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    • 191. 发明申请
    • RESIN PARTICLE AND METHOD FOR PRODUCING THE SAME
    • 树脂颗粒及其制造方法
    • US20110130523A1
    • 2011-06-02
    • US13057906
    • 2009-07-22
    • Takao MukaiKoji Ota
    • Takao MukaiKoji Ota
    • C08G63/91
    • C08J3/12C08J7/04C08J2300/12C08J2367/04G03G9/0804G03G9/08755G03G9/08797Y02P20/544
    • There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a lactone ring-opening polymer (p), and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0≦H2/H1≦0.9  (1) [in the relational formula (1), H1 represents a measurement value of a heat of fusion (J/g) at the time of the initial temperature elevation measured by DSC; and H2 represents a measurement value of a heat of fusion (J/g) at the time of the second temperature elevation measured by DSC].
    • 提供一种能够以前所未有的优异的耐热保持性和熔融性实现的树脂粒子的制造方法。 本发明是一种树脂粒子(X)的制造方法,其特征在于,包括以下步骤:处理含有由含有作为必需构成成分的内酯环的结晶性部分(a)构成的树脂(A)的树脂粒子(B) (C),通过差示扫描量热法(DSC)测得的熔化热(C),其中, 满足以下关系式(1):0≦̸ H2 / H1≦̸ 0.9(1)[在关系式(1)中,H1表示初始温度时的熔解热(J / g) 通过DSC测量的高程; H2表示通过DSC测定的第二升温时的熔解热的测定值(J / g)。
    • 194. 发明授权
    • Apparatus and method for recovering polymer
    • 用于回收聚合物的装置和方法
    • US07947803B2
    • 2011-05-24
    • US12312857
    • 2007-12-05
    • Sung-Don HongIn-Su LeeJong-Ku LeeSung-Ho ChunSeung-Young ParkSung-Cheol Yoon
    • Sung-Don HongIn-Su LeeJong-Ku LeeSung-Ho ChunSeung-Young ParkSung-Cheol Yoon
    • C08F6/00C08G63/02
    • C08J3/12C08J11/04C08J2333/14C08J2365/00Y02P20/143Y02W30/70
    • The present invention provides an apparatus for recovering a polymer from polymer solution, and a method of recovering a polymer using the apparatus. The apparatus includes a polymer solution-storage tank for storing a polymer solution; a polymer solution feeding pump for pumping the polymer solution from the polymer solution storage tank; an antisolvent storage tank for storing an antisolvent; an antisolvent feeding pump for pumping the antisolvent from the antisolvent storage tank; a reaction chamber to which the polymer solution pumped by the polymer solution feeding pump and the antisolvent pumped by the antisolvent feeding pump are supplied; a high-speed mixer that is rotated in the reaction chamber at a speed range of 1000 to 30000 rpm, mixes the polymer solution with the antisolvent under a shearing force corresponding to a tip speed of 5 to 30 m/sec, and precipitates a polymer; and a precipitate storage tank for storing the precipitation mixture of the polymer and the solvent/antisolvent.
    • 本发明提供了一种从聚合物溶液中回收聚合物的装置,以及使用该装置回收聚合物的方法。 该装置包括用于储存聚合物溶液的聚合物溶液 - 储存罐; 用于从聚合物溶液储罐泵送聚合物溶液的聚合物溶液进料泵; 用于储存抗溶剂的抗溶剂储罐; 用于从抗溶剂储罐泵出抗溶剂的反溶剂供给泵; 提供由聚合物溶液供给泵泵送的聚合物溶液和由反溶剂供给泵泵送的反溶剂的反应室; 以1000〜30000rpm的速度在反应室内旋转的高速混合机,在对应于5〜30m /秒的叶尖速度的剪切力下将聚合物溶液与抗溶剂混合,并使聚合物 ; 以及用于储存聚合物和溶剂/反溶剂的沉淀混合物的沉淀储存罐。
    • 196. 发明授权
    • Production of fine spherical thermoplastic resin particles
    • 生产细球形热塑性树脂颗粒
    • US07947369B2
    • 2011-05-24
    • US11439985
    • 2006-05-25
    • Arimichi Okumura
    • Arimichi Okumura
    • B32B5/66
    • C08J3/12C08J3/005C08J2377/00Y10T428/2982Y10T428/2991Y10T428/2998
    • Fine spherical thermoplastic resin particles are produced by preparing a resin composition including a matrix of a water-soluble material, and fine particles of a water-insoluble thermoplastic resin dispersed in the matrix, the fine particles and the matrix each being melted or softened in the resin composition; cooling and solidifying the resin composition under such conditions that the resin composition does not undergo deformation due to stress; and removing the water-soluble material by washing with water to thereby yield fine spherical particles containing the water-insoluble thermoplastic resin. This method has wide applicability, applies less loads on the environment, does not require special devices, can be easily conducted, and can efficiently produce such particles. The resulting particles are highly spherical.
    • 通过制备包含水溶性材料的基体的树脂组合物和分散在基质中的水不溶性热塑性树脂的细颗粒,每个在其中熔融或软化的微粒和基体,制备细球形热塑性树脂颗粒。 树脂组成; 在树脂组合物由于应力而不发生变形的条件下冷却和固化树脂组合物; 用水洗涤除去水溶性物质,得到含有水不溶性热塑性树脂的细小球形粒子。 该方法具有广泛的适用性,在环境中施加较少的载荷,不需要特殊装置,可以容易地进行,并且可以有效地产生这种颗粒。 所得颗粒高度球形。
    • 197. 发明授权
    • Powder of a vinylpyrrolidone polymer and a process for production thereof
    • 乙烯基吡咯烷酮聚合物的粉末及其制备方法
    • US07910672B2
    • 2011-03-22
    • US11666883
    • 2005-11-02
    • Kazuhiro OkamuraNorihiro WakaoKeiji WatanabeKeiichi Fujise
    • Kazuhiro OkamuraNorihiro WakaoKeiji WatanabeKeiichi Fujise
    • C08F26/10
    • C08F226/10C08J3/12C08J2339/00C09D139/06C09J139/06
    • The present invention is a powder of a vinylpyrrolidone polymer having a K value of smaller than 50, characterized in that a content of particles having a particle diameter of 106 μm or smaller is 10% by mass or less and a content of particles having a particle diameter of greater than 1,000 μm is 5% by mass or lower. A process for production of a powder of a vinylpyrrolidone polymer according to the present invention is characterized in that a vinylpyrrolidone polymer having a K value of smaller than 50 is formed into a solution having a concentration from 30% to 70% by mass, and the solution is dried by using a hot surface adhesion-type dryer, followed by pulverization so that a content of particles having a particle diameter of 106 μm or smaller is 10% by mass or lower and a content of particles having a particle diameter of greater than 1,000 μm is 5% by mass or lower.Thus, there is provided a powder of a vinylpyrrolidone polymer, which has excellent solubility in spite of having a low K value determined by a Fikentscher method and can be made into solution with favorable handleability without dust rising, and a process for production of the same.
    • 本发明是K值小于50的乙烯基吡咯烷酮聚合物的粉末,其特征在于,粒径为10μm以下的粒子的含量为10质量%以下,具有粒子的粒子的含量 大于1000μm的直径为5质量%以下。 本发明的乙烯基吡咯烷酮聚合物粉末的制造方法的特征在于,将K值小于50的乙烯基吡咯烷酮聚合物形成浓度为30〜70质量%的溶液, 溶液通过使用热表面粘附型干燥器进行干燥,然后粉碎,使得粒径为10μm以下的颗粒的含量为10质量%以下,粒径为 1,000μm为5质量%以下。 因此,提供了一种乙烯基吡咯烷酮聚合物的粉末,尽管具有通过Fikentscher方法测定的低K值而具有优异的溶解性,并且可以制成具有良好可操作性而没有粉尘升高的溶液及其制备方法 。