的复合氧化物微粒，其含有钛，锡和任选的硅，并且具有金红石型晶体结构，（B）由式R1aR2bSi（OR3）4-（a + b）和/或其水解产物表示的有机硅化合物和（C）氰酰胺衍生物化合物。由该组合物形成的硬涂层不仅透明性，耐划伤性，粘合性，耐候性，耐冲击性等优异，而且在曝光或照射时也不会着色或着色不足，特别是蓝色或黄色即使设置有防反射膜，也可以使用紫外线。

22. 发明申请

US20090136746A1 Composite Polymer, Thermosetting Coating Composition, and Molded Article 审中-公开
标题翻译：复合聚合物，热固性涂料组合物和成型品
公开(公告)号：US20090136746A1
公开(公告)日：2009-05-28
申请号：US12064881
申请日：2006-08-11
申请人： Sachio Murai , Hideki Ito , Yoshifumi Miyano , Hirokazu Tanaka , Eiko Tanaka
发明人： Sachio Murai , Hideki Ito , Yoshifumi Miyano , Hirokazu Tanaka , Eiko Tanaka
IPC分类号： B32B27/40 , C08G18/83
CPC分类号： C09D113/00 , C08G18/0823 , C08G18/831 , C08J7/045 , C08J2475/04 , C08K3/22 , C08K9/06 , C09D5/002 , C09D175/04 , G02B1/105 , G02B1/14 , Y10T428/269 , Y10T428/31609 , C08L13/00 , C08L2666/54
摘要： A composite polymer is obtained by reacting (a) an elastomer having a carboxyl group with (b) metal oxide fine particles each having an epoxy ring-containing group on the particle surface. A thermally cured product of the composite polymer is a material favorable for forming a primer layer which has not only high transparency but also excellent adhesion to a hard coat layer and is excellent also in scratch resistance, heat resistance, weathering resistance, dyeing property, impact resistance and the like. An article such as an optical article whose primer layer comprises the thermally cured product of the composite polymer has high transparency and is excellent also in heat resistance.
摘要翻译：通过使（a）具有羧基的弹性体与（b）在颗粒表面上具有含环氧基环的基团的金属氧化物微粒反应而获得复合聚合物。复合聚合物的热固化产物是有利于形成底漆层的材料，其不仅具有高透明度，而且对硬涂层具有优异的粘附性，并且在耐刮擦性，耐热性，耐候性，染色性，冲击性方面也优异电阻等。包含复合聚合物的热固化产物的底漆层的光学制品等具有高透明性且耐热性优异的物品。

23. 发明申请

US20080057228A1 Anti-glare film and liquid crystal display apparatus 审中-公开
标题翻译：防眩光胶片和液晶显示装置
公开(公告)号：US20080057228A1
公开(公告)日：2008-03-06
申请号：US11896262
申请日：2007-08-30
申请人： Wataru Horie , Toshiharu Hirai , Masayuki Matsuda , Mitsuaki Kumazawa , Hiroshi Takahashi , Shinji Kikuchi
发明人： Wataru Horie , Toshiharu Hirai , Masayuki Matsuda , Mitsuaki Kumazawa , Hiroshi Takahashi , Shinji Kikuchi
IPC分类号： B32B3/00 , B32B3/26 , B32B7/02 , C09K19/02
CPC分类号： G02F1/133502 , G02B5/0215 , G02B5/0268 , G02B5/0278 , G02B5/0294 , G02B6/0051 , Y10T428/1045 , Y10T428/24612 , Y10T428/24942 , Y10T428/249974
摘要： An anti-glare film comprises an anti-glare layer, and a low-refraction-index layer formed on at least one surface thereof and comprising a low-refraction-index resin and a hollow silica particle. The film has an internal haze of 0 to 1%, a haze of 5 to 6.5%, a transmitted image clarity of 20 to 30%, and a reflected light of the film has a* of 0.5 to 1.3 and b* of −2.3 to −0.5. The particle may have a mean particle diameter of about 50 to 70 nm and a refraction index of about 1.2 to 1.25. The film may have an uneven surface, and the average inclination angle of the surface may be about 0.7 to 1°. The anti-glare layer may comprise plural polymers and have a domain formed by a phase separation, and a difference in refraction index between the polymers may be about 0 to 0.04.
摘要翻译：防眩光膜包括抗眩光层和在其至少一个表面上形成的低折射率层，并且包括低折射率树脂和中空二氧化硅颗粒。膜的内部雾度为0〜1％，雾度为5〜6.5％，透射图像透明度为20〜30％，膜的反射光的*为0.5〜1.3，b *为-2.3 至-0.5。颗粒的平均粒径可以为约50至70nm，折射率为约1.2至1.25。该膜可能具有不平坦的表面，并且该表面的平均倾斜角可以为约0.7°至1°。抗眩光层可以包含多个聚合物并且具有通过相分离形成的结构域，并且聚合物之间的折射率差可以为约0至0.04。

24. 发明授权

US07309457B2 Chain inorganic oxide fine particle groups 失效
标题翻译：链无机氧化物微粒组
公开(公告)号：US07309457B2
公开(公告)日：2007-12-18
申请号：US10981845
申请日：2004-11-05
申请人： Ryo Muraguchi , Masayuki Matsuda , Hiroyasu Nishida , Toshiharu Hirai , Mitsuaki Kumazawa
发明人： Ryo Muraguchi , Masayuki Matsuda , Hiroyasu Nishida , Toshiharu Hirai , Mitsuaki Kumazawa
IPC分类号： H01B1/00 , H01B1/02 , H01B1/08
CPC分类号： C01G30/005 , B82Y30/00 , C01B33/146 , C01F7/02 , C01P2004/62 , C01P2004/64 , C01P2006/40 , H01C17/06533
摘要： A chain antimony oxide fine particle group comprising antimony oxide fine particles which have an average particle diameter of 5 to 50 nm, are connected in the form of a chain and have an average connection number of 2 to 30 and preferably used for forming a hard coating film. The fine particle group can be prepared by a process comprising treating an alkali antimonate aqueous solution with a cation exchange resin to prepare an antimonic acid (gel) dispersion and then treating the dispersion with an anion exchange resin and/or adding a base to the dispersion. Also provided is a substrate with a film comprising a substrate and a hard coating film. The hard coating film includes a chain inorganic oxide fine particle group, in which inorganic oxide fine particles of 2 to 30 on the average are connected in the form of a chain, and a matrix. The inorganic oxide particles may be silica particles, silica-alumina particles being preferable, and porous particles and/or hollow particles having a cavity inside being more preferable.
摘要翻译：包含平均粒径为5〜50nm的氧化锑微粒的链状氧化锑微粒组以链状连接，平均连接数为2〜30，优选用于形成硬涂层电影。微粒子组可以通过以下方法制备，该方法包括用阳离子交换树脂处理碱式锑酸盐水溶液以制备锑酸（凝胶）分散体，然后用阴离子交换树脂处理分散体和/或向分散体中加入碱。还提供了具有包括基底和硬涂膜的薄膜的基底。硬涂膜包括链状无机氧化物细粒子群，其中平均形式为2至30的无机氧化物细颗粒以链的形式连接，并且基质。无机氧化物颗粒可以是二氧化硅颗粒，二氧化硅 - 氧化铝颗粒是优选的，并且更优选具有内部空腔的多孔颗粒和/或中空颗粒。

25. 发明申请

US20070249736A1 Titanium-Containing Silica Sol and Process for Producing the Same, Antifouling Film and Base Material with Ink-Receptive Layer, and Method for Reproducing Recording Base Material 审中-公开
标题翻译：含钛二氧化硅溶胶及其制造方法，具有油墨接受层的防污膜和基材以及用于再现记录基材的方法
公开(公告)号：US20070249736A1
公开(公告)日：2007-10-25
申请号：US11661799
申请日：2005-09-01
申请人： Manabu Watanabe , Tatsuo Ogawa , Hiroyasu Nishida , Michio Komatsu
发明人： Manabu Watanabe , Tatsuo Ogawa , Hiroyasu Nishida , Michio Komatsu
IPC分类号： C01G23/047 , B41M5/00 , B41M5/50 , B41M5/52 , C01B33/149
CPC分类号： C01B33/146 , B41M5/5218 , B82Y30/00 , C01B33/149 , C01P2002/30 , C01P2004/34 , C01P2004/64 , C01P2006/12 , C01P2006/40 , C08K3/22 , C08K3/36 , C08K7/26 , C08K9/04 , C09C1/3054 , C09C1/3607 , C09D1/00 , C09D5/1618 , C09D7/62 , C09D7/67 , Y02P20/582
摘要： It is an object of the present invention to provide a material which is applied to substrates by an easy and simple process, is applicable to substrates of a wide range and is capable of forming an antifouling film exhibiting excellent antifouling performance, and a substrate with an ink-receiving layer having excellent decoloring property. The titanium-containing silica sol of the invention includes (a) the following fine particles (a1) or the following fine particles (a2) and (b) a dispersion medium: (a1) titania fine particles having a mean particle diameter of 2 to 50 nm and porous silica fine particles having a mean particle diameter of 5 to 100 nm and a specific surface area, as determined by BET method, of not less than 300 m2/g, or (a2) porous silica fine particles obtained by surface-modifying surfaces of porous silica fine particles having a mean particle diameter of 5 to 100 nm and a specific surface area, as determined by BET method, of not less than 300 m2/g with a titanate compound.
摘要翻译：本发明的目的是提供一种通过简单和简单的方法施加到基材上的材料，可应用于宽范围的基材，并且能够形成显示出优异的防污性能的防污膜，以及具有油墨接收层具有优异的脱色性能。本发明的含钛硅溶胶包含（a）下述细颗粒（a1）或以下微粒（a2）和（b）分散介质：（a1）平均粒径为2〜 50nm，通过BET法测定的平均粒径为5〜100nm，比表面积为300μm2 / g以上的多孔二氧化硅微粒，或（a2）通过BET法测定的平均粒径为5〜100nm的多孔二氧化硅微粒表面改性比表面积为300μm2以上的多孔二氧化硅微粒 > / g与钛酸盐化合物。

26. 发明申请

US20060084277A1 Method of forming amorphous silica-based coating film with low dielectric constant and thus obtained silica-based coating film 有权
标题翻译：形成具有低介电常数的无定形二氧化硅基涂膜的方法，由此得到二氧化硅基涂膜
公开(公告)号：US20060084277A1
公开(公告)日：2006-04-20
申请号：US10533238
申请日：2003-10-27
申请人： Akira Nakashima , Miki Egami , Michio Komatsu , Yoshihiro Nakata , Ei Yano , Katsumi Suzuki
发明人： Akira Nakashima , Miki Egami , Michio Komatsu , Yoshihiro Nakata , Ei Yano , Katsumi Suzuki
IPC分类号： H01L21/31 , H01L21/469
CPC分类号： C09D183/02 , C08G77/08 , H01L21/02126 , H01L21/02203 , H01L21/02216 , H01L21/02282 , H01L21/02337 , H01L21/316 , H01L21/31695
摘要： The present invention relates to an amorphous silica-based coating film with a low specific dielectric constant of 2.5 or below and the Young's modulus of 6.0 GPa or more and having excellent hydrophobic property, and to a method of forming the same. A liquid composition containing a silicon compound obtained by hydrolyzing tetraalkyl ortho silicate (TAOS) and specific alkoxysilane (AS) in the presence of tetraalkyl ammonium hydroxide (TAAOH) is prepared. The liquid composition is then applied on a substrate, heated and cured to obtain a coating film. The coating film obtained as described has a smooth surface and also has specific micropores therein.
摘要翻译：本发明涉及具有2.5以下的比介电常数低，6.0GPa以上的杨氏模量和疏水性优异的无定形二氧化硅系涂膜及其形成方法。制备含有在四烷基氢氧化铵（TAAOH）存在下水解四烷基原硅酸盐（TAOS）和特定烷氧基硅烷（AS））得到的硅化合物的液体组合物。然后将液体组合物涂布在基材上，加热固化，得到涂膜。如上所述获得的涂膜具有光滑表面，并且其中也具有特定的微孔。

27. 发明申请

US20050037201A1 Inorganic compound particle and process for preparation thereof 有权
标题翻译：无机化合物颗粒及其制备方法
公开(公告)号：US20050037201A1
公开(公告)日：2005-02-17
申请号：US10898894
申请日：2004-07-26
申请人： Toshiharu Hirai , Hiroyasu Nishida , Michio Komatsu
发明人： Toshiharu Hirai , Hiroyasu Nishida , Michio Komatsu
IPC分类号： C03C17/00 , C03C17/34 , C03C17/36 , C01B15/14 , B32B5/16
CPC分类号： C03C17/3655 , C03C17/007 , C03C17/34 , C03C17/36 , C03C17/3676 , C03C2217/425 , C03C2217/445 , C03C2217/475 , C03C2217/76 , C03C2217/78 , Y10T428/249953 , Y10T428/249962 , Y10T428/249998 , Y10T428/25 , Y10T428/2982 , Y10T428/2984 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , Y10T428/2998
摘要： Inorganic compound particles constituted of a shell, a porous matter or a cavity enclosed therein, and the porous matter or the cavity being kept unchanged in a subsequently formed transparent coating film.
摘要翻译：由外壳，多孔物质或其中包围的空腔构成的无机化合物颗粒，并且多孔物质或空腔在随后形成的透明涂膜中保持不变。

28. 发明申请

US20030171475A1 Resin-coated scale-like inorganic particles and cosmetics with the same blended therein 有权
标题翻译：树脂涂覆的鳞片状无机颗粒和与其混合的化妆品
公开(公告)号：US20030171475A1
公开(公告)日：2003-09-11
申请号：US10078544
申请日：2002-02-21
申请人： CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.
发明人： Takumi Miyazaki , Hirokazu Tanaka
IPC分类号： C08K003/34
CPC分类号： C09C1/0018 , A61K8/25 , A61K8/29 , A61K8/8111 , A61Q1/02 , C01P2004/20 , C01P2004/61 , C01P2006/60 , C01P2006/80 , C01P2006/90 , C09C1/0015 , C09C1/3072 , C09C3/10 , C09C2200/308 , C09C2200/405
摘要： The resin-coated scale-like inorganic particles have soft feel, adhesivity to human skin and effective in suppressing excessive luster. The scale-like inorganic particles are those with the surface coated with resin, and are characterized in that the 100% modulus of the resin in the tensile test is in a rage from 50 to 3000 N/cm2. The resin is preferably one or more selected from the group consisting of polyurethane, a styrene-butadiene copolymer, an acrylonitrile-butadiene copolymer, a silicone-based elastomer, and a polyolefin-based elastomer. The resin-coated scale-like inorganic particles are blended in the cosmetics according to the present invention.
摘要翻译：树脂涂覆的鳞片状无机颗粒具有柔软的手感，对人体皮肤的粘合性并且有效地抑制过度光泽。鳞片状无机颗粒是表面涂有树脂的颗粒，其特征在于拉伸试验中树脂的100％模量为50-3000N / cm 2。树脂优选选自聚氨酯，苯乙烯 - 丁二烯共聚物，丙烯腈 - 丁二烯共聚物，硅酮类弹性体和聚烯烃类弹性体中的一种以上。将树脂涂覆的鳞状无机颗粒混合在根据本发明的化妆品中。

29. 发明申请

US20030150485A1 Photoelectric cell and process for producing metal oxide semiconductor film for use in photoelectric cell 失效
公开(公告)号：US20030150485A1
公开(公告)日：2003-08-14
申请号：US10361079
申请日：2003-02-06
申请人： Catalysts & Chemicals Industries Co., LTD.
发明人： Tsuguo Koyanagi , Michio Komatsu , Hirokazu Tanaka , Katsuhiro Shirono
IPC分类号： H01L031/04
CPC分类号： B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C09C1/3054 , H01G9/2004 , H01G9/2031 , Y02E10/542 , Y02P70/521
摘要： The first photoelectric cell of the present invention comprises: an insulating base having on its surface an electrode layer (1), the electrode layer (1) having on its surface a metal oxide semiconductor film (2) on which a photosensitizer is adsorbed; an insulating base having on its surface an electrode layer (3), the electrode layer (1) and the electrode layer (3) arranged opposite to each other; and an electrolyte sealed between the metal oxide semiconductor film (2) and the electrode layer (3), wherein at least one of the electrode-having insulating bases is transparent; and the metal oxide semiconductor film (2) comprises anatase titanium oxide particles. This first photoelectric cell includes a semiconductor film comprising anatase titanium oxide particles, having a high proportion of photosensitizer adsorbed, so that the electron mobility in the semiconductor film is high to thereby realize excellent photoelectric transfer efficiency. The second photoelectric cell of the present invention comprises: an insulating base having on its surface an electrode layer (1), the electrode layer (1) having on its surface a metal oxide semiconductor layer (2) on which a photosensitizer is adsorbed; an insulating base having on its surface an electrode layer (3), the electrode layer (1) and the electrode layer (3) arranged opposite to each other; and an electrolyte sealed between the metal oxide semiconductor layer (2) and the electrode layer (3), wherein conductive protrusions (4) jutting from the surface of the electrode layer (1) exist, the metal oxide semiconductor layer (2) formed so as to cover the conductive protrusions (4) and the electrode layer (1), and at least one of the electrode-layer-having insulating bases is transparent. In this second photoelectric cell, conductive protrusions are provided on the electrode surface, so that generated electrons not only can rapidly move toward the electrode but also are free from recombining with the photosensitizer. Moreover, in this photoelectric cell, not only is the adsorption proportion of photosensitizer high but also the moving of generated electrons is smooth. Therefore, the second photoelectric cell exhibits excellent photoelectric transfer efficiency.

30. 发明申请

US20030089045A1 Silica particles for polishing and a polishing agent 有权
标题翻译：用于抛光的二氧化硅颗粒和抛光剂
公开(公告)号：US20030089045A1
公开(公告)日：2003-05-15
申请号：US10291643
申请日：2002-11-12
申请人： CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.
发明人： Kazuhiro Nakayama , Akira Nakashima , Michio Komatsu
IPC分类号： C09C001/68 , C09K003/14
CPC分类号： B82Y30/00 , C01P2004/62 , C01P2004/64 , C01P2004/80 , C01P2006/90 , C09C1/3081 , C09K3/1409
摘要： Silica particles for polishing to planarize a surface of a substrate without generating scratches, having the average particle diameter in the range from 5 to 300 nm, carbon content in the range from 0.5 to 5 weight %, and 10%-compressive elasticity modulus in the range from 500 to 3000 kgf/mm2. When the carbon content in the silica particles is less than 0.5 weight %, there is no residual alkoxy group and siloxane bonding proceeds, so that the obtained particles are hard. In that case, although the polishing rate is high, scratches remain or are generated anew after polishing, and planarity of the polished surface is insufficient. On the other hand, when the carbon content is over 5 weight %, many residual alkoxy group are contained in the particles, so that the particles are relatively soft and a sufficient polishing rate can not be achieved.
摘要翻译：用于抛光以平面化基材表面的二氧化硅颗粒，而不产生刮痕，其平均粒径在5至300nm的范围内，碳含量在0.5至5重量％的范围内，并且10％的压缩弹性模量在范围从500至3000 kgf / mm2。当二氧化硅颗粒中的碳含量小于0.5重量％时，不存在残留的烷氧基并进行硅氧烷键合，所以得到的颗粒是硬的。在这种情况下，虽然抛光速度高，但抛光后残留或重新产生划痕，抛光面的平面度不足。另一方面，当碳含量超过5重量％时，颗粒中含有许多残留的烷氧基，使得颗粒相对较软并且不能获得足够的抛光速率。

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