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11. 发明授权

US5248742A Unsaturated polyester-epoxy resin network composition 失效
标题翻译：不饱和聚酯环氧树脂网络组成
公开(公告)号：US5248742A
公开(公告)日：1993-09-28
申请号：US874788
申请日：1992-04-27
申请人： Frederick J. McGarry , Ramnath Subramaniam
发明人： Frederick J. McGarry , Ramnath Subramaniam
IPC分类号： C08G59/40 , C08G59/50 , C08L63/00 , C08L63/10 , C08L67/06
CPC分类号： C08L63/10 , C08L63/00 , C08L67/06 , Y10S525/942
摘要： A unsaturated polyester resin composition is described that contains an epoxy resin reacted with an amine-terminated flexible polymer while dissolved in the unsaturated polyester resin and its ethylenically unsaturated crosslinking monomer. A compatible system results from the reaction which has a controllable modulus based on the amount of flexible polymer included in the resin. The resin is generally transparent if unfilled and has a higher calculated fracture energy than similar unsaturated polyester resin without modification. The unsaturated polyester resin can be filled with particulate filler or reinforced with fibrous fillers.

12. 发明授权

US5000981A Compositions of elastomer-coated fibers 失效
标题翻译：弹性体涂层纤维的组成
公开(公告)号：US5000981A
公开(公告)日：1991-03-19
申请号：US403060
申请日：1989-09-05
申请人： Frederick J. McGarry , Alan R. Siebert , Changkiu K. Riew
发明人： Frederick J. McGarry , Alan R. Siebert , Changkiu K. Riew
IPC分类号： C03C25/12 , C03C25/26 , C08J5/06
CPC分类号： C08J5/06 , C03C25/12 , C03C25/26
摘要： Fibers are conveniently coated with a uniformly thin and continuous elastomeric coating by contacting the fibers with a (1) a water-dispersed reactive polymer, (2) epoxy resin, and (3) curing agent; and wherein said water-dispersed reactive polymer is a composition comprising. (a) a lower molecular weight reactive polymer, (b) a select solvent, (c) a dispersing agent, and (d) water. The elastomeric films have a Tg value of about 0.degree. C. or below. The elastomer coated fibers are useful as strengtheners and impact modifiers for brittle materials such as epoxy resins.
摘要翻译：通过使纤维与（1）水分散的反应性聚合物，（2）环氧树脂和（3）固化剂接触使纤维方便地涂覆均匀薄且连续的弹性体涂层。并且其中所述水分散反应性聚合物是包含的组合物。（a）较低分子量的反应性聚合物，（b）选择性溶剂，（c）分散剂和（d）水。弹性膜的Tg值约为0℃或更低。弹性体涂覆的纤维可用作脆化材料如环氧树脂的增强剂和抗冲击改性剂。

13. 发明授权

US5428105A Low-profile additives for thermosetting polyester compositions 失效
标题翻译：用于热固性聚酯组合物的低轮廓添加剂
公开(公告)号：US5428105A
公开(公告)日：1995-06-27
申请号：US329586
申请日：1994-10-26
申请人： Frederick J. McGarry , Mary B. Chan-Park
发明人： Frederick J. McGarry , Mary B. Chan-Park
IPC分类号： C08L67/06 , C08L9/00 , C08L9/06 , C08L53/02
CPC分类号： C08L67/06
摘要： A curable polyester molding composition incorporating an elastomeric low profile additive dispersed in voided rubbery particle form throughout the composition is used in association with a compatibilizing agent to form a molded thermoset article having very smooth, light reflective, class A surfaces and having a matrix fracture energy which is comparable to articles formed from similar or identical molding compositions which are free of low profile additives. The low profile additive is an epoxidized elastomer or block copolymer having at least one flexible elastomer block and one monovinyl aromatic block. The compatibilizing agent is a copolymer having a diene polymer backbone which is compatible with the elastomer or the flexible diene block of the low profile additive, with constituents which are compatible or reactive with the polyester being grafted or adducted onto the diene polymer backbone. The compatibilizing agent improves the solubility of the low profile additive in the uncured molding composition to promote good dispersion, to promote and maintain small particle size of the low profile additive, and to enhance compatibility between the cured polyester matrix and the low profile additive, thereby providing a low profile mechanism wherein shrinkage compensation during curing of the composition occurs almost exclusively through voiding of the small tough elastomeric particles of the low profile additive dispersed in the cured polyester matrix.
摘要翻译：将一种可固化的聚酯模塑组合物结合到整个组合物中分散成空隙橡胶颗粒形式的弹性薄型添加剂与相容剂结合使用以形成具有非常光滑，光反射，A级表面并具有基体断裂能的模制热固性制品其与由不含低调添加剂的相似或相同的模制组合物形成的制品相当。低调添加剂是具有至少一个柔性弹性体嵌段和一个单乙烯基芳族嵌段的环氧化弹性体或嵌段共聚物。相容剂是具有与低分子添加剂的弹性体或柔性二烯嵌段相容的二烯聚合物主链的共聚物，其与被接枝或加成到二烯聚合物主链上的聚酯相容或反应的成分。相容剂改善了未固化的模塑组合物中的低轮廓添加剂的溶解度，以促进良好的分散性，促进和保持小型添加剂的小颗粒尺寸，并且增强了固化的聚酯基体和低轮廓添加剂之间的相容性提供了一种低调机理，其中在组合物固化期间的收缩补偿几乎完全通过分散在固化的聚酯基质中的低分子量添加剂的小韧性弹性体颗粒的排空。

14. 发明授权

US5358779A Enhanced surface appearance of glass fiber reinforced plastics (FRP) 失效
标题翻译：增强玻璃纤维增强塑料（FRP）的表面外观
公开(公告)号：US5358779A
公开(公告)日：1994-10-25
申请号：US904811
申请日：1992-06-26
申请人： Frederick J. McGarry
发明人： Frederick J. McGarry
IPC分类号： B62D29/04 , C08J7/04 , C09D163/00 , B62D29/00 , B32B7/00 , D04H1/58
CPC分类号： C08J7/047 , B62D29/04 , C09D163/00 , C08J2409/00 , C08J2463/00 , Y10S296/90 , Y10T428/249952 , Y10T428/31786
摘要： A method for enhancing the surface appearance of thermoset FRP wherein a thin rubbery coating is applied to a sheet molded compound (SMC). This coating, when applied to FRP inhibits propagation of micro cracks to the surface of compliant rubbery coating of the parts, while not sacrificing the physical properties of the molded parts. The coating also supplies a suitable smooth surface for automotive body panel applications that serves as a substrate for further paint applications.
摘要翻译：一种用于增强热固性FRP的表面外观的方法，其中将薄橡胶涂层施加到片状模塑料（SMC）上。当涂覆在FRP上时，这种涂层可以抑制微裂纹扩展到零件的柔性橡胶层的表面，同时不会牺牲模制件的物理性能。涂层还为汽车车身面板应用提供了合适的光滑表面，用作进一步涂料应用的基材。

15. 发明授权

US5415894A Enhanced surface appearance of glass fiber reinforced plastics 失效
标题翻译：增强玻璃纤维增强塑料的表面外观
公开(公告)号：US5415894A
公开(公告)日：1995-05-16
申请号：US252480
申请日：1994-06-01
申请人： Frederick J. McGarry
发明人： Frederick J. McGarry
IPC分类号： B62D29/04 , C08J7/04 , C09D163/00 , B32B27/08 , B32B27/36 , B32B27/38
CPC分类号： C08J7/047 , B62D29/04 , C09D163/00 , C08J2409/00 , C08J2463/00 , Y10S296/90 , Y10T428/249952 , Y10T428/31786
摘要： A method for enhancing the surface appearance of thermoset FRP wherein a thin rubbery coating is applied to a sheet molded compound (SMC). This coating, when applied to FRP inhibits propagation of micro cracks to the surface of compliant rubbery coating of the parts, while not sacrificing the physical properties of the molded parts. The coating also supplies a suitable smooth surface for automotive body panel applications that serves as a substrate for further paint applications.
摘要翻译：一种用于增强热固性FRP的表面外观的方法，其中将薄橡胶涂层施加到片状模塑料（SMC）上。当涂覆在FRP上时，这种涂层可以抑制微裂纹扩展到零件的柔性橡胶层的表面，同时不会牺牲模制件的物理性能。涂层还为汽车车身面板应用提供了合适的光滑表面，用作进一步涂料应用的基材。

16. 发明授权

US5362799A Unsaturated polyester-flexible polymer network composition 失效
标题翻译：不饱和聚酯 - 柔性聚合物网络组成
公开(公告)号：US5362799A
公开(公告)日：1994-11-08
申请号：US121111
申请日：1993-09-13
申请人： Frederick J. McGarry , Ramnath Subramaniam
发明人： Frederick J. McGarry , Ramnath Subramaniam
IPC分类号： C08G59/40 , C08G59/50 , C08L63/00 , C08L63/10 , C08L67/06
CPC分类号： C08L63/10 , C08L63/00 , C08L67/06 , Y10S525/942
摘要： An unsaturated polyester resin composition is described that contains an amine-terminated flexible polymer that can react with the unsaturation in the polyester. A compatible system results that has higher fracture toughness. The preferred amine-terminated flexible polymer is an amine-terminated poly(butadiene-co-acrylonitrile). The resin composition can be extended with fillers and reinforced with fibers. In these applications, the resin is known as a matrix resin.
摘要翻译：描述了一种不饱和聚酯树脂组合物，其包含可与聚酯中的不饱和键反应的胺封端的柔性聚合物。兼容的系统具有较高的断裂韧性。优选的胺封端的柔性聚合物是胺封端的聚（丁二烯 - 共 - 丙烯腈）。树脂组合物可以用填料延长并用纤维增强。在这些应用中，树脂被称为基质树脂。

17. 发明授权

US5021258A Method of coating fibers with metal or ceramic material 失效
标题翻译：用金属或陶瓷材料涂覆纤维的方法
公开(公告)号：US5021258A
公开(公告)日：1991-06-04
申请号：US564485
申请日：1990-08-08
申请人： Frederick J. McGarry
发明人： Frederick J. McGarry
IPC分类号： C23C14/20 , D06M11/45 , D06M11/46 , D06M11/74 , D06M11/77 , D06M11/80 , D06M11/83
CPC分类号： D06M11/46 , C23C14/20 , D06M11/45 , D06M11/74 , D06M11/77 , D06M11/80 , D06M11/83 , D06M2101/36
摘要： Ordered polymer fibers, such as aramid or polybenzazole, can be coated with a ceramic coating by physical vapor deposition to yield a coated fiber having improved properties.
摘要翻译：有序的聚合物纤维，例如芳族聚酰胺或聚吲哚，可通过物理气相沉积涂覆陶瓷涂层，得到具有改进性能的涂层纤维。

18. 发明授权

US4478963A Filler particles coated with reactive liquid polymers in a matrix resin 失效
标题翻译：在基体树脂中涂覆反应性液体聚合物的填料颗粒
公开(公告)号：US4478963A
公开(公告)日：1984-10-23
申请号：US499618
申请日：1983-05-31
申请人： Frederick J. McGarry
发明人： Frederick J. McGarry
IPC分类号： C08K9/08 , C08L67/06
CPC分类号： C08K9/08
摘要： A composite comprising filler particles having a thin film of a reactive liquid polymer embedded in a polymeric matrix made by the method which includes the steps of mixing said reactive liquid polymer and said filler in order to provide a thin film of said reactive liquid polymer on said filler particles, mixing said coated filler particles with a polymeric matrix, and forming said composite.
摘要翻译：一种复合材料，其包含填充剂颗粒，该填料颗粒具有通过该方法制成的聚合物基体中的反应性液体聚合物薄膜，该方法包括以下步骤：混合所述反应性液体聚合物和所述填料，以便在所述反应性液体聚合物上形成薄膜填充剂颗粒，将所述涂覆的填料颗粒与聚合物基质混合，并形成所述复合材料。

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