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    • 11. 发明授权
    • Ground rubber elastomeric composite useful in surfacings and the like,
and methods
    • 用于表面等的地面橡胶弹性体复合物和方法
    • US4112176A
    • 1978-09-05
    • US659751
    • 1976-02-20
    • Allen R. Bailey
    • Allen R. Bailey
    • B32B5/16D06N7/00E01C13/06E01C13/08E04F15/22B32B3/26C09J3/18
    • D06N7/0089B32B5/16D06N7/0071D06N7/0076E01C13/065E01C13/08E04F15/22D06N2203/02D06N2203/068D06N2205/10D06N2205/20Y10T428/23979Y10T428/254Y10T428/2991Y10T428/2998Y10T428/31569Y10T428/31583Y10T428/31587Y10T428/31598
    • There is provided a polyurethane ground rubber composite and a new method for formation and preparation thereof. The composite is suitable for use in laminated and other surfacing or as a surfacing and has excellent flexibility, resiliency, weatherability, and elastomeric qualities; and comprises particulate vulcanized rubber substantially coated on each particle with about 3 to about 8 microns, and in some instances about 3 to about 10 microns, of a cross-linked binder derived from an essentially solvent-free polymeric isocyanate prepolymer having a number average molecular weight of 800-4000, the cross-linking of the isocyanate prepolymer being accomplished by controlled reaction with water using an equivalent ratio of NCO/OH of 0.14/1 to 0.83/1 to form urea and buiret linkages, and providing a void content of 25-60 volume percent, so that the carbon dioxide generated by the water/isocyanate reaction can readily diffuse through the film and so that the vented carbon dioxide does not cause foaming of the composite; and methods of controlling the forming of the composite, the layering of the composite, and/or mixing it in situ.
    • 提供了一种聚氨酯研磨橡胶复合材料及其形成和制备的新方法。 该复合材料适用于层压和其他表面处理或表面处理,具有优异的柔韧性,弹性,耐候性和弹性质量; 并且包含基本上涂覆在每个颗粒上的颗粒硫化橡胶,其具有约3至约8微米,并且在一些情况下约3至约10微米的衍生自基本上无溶剂的聚合异氰酸酯预聚物的交联粘合剂,其具有数均分子量 重量为800-4000,异氰酸酯预聚物的交联通过使用NCO / OH的当量比为0.14 / 1至0.83 / 1与水的控制反应来实现,以形成尿素和提取物键,并提供空隙含量 25-60体积%,使得由水/异氰酸酯反应产生的二氧化碳可以容易地通过膜扩散,使得排出的二氧化碳不会引起复合材料的起泡; 以及控制复合材料成型,复合材料层压和/或原位混合的方法。