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11. 发明授权

US08975351B2 Latex resin composition for rubber gloves without sulfur and vulcanization acceleator and method of manufacturing dip-formed article using the composition 有权
标题翻译：无硫硫化橡胶手套的乳胶树脂组合物和使用该组合物制造浸渍成型制品的方法
公开(公告)号：US08975351B2
公开(公告)日：2015-03-10
申请号：US13121151
申请日：2009-08-10
申请人： Byoung Yun Kim , Jung Su Han , Ho Yeul Choi , Seung Hun Yang , Jung Eun Kim , Chang Sun Han
发明人： Byoung Yun Kim , Jung Su Han , Ho Yeul Choi , Seung Hun Yang , Jung Eun Kim , Chang Sun Han
IPC分类号： C08F220/46 , C08F222/30 , C08F212/34 , C08F136/04 , C08F236/12 , C08J5/02 , C08L13/02 , C08F36/06 , C08F36/08 , C08F36/04 , C08F222/02
CPC分类号： C08F236/12 , C08F36/04 , C08F36/045 , C08F36/06 , C08F36/08 , C08F222/02 , C08F222/30 , C08J5/02 , C08J2321/02 , C08L13/02
摘要： The present invention provides a latex resin composition for rubber gloves without sulfur and a vulcanization accelerator and a method of manufacturing dip-formed article using the composition. The composition comprises a conjugated diene monomer; an ethylenically unsaturated nitrile monomer; an ethylenically unsaturated acid monomer; an ethylenically unsaturated monomer copolymerizable with the ethylenically unsaturated nitrile monomer and the ethylenically unsaturated acid monomer; and a reactive compound including two or more reactive groups. According to the manufacturing method, productivity is improved by omitting a long maturation process included in a traditional glove manufacturing process; not only an adverse effect caused by traditional sulfur and vulcanization accelerator is reduced but also rubber gloves with excellent physical properties can be provided.
摘要翻译：本发明提供了一种无硫橡胶手套的胶乳树脂组合物和硫化促进剂，以及使用该组合物制造浸渍成型制品的方法。组合物包含共轭二烯单体; 烯属不饱和腈单体; 烯属不饱和酸单体; 可与烯键式不饱和腈单体和烯属不饱和酸单体共聚的烯属不饱和单体; 和包含两个或更多个反应性基团的反应性化合物。根据制造方法，通过省略包括在传统手套制造工艺中的长成熟工艺来提高生产率; 不仅可以减少由传统硫磺和硫化促进剂引起的不利影响，而且可以提供具有优异物理性能的橡胶手套。

12. 发明授权

US3147237A 2, 3-dimethyl-butadiene-1, 3 polymers and copolymers and method of preparing same 失效
标题翻译： 2,3-二甲基 - 丁二烯-1,3聚合物和共聚物及其制备方法
公开(公告)号：US3147237A
公开(公告)日：1964-09-01
申请号：US4709660
申请日：1960-08-02
申请人： MONTEDISON SPA
发明人： CARLO LONGIAVE , RENATO CASTELLI , MARIO FERRARIS
IPC分类号： C08F36/04 , C08F236/04
CPC分类号： C08F236/045 , C08F36/045 , C08F4/70

13. 发明申请

US20190203083A1 CURABLE PETROLEUM RESIN, PREPARATION METHOD THEREFOR, AND USE THEREOF 审中-公开
公开(公告)号：US20190203083A1
公开(公告)日：2019-07-04
申请号：US16314351
申请日：2017-06-30
申请人： KOLON INDUSTRIES, INC.
发明人： Je Min LEE , Jae Kyung HWANG , Wan Jae LEE , Myung Jong KIM , Won Seok GONG , Jun Hyo PARK
IPC分类号： C09J11/08 , C08F36/04 , C09J123/02
CPC分类号： C09J11/08 , C08F36/045 , C08F222/04 , C08F240/00 , C08F289/00 , C08G77/42 , C08G77/442 , C09J123/02 , C09J145/00 , C09J191/00
摘要： The present invention relates to a curable petroleum resin, a preparation method therefor, and use thereof, wherein the curable petroleum resin comprises a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a cyclic anhydride monomer, and wherein the curable petroleum resin is used as an additive for a reactive polyolefin-based adhesive composition to increase the adhesive strength to a polyolefin-based substrate used for various parts.

14. 发明申请

US20180304684A1 METHOD FOR SYNTHESISING A POLYMER HAVING A HYDROXYARYL GROUP, PRODUCT OBTAINED USING SAID METHOD AND COMPOSITION CONTAINING SAME 审中-公开
公开(公告)号：US20180304684A1
公开(公告)日：2018-10-25
申请号：US15523857
申请日：2015-10-22
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , MICHELIN RECHERCHE ET TECHNIQUE, S.A.
发明人： Claire RANNOUX , Rachid MATMOUR , Cédric LOUBAT , Camille CHATARD
IPC分类号： B60C1/00 , C08C19/24 , C08C19/06 , C08C19/40
CPC分类号： B60C1/0016 , C08C19/06 , C08C19/24 , C08C19/40 , C08F36/045 , C08F36/06 , C08F36/08 , C08F36/20 , C08F136/08
摘要： The invention relates to a process for the synthesis of a polymer bearing one or more pendant hydroxyaryl groups, comprising the reaction of a polymer bearing at least one epoxide functional group with a nucleophilic compound simultaneously bearing the hydroxyaryl group and a nucleophilic functional group selected from the group consisting of the phosphonic acid functional group and its ionic form.

15. 发明申请

US20110229646A1 LATEX RESIN COMPOSITION FOR RUBBER GLOVES WITHOUT SULFUR AND VULCANIZATION ACCELEATOR AND METHOD OF MANUFACTURING DIP-FORMED ARTICLE USING THE COMPOSITION 有权
标题翻译：不含硫和硫化橡胶的橡胶手套的LATEX树脂组合物和使用该组合物制造DIP形成的制品的方法
公开(公告)号：US20110229646A1
公开(公告)日：2011-09-22
申请号：US13121151
申请日：2009-08-10
申请人： Byoung Yun Kim , Jung Su Han , Ho Yeul Choi , Seung Hun Yang , Jung Eun Kim , Chang Sun Han
发明人： Byoung Yun Kim , Jung Su Han , Ho Yeul Choi , Seung Hun Yang , Jung Eun Kim , Chang Sun Han
IPC分类号： B05D3/02 , C08L33/18
CPC分类号： C08F236/12 , C08F36/04 , C08F36/045 , C08F36/06 , C08F36/08 , C08F222/02 , C08F222/30 , C08J5/02 , C08J2321/02 , C08L13/02
摘要： The present invention provides a latex resin composition for rubber gloves without sulfur and a vulcanization accelerator and a method of manufacturing dip-formed article using the composition. The composition comprises a conjugated diene monomer; an ethylenically unsaturated nitrile monomer; an ethylenically unsaturated acid monomer; an ethylenically unsaturated monomer copolymerizable with the ethylenically unsaturated nitrile monomer and the ethylenically unsaturated acid monomer; and a reactive compound including two or more reactive groups. According to the manufacturing method, productivity is improved by omitting a long maturation process included in a traditional glove manufacturing process; not only an adverse effect caused by traditional sulfur and vulcanization accelerator is reduced but also rubber gloves with excellent physical properties can be provided.
摘要翻译：本发明提供了一种无硫橡胶手套的胶乳树脂组合物和硫化促进剂，以及使用该组合物制造浸渍成型制品的方法。组合物包含共轭二烯单体; 烯属不饱和腈单体; 烯属不饱和酸单体; 可与烯键式不饱和腈单体和烯属不饱和酸单体共聚的烯属不饱和单体; 和包含两个或更多个反应性基团的反应性化合物。根据制造方法，通过省略包括在传统手套制造工艺中的长成熟工艺来提高生产率; 不仅可以减少由传统硫磺和硫化促进剂引起的不利影响，而且可以提供具有优异物理性能的橡胶手套。

16. 发明授权

US4482771A Anionic polymerization of cis- and trans-1,3-pentadiene from a mixture of saturated and unsaturated hydrocarbons 失效
标题翻译：来自饱和和不饱和烃的混合物的顺式和反式-1,3-戊二烯的阴离子聚合
公开(公告)号：US4482771A
公开(公告)日：1984-11-13
申请号：US559525
申请日：1983-12-08
申请人： John W. Bozzelli , Kent S. Dennis , Felipe A. Donate
发明人： John W. Bozzelli , Kent S. Dennis , Felipe A. Donate
IPC分类号： C08F4/46 , C08F36/00 , C08F36/04 , C08F240/00 , C07C1/16 , C07C2/02 , C07C2/74
CPC分类号： C08F36/045
摘要： 1,3-Pentadiene is polymerized in an inert gaseous atmosphere from a mixture of saturated and unsaturated hydrocarbon molecules. At least 50 percent by weight of said molecules have 5 carbon atoms. An anionic polymerization initiator in conjunction with an organic polar solvent is used to effect polymerization. Cyclopentadiene, active hydrogen compounds and other polymerization-terminating compounds may be inactivated and separated from the mixture of hydrocarbon compounds before starting polymerization. As an alternative, inactivation and separation of cyclopentadiene, active hydrogen compounds and polymerization-terminating compounds may be omitted provided the anionic polymerization initiator is employed in an amount to (a) inactivate such compounds and (b) initiate polymerization of 1,3-pentadiene.The polymer of 1,3-pentadiene so prepared is then hydrogenated or functionalized by further reaction.
摘要翻译： 1,3-丁二烯在惰性气体气氛中由饱和和不饱和烃分子的混合物聚合。所述分子的至少50重量％具有5个碳原子。使用与有机极性溶剂结合的阴离子聚合引发剂进行聚合。在开始聚合之前，可以将环戊二烯，活性氢化合物和其它聚合终止化合物失活并与烃化合物的混合物分离。作为替代方案，可以省略环戊二烯，活性氢化合物和聚合终止化合物的灭活和分离，只要阴离子聚合引发剂的用量为（a）灭活这些化合物和（b）引发1,3-戊二烯的聚合。然后将如此制备的1,3-戊二烯的聚合物通过进一步的反应氢化或官能化。

17. 发明授权

US4131567A Catalyst for cationic polymerization process 失效
标题翻译：阳离子聚合工艺用催化剂
公开(公告)号：US4131567A
公开(公告)日：1978-12-26
申请号：US845992
申请日：1977-10-27
申请人： Ronald T. Wojcik
发明人： Ronald T. Wojcik
IPC分类号： B01J27/16 , C08F4/00 , C08F4/06 , C08F36/00 , C08F36/04
CPC分类号： B01J27/16 , C08F36/045
摘要： There is provided a process for cationically polymerizing piperylene batchwise or continuously by the addition of piperylene either alone or in admixture with a minor amount of at least another hydrocarbon monomer, incrementally, to a catalyst system consisting essentially of a major amount of an aluminum halide and a minor amount of an inorganic phosphorus acid in an inert solvent while controlling the temperature of reaction in the range of 0.degree. C. to 50.degree. C., drowning the polymerization mixture in water, separating the organic phase therefrom, then removing the solvent and recovering a solid polymer in good color and yield, free from an intractable gel, rendering the same useful as a tackifying resin.

18. 发明授权

US4124546A Green strength of elastomers 失效
标题翻译：弹性体的绿色强度
公开(公告)号：US4124546A
公开(公告)日：1978-11-07
申请号：US692267
申请日：1976-06-03
申请人： Diego C. Rubio, Jr. , Richard G. Bauer , Richard M. Scriver, Jr.
发明人： Diego C. Rubio, Jr. , Richard G. Bauer , Richard M. Scriver, Jr.
IPC分类号： C08F36/04 , C08L21/00 , C08L7/00 , C08L9/00
CPC分类号： C08F36/045 , C08L21/00
摘要： Improved green strength of elastomers made from monomers selected from the class consisting of at least one conjugated diene having from 4 to 10 carbon atoms, olefins having from 2 to 14 carbon atoms along with a diene having from 4 to 6 carbon atoms, and combinations thereof, is achieved by adding an amount of a polydimethylbutadiene compound to form a blend having a glass transition temperature of from about 0.degree. C to about -100.degree. C. The polydimethylbutadiene compound may be merely the homopolymer of dimetylbutadiene, the copolymer, the terpolymer or the tetrapolymer of dimethylbutadiene in various combinations with monomers such as butadiene, isoprene, piperylene, acrylonitrile, vinylidene chloride, vinyl pyridine, methacrylic acid and vinyl substituted aromatic compounds.
摘要翻译：由选自至少一种具有4至10个碳原子的共轭二烯，具有2至14个碳原子的烯烃以及具有4至6个碳原子的二烯的单体制成的弹性体的改善的生坯强度，以及其组合通过加入一定量的聚二甲基丁二烯化合物以形成玻璃化转变温度为约0℃至约-100℃的共混物来实现。聚二甲基丁二烯化合物可以仅仅是二甲基丁二烯的均聚物，共聚物，三元共聚物或与丁二烯，异戊二烯，戊间二烯，丙烯腈，偏二氯乙烯，乙烯基吡啶，甲基丙烯酸和乙烯基取代的芳族化合物等单体的各种组合的二甲基丁二烯的四元共聚物。

19. 发明授权

US4098982A Cationic polymerization of piperylene using as the catalyst system an aluminum halide and an inorganic phosphoric acid 失效
标题翻译：使用铝催化剂和无机磷酸作为催化剂体系的阳离子聚合
公开(公告)号：US4098982A
公开(公告)日：1978-07-04
申请号：US775503
申请日：1977-03-08
申请人： Ronald Thomas Wojcik
发明人： Ronald Thomas Wojcik
IPC分类号： B01J27/16 , C08F4/00 , C08F4/06 , C08F36/00 , C08F36/04
CPC分类号： B01J27/16 , C08F36/045
摘要： There is provided a process for cationically polymerizing piperylene batchwise or continuously by the addition of piperylene either alone or in admixture with a minor amount of at least another hydrocarbon monomer, incrementally, to a catalyst system consisting essentially of a major amount of an aluminum halide and a minor amount of an inorganic phosphorus acid in an inert solvent while controlling the temperature of reaction in the range of 0.degree. C. to 50.degree. C., drowning the polymerization mixture in water, separating the organic phase therefrom, then removing the solvent and recovering a solid polymer in good color and yield, free from an intractable gel, rendering the same useful as a tackifying resin.
摘要翻译：提供了通过单独或与少量至少另一种烃单体混合添加戊间二烯以间歇或连续的方式阳离子聚合戊间二烯的方法，该催化剂体系基本上由主要量的卤化铝和在惰性溶剂中加入少量的无机磷酸，同时将反应温度控制在0℃至50℃的范围内，将聚合混合物浸入水中，从中分离有机相，然后除去溶剂，回收固体聚合物，其颜色和产率良好，不含难溶性凝胶，使其与增粘树脂相同。

20. 发明授权

US3652512A Polymers of 3-methyl-1 3-pentadiene 失效
标题翻译： 3-甲基-1,3-苯二甲酸的聚合物
公开(公告)号：US3652512A
公开(公告)日：1972-03-28
申请号：US3652512D
申请日：1970-06-16
申请人： GOODYEAR TIRE & RUBBER
发明人： HENDERSON JAMES NEIL
IPC分类号： C08F36/04 , C08D3/08 , C08D1/14
CPC分类号： C08F36/04 , C08F10/00 , C08F36/045 , C08F4/6421 , C08F4/68
摘要： A POLYMER OF 3-METHYL-1,3-PENTADIENE HAVING A HIGH CIS-1,4 CONTENT PREPARED BY SUBJECTING 3-MITHYL-1,3-PENTADIENE TO POLYMERIZATION IN THE PRESENCE OF A CATALYST FORMED FROM (1) AT LEAST ONE METAL HALIDE SELECTED FROM THE GROUP CONSISTING OF TITANIUM TETRACHLORIDE AND VANADIUM TRICHLORIDE, AND (2) AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF (A) AN ORGANOALUMINUM COMPOUND OF THE FORMULA

R1-AL(-R2)-R3

AND (B) ORGANO ETHERATES OF COMPOUNDS HAVING THE FORMULA:

R1-AL(-R2)(-R3).O(-R4)-R6

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