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11. 发明授权

US5521011A Thermosetting compositions, thermal latent acid catalysts, methods of coating and coated articles 失效
标题翻译：热固性组合物，热潜伏酸催化剂，涂覆方法和涂层制品
公开(公告)号：US5521011A
公开(公告)日：1996-05-28
申请号：US444160
申请日：1995-05-18
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： An article coated by a method of coating which comprises coating a substrate with a top coating material comprising at least one pigment and a thermosetting composition, the at least one pigment being in an amount of 0 to 100 weight parts based on 100 weight parts of the thermosetting composition, the thermosetting composition comprising (A) a compound having in the molecule two or more functional groups of the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each selected from the group consisting of a hydrogen atom and an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the hetero atom; (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the functional groups of the compound (A) by heating, the reactive functional groups of the compound (B) are epoxy groups; and (F) a complex compound formed by coordination of a conjugated base of a Bronsted acid or a Bronsted salt to a vacant orbital of a Lewis acid in a mol ratio of the Bronsted acid or Bronsted salt to the vacant orbital of the Lewis acid of 0.1 to 4.
摘要翻译：一种通过涂覆方法涂覆的制品，其包括用包含至少一种颜料和热固性组合物的顶部涂料涂覆基材，所述至少一种颜料的量为0至100重量份，基于100重量份的所述热固性组合物包含（A）分子中具有式（I）的两个或多个官能团的化合物：其中R 1，R 2和R 3各自选自氢原子和1至18个碳原子的有机基团，R 4是1至18个碳原子的有机基团，Y 1是氧或硫，或者R 3和R 4彼此键合，形成杂环结构，其包含Y1作为杂原子原子; （B）化合物在分子中具有两个或更多个可通过加热与化合物（A）的官能团形成化学键的反应性官能团，化合物（B）的反应性官能团是环氧基; 和（F）通过将布朗斯台德酸或布朗斯台德盐的共轭碱与布朗斯台德酸或布朗斯特盐的摩尔比与路易斯酸的空位轨道配位的络合物与路易斯酸的空位轨道 0.1至4。

12. 发明授权

US4963601A Polymer non-aqueous dispersion, process for preparing the same and coating composition formulated therewith 失效
标题翻译：聚合物非水分散体，其制备方法和用其配制的涂料组合物
公开(公告)号：US4963601A
公开(公告)日：1990-10-16
申请号：US384098
申请日：1989-07-24
申请人： Kishio Shibato , Fumio Sakurai , Atsuhiro Sakai , Toru Imai , Osamu Ohe
发明人： Kishio Shibato , Fumio Sakurai , Atsuhiro Sakai , Toru Imai , Osamu Ohe
IPC分类号： C08F2/22 , C08F2/24 , C08F6/00 , C08F6/14 , C08F8/44 , C08F291/00 , C08J3/09 , C08L61/20 , C09D5/00 , C09D5/38 , C09D7/12 , C09D133/06 , C09D167/00 , C09D201/06
CPC分类号： C09D133/066 , C08F291/00 , C08F8/44 , C08J3/09 , C09D167/00 , C08L2205/18 , C08L61/20 , Y10S524/901
摘要： A process for preparing polymer non-aqueous dispersions to be formulated together with a binder component in coating compositions, which comprises the steps of: (1) emulsion polymerizing a hydroxy group containing .alpha.,.beta.-ethylenically unsaturated monomer, a polyfunctional .alpha.,.beta.-ethylenically unsaturated monomer and an .alpha.,.beta.-ethylenically unsaturated monomer different therefrom by using a water-soluble polymerization initiator, preferably a persulphate, in a soap free system or in the presence of an ester group containing anionic or cationic surfactant; adding an organic solvent, preferably comprising an amphipathic organic solvent, to a resultant polymer aqueous dispersion; and then adding a basic compound catalyst when anionic surfactant is used or an acidic compound catalyst when the cationic surfactant is used, to thereby hydrolyze completely said surfactant and water-soluble polymerization initiator at a temperature not exceeding 95.degree. C. as in the condition of suspension; (2) adding an acidic or basic compound to said suspension to neutralize said basic or acidic compound catalyst: then after adding dispersion stabilizing resin, further adding an amine salt of organic acid, followed by leaving said suspension to stand to separate into organic and water layers; and isolating the organic layer from the water layer; and (3) removing residual water in the organic layer. The resultant polymer non-aqueous dispersion comprises polymer particles having a total ionic group concentration (I) less than 2.times.10.sup.-5 mol/g particle, a hexane tolerance (HT) from 5 to 40 exclusive and a degree of swelling in acetone (S) less than 10, and used with a binder component comprising a polyol resin and a curing agent for preparing coating compositions.

13. 发明授权

US5549932A Thermosetting compositions, methods of coating and coated articles 失效
标题翻译：热固组合物，涂层方法和涂层制品
公开(公告)号：US5549932A
公开(公告)日：1996-08-27
申请号：US401198
申请日：1995-03-09
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
摘要翻译：热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基的化合物，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或更多个可通过加热与封端的羧基化合物形成化学键的反应性官能团，特定的乙烯基醚或乙烯基硫醚和热潜在酸催化剂。第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。热固性组合物提供具有优异的化学性质，物理性质，耐候性和储存稳定性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料。

14. 发明授权

US5093390A Polymer non-aqueous dispension, process for preparing the same and coating composition formulated therewith 失效
标题翻译：聚合物非水性配方，其制备方法和配方的涂料组合物
公开(公告)号：US5093390A
公开(公告)日：1992-03-03
申请号：US535501
申请日：1990-06-11
申请人： Kishio Shibato , Fumio Sakurai , Atsuhiro Sakai , Toru Imai , Osamu Ohe
发明人： Kishio Shibato , Fumio Sakurai , Atsuhiro Sakai , Toru Imai , Osamu Ohe
IPC分类号： C08F2/22 , C08F2/24 , C08F6/00 , C08F6/14 , C08F8/44 , C08F291/00 , C08J3/09 , C08L61/20 , C09D5/00 , C09D5/38 , C09D7/12 , C09D133/06 , C09D167/00 , C09D201/06
CPC分类号： C09D133/066 , C08F291/00 , C08F8/44 , C08J3/09 , C09D167/00 , C08L2205/18 , C08L61/20 , Y10S524/901
摘要： A process for preparing polymer non-aqueous dispersions to be formulated together with a binder component in coating compositions, which comprises the steps of: (1) emulsion polymerizing a hydroxy group containing .alpha.,.beta.-ethylenically unsaturated monomer, a polyfunctional .alpha.,.beta.-ethylenically unsaturated monomer and an .alpha.,.beta.-ethylenically unsaturated monomer different therefrom by using a water-soluble polymerization initiator, preferably a persulphate, in a soap free system or in the presence of an ester group containing anionic or cationic surfactant; adding an organic solvent, preferably comprising an amphipathic organic solvent, to a resultant polymer aqueous dispersion; and then adding a basic compound catalyst when the anionic surfactant is used or an acidic compound catalyst when the cationic surfactant is used, to thereby hydrolyze completely said surfactant and water-soluble polymerization initiator at a temperature not exceeding 95.degree. C. as in the condition of suspension; (2) adding an acidic or basic compound to said suspension to neutralize said basic or acidic compound catalyst: then after adding dispersion stabilizing resin, further adding an amine salt of organic acid, followed by leaving said suspension to stand to separate into organic and water layers; and isolating the organic layer from the water layer; and (3) removing residual water in the organic layer. The resultant polymer nonaqueous dispersion comprises polymer particles having a total ionic group concentration (I) less than 2.times.10.sup.-5 mol/g particle, a hexane tolerance (HT) from 5 to 40 exclusive and a degree of swelling in acetone (S) less than 10, and used with a binder component comprising a polyol resin and a curing agent for preparing coating compositions.

15. 发明授权

US5091492A Resin composition for use as paint 失效
标题翻译：用作涂料的树脂组合物
公开(公告)号：US5091492A
公开(公告)日：1992-02-25
申请号：US564024
申请日：1990-08-07
申请人： Masahiro Ishidoya , Kishio Shibato , Osamu Ohe , Masaaki Kawasaki
发明人： Masahiro Ishidoya , Kishio Shibato , Osamu Ohe , Masaaki Kawasaki
IPC分类号： C09D133/06 , C08F220/18 , C09D4/00 , C09D133/04
CPC分类号： C08F220/18 , C09D4/00
摘要： A resin composition for use as a paint contains a copolymer prepared by copolymerizing a monomer (I) represented by the following formula (I): ##STR1## wherein either one of X.sub.1 and X.sub.2 stands for an acryloyloxy or methacryloyloxy group, the other being a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R.sub.1 to R.sub.10 each stand for a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and n is an integer of 1 to 4; with an .alpha.,.beta.-ethylenically unsaturated monomer having a reactive functional group and an .alpha.,.beta.-ethylenically unsaturated monomer having no reactive functional group. A monomer mixture for preparing the copolymer contains 5 to 95 wt % of the monomer (I).

16. 发明授权

US4879337A Polyol resin coating composition containing non-aqueous polymer dispersion and aliphatic sulfonic acid compound 失效
标题翻译：含有非水性聚合物分散体和脂族磺酸化合物的多元醇树脂涂料组合物
公开(公告)号：US4879337A
公开(公告)日：1989-11-07
申请号：US115868
申请日：1987-11-02
申请人： Kishio Shibato , Masataka Kawamura
发明人： Kishio Shibato , Masataka Kawamura
IPC分类号： B01F17/52 , C09D161/20 , C09D201/06
CPC分类号： C09D201/06
摘要： A higher solid coating composition comprises a solid resin mixture of polyol resin and alkyletherified melamine resin, 0.2.about.10 parts by weight of an aliphatic sulfonic acid compound and 1.about.100 parts by weight of a non-aqueous polymer dispersion based on 100 parts by weight of the resin mixture. The non-aqueous polymer dispersion consists of (a) organic solvent component, (b) particle component insoluble in the component (a), and (c) particular dispersion stabilizer component soluble in the component (a) and capable of stably dispersing the component (b) into the component (a).
摘要翻译：更高的固体涂料组合物包含多元醇树脂和烷基醚化三聚氰胺树脂的固体树脂混合物，0.2重量份脂族磺酸化合物和1重量份100重量份基于100重量份的非水性聚合物分散体的树脂混合物。非水性聚合物分散体由（a）有机溶剂组分，（b）不溶于组分（a）的颗粒组分和（c）可溶于组分（a）的特定分散稳定剂组分组成，并且能够稳定地分散组分（b）进入组分（a）。

17. 发明授权

US5821315A Thermoset covering compositions 失效
标题翻译：热固性涂层组合物
公开(公告)号：US5821315A
公开(公告)日：1998-10-13
申请号：US682521
申请日：1996-07-24
申请人： Joichi Moriya , Fumi Maruyama , Kishio Shibato , Peter Betz
发明人： Joichi Moriya , Fumi Maruyama , Kishio Shibato , Peter Betz
IPC分类号： C08F290/06 , C08F290/00 , C08G18/62 , C08G18/80 , C09D161/20 , C09D161/32 , C09D175/04
CPC分类号： C08G18/8093 , C08G18/6233 , C09D175/04
摘要： Provided are compositions useful as paints which have excellent acid resistance and scratching resistance, and provide a good appearance. The thermoset compositions are comprised of a vinyl copolymer (A) comprised of lactone modified acrylic monomer and other monomer, a blocked polyisocyanate compound (B) which has been reacted with a mixture of malonic acid and acetoacetic acid, and an alkyl etherified amino resin (C).
摘要翻译： PCT No.PCT / EP95 / 00172 Sec。 371日期：1996年7月24日 102（e）日期1996年7月24日PCT提交1995年1月18日PCT公布。 WO95 / 20003 PCT出版物日期1995年7月27日提供了可用作具有优异的耐酸性和耐划伤性并且提供良好外观的油漆的组合物。热固性组合物由内酯改性丙烯酸单体和其它单体组成的乙烯基共聚物（A），与丙二酸和乙酰乙酸的混合物反应的封端多异氰酸酯化合物（B）和烷基醚化氨基树脂（ C）。

18. 发明授权

US5710201A Paint composition 失效
标题翻译：油漆组成
公开(公告)号：US5710201A
公开(公告)日：1998-01-20
申请号：US379553
申请日：1995-03-08
申请人： Takeshi Hayakawa , Kishio Shibato
发明人： Takeshi Hayakawa , Kishio Shibato
IPC分类号： C09D5/00 , C08G18/40 , C08G18/61 , C09D143/04 , C09D183/04 , C09D183/10 , C08G18/62
CPC分类号： C09D143/04 , C08G18/4063 , C08G18/61
摘要： Paint compositions containing (A) a vinyl type copolymer obtained by polymerizing (i) specific silicone type vinyl monomers 1-50% by weight, (ii) vinyl monomers containing hydroxyl groups 5-60% by weight, and (iii) other vinyl monomers 5-80% by weight, (B) specific hydroxyl-group-containing silicone type compounds, and (C) a hardening agent that allows reaction with hydroxyl groups. Paint films can be formed which have excellent water-repellence and oil-repellence, and in which there is no lowering of water-repellence or oil-repellence when they are exposed for long periods in natural environments.
摘要翻译： PCT No.PCT / EP93 / 02065 Sec。 371日期：1995年3月8日 102（e）1995年3月8日PCT PCT 1993年8月3日PCT公布。第WO94 / 03547号公报日期：1994年2月17日含有（A）通过聚合（ⅰ）1-50重量％的特定硅酮型乙烯基单体得到的（A）乙烯基类共聚物的组合物，（ⅱ）含有5-60重量％羟基的乙烯基单体和（ iii）5-80重量％的其它乙烯基单体，（B）特定的含羟基的有机硅类化合物，和（C）能够与羟基反应的固化剂。可以形成具有优异的拒水性和拒油性的油漆膜，并且当在自然环境中长时间暴露时，不会降低拒水性或拒油性。

19. 发明授权

US5578677A Thermosetting compositions 失效
标题翻译：热固性组合物
公开(公告)号：US5578677A
公开(公告)日：1996-11-26
申请号：US578083
申请日：1995-12-27
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： C08F299/02 , C07C69/00 , C08F8/14 , C08F290/00 , C08G18/42 , C08G18/82 , C08G59/00 , C08G59/20 , C08G59/32 , C08G59/40 , C08G59/68 , C08G63/00 , C08G63/91 , C08G69/00 , C08L33/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L67/06 , C09D163/00 , C09D167/00 , C09D167/06 , C09J167/00 , C09J167/06
CPC分类号： C09D167/00 , C08L67/00 , C09D163/00 , C09J167/00
摘要： A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the heteroatom component; and/or, (B) optionally, a compound having in the molecule two or more reactive functional groups which can form a chemical bond by heating with either one or both of the functional group of the formula (1) and the functional group of the formula (2).
摘要翻译：一种热固性组合物，其包含：（D）在分子（a）中具有一个或多个式（2）的官能团的自交联化合物：其中R5，R6和R7各自为氢或碳原子数为1〜18的有机基团，R 8为碳原子数为1〜18的有机基团，Y2为氧或硫，或者R 7和R 8相互结合形成杂环结构，该杂环结构包含Y2作为杂原子成分。和（b）可以与（a）通过加热再生的羧基官能团形成化学键的一个或多个反应性官能团; （C）任选地，通过加热在组合物固化期间活化的热潜伏酸催化剂; （A）任选地，在分子中具有式（1）的两个或更多个官能团的化合物：其中R 1，R 2和R 3各自为氢或碳原子数为1至18的有机基团，R 4为 1到18个碳的有机基团，Y1是氧或硫，或者R3和R4彼此键合，形成包含Y1作为杂原子成分的杂环结构; 和/或（B）任选地，在分子中具有两个或更多个反应性官能团的化合物，所述反应性官能团可以通过用式（1）的官能团中的一个或两个加成而形成化学键，公式（2）。

20. 发明授权

US5523164A Method for forming a paint film and coating obtained by the method 失效
标题翻译：通过该方法获得的形成漆膜和涂层的方法
公开(公告)号：US5523164A
公开(公告)日：1996-06-04
申请号：US424416
申请日：1995-06-23
申请人： Kishio Shibato , Masataka Kawamura , Atsushi Sato , Shigekazu Sato
发明人： Kishio Shibato , Masataka Kawamura , Atsushi Sato , Shigekazu Sato
IPC分类号： B05D1/36 , B05D5/00 , B05D7/00 , B05D7/14 , B05D7/24 , C08G18/62 , C08L1/00 , C08L33/06 , C08L33/14 , C08L61/28 , C09D133/04 , C09D133/06 , C09D133/14 , C09D161/28
CPC分类号： B05D7/532 , C08G18/6229 , C08G18/6233 , C09D133/06 , C09D133/14 , C09D161/28 , C08L1/00 , C08L33/06 , C08L33/14 , C08L61/28 , Y10T428/31692 , Y10T428/31699
摘要： Method for forming paint films by the 2-coats/1-bake method, using a clearcoat paint in which the resin component comprises (a) a copolymer of a vinyl monomer mixture containing at least 20 wt % (meth)acrylic acid cycloalkyl esters 40-90 wt %, (b) alkyl-etherified melamine resin 5-50 wt %, and (c) blocked polyisocyanate 5-50 wt %, and a basecoat paint in which the resin component comprises (d) a copolymer of a vinyl monomer mixture containing at least 10% of monomers represented by the general formula ##STR1## (X.sup.1 -X.sup.5 are H or a methyl group, i is 0-2, j is 0 or 1, k is 0-3, m is 0-3, and n is 1-10), 40-80 wt %, (e) alkyl-etherified melamine resin 10-50 wt %, (f) blocked polyisocyanate 0-40 wt %, (g) cellulose type resin 0-20 wt %, and (h) organic crosslinked fine particles 0-30 wt %, and coatings obtained by the said method.
摘要翻译： PCT No.PCT / EP93 / 03035 Sec。 371日期：1995年6月23日 102（e）日期1995年6月23日PCT提交1993年10月30日PCT公布。第WO94 / 09916号公报日本专利日：1994年5月11日。通过2-涂层/ 1烘烤法形成漆膜的方法，使用透明涂料，其中树脂组分包含（a）含有至少20重量％的乙烯基单体混合物的共聚物（甲基）丙烯酸环烷酯40-90重量％，（b）5-50重量％的烷基醚化三聚氰胺树脂和（c）5-50重量％的封端多异氰酸酯，以及其中树脂组分包含（d）含有至少10％由通式（1）表示的单体的乙烯基单体混合物的共聚物（X1-X5是H或甲基，i是0-2，j是0或1 ，k为0-3，m为0-3，n为1-10），40-80重量％，（e）烷基醚化蜜胺树脂10-50重量％，（f）封端多异氰酸酯0-40重量％％，（g）0-20重量％的纤维素类树脂，和（h）0-30重量％的有机交联微粒，以及通过所述方法获得的涂层。

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