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11. 发明授权

US06461995B1 Extruded honeycomb dehydrogenation catalyst and method 失效
标题翻译：挤压蜂窝状脱氢催化剂及方法
公开(公告)号：US06461995B1
公开(公告)日：2002-10-08
申请号：US09566544
申请日：2000-05-08
申请人： William P. Addiego , Wei Liu
发明人： William P. Addiego , Wei Liu
IPC分类号： B01J2300
CPC分类号： B01J37/0009 , B01J23/78 , B01J23/8872 , B01J35/04 , C07C5/3332 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/745 , C07C2523/78 , Y10T428/24149 , C07C15/46
摘要： Extruded honeycomb dehydrogenation catalysts of high structural integrity, composed of potassium oxide (carbonate)-promoted oxide-stabilized iron oxides and having a honeycomb cell density in the range of 15-400 channels per square inch, a channel wall thickness in the range of 0.2-3 mm, and an axial crushing strength in excess of 100 psi, are prepared from extrusion batches incorporating polymer binders exhibiting improved compatibility with high batch concentrations of dissolved catalyst precursors or constituents.
摘要翻译：具有高度结构完整性的挤压蜂窝状脱氢催化剂，由氧化钾（碳酸盐） - 氧化物稳定的氧化铁组成，蜂窝状电池密度在15-400通道/平方英寸的范围内，通道壁厚在0.2 -3mm，并且轴向破碎强度超过100psi，由挤出批料制备，其包含与高批次浓度的溶解的催化剂前体或组分具有改善的相容性的聚合物粘合剂。

12. 发明授权

US06391822B1 Dual NOx adsorber catalyst system 有权
标题翻译：双NOx吸附剂催化剂体系
公开(公告)号：US06391822B1
公开(公告)日：2002-05-21
申请号：US09500615
申请日：2000-02-09
申请人： Danan Dou , Owen H. Bailey
发明人： Danan Dou , Owen H. Bailey
IPC分类号： B01J2300
CPC分类号： B01D53/9422 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2042 , B01D2255/91 , B01J23/58 , B01J35/0006
摘要： A NOx adsorber catalyst system for treatment of gases in an exhaust discharge passage of an internal combustion engine comprising: a first adsorber catalyst supporting effective amounts of at least one noble metal component and a Ba component; and, a second adsorber catalyst supporting effective amounts of at least one noble metal catalyst, a Ba component, and a K component.
摘要翻译：一种用于处理内燃机排气通道中的气体的NOx吸附剂催化剂系统，包括：第一吸附剂催化剂，其负载有效量的至少一种贵金属组分和Ba组分; 以及支持有效量的至少一种贵金属催化剂，Ba成分和K成分的第二吸附剂催化剂。

13. 发明授权

US06387844B1 Titanium dioxide photocatalyst 失效
标题翻译：二氧化钛光催化剂
公开(公告)号：US06387844B1
公开(公告)日：2002-05-14
申请号：US09042609
申请日：1998-03-17
申请人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
发明人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
IPC分类号： B01J2300
CPC分类号： A61L9/205 , B01D2255/20707 , B01D2255/802 , B01J21/06 , B01J21/063 , B01J21/066 , B01J35/002 , B01J35/004 , B01J37/0244 , C03C17/2456 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , H01J61/35 , H01J61/42
摘要： A titanium dioxide film having at least photocatalytic activity, whose light linear transmittance corresponding to light having a wavelength of 550 nm is not less than 50 % and whose thickness is 0.1 to 5 &mgr;m or so, is formed on a transparent substrate constituted by a glass plate or the like. Preferably, a precoat film, which has optical transmissivity and is constituted by a SiO2 film having a thickness of 0.02 to 0.2 &mgr;m or so, is provided between the transparent substrate and the titanium dioxide film. Thereby, excellent photocatalytic action and optical transmissivity can be obtained. Moreover, members composing various structures such as a glass window, which are especially required to have optical transparency, can be further provided with photocatalytic activities.
摘要翻译：在由玻璃构成的透明基板上形成具有至少具有波长为550nm的光的光线性透射率为50％以上且厚度为0.1〜5μm的至少具有光催化活性的二氧化钛膜板等。优选地，在透明基板和二氧化钛膜之间设置具有透光性并由SiO 2膜构成的厚度为0.02〜0.2μm的预涂膜。由此，可以获得优异的光催化作用和光透射率。此外，特别需要具有光学透明性的构成诸如玻璃窗的各种结构的构件可进一步具有光催化活性。

14. 发明授权

US06358879B1 Premixed combustion method 有权
标题翻译：预混燃烧法
公开(公告)号：US06358879B1
公开(公告)日：2002-03-19
申请号：US09533291
申请日：2000-03-22
申请人： William C. Pfefferle , Theodore R Strickland
发明人： William C. Pfefferle , Theodore R Strickland
IPC分类号： B01J2300
CPC分类号： F23R3/40 , Y10T29/49345
摘要： This invention pertains to an apparatus and means to lower emissions of carbon monoxide and nitrogen oxides in lean, pre-mixed gas turbine combustors. Specifically, this invention employs a catalyst deposited on the inner surfaces of the combustor in the region of combustion which oxidizes CO combustion products. Also provided is a means for depositing a catalyst within the thermal barrier coating on the combustor liner walls.
摘要翻译：本发明涉及一种减少贫燃混合燃气轮机燃烧器中一氧化碳和氮氧化物排放的装置和方法。具体地说，本发明采用在氧化CO燃烧产物的燃烧区域内沉积在燃烧器的内表面上的催化剂。还提供了用于在燃烧器衬套壁上的热障涂层内沉积催化剂的方法。

15. 发明授权

US06355595B1 Group 5 metal promoted iridium carbonylation catalyst 有权
标题翻译：第5族金属促进铱羰基化催化剂
公开(公告)号：US06355595B1
公开(公告)日：2002-03-12
申请号：US09382957
申请日：1999-08-25
申请人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
发明人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
IPC分类号： B01J2300
CPC分类号： C07C67/37 , B01J23/468 , C07C51/12 , C07C67/36 , Y02P20/142 , C07C53/08 , C07C69/14
摘要： A solid supported catalyst suitable for the vapor phase carbonylation of lower aliphatic alcohols, ethers, ester, and ester-alcohol mixtures, and desirably, methanol, to produce acetic acid, methyl acetate and mixtures thereof. The solid supported catalyst includes an effective amount of iridium and at least one second metal selected from group metals of the periodic table of elements, their respective salts and mixtures thereof associated with a solid support material. Desirably, the support material is selected from carbon, activated carbon, pumice, alumina, silica, silica-alumina, magnesia, diatomaceous earth, bauxite, titania, zirconia, clay, magnesium silicate, silicon carbide, zeolites, ceramics and combinations thereof.
摘要翻译：适用于低级脂族醇，醚，酯和酯 - 醇混合物以及理想的甲醇的气相羰基化产生乙酸，乙酸甲酯及其混合物的固体负载型催化剂。固体负载催化剂包括有效量的铱和至少一种选自元素周期表的族金属的第二金属，它们各自的盐和与固体支持材料的混合物。理想地，载体材料选自碳，活性炭，浮石，氧化铝，二氧化硅，二氧化硅 - 氧化铝，氧化镁，硅藻土，铝土矿，二氧化钛，氧化锆，粘土，硅酸镁，碳化硅，沸石，陶瓷及其组合。

16. 发明授权

US06303536B1 Process of preparing catalyst for producing alkenyl acetates 有权
标题翻译：制备炔基乙酸酯催化剂的方法
公开(公告)号：US06303536B1
公开(公告)日：2001-10-16
申请号：US09374662
申请日：1999-08-16
申请人： Shien-Chang Chen , Fu-Shen Lin , Yuh-Lih Jong , Pi-Fwu Jang
发明人： Shien-Chang Chen , Fu-Shen Lin , Yuh-Lih Jong , Pi-Fwu Jang
IPC分类号： B01J2300
CPC分类号： C07C67/055 , B01J23/52 , B01J23/58 , B01J23/8946 , B01J37/0201 , B01J37/03 , B01J37/18 , C07C69/007 , C07C69/01 , C07C69/15 , C07C69/155
摘要： This invention relates to a preparation process of a catalyst which comprises a noble metal and a metal as catalysis promoter in combination with an alkali or alkaline earth metal compound, supported on the outer surface of a carrier. The preparation process comprises impregnating the carrier with a solution containing an oxidative state noble metal as the main catalyst and an oxidative state metal as catalysis promoter, reducing the oxidative state metals into the metallic state in gaseous phase with a gaseous reducing agent under certain temperature, pressure, moisture and gas concentration, then impregnating the reduced carrier with a solution of an alkali or alkaline earth metal compound. The metal components-supporting catalyst prepared by the process according to the present invention has a high surface area and exhibits high catalytic activity, which leads to increase the catalytic efficiency and life of this heterogeneous catalyst. The catalyst prepared in the present invention is suitable for producing alkenyl acetates through reaction of olefins, acetic acid and oxygen in vapor phase.
摘要翻译：本发明涉及一种催化剂的制备方法，该催化剂包含贵金属和金属作为催化促进剂与碱金属或碱土金属化合物的组合，负载在载体的外表面上。制备方法包括用包含氧化态贵金属作为主要催化剂的溶液和作为催化促进剂的氧化态金属浸渍载体，在一定温度下用气态还原剂将氧化态金属还原成金属状态，压力，水分和气体浓度，然后用碱金属或碱土金属化合物的溶液浸渍还原的载体。通过本发明方法制备的金属组分载体催化剂具有较高的表面积，并具有较高的催化活性，从而提高了该催化剂的催化效率和寿命。在本发明中制备的催化剂适用于通过气相中烯烃，乙酸和氧气的反应生产烯基乙酸酯。

17. 发明授权

US06251821B1 Solid mixed oxide composition containing molybdenum, cobalt and bismuth, which is suitable for the manufacture of acrolein from propylene by a redox reaction 失效
标题翻译：含有钼，钴和铋的固体混合氧化物组合物，适用于通过氧化还原反应从丙烯制备丙烯醛
公开(公告)号：US06251821B1
公开(公告)日：2001-06-26
申请号：US09459888
申请日：1999-12-14
申请人： Gerard Hecquet , Jean-Pierre Schirmann , Michel Simon , Gilles Descat , Eric Etienne
发明人： Gerard Hecquet , Jean-Pierre Schirmann , Michel Simon , Gilles Descat , Eric Etienne
IPC分类号： B01J2300
CPC分类号： C07C45/28 , C07C47/22
摘要： A mixed oxide solid composition of the formulas (I): (a) Mo12Co4.7Bi1Ni2.6Fe3.7W0.5Sn0.5Si1K0.08Ox; (b) Mo12Co3.5Bi1.1Fe0.8W0.5Si1.4K0.05Ox; and (c) Mo12Co3.8Bi1.2Fe0.9W1.1Si1.5K0.05Ox, wherein x is the quantity of oxygen bonded to the other elements and depends on their oxidation states, is suitable for the manufacture of acrolein by oxidizing propylene. The solid composition reacts with propylene according to the redox reaction (1): solidoxidized+propylene→solidreduced+acrolein (1) To manufacture acrolein, gaseous propylene is passed over the solid composition. Redox reaction (1) is conducted at a temperature of 200 to 600° C., at a pressure of 1.01×104 to 1.01 to 106 Pa (0.1 to 10 atmospheres) and with a residence time of 0.01 second to 90 seconds, in the absence of molecular oxygen.
摘要翻译：式（I）:( a）Mo12Co4.7Bi1Ni2.6Fe3.7W0.5Sn0.5Si1K0.08Ox的混合氧化物固体组合物;（b）Mo12Co3.5Bi1.1Fe0.8W0.5Si1.4K0.05Ox; 和（c）Mo12Co3.8Bi1.2Fe0.9W1.1Si1.5K0.05Ox，其中x是与其他元素结合并依赖于其氧化态的氧的量，适用于通过氧化丙烯制备丙烯醛。固体组合物根据氧化还原反应（1）与丙烯反应：为了制备丙烯醛，气态丙烯通过固体组合物。氧化还原反应（1）在200〜600℃的温度下，在1.01×10 4〜1.01〜10 6 Pa（0.1〜10个大气压）的压力下进行，停留时间为0.01秒〜90秒，的分子氧。

18. 发明授权

US06225255B1 Additive catalyst for the cracking of heavy oil 失效
标题翻译：用于重油开裂的添加剂催化剂
公开(公告)号：US06225255B1
公开(公告)日：2001-05-01
申请号：US09093443
申请日：1998-06-08
申请人： Masato Shibasaki , Nobuo Ootake , Kaori Nakamura
发明人： Masato Shibasaki , Nobuo Ootake , Kaori Nakamura
IPC分类号： B01J2300
CPC分类号： C10G11/04 , B01J21/08 , B01J21/16
摘要： An additive catalyst for the cracking of heavy oil, characterized in that the additive catalyst includes: (i) a mixed metal oxide composed of an acidic metal oxide and a basic metal oxide, in which the proportion of the basic metal oxide is from 5 to 50 mole %, (ii) clay, and (iii) silica.
摘要翻译：一种用于重油裂化的添加剂催化剂，其特征在于添加剂催化剂包括：（i）由酸性金属氧化物和碱性金属氧化物组成的混合金属氧化物，其中碱性金属氧化物的比例为5〜 50摩尔％，（ii）粘土和（iii）二氧化硅。

19. 发明授权

US06180558B2 Material for exhaust gas purifying catalyst, exhaust gas purifying catalyst made of the material and method for producing the exhaust gas purifying catalyst 失效
标题翻译：废气净化催化剂材料，由该材料制成的废气净化催化剂和废气净化催化剂的制造方法
公开(公告)号：US06180558B2
公开(公告)日：2001-01-30
申请号：US08829688
申请日：1997-03-31
申请人： Takahiro Kurokawa , Akihide Takami , Hideharu Iwakuni , Makoto Kyogoku , Shinichi Tanioka , Kenichi Yamamoto , Yoko Kawakami , Hiroshi Murakami , Hirosou Oda , Tadashi Tokuyama
发明人： Takahiro Kurokawa , Akihide Takami , Hideharu Iwakuni , Makoto Kyogoku , Shinichi Tanioka , Kenichi Yamamoto , Yoko Kawakami , Hiroshi Murakami , Hirosou Oda , Tadashi Tokuyama
IPC分类号： B01J2300
CPC分类号： B01D53/945 , B01D2255/91 , B01J23/10 , Y02A50/2324 , Y02T10/22
摘要： A catalytic base material for an exhaust gas purifying catalyst is produced by impregnating ceria powders with a barium contained solution and heating the ceria particles at approximately 400 to 1100° C. to create and accumulate barium oxides fixed to surfaces of the ceria particles.
摘要翻译：通过用含钡溶液浸渍二氧化铈粉末并在大约400至1100℃下加热二氧化铈颗粒以产生并积聚固定在二氧化铈颗粒表面上的氧化钡来制备废气净化催化剂用催化基材。

20. 发明授权

US06797668B2 Exhaust gas purifying catalyst 有权
标题翻译：废气净化催化剂
公开(公告)号：US06797668B2
公开(公告)日：2004-09-28
申请号：US10014027
申请日：2001-12-10
申请人： Tatsuya Yoshikawa
发明人： Tatsuya Yoshikawa
IPC分类号： B01J2300
CPC分类号： B01J23/63 , B01D53/945 , B01D2255/102 , B01D2255/204 , B01D2255/206 , B01D2255/20715 , B01D2255/40 , B01J21/066 , B01J23/002 , B01J23/10 , B01J2523/00 , Y02T10/22 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/3706 , B01J2523/3725
摘要： A catalyst for purifying exhaust gases from internal combustion engines with high efficiencies of CO/NOx even under the conditions large A/F fluctuations. The catalyst includes a complex in which the oxides of cerium are deposited on a solid solution oxide containing Zr and Ce.
摘要翻译：即使在较大的A / F波动条件下，即使在CO / NOx效率较高的情况下也能从内燃机中排出废气的催化剂。催化剂包括其中铈的氧化物沉积在含有Zr和Ce的固溶体氧化物上的络合物。

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