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    • 14. 发明授权
    • One pot diazotization, coupling and quaternization of aminotriazoles
    • 氨基三唑的一锅重氮化,偶联和季铵化
    • US4392998A
    • 1983-07-12
    • US236490
    • 1981-02-23
    • Hans-Peter Kuhlthau
    • Hans-Peter Kuhlthau
    • C09B44/18D06P1/08C07C107/00C09B43/00
    • C09B44/18D06P1/08
    • In the preparation of a quaternized dyestuff of the formula ##STR1## in which R.sup.1 and R.sup.2 each is an optionally substituted alkyl, alkenyl or aralkyl radical,R.sup.3 is hydrogen, or an optionally substituted alkyl, aralkyl, cycloalkyl or aryl radical,K is the radical of a coupling component+HK, and X is an anion,wherein an aminotriazole of the formula ##STR2## is diazotized and coupled to a coupling component HK to form an intermediate dyestuff of the formula ##STR3## and the intermediate dyestuff is quaternized with an alkylating or aralkylating agent capable of providing the radicals R.sup.1 and R.sup.2 in a medium also providing the anion X.sup.-, the improvement which comprises effecting the coupling at a pH of 4 to 6 and thereafter, without isolation of the intermediate dyestuff, effecting the quaternization.
    • 在制备式“IMAGE”的季铵化染料的制备中,其中R 1和R 2各自为任选取代的烷基,烯基或芳烷基,R 3为氢或任选取代的烷基,芳烷基,环烷基或芳基,K为 偶联组分+ HK的基团,X是阴离子,其中将式“IMAGE”的氨基三唑重氮化并偶联至偶联组分HK以形成式“IMAGE”的中间体染料,并将中间体染料季铵化 能够在还提供阴离子X的介质中提供基团R 1和R 2的烷基化或芳烷基化试剂,其改进包括在4至6的pH下进行偶联,此后不分离中间体染料,进行季铵化 。
    • 20. 发明授权
    • 1,2,4-Triazole-azo-aniline cationic dyestuffs
    • 1,2,4-三唑 - 偶氮苯胺阳离子染料
    • US4039539A
    • 1977-08-02
    • US598272
    • 1975-07-23
    • Hans-Peter Kuhlthau
    • Hans-Peter Kuhlthau
    • C09B44/18D06P1/41C09B29/08C09B29/26D06P1/08D06P1/10
    • C09B44/18D06P1/41
    • Cationic dyestuffs of the formula ##STR1## in which R, R' and R" denote alkyl, alkenyl, cycloalkyl or aralkyl andR.sub.1 denotes hydrogen, alkyl, alkenyl, cycloalkyl or aralkyl orR.sub.1 can form a five-membered or six-membered heterocyclic ring with the ring B,R.sub.2 denotes an alkylene group of which the chain can be interrupted by 0,Y denotes a --CO-- or --O--CO--O-- group,A denotes an aromatic ring andX.sup.- denotes an anion, andn, n' and n" independently of one another are 0 or 1, with the proviso that the sum n + n' + n" is 2,Are suitable for dyeing and printing of natural and synthetic materials with good fastness properties with respect to light, wet processing, rubbing, decatizing, sublimation and perspiration.
    • 式(I)的阳离子染料其中R,R'和R“表示烷基,烯基,环烷基或芳烷基,R 1表示氢,烷基,烯基,环烷基或芳烷基或R 1可以形成五元或 具有环B的六元杂环,R 2表示可被中断链的亚烷基,Y表示-CO-或-O-CO-O-基团,A表示芳环,X < >表示阴离子,N,N'和N“独立地为0或1,其中N'N + N'+ N”为2,适用于天然和合成的染色和印刷 材料与良好的快速性能相关的光,湿处理,润滑,分解,分解和吸收。