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11. 发明授权

US09193628B2 Cementitious mixture for materials having “easy-to-clean” properties by modification of the unset material by means of fluorine-containing active ingredients 有权
标题翻译：通过含氟活性成分改性未固化物质的具有“易清洁”特性的材料的水泥混合物
公开(公告)号：US09193628B2
公开(公告)日：2015-11-24
申请号：US13638734
申请日：2011-03-30
申请人： Manuel Friedel , Philipp Albert , Burkhard Standke , Spomenko Ljesic
发明人： Manuel Friedel , Philipp Albert , Burkhard Standke , Spomenko Ljesic
IPC分类号： C04B24/42 , C04B28/02 , C04B24/00 , C04B111/20 , C04B111/27
CPC分类号： C04B24/42 , C04B24/005 , C04B28/02 , C04B2111/203 , C04B2111/27 , C04B14/06
摘要： The present invention relates to a hydraulically setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.01% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulically setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as facing concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
摘要翻译：本发明涉及一种水硬固化混合物，其包含：a）6重量％至25重量％的水泥，b）50重量％至90重量％的至少一种骨料，和c）0.01重量％至8重量％至少一种氟代取代的硅化合物，以及由该混合物制备的材料，更具体地说是组分，混凝土制品或模制品。本发明还涉及本发明的水硬设置混合物用于生产材料，特别是组分，混凝土制品或模制品，例如面向混凝土的应用，其中材料的表面仅具有相对较低的污染趋势（“ 清洁“财产）即使磨损。

12. 发明授权

US08809209B2 Fluorinated copolymers 有权
标题翻译：氟化共聚物
公开(公告)号：US08809209B2
公开(公告)日：2014-08-19
申请号：US13300999
申请日：2011-11-21
申请人： Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , Siddhartha Shenoy , Libby Xiaowei Hu
发明人： Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , Siddhartha Shenoy , Libby Xiaowei Hu
IPC分类号： B32B5/02 , B32B27/04 , B32B27/12
CPC分类号： C04B41/4842 , B27K3/153 , C04B41/009 , C04B2111/203 , C04B2111/27 , C08L33/04 , C08L33/16 , C08L97/02 , D06M15/277 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T442/2164 , Y10T442/2172 , Y10T442/2189 , C04B14/28 , C04B41/483
摘要： A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.
摘要翻译：一种耐污染，防油和防水的组合物，其包含由氟化甲基丙烯酸酯，甲基丙烯酸碳酸酯和甲基丙烯酸或其盐制备的共聚物，对基材提供耐污性，防油和拒水性的方法以及经处理的基材。

13. 发明申请

US20130115375A1 STONE SEALING SYSTEMS AND METHODS 审中-公开
标题翻译：石密封系统和方法
公开(公告)号：US20130115375A1
公开(公告)日：2013-05-09
申请号：US13288923
申请日：2011-11-03
申请人： Justin Howe
发明人： Justin Howe
IPC分类号： B05D3/02 , B05C5/00
CPC分类号： C04B41/009 , C04B41/45 , C04B2111/203 , C04B14/00 , C04B41/0072
摘要： This disclosure is related to systems and methods of sealing a stone and is particularly useful for sealing a stone countertop, though it could also be applied to stone tiles or other types of stone products. In one example, a method for sealing stone may include applying heat to a stone and applying a sealant to the stone when the temperature of the stone is above a temperature threshold. The sealant may be an impregnating sealer.
摘要翻译：本公开涉及密封石头的系统和方法，并且特别可用于密封石材对接面，尽管其也可以应用于石瓦或其他类型的石制品。在一个实例中，用于密封石材的方法可以包括当石头的温度高于温度阈值时，向石头施加热量并向石头施加密封剂。密封剂可以是浸渍密封剂。

14. 发明申请

US20130085210A1 CURABLE MIXTURE 有权
标题翻译：可固化混合物
公开(公告)号：US20130085210A1
公开(公告)日：2013-04-04
申请号：US13638733
申请日：2011-03-30
申请人： Manuel Friedel , Philipp Albert , Burkhard Standke , Spomenko Ljesic , Ulf Kehrer
发明人： Manuel Friedel , Philipp Albert , Burkhard Standke , Spomenko Ljesic , Ulf Kehrer
IPC分类号： C04B24/42 , C08L29/04 , C08K9/10
CPC分类号： C04B24/42 , C04B28/02 , C04B40/0042 , C04B2111/203 , C04B2111/27 , C08K9/10 , C08L29/04 , C04B2103/0053 , C04B24/2623 , C04B2103/0057
摘要： The present invention relates to a curable mixture suitable for obtaining “easy-to-clean” properties in the cured mixture, comprising at least one mineral binder, a powder comprising at least one fluoroorganyl-substituted silicon compound encapsulated in a water-soluble polymer, the amount of the silicon compound being 0.001% to 8% by weight, based on the present mixture, and optionally further adjuvants, and also to a process for preparing the mixture and to the use thereof. The invention further relates to a water-redispersible powder and also to a corresponding intermediate for use in the curable mixture in order to obtain “easy-to-clean” properties in the cured mixture. Also claimed, furthermore, is a process for preparing the powder, and the use thereof.
摘要翻译：本发明涉及一种适用于在固化混合物中获得易清洁性能的可固化混合物，其包含至少一种矿物粘合剂，包含至少一种包封在水溶性聚合物中的氟代取代的硅化合物的粉末，的硅化合物的重量百分数为0.001％至8％，基于本混合物，以及任选的其它助剂，以及制备该混合物及其用途的方法。本发明还涉及一种水可再分散粉末，还涉及用于可固化混合物的相应中间体，以便在固化混合物中获得易于清洁的性能。此外，还要求的是制备粉末的方法及其用途。

15. 发明申请

US20120156515A1 FLUORINATED COPOLYMERS OF (METH)ACRYLATES AND (METH)ACRYLIC ACID AMINE COMPLEXES 有权
标题翻译：（甲基）丙烯酸酯和（甲基）丙烯酸胺复合物的氟化共聚物
公开(公告)号：US20120156515A1
公开(公告)日：2012-06-21
申请号：US13301041
申请日：2011-11-21
申请人： Siddhartha Shenoy , Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , John Russell Crompton, JR.
发明人： Siddhartha Shenoy , Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , John Russell Crompton, JR.
IPC分类号： C09D133/16 , C08F220/28 , C08F230/02 , C08F230/08 , C08F228/02 , B32B27/06 , B05D1/02 , B05D1/18 , B05D1/40 , B05D7/06 , B05D7/00 , C08F220/22 , B05D1/28
CPC分类号： C08F220/06 , B27K3/153 , C04B41/009 , C04B41/4842 , C04B2111/203 , C04B2111/27 , C08F8/44 , C08F220/24 , C08F2800/10 , C08L33/04 , C08L33/16 , C08L97/02 , Y10T428/31906 , Y10T428/31935 , C04B14/28 , C04B41/483
摘要： A stain resistant, oil and water repellent copolymer comprising a copolymer prepared from fluorinated (meth)acrylate and amine salts of (meth)acrylic acid, and a method of providing stain resistance, oil and water repellency to substrates and a treated substrate.
摘要翻译：包含由氟化（甲基）丙烯酸酯制备的共聚物和（甲基）丙烯酸的胺盐的防污，防油和防水的共聚物，以及对基材和经处理的基材提供耐污性，防油和拒水性的方法。

16. 发明申请

US20110123810A1 Protecting agent for concrete, masonry surface, bricks, clay roofing, tiles, marble, granite, concrete slate, stucco, paving stones, unglazed ceramic, sandstone, limestone, wood and other objects against stains, dirt, water and oil penetration 有权
标题翻译：混凝土保护剂，砖石，砖，粘土屋面，瓷砖，大理石，花岗岩，混凝土板岩，灰泥，铺路石，无釉陶瓷，砂岩，石灰石，木材等物品，防止污渍，污垢，水和油渗透
公开(公告)号：US20110123810A1
公开(公告)日：2011-05-26
申请号：US12591627
申请日：2009-11-25
申请人： Yassin Elgarhy
发明人： Yassin Elgarhy
IPC分类号： C08L27/12 , B05D3/00 , C08K5/5415 , C08K5/5419 , C08K5/21 , C08L33/14 , B32B27/06
CPC分类号： C09D127/12 , C04B41/4842 , C04B2111/203 , C04B2111/27 , Y10T428/3154 , Y10T428/31663 , Y10T428/4935
摘要： An aqueous composition of a non-siliceous fluorocarbon polymer forms a dry deposit derived from the non-siliceous fluorocarbon polymer on the surface of construction material; the non-siliceous fluorocarbon polymer being characterized by the presence of fluorocarbon units of up to 6 carbon atoms; this non-siliceous fluorocarbon polymer is a protecting agent imparting an excellent water and oil repellency and also protection against stains and dirt, to bricks, clay roofing, different kinds of tiles, marble, granite, slate, stucco,paving stones, unglazed ceramic, sandstones, limestone, wood and other objects; it is durable and can be processed at low temperature; the composition may also include silicone based agents and acrylics and can provide a natural, satin or wet look to the construction material surface.
摘要翻译：非硅质碳氟化合物聚合物的水性组合物在建筑材料的表面上形成由非硅质碳氟聚合物衍生的干沉积物; 非硅质碳氟聚合物的特征在于存在多达6个碳原子的氟碳单元; 这种非硅质碳氟聚合物是赋予防水防油性优异的保护剂，防污染，砖，粘土屋面，不同种类的瓷砖，大理石，花岗岩，石板，灰泥，铺路石，无釉陶瓷，砂岩，石灰石，木材等物体; 耐用，可在低温下加工; 组合物还可以包括基于硅酮的试剂和丙烯酸树脂，并且可以对建筑材料表面提供天然的，缎面的或湿的外观。

17. 发明申请

US20100227173A1 WATER-REPELLENT OIL-REPELLENT ANTIFOULING AGENT HAVING GOOD SOLUBILITY IN SOLVENT 审中-公开
标题翻译：具有溶剂中良好溶解性的耐水防油剂
公开(公告)号：US20100227173A1
公开(公告)日：2010-09-09
申请号：US12599790
申请日：2008-05-14
申请人： Akihiko Ueda , Masahiko Maeda , Tetsuya Masutani
发明人： Akihiko Ueda , Masahiko Maeda , Tetsuya Masutani
IPC分类号： C08L33/16 , C08F220/22 , B32B27/00
CPC分类号： C04B41/4846 , C03C17/32 , C03C2217/76 , C04B41/009 , C04B2111/203 , C04B2111/27 , C08F214/186 , C08F220/22 , C08F220/24 , Y10T428/3154 , C04B41/463 , C04B41/483 , C04B41/4922 , C04B14/048 , C04B14/28
摘要： Disclosed is a water-repellent oil-repellent antifouling agent containing a fluorine-containing polymer for a treatment for providing water repellency, oil repellency and antifouling property. The fluorine-containing polymer has a repeating unit (A) derived from a fluorine-containing acrylate monomer, and a repeating unit (B) derived from at least one non-fluorine acrylate monomer selected from the group consisting of a monomer (B1) having a cyclic hydrocarbon group and a monomer (B2) having a short chain hydrocarbon group. This water-repellent oil-repellent antifouling agent has good solubility in solvents, and exhibits excellent effects on various bases, especially on masonries.
摘要翻译：公开了含有含氟聚合物的防水防油防污剂，用于提供防水性，防油性和防污性的处理。含氟聚合物具有由含氟丙烯酸酯单体衍生的重复单元（A）和由至少一种选自以下的非氟丙烯酸酯单体衍生的重复单元（B）：单体（B1），其具有环状烃基和具有短链烃基的单体（B2）。该防水防油防污剂在溶剂中的溶解性良好，对各种碱，特别是在砌体上表现出优异的效果。

18. 发明授权

US6120892A Waterborne fluoropolymer solutions for treating hard surfaces 有权
标题翻译：用于处理硬表面的水性氟聚合物溶液
公开(公告)号：US6120892A
公开(公告)日：2000-09-19
申请号：US248068
申请日：1999-02-11
申请人： John J. Fitzgerald , Thomas Clark Felder, III
发明人： John J. Fitzgerald , Thomas Clark Felder, III
IPC分类号： C03C17/32 , C04B41/48 , C09D133/16 , B32B13/12 , B32B17/10
CPC分类号： C04B41/4846 , C03C17/32 , C09D133/16 , C04B2111/203 , C04B2111/27 , Y10T428/273
摘要： A method for imparting water, oil or stain repellency to HARD SURFACES comprising application to the surface of an effective amount of a composition comprising monomers copolymerized in the following percentages by weight:(a) from about 40% to about 90% of at least one monomer of formula I:R.sub.f --Q--A--C(O)--C(R).dbd.CH.sub.2 IwhereinR.sub.f is a straight or branched-chain perfluoroalkyl group of 2 to about 20 carbon atoms,R is H or CH.sub.3,A is O, S, or NR.sub.1 wherein R.sub.1 is H or a C.sub.1 -C.sub.4 alkyl, and Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 3 to about 15 carbon atoms,--(C.sub.n H.sub.2n) (OC.sub.q H.sub.2q).sub.m --, --SO.sub.2 --NR.sub.1 (C.sub.n H.sub.2n)-- or --CONR.sub.1 (C.sub.n H.sub.2n)-- wherein R.sub.1 is H or C.sub.1 -C.sub.4 alkyl, n is 1 to about 15, q is 2 to about 4, and m is 1 to about 15;(b) from about 2% to about 50% of a monomer of formula IIA or IIB or a mixture thereof:(CH.sub.2 .dbd.C(R)COZ(CH.sub.2).sub.r.sup.+ NR.sub.2 R.sub.3 R.sub.4)X.sup.- IIAandCH.sub.2 .dbd.C(R)COZ(CH.sub.2).sub.r NR.sub.2 R.sub.3 (O) IIBwhereinR is H or CH.sub.3,R.sub.2 and R.sub.3 are each independently C.sub.1 -C.sub.4 alkyl, hydroxyethyl, or benzyl or R.sub.2 and R.sub.3 together with the nitrogen atom form a morpholine, pyrrolidine, or piperidine ring,R.sub.4 is H or C.sub.1 -C.sub.4 alkyl or R.sub.2, R.sub.3, and R.sub.4 together with the nitrogen form a piperidine ring,Z is --O-- or --NR.sub.4 --r is 2 to 4, andX.sup.- is an anion,provided that the nitrogen is from about 40% to 100% salinized, quaternized, or present as amine oxide.
摘要翻译：一种向硬表面赋予水，油或防污性的方法，包括向所述表面施用有效量的包含单体的组合物，所述组合物按以下重量百分比共聚合：（a）约40％至约90％的至少一种式I的单体：Rf-QAC（O）-C（R）= CH 2 I，其中R f是2至约20个碳原子的直链或支链全氟烷基，R是H或CH 3，A是O，S或 NR1其中R1为H或C1-C4烷基，Q为1至约15个碳原子的亚烷基，3至约15个碳原子的羟基亚烷基， - （CnH2n）（OCqH2q）m-，-SO2-NR1（CnH2n） - 或-CONR1（C n H 2n） - 其中R 1为H或C 1 -C 4烷基，n为1至约15，q为2至约4，m为1至约15; （b）约2％至约50％的式IIA或IIB的单体或其混合物：（CH 2 = C（R）COZ（CH 2）r + NR 2 R 3 R 4）X-IIA和CH 2 = C（R）COZ （CH2）rNR2R3（O）IIB其中R是H或CH3，R2和R3各自独立地是C1-C4烷基，羟乙基或苄基或R2和R3与氮原子一起形成吗啉，吡咯烷或哌啶环，R4 是H或C 1 -C 4烷基或R 2，R 3和R 4与氮一起形成哌啶环，Z为-O-或-NR 4 -r为2至4，X为阴离子，条件是氮是约40％至100％盐化，季铵化或作为氧化胺存在。

19. 发明授权

US5527931A Aqueous dispersable oil and water repellent silane masonry penetrants 失效
标题翻译：水性分散油和拒水硅烷矽胶渗透剂
公开(公告)号：US5527931A
公开(公告)日：1996-06-18
申请号：US266116
申请日：1994-06-27
申请人： Larry D. Rich , James F. Sanders
发明人： Larry D. Rich , James F. Sanders
IPC分类号： C04B38/00 , C04B41/49 , C04B41/64 , C07F7/18 , C09D4/00 , C09D183/08 , C09K3/18 , C07F7/10
CPC分类号： C09D183/08 , C04B41/4922 , C09D4/00 , C04B2111/203
摘要： The present invention relates to organosilane compounds used for treating porous substrates to render them repellent to water-based and oil-based challenges and to enhance the cleanibility of the protected surfaces from such challenges.
摘要翻译：本发明涉及用于处理多孔基材的有机硅烷化合物，使其对水基和油基的挑战具有驱避作用，并提高了保护表面的清洁能力。

20. 发明授权

US08808868B2 Fluorinated copolymers of (meth)acrylates and (meth)acrylic acid amine complexes 有权
标题翻译：（甲基）丙烯酸酯和（甲基）丙烯酸胺络合物的氟化共聚物
公开(公告)号：US08808868B2
公开(公告)日：2014-08-19
申请号：US13301041
申请日：2011-11-21
申请人： Siddhartha Shenoy , Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , John Russell Crompton, Jr.
发明人： Siddhartha Shenoy , Joel M. Pollino , Anilkumar Raghavanpillai , Brad M. Rosen , John Russell Crompton, Jr.
IPC分类号： B32B27/30 , B32B23/08 , C08F220/22 , C08F220/28 , C08F228/02 , C08F230/02 , C08F230/08
CPC分类号： C08F220/06 , B27K3/153 , C04B41/009 , C04B41/4842 , C04B2111/203 , C04B2111/27 , C08F8/44 , C08F220/24 , C08F2800/10 , C08L33/04 , C08L33/16 , C08L97/02 , Y10T428/31906 , Y10T428/31935 , C04B14/28 , C04B41/483
摘要： A stain resistant, oil and water repellent copolymer comprising a copolymer prepared from fluorinated (meth)acrylate and amine salts of (meth)acrylic acid, and a method of providing stain resistance, oil and water repellency to substrates and a treated substrate.
摘要翻译：包含由氟化（甲基）丙烯酸酯制备的共聚物和（甲基）丙烯酸的胺盐的防污，防油和防水的共聚物，以及对基材和经处理的基材提供耐污性，防油和拒水性的方法。

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