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11. 发明申请

US20150299086A1 METHOD FOR THE PRODUCTION OF POLYETHYLENE TEREPHTHALATE WITH A LOW CARBON FOOTPRINT 审中-公开
标题翻译：用低碳碳酸钙生产聚乙烯三烯酸盐的方法
公开(公告)号：US20150299086A1
公开(公告)日：2015-10-22
申请号：US14646742
申请日：2013-11-21
申请人： ETH ZURICH , CEDAR ADVANCED TECHNOLOGY GROUP LTD.
发明人： Said FARHA , Kamal FARHA , Philip FARHA
IPC分类号： C07C51/265 , C07C7/08 , B01D3/40 , C07C29/151 , C01B31/08 , C01B31/20 , C08G63/183 , C07C45/50
CPC分类号： C07C51/265 , B01D3/40 , C01B32/324 , C01B32/336 , C01B32/342 , C01B32/40 , C01B32/50 , C07C7/08 , C07C29/1518 , C07C45/49 , C07C45/505 , C08G63/183 , C10B53/02 , C10B57/06 , C10G2300/1003 , C10G2300/1014 , C10G2400/30 , Y02E50/14 , Y02E50/32 , Y02P30/20 , C07C47/542 , C07C63/26
摘要： The present invention relates to a method for producing terephthalic acid from lignocellulosic biomass including the steps of pyrolysis of lignocellulosic biomass in the presence of a catalyst obtaining biochar, crude bio-oil and gases; collecting an aromatic fraction from the crude bio-oil and/or from the gases, extracting toluene from the aromatic fraction by distillation; converting the toluene to a p-tolualdehyde by catalyzed carbonylation; oxidation of the p-tolualdehyde in a liquid phase oxidation to tereph thalic acid.
摘要翻译：本发明涉及从木质纤维素生物质生产对苯二甲酸的方法，包括在获得生物炭，粗生物油和气体的催化剂存在下热解木质纤维素生物质的步骤; 从粗生物油和/或从气体中收集芳族馏分，通过蒸馏从芳族馏分中提取甲苯; 通过催化羰基化将甲苯转化成对甲苯甲醛; 在液相氧化中将对甲苯甲醛氧化成对苯二甲酸。

12. 发明申请

US20150182939A1 SYSTEM FOR PRODUCING OXYGENATE AND METHOD FOR PRODUCING OXYGENATE 有权
标题翻译：生产氧气的系统和生产氧气的方法
公开(公告)号：US20150182939A1
公开(公告)日：2015-07-02
申请号：US14416374
申请日：2013-07-23
申请人： SEKISUI CHEMICAL CO., LTD. , RENAISSANCE ENERGY RESEARCH CORPORATION
发明人： Toshihito Miyama , Tomoaki Nishino , Osamu Okada , Tamotsu Nonouchi
IPC分类号： B01J19/24 , C07C29/141
CPC分类号： B01J19/245 , B01J21/063 , B01J21/08 , B01J23/6562 , B01J23/80 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/031 , B01J37/033 , B01J2219/24 , C01B3/58 , C01B2203/045 , C01B2203/0485 , C07C29/141 , C07C29/158 , C07C45/49 , C07C31/08 , C07C47/06
摘要： A system for producing an oxygenate, comprising: a desulfurization apparatus for contacting a raw material gas comprising hydrogen and carbon monoxide with a desulfurizing agent comprising copper; and a synthesis apparatus for contacting the raw material gas treated by the desulfurizing apparatus with an oxygenate-synthesis catalyst comprising rhodium.
摘要翻译：一种含氧化合物的制造方法，其特征在于，包括：使包含氢和一氧化碳的原料气体与包含铜的脱硫剂接触的脱硫装置; 以及使由脱硫装置处理的原料气体与含有铑的含氧化合物催化剂接触的合成装置。

13. 发明授权

US08912367B2 Method and system for liquid phase reactions using high shear 有权
标题翻译：使用高剪切的液相反应的方法和系统
公开(公告)号：US08912367B2
公开(公告)日：2014-12-16
申请号：US13530032
申请日：2012-06-21
申请人： Abbas Hassan , Aziz Hassan , Rayford G. Anthony , Gregory Borsinger
发明人： Abbas Hassan , Aziz Hassan , Rayford G. Anthony , Gregory Borsinger
IPC分类号： C07B41/08 , B01J19/00 , C07B41/02 , C07C2/88 , B01J19/18 , B01F7/00 , B01F13/10
CPC分类号： C07B41/08 , B01F7/00766 , B01F13/1016 , B01J19/0066 , B01J19/1806 , B01J2219/00083 , C07B41/02 , C07C2/88 , C07C29/149 , C07C45/49 , C07C45/87 , C07C51/12 , C10G2/30 , C10G2/35 , C10G2/50 , C07C53/08 , C07C31/08 , C07C47/06 , C07C49/90
摘要： A method of reacting one or more components in a liquid phase to form an organic product, the method including feeding a carbon-based gas to a high shear device; feeding a hydrogen-based liquid medium to the high shear device; using the high shear device to form a dispersion comprising the carbon-based gas and the hydrogen-based liquid medium, wherein the dispersion comprises gas bubbles with a mean diameter of less than about 5 μm; introducing the dispersion into a reactor; and reacting the dispersion to produce the organic product.
摘要翻译：一种在液相中使一种或多种组分反应以形成有机产物的方法，所述方法包括将碳基气体进料到高剪切装置; 将氢基液体介质供给高剪切装置; 使用高剪切装置形成包含碳基气体和氢基液体介质的分散体，其中分散体包含平均直径小于约5μm的气泡; 将分散体引入反应器; 并使该分散体反应生成有机产物。

14. 发明申请

US20140088321A1 PROCESS FOR PRODUCING ALDEHYDE COMPOUNDS 有权
标题翻译：生产甲醛化合物的方法
公开(公告)号：US20140088321A1
公开(公告)日：2014-03-27
申请号：US14114774
申请日：2012-05-07
申请人： Shigetoshi Kuma , Michiharu Sakata , Kouichi Tokunaga , Chitoshi Shimakawa , Naoyuki Kakinuma , Masayuki Furuya , Mamoru Tanaka
发明人： Shigetoshi Kuma , Michiharu Sakata , Kouichi Tokunaga , Chitoshi Shimakawa , Naoyuki Kakinuma , Masayuki Furuya , Mamoru Tanaka
IPC分类号： C07C253/30 , C07C263/10 , C07C209/26
CPC分类号： C07C253/30 , C07C45/29 , C07C45/49 , C07C209/26 , C07C209/48 , C07C209/52 , C07C263/10 , C07C2602/42 , C07C211/19 , C07C265/14 , C07C255/47 , C07C47/347
摘要： A process for producing an aldehyde compound of the invention comprising: reacting a compound represented by the following formula (a1) or (a2) with a hydrogen and a carbon monoxide in a presence of a compound containing a metal belonging to Groups 8 to 10 and a phosphorous compound so as to satisfy the following conditions (1) and (2) to synthesize an aldehyde compound; wherein the condition (1) is that a content of a metal included in the compound containing a metal belonging to Groups 8 to 10 is 0.01 ppmmol to 300 ppmmol with respect to 1 mol of the compound represented by the formula (a1) or (a2), and wherein the condition (2) is that a molar ratio represented by the phosphorous compound (mol)/the metal (mol) is 100 or more;
摘要翻译：一种制备本发明的醛化合物的方法，包括：在含有属于第8〜10族的金属的化合物的存在下，使由下式（a1）或（a2）表示的化合物与氢和一氧化碳反应，以及一种磷化合物，以满足以下条件（1）和（2）来合成醛化合物; 其中，条件（1）是含有属于第8〜10族的金属的化合物中含有的金属的含量相对于1摩尔式（a1）表示的化合物或（a2（a2））为0.01ppmmol〜300ppmmol ），其中条件（2）是由磷化合物（摩尔）/金属（摩尔）表示的摩尔比为100以上;

15. 发明授权

US08450495B2 11C-labeled benzophenone/benzoxazole analogues as an inflammation imaging agent 失效
标题翻译： 11C标记的二苯甲酮/苯并恶唑类似物作为炎症显像剂
公开(公告)号：US08450495B2
公开(公告)日：2013-05-28
申请号：US13609815
申请日：2012-09-11
申请人： Farhad Karimi , Bengt Langstrom
发明人： Farhad Karimi , Bengt Langstrom
IPC分类号： C07D263/58 , C07C49/786
CPC分类号： C07C235/20 , A61K51/04 , A61K51/0453 , A61K51/0455 , C07B59/001 , C07B59/002 , C07B2200/05 , C07C45/49 , C07C49/83 , C07C49/84 , C07C235/24 , C07D263/58
摘要： A method of preparing novel [11C]-labeled benzophenone/bezoxazole analogues is provided. The present invention also provides novel [11C]-labeled benzophenone/bezoxazole analogues prepared from the GMP synthesis method. Kit claims for preparing novel [11C]-labeled benzophenone/bezoxazole analogues and a method of use thereof are also provided.
摘要翻译：提供了制备新的[11C]标记的二苯甲酮/异唑唑类似物的方法。本发明还提供了由GMP合成法制备的新的[11C]标记二苯甲酮/异唑唑类似物。还提供了制备新的[11C]标记的二苯甲酮/异唑唑类似物的试剂盒说明书及其使用方法。

16. 发明申请

US20130005984A1 11C-LABELED BENZOPHENONE/BENZOXAZOLE ANALOGUES AS AN INFLAMMATION IMAGING AGENT 失效
标题翻译： 11C标记的苯并噻唑/苯并噻唑类似物作为炎症成像剂
公开(公告)号：US20130005984A1
公开(公告)日：2013-01-03
申请号：US13609815
申请日：2012-09-11
申请人： FARHAD KARIMI , BENGT LANGSTROM
发明人： FARHAD KARIMI , BENGT LANGSTROM
IPC分类号： C07D263/58 , C07C49/786
CPC分类号： C07C235/20 , A61K51/04 , A61K51/0453 , A61K51/0455 , C07B59/001 , C07B59/002 , C07B2200/05 , C07C45/49 , C07C49/83 , C07C49/84 , C07C235/24 , C07D263/58
摘要： A method of preparing novel [11C]-labeled benzophenone/bezoxazole analogues is provided. The present invention also provides novel [11C]-labeled benzophenone/bezoxazole analogues prepared from the GMP synthesis method. Kit claims for preparing novel [11C]-labeled benzophenone/bezoxazole analogues and a method of use thereof are also provided.
摘要翻译：提供了制备新的[11C]标记的二苯甲酮/异唑唑类似物的方法。本发明还提供了由GMP合成法制备的新的[11C]标记二苯甲酮/异唑唑类似物。还提供了制备新的[11C]标记的二苯甲酮/异唑唑类似物的试剂盒说明书及其使用方法。

17. 发明授权

US08273861B2 Method for the use of [11C] carbon monoxide in labeling synthesis of 11C-labelled ketones by photo-induced free radical carbonylation 有权
标题翻译：使用[11C]一氧化碳通过光诱导的自由基羰基化标记11C标记的酮的合成方法
公开(公告)号：US08273861B2
公开(公告)日：2012-09-25
申请号：US12065094
申请日：2006-08-29
申请人： Bengt Langstrom , Oleksiy Itsenko , Tor Kihlberg
发明人： Bengt Langstrom , Oleksiy Itsenko , Tor Kihlberg
IPC分类号： C07F5/00 , C07C233/02
CPC分类号： C07B59/001 , C07C45/49
摘要： Methods and reagents for photo-initiated carbonylation with carbon-isotope labeled carbon monoxide using alkyl/aryl iodides with carbanion precursors pretreated by a base are provided. The resultant carbon-isotope labeled ketones, and pharmaceutical acceptable salts and solvates are useful as radiopharmaceuticals, especially for use in Positron Emission Tomography (PET). Associated kits and method for PET studies are also provided.
摘要翻译：提供了使用具有由碱预处理的碳负离子前体的烷基/芳基碘化物用碳同位素标记的一氧化碳进行光引发羰基化的方法和试剂。所得的碳同位素标记酮和药学上可接受的盐和溶剂化物可用作放射性药物，特别是用于正电子发射断层扫描（PET）。还提供了关于PET研究的试剂盒和方法。

18. 发明申请

US20120203042A1 SYSTEMS AND PROCESSES FOR CATALYTIC PYROLYSIS OF BIOMASS AND HYDROCARBONACEOUS MATERIALS FOR PRODUCTION OF AROMATICS WITH OPTIONAL OLEFIN RECYCLE, AND CATALYSTS HAVING SELECTED PARTICLE SIZE FOR CATALYTIC PYROLYSIS 有权
标题翻译：生物质催化裂解和用于生产具有可选烯烃回收的芳族化合物的烃类物质的系统和方法以及具有选择的颗粒尺寸用于催化热解的催化剂
公开(公告)号：US20120203042A1
公开(公告)日：2012-08-09
申请号：US13394559
申请日：2010-09-09
申请人： George W. Huber , Anne Mae Gaffney , Jungho Jae , Yu-Ting Cheng
发明人： George W. Huber , Anne Mae Gaffney , Jungho Jae , Yu-Ting Cheng
IPC分类号： C07C1/20 , B82Y5/00
CPC分类号： C10G3/49 , B01J29/40 , B01J29/405 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/87 , C07C45/49 , C10B49/22 , C10B53/02 , C10B57/06 , C10G1/002 , C10G1/02 , C10G1/10 , C10G3/00 , C10G11/18 , C10G45/32 , C10G50/00 , C10G2300/1003 , C10G2300/1014 , C10G2300/4018 , C10G2300/4081 , C10G2300/70 , C10G2400/20 , C10G2400/30 , Y02E50/14 , Y02P20/52 , Y02P30/20 , Y02P30/42
摘要： This invention relates to compositions and methods for fluid hydrocarbon product, and more specifically, to compositions and methods for fluid hydrocarbon product via catalytic pyrolysis. Some embodiments relate to methods for the production of specific aromatic products (e.g., benzene, toluene, naphthalene, xylene, etc.) via catalytic pyrolysis. Some such methods may involve the use of a composition comprising a mixture of a solid hydrocarbonaceous material and a heterogeneous pyrolytic catalyst component. In some embodiments, an olefin compound may be co-fed to the reactor and/or separated from a product stream and recycled to the reactor to improve yield and/or selectivity of certain products. The methods described herein may also involve the use of specialized catalysts. For example, in some cases, zeolite catalysts may be used. In some instances, the catalysts are characterized by particle sizes in certain identified ranges that can lead to improve yield and/or selectivity of certain products.
摘要翻译：本发明涉及流体烃产物的组合物和方法，更具体地说，涉及通过催化裂解的流化烃产物的组合物和方法。一些实施方案涉及通过催化热解生产特定芳族产物（例如苯，甲苯，萘，二甲苯等）的方法。一些这样的方法可以涉及使用包含固体烃类材料和非均相热解催化剂组分的混合物的组合物。在一些实施方案中，烯烃化合物可以共同进料至反应器和/或从产物流中分离并再循环至反应器以提高某些产物的产率和/或选择性。本文所述的方法还可以涉及使用专门的催化剂。例如，在一些情况下，可以使用沸石催化剂。在一些情况下，催化剂的特征在于可以导致某些产物的产率和/或选择性的某些确定范围内的粒度。

19. 发明申请

US20110201844A1 CATALYST COMPOSITION FOR HYDROFORMYLATION AND METHOD FOR PRODUCING ALDEHYDE USING THE SAME 有权
标题翻译：用于氢化的催化剂组合物及其制备方法
公开(公告)号：US20110201844A1
公开(公告)日：2011-08-18
申请号：US13092817
申请日：2011-04-22
申请人： Jae Hui Choi , Dong Hyun Ko , Sung Shik Eom , Moo Ho Hong , O Hark Kwon , Dae Chul Kim
发明人： Jae Hui Choi , Dong Hyun Ko , Sung Shik Eom , Moo Ho Hong , O Hark Kwon , Dae Chul Kim
IPC分类号： C07C45/50 , B01J31/24
CPC分类号： C07C45/49 , B01J31/1875 , B01J31/20 , B01J31/2208 , B01J31/2404 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C45/50 , C07F9/46 , C07F9/5022 , C07F9/655345 , C07F9/6571 , C07F9/657127 , C07C47/228 , C07C47/02
摘要： The present invention relates to a catalyst composition for hydroformylation and a method for preparing aldehydes using the same, wherein the catalyst composition for hydroformylation comprises: a triaryl phosphine ligand; a phosphine oxide or phosphine sulfide ligand having a specific chemical formula; and a transition metal catalyst. The catalyst composition provides high catalyst activity and stability and selectivity to normal aldehydes when used in the hydroformylation for preparing aldehydes from olefins.
摘要翻译：本发明涉及一种用于加氢甲酰化的催化剂组合物及其制备方法，其中用于加氢甲酰化的催化剂组合物包括：三芳基膦配体; 具有特定化学式的氧化膦或硫化膦配体; 和过渡金属催化剂。当用于从烯烃制备醛的加氢甲酰化中时，催化剂组合物提供高的催化剂活性和对正醛的稳定性和选择性。

20. 发明授权

US07781620B2 Hydroformylation process 有权
标题翻译：加氢甲酰化过程
公开(公告)号：US07781620B2
公开(公告)日：2010-08-24
申请号：US12519965
申请日：2007-12-19
申请人： Wilhelmus Petrus Mul
发明人： Wilhelmus Petrus Mul
IPC分类号： C07C45/50 , C07C29/14
CPC分类号： C07C45/50 , C07C29/16 , C07C45/49 , C07C2601/08 , C07C47/14 , C07C47/30 , C07C47/228 , C07C31/125 , C07C31/36 , C07C31/135 , C07C33/20
摘要： A hydroformylation process comprising reacting, in a reactor system comprising one or more feed streams, a reaction environment and an output stream, a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydroformylation catalyst, wherein the hydroformylation process is carried out in the reaction environment, which comprises at least two reaction zones, wherein the at least two reaction zones comprise an earlier reaction zone and a later reaction zone, wherein the temperature of the later reaction zone is at a temperature which is at least 2° C. greater than the temperature in the earlier reaction zone, and the temperature of the later reaction zone is in the range of from 140° C. to 220° C., and the temperature of the earlier reaction zone is at least 130° C., and wherein water is added into the reactor system.
摘要翻译：加氢甲酰化方法包括在包含一种或多种进料流的反应器系统中反应反应环境和输出流，原料组合物包含在存在下具有至少一个烯烃碳 - 碳键与氢和一氧化碳的化合物的有机膦修饰的羰基羰基化催化剂，其中所述加氢甲酰化方法在包含至少两个反应区的反应环境中进行，其中所述至少两个反应区包含较早的反应区和较后的反应区，后一反应区的温度比早期反应区的温度高至少2℃，后反应区的温度在140℃至220℃的范围内，并且较早的反应区的温度为至少130℃，并且其中将水加入到反应器系统中。

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