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11. 发明申请

US20100076396A1 HYDROGENATED NORBORNENE-BASED RING-OPENING POLYMERIZATION POLYMER, RESIN COMPOSITION, AND MOLDED OBJECT 审中-公开
标题翻译：基于NORBORNENE的开环聚合聚合物，树脂组合物和模塑对象
公开(公告)号：US20100076396A1
公开(公告)日：2010-03-25
申请号：US12439360
申请日：2007-08-31
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： A61J1/10 , C08F132/08 , C08L55/00 , B32B27/08 , B32B1/00
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening polymerization of 2-norbornene is disclosed. The hydrogenated norbornene ring-open polymer has a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution (Mw/Mn) of 1.5 to 10.0, and a melting point of 110 to 145° C. Also disclosed is a hydrogenated norbornene ring-open polymer (hydrogenated polymer) obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. The hydrogenated ring-open polymer has a melting point of 110 to 145° C. A resin composition and a molding material containing these hydrogenated polymers, a molded article, a resin film, a resin sheet, a multilayer laminate, a packing material, a molded article for medical supplies, a blister molding sheet, a blister molded article, and a multilayer blow-molded container made of these hydrogenated polymers are also disclosed.
摘要翻译：公开了通过2-取代降冰片烯的开环聚合获得的开环聚合物的80％以上的主链碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为50,000〜200,000，分子量分布（Mw / Mn）为1.5〜10.0，熔点为110〜 145℃。还公开了通过将通过2-降冰片烯的开环共聚获得的开环聚合物的80％以上的碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物（氢化聚合物）和含有取代基的降冰片烯单体，其中，来自2-降冰片烯的重复单元（A）相对于所有重复单元的比例为90〜99重量％，衍生自取代基的降冰片烯的重复单元（B）含有降冰片烯单体相对于所有重复单元为1〜10重量％。氢化开环聚合物的熔点为110〜145℃。树脂组合物和含有这些氢化聚合物的成型材料，模塑制品，树脂膜，树脂片，多层压板，包装材料，还公开了用于医疗用品的模制品，泡罩成型片，泡罩模制品和由这些氢化聚合物制成的多层吹塑容器。

12. 发明授权

US5681900A Hydrogenated norbornene ring-opening polymerization product, a process for production thereof and uses thereof 失效
标题翻译：氢化降冰片烯开环聚合产物，其制备方法和用途
公开(公告)号：US5681900A
公开(公告)日：1997-10-28
申请号：US537866
申请日：1996-01-22
申请人： Toshihide Murakami , Teiji Kohara , Tadao Natsuume
发明人： Toshihide Murakami , Teiji Kohara , Tadao Natsuume
IPC分类号： C08G61/06 , C08G61/08 , G02B1/04 , H01B3/30 , C08F32/08
CPC分类号： C08G61/08
摘要： A resin obtained by subjecting a norbornene type monomer having an aromatic ring structure (e.g. 5-phenyl-2-norbornene) to ring-opening polymerization and hydrogenating 95% or more of the unsaturated bonds in the backbone structure of the resulting polymer by the use of a catalyst composed of a combination of a transition metal compound and an alkyl metal compound, while leaving 80% or more of the aromatic ring structures, which resin has not only a high refractive index but also characteristics of a hydrogenated norbornene ring-opening polymerization product, i.e., excellent heat resistance, transparency, low birefringent properties, weather resistance, light resistance, low water absorption properties, moisture resistance, small dielectric constant, small dielectric loss, chemical resistance, etc., said resin being usable in optical materials, medical tools and materials, tools and materials for treating electronic parts, etc.
摘要翻译： PCT No.PCT / JP94 / 01244 Sec。 371日期1996年1月22日 102（e）日期1996年1月22日PCT提交1994年7月28日PCT公布。出版物WO95 / 04096 日期1995年2月9日通过使具有芳环结构的降冰片烯型单体（例如5-苯基-2-降冰片烯）进行开环聚合，并在其主链结构中氢化95％以上的不饱和键而得到的树脂通过使用由过渡金属化合物和烷基金属化合物的组合组成的催化剂，同时留下80％或更多的芳族环结构，该树脂不仅具有高折射率，而且具有氢化特性降冰片烯开环聚合产物，即优异的耐热性，透明性，低双折射性，耐候性，耐光性，低吸水性，耐湿性，介电常数小，介电损耗小，耐化学腐蚀等特性。可用于光学材料，医疗工具和材料，用于处理电子部件的工具和材料等。

13. 发明授权

US5580934A Ring-opening hydrogenated copolymer and process for producing the same 失效
标题翻译：开环氢化共聚物及其制备方法
公开(公告)号：US5580934A
公开(公告)日：1996-12-03
申请号：US476489
申请日：1990-06-07
申请人： Yoshikatsu Nishi , Masayoshi Oshima , Teiji Kohara , Tadao Natsuume
发明人： Yoshikatsu Nishi , Masayoshi Oshima , Teiji Kohara , Tadao Natsuume
IPC分类号： C08G61/08 , C08F232/08 , C08F8/04
CPC分类号： C08G61/08
摘要： There are disclosed a polycyclic norbornene or its derivative hydrogenated copolymer which containsa repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof (A),a repeating unit represented by the following formula [II] or the alkyl-substituted derivative thereof (B) and, as desired,5-85% by mole of at least one repeating unit (C) selected from a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [IV], the alkyl-substituted derivative and the alkylidene-substituted derivative thereof, and a process for producing the polycyclic norbornene or its derivative ring-opening hydrogenated copolymer ##STR1## wherein ------ represents either a single bond or a double bond.
摘要翻译： PCT No.PCT / JP88 / 01331 Sec。 371日期1990年6月7日 102（e）日期1990年6月7日PCT提交1988年12月26日PCT公布。出版物WO89 / 06254 日期：1989年7月13日公开了含有下述式[I]表示的重复单元或其烷基取代衍生物（A）的多环降冰片烯或其衍生物氢化共聚物，由下式[II ]或其烷基取代的衍生物（B），根据需要，5-85摩尔％至少一种选自下式[III]表示的重复单元的重复单元（C），烷基取代的衍生物由下式[Ⅳ]表示的重复单元，烷基取代的衍生物和亚烷基取代的衍生物，以及制备多环降冰片烯或其衍生物开环氢化共聚物的方法， [II] [III] [IV]其中+ E，uns --- + EE表示单键或双键。

14. 发明授权

US6066380A Disc medium substrate and disc device 有权
标题翻译：盘式介质基板和光盘装置
公开(公告)号：US6066380A
公开(公告)日：2000-05-23
申请号：US51938
申请日：1998-10-13
申请人： Eiki Oyanagi , Takeshi Sasa , Yasuyuki Imai , Hiroshi Takino , Teiji Kohara , Masayoshi Oshima
发明人： Eiki Oyanagi , Takeshi Sasa , Yasuyuki Imai , Hiroshi Takino , Teiji Kohara , Masayoshi Oshima
IPC分类号： B29C70/64 , C08F32/04 , G11B5/596 , G11B5/60 , G11B5/73 , G11B5/82 , G11B5/84 , G11B21/21 , G11B23/00 , B32B3/00
CPC分类号： G11B23/0021 , B29C70/64 , C08F32/04 , G11B5/7315 , G11B5/82 , G11B5/8404 , G11B21/21 , G11B5/59633 , G11B5/6011 , Y10S428/913 , Y10T428/21
摘要： A molded thermoplastic resin disc substrate specially adapted for use with floating head type recording/reproduction apparatus is provided. The molded disc substrate has surface smoothness characteristics which are the same or better than are provided with mirror polished aluminum discs. The molded disc substrates include a floating head scanning surface wherein the maximum projection height or maximum surface irregularity is less than about 50 nm to reduce or eliminate damage to either the disc or floating head caused by unwanted collisions between them. In a preferred embodiment, the molded disc substrates are molded from a thermoplastic resin composition containing 10000 particles/gram or less of particles having a particle diameter of 0.5 .mu.m or more. In a preferred embodiment, control of particle size and content is achieved by subjecting the resin molding composition to a sequence of filtering steps using filters of decreasing mesh size.
摘要翻译： PCT No.PCT / JP97 / 02927 Sec。 371日期：1998年10月13日 102（e）日期1998年10月13日PCT 1997年8月22日PCT公布。第WO98 / 08217号公报日期1998年2月26日提供特别适用于浮头型记录/再现装置的模制热塑性树脂盘基片。模制的盘基片具有与设置有镜面抛光的铝盘相同或更好的表面平滑度特性。模制的盘基底包括浮动头扫描表面，其中最大突出高度或最大表面不规则小于约50nm，以减少或消除由它们之间的不必要的碰撞引起的盘或浮动头的损坏。在优选的实施方式中，由含有10000粒子/克以上的粒径为0.5μm以上的粒子的热塑性树脂组合物成型成型的盘基片。在优选的实施方案中，通过使用减小网眼尺寸的滤膜对树脂模塑组合物进行一系列过滤步骤来实现颗粒尺寸和含量的控制。

15. 发明授权

US5885505A Method for producing electronic part sealed body 失效
标题翻译：电子部件密封体的制造方法
公开(公告)号：US5885505A
公开(公告)日：1999-03-23
申请号：US916781
申请日：1997-08-25
申请人： Yuji Koushima , Teiji Kohara , Tadao Natsuume
发明人： Yuji Koushima , Teiji Kohara , Tadao Natsuume
IPC分类号： B29C33/40 , B29C35/02 , B29C41/20 , B29C45/02 , B29C45/14 , B29C45/26 , B29C70/70 , B29L31/34 , C08G61/00 , H01C17/02 , H01G13/00 , H01L21/56
CPC分类号： H01L21/565 , B29C33/40 , H01C17/02 , H01G13/003 , H01L2924/0002
摘要： A molding frame made by molding a thermoplastic norbornene resin which hardly deforms even after repeated use is used for production of electronic part sealed bodies by sealing the electronic devices of integrated circuits such as light emitting diodes, diodes, transistors, LSI devices, IC devices and CCD devices and capacitors, resistors, coils, microswitches and dipswitches with thermosetting resins such as epoxy resins as sealants.
摘要翻译：通过模制热塑性降冰片烯树脂制成的模制框架，即使在重复使用后几乎不变形的情况下也被用于通过密封诸如发光二极管，二极管，晶体管，LSI器件，IC器件等集成电路的电子器件的电子部件密封体的制造 CCD器件和电容器，电阻器，线圈，微动开关和具有热固性树脂的开关，例如作为密封剂的环氧树脂。

16. 发明授权

US5686156A Press-through package 失效
标题翻译：直通包装
公开(公告)号：US5686156A
公开(公告)日：1997-11-11
申请号：US464630
申请日：1995-06-26
申请人： Toshiyasu Matsui , Tsutomu Hani , Teiji Kohara , Tadao Natsuume
发明人： Toshiyasu Matsui , Tsutomu Hani , Teiji Kohara , Tadao Natsuume
IPC分类号： B32B15/08 , B65B9/04 , B65D75/32 , B65D75/34 , B65D83/04
CPC分类号： B65D75/32 , B65D75/326 , B65D75/327 , Y10T428/1352 , Y10T428/1379
摘要： A press-through package obtained by placing objects to be packed, in the accommodating pockets formed by vacuum forming or the like of a sheet made of a thermoplastic norbornene type resin, particularly preferably a hydrogenated product of ring-opening polymerization product of a dicyclopentadiene type monomer, and then closing the openings of pockets of the sheet with another sheet such as metal foil to pack the objects to be packed, which package makes the packed objects clearly visible in the pocket portions, prevents the deterioration of the packed objects by moisture bacause of its excellent water vapor barrier properties, and is good in production efficiency.
摘要翻译： PCT No.PCT / JP94 / 00122 Sec。 371日期：1995年6月26日 102（e）日期1995年6月26日PCT 1994年1月28日PCT PCT。 WO94 / 16965 PCT公开号日期1995年8月4日通过将待包装物体放置在由热塑性降冰片烯类树脂制成的片材的真空成型等形成的容纳袋中，特别优选开环聚合的氢化产物二环戊二烯型单体的产物，然后用诸如金属箔的另一片材封闭片材的袋口的开口以包装要包装的物品，该包装使得包装物体在袋部分中清晰可见防止了水分阻滞性优良，生产效率好。

17. 发明授权

US5585989A Magnetic disc substrate and a magnetic disc using the same 失效
标题翻译：磁盘基板和使用其的磁盘
公开(公告)号：US5585989A
公开(公告)日：1996-12-17
申请号：US347086
申请日：1994-11-23
申请人： Miyuki Kuromiya , Hiroshi Takino , Masayoshi Oshima , Teiji Kohara
发明人： Miyuki Kuromiya , Hiroshi Takino , Masayoshi Oshima , Teiji Kohara
IPC分类号： G11B5/596 , G11B5/73 , G11B5/733 , G11B5/82
CPC分类号： G11B5/82 , G11B5/7315 , G11B5/733 , G11B5/59633
摘要： Using a thermoplastic norbornene type plastic as a material for the magnetic disc substrate, a magnetic disc substrate having a small deformation and a high modulus of elasticity is prepared. By optimizing the thickness of the substrate, the resonance frequency of the magnetic disc can be elevated to a level higher than the servo band. As a result, a magnetic disc substrate can form a servo mark having a high positional precision, and can carry out tracking with high precision.
摘要翻译：使用热塑性降冰片烯型塑料作为磁盘基板的材料，制备具有小变形和高弹性模量的磁盘基片。通过优化衬底的厚度，磁盘的谐振频率可以提高到高于伺服带的水平。结果，磁盘基板可以形成具有高定位精度的伺服标记，并且可以高精度地执行跟踪。

18. 发明授权

US5334424A Thermoplastic norbornene resin formed articles and sustrates for liquid crystal display 失效
标题翻译：用于液晶显示的热塑性降冰片烯树脂制成物和底物
公开(公告)号：US5334424A
公开(公告)日：1994-08-02
申请号：US950152
申请日：1992-09-24
申请人： Tsutomu Hani , Nobukazu Takahashi , Teiji Kohara , Tadao Natsuume
发明人： Tsutomu Hani , Nobukazu Takahashi , Teiji Kohara , Tadao Natsuume
IPC分类号： G02F1/1333 , C09K19/00
CPC分类号： G02F1/133305 , Y10T428/1086 , Y10T428/24355 , Y10T428/31855
摘要： A thermoplastic norbornene based molded article which can be used as a substrate for liquid crystal display having an excellent performance; said substrate having a specified surface roughness of 0.05 .mu.m or less, and a liquid crystal display produced therefrom.
摘要翻译：可用作液晶显示器用基板的热塑性降冰片烯系成形体，性能优异; 所述基板具有0.05μm以下的特定表面粗糙度，以及由其制造的液晶显示器。

19. 发明授权

US5061771A Ring-opened polymer from norbornene type of polycyclic monomer and process for producing the polymer 失效
标题翻译：来自降冰片烯类型的多环单体的开环聚合物和用于制备聚合物的方法
公开(公告)号：US5061771A
公开(公告)日：1991-10-29
申请号：US433106
申请日：1989-11-08
申请人： Masayoshi Oshima , Teiji Kohara , Tohru Hosaka , Tadao Natsuume
发明人： Masayoshi Oshima , Teiji Kohara , Tohru Hosaka , Tadao Natsuume
IPC分类号： C08F36/22 , C08F4/60 , C08F4/64 , C08F4/649 , C08F36/00 , C08F36/20 , C08G61/06 , C08G61/08
CPC分类号： C08G61/08
摘要： (1) A solvent-soluble ring-opened polymer constituted of 100-50% by weight of a norbornene derivative of monomer (A) represented by the formula ##STR1## wherein, R.sub.1 and R.sub.2 are the same or different and each denote hydrogen or alkyl and m denotes an interger of 0 to 2, and 0-50% by weight of another norbornene derivative of monomer (B) capable of undergoing ring-opening copolymerization with the preceding monomer (A), the polymer having a number average molecular weight of 10,000 to 50,000, a weight average molecular weight-to-number average molecular weight ratio (Mw/Mn) of up to 3, and a glass transition temperature of at least 80.degree. C., and(2) a process for producing such ring-opened polymers as stated above.
摘要翻译：（1）由式（I）表示的单体（A）的降冰片烯衍生物100-50重量％构成的溶剂可开环聚合物，其中，R1和R2相同或不同，各自相同或不同，表示氢或烷基，m表示0至2的整数，和0-50重量％的能够与前述单体（A）进行开环共聚的单体（B）的另一降冰片烯衍生物，所述聚合物具有数平均分子量为10,000〜50,000，重均分子量平均分子量比（Mw / Mn）为3，玻璃化转变温度为80℃以上，（2）用于制备如上所述的这种开环聚合物。

20. 发明授权

US08481166B2 Hydrogenated norbornene-based ring-opening polymerization polymer, resin composition, and molded object 有权
标题翻译：氢化降冰片烯类开环聚合物，树脂组合物和成型体
公开(公告)号：US08481166B2
公开(公告)日：2013-07-09
申请号：US13336522
申请日：2011-12-23
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： B32B27/32 , C08F32/08
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要翻译：通过2-取代的降冰片烯的开环聚合得到的开环聚合物的80％以上的主链碳 - 碳双键进行氢化而得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物的重均分子量通过凝胶渗透色谱法（GPC）测定为50,000〜200,000，分子量分布为1.5〜10.0，熔点为110〜145℃。氢化降冰片烯环通过将通过2-降冰片烯与含取代基的降冰片烯单体的开环共聚而得到的开环聚合物的碳 - 碳双键的80％以上氢化得到的开环聚合物，其中，重复单元（A）衍生自所有重复单元的2-降冰片烯的比例为90〜99重量％，相对于所有重复单元衍生自含取代基的降冰片烯单体的重复单元（B）的比例为1〜10重量％。树脂组合物和成型材料。

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