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11. 发明授权

US07893153B2 Process for producing modified conjugated diene polymer, modified conjugated diene polymer obtained by the process, and rubber composition containing the same 有权
标题翻译：通过该方法得到的改性共轭二烯系聚合物，改性共轭二烯系聚合物的制造方法以及含有它们的橡胶组合物
公开(公告)号：US07893153B2
公开(公告)日：2011-02-22
申请号：US12089216
申请日：2006-10-04
申请人： Ryouji Tanaka , Kouichirou Tani , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
发明人： Ryouji Tanaka , Kouichirou Tani , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
IPC分类号： C08L83/00 , C08F8/00
CPC分类号： C08C19/44 , C08K3/04 , C08K3/36 , C08L7/00 , C08L15/00 , C08L21/00 , C08L23/16 , C08L2666/08
摘要： A process for producing a modified conjugated diene polymer includes subjecting an active terminal of a conjugated diene polymer having a vinyl content of less than 10% and a cis-1,4 bond content of 75% or more to a modification reaction with an alkoxysilane compound, and subjecting the alkoxysilane compound (residue) to a condensation reaction in an aqueous solution at a pH of 9 to 14 and a temperature of 85 to 180° C. in the presence of a condensation accelerator including a compound containing titanium. The modified conjugated diene polymer exhibits low heat build-up and increased reinforcing properties when used for a rubber composition, and exhibits excellent wear resistance, mechanical characteristics, and processability.
摘要翻译：改性共轭二烯系聚合物的制造方法包括使乙烯基含量小于10％，顺式-1,4-键含量为75％以上的共轭二烯聚合物的活性末端与烷氧基硅烷化合物进行改性反应在包含含钛化合物的缩合促进剂的存在下，在9〜14的pH值和85〜180℃的温度下，在水溶液中使烷氧基硅烷化合物（残基）进行缩合反应。当用于橡胶组合物时，改性共轭二烯聚合物显示出低的发热性和增强的性能，并表现出优异的耐磨性，机械性能和加工性能。

12. 发明申请

US20120142851A1 PROCESS FOR PRODUCING CONJUGATED DIENE POLYMER, CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION 有权
标题翻译：生产聚合二烯聚合物，共混二烯聚合物和橡胶组合物的方法
公开(公告)号：US20120142851A1
公开(公告)日：2012-06-07
申请号：US13371780
申请日：2012-02-13
申请人： Takahiro NAKAMURA , Kouichirou Tani , Ryouji Tanaka , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
发明人： Takahiro NAKAMURA , Kouichirou Tani , Ryouji Tanaka , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
IPC分类号： C08L9/00 , C08F36/04 , C08K3/04 , C08F4/12 , C08K3/36
CPC分类号： C08L9/00 , C08F36/04 , C08K3/013 , C08F4/545
摘要： A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.
摘要翻译：提供了一种以低成本简单且廉价地制备具有窄分子量分布和高顺式键含量的共轭二烯聚合物的方法。该方法包括聚合步骤，其中顺式-1,4-键含量为98.5质量％以上的共轭二烯聚合物和重均分子量（Mw）与数均分子量（Mw）的比（Mw / Mn）通过凝胶渗透色谱法测定的重量（Mn）为2.5以下，通过使用含有含稀土元素化合物的催化剂组合物或含稀土元素化合物的反应产物与共轭二烯化合物的反应，路易斯碱，铝氧烷和/或有机铝化合物，以及含碘化合物。

13. 发明申请

US20100222502A1 PROCESS FOR PRODUCING MODIFIED CONJUGATED DIENE POLYMER, MODIFIED CONJUGATED DIENE POLYMER OBTAINED BY THE PROCESS, AND RUBBER COMPOSITION CONTAINING THE SAME 有权
标题翻译：生产改性共轭二烯聚合物，由该方法获得的改性共轭二烯聚合物的方法和含有该共聚物的橡胶组合物
公开(公告)号：US20100222502A1
公开(公告)日：2010-09-02
申请号：US12089216
申请日：2006-10-04
申请人： Ryouji Tanaka , Kouichirou Tani , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
发明人： Ryouji Tanaka , Kouichirou Tani , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
IPC分类号： C08L83/04 , C08F279/02
CPC分类号： C08C19/44 , C08K3/04 , C08K3/36 , C08L7/00 , C08L15/00 , C08L21/00 , C08L23/16 , C08L2666/08
摘要： A process for producing a modified conjugated diene polymer includes subjecting an active terminal of a conjugated diene polymer having a vinyl content of less than 10% and a cis-1,4 bond content of 75% or more to a modification reaction with an alkoxysilane compound, and subjecting the alkoxysilane compound (residue) to a condensation reaction in an aqueous solution at a pH of 9 to 14 and a temperature of 85 to 180° C. in the presence of a condensation accelerator including a compound containing titanium. The modified conjugated diene polymer exhibits low heat build-up and increased reinforcing properties when used for a rubber composition, and exhibits excellent wear resistance, mechanical characteristics, and processability.
摘要翻译：改性共轭二烯系聚合物的制造方法包括使乙烯基含量小于10％，顺式-1,4-键含量为75％以上的共轭二烯聚合物的活性末端与烷氧基硅烷化合物进行改性反应在包含含钛化合物的缩合促进剂的存在下，在9〜14的pH值和85〜180℃的温度下，在水溶液中使烷氧基硅烷化合物（残基）进行缩合反应。当用于橡胶组合物时，改性共轭二烯聚合物显示出低的发热性和增强的性能，并表现出优异的耐磨性，机械性能和加工性能。

14. 发明申请

US20090247695A1 PROCESS FOR PRODUCING CONJUGATED DIENE POLYMER, CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION 有权
标题翻译：生产聚合二烯聚合物，共混二烯聚合物和橡胶组合物的方法
公开(公告)号：US20090247695A1
公开(公告)日：2009-10-01
申请号：US12096263
申请日：2006-12-05
申请人： Takahiro Nakamura , Kouichirou Tani , Ryouji Tanaka , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
发明人： Takahiro Nakamura , Kouichirou Tani , Ryouji Tanaka , Takuo Sone , Toshihiro Tadaki , Junko Kurazumi , Koji Masaki , Yoichi Ozawa
IPC分类号： C08L9/00 , C08F2/00 , C08F4/12
CPC分类号： C08L9/00 , C08F36/04 , C08K3/013 , C08F4/545
摘要： A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.
摘要翻译：提供了一种以低成本简单且廉价地制备具有窄分子量分布和高顺式键含量的共轭二烯聚合物的方法。该方法包括聚合步骤，其中顺式-1,4-键含量为98.5质量％以上的共轭二烯聚合物和重均分子量（Mw）与数均分子量（Mw）的比（Mw / Mn）通过凝胶渗透色谱法测定的重量（Mn）为2.5以下，通过使用含有含稀土元素化合物的催化剂组合物或含稀土元素化合物的反应产物与共轭二烯化合物的反应，路易斯碱，铝氧烷和/或有机铝化合物，以及含碘化合物。

15. 发明授权

US06838526B1 Modified conjugated diene polymer and method of producing the same and rubber composition 有权
标题翻译：改性共轭二烯聚合物及其制备方法和橡胶组合物
公开(公告)号：US06838526B1
公开(公告)日：2005-01-04
申请号：US09709563
申请日：2000-11-13
申请人： Takuo Sone , Ryouji Tanaka , Kouichirou Tani , Iwakazu Hattori , Hiroshi Akema , Atsushi Nakayama
发明人： Takuo Sone , Ryouji Tanaka , Kouichirou Tani , Iwakazu Hattori , Hiroshi Akema , Atsushi Nakayama
IPC分类号： B60C1/00 , C08C19/00 , C08C19/44 , C08L19/00 , C08F8/34
CPC分类号： C08L19/006 , B60C1/0016 , B60C1/0025 , C08C19/00 , C08C19/44 , C08K3/04 , C08L7/00 , C08L9/00 , C08L9/02 , C08L9/06 , C08L11/00 , C08L23/0815 , C08L23/16 , C08L23/283 , C08L2666/08 , C08L2666/06
摘要： A novel modified conjugated diene polymer is obtained by polymerizing a conjugated diene compound with a specified catalyst consisting of components (a)-(c) and then reacting with at least one specified compound selected from the group consisting of components (d)-(l), and has a content of cis-1,4-bond of not less than 85% and a ratio of weight average molecular weight to number average molecular weight of not more than 4. And also, a rubber composition comprises the modified conjugated diene polymer a rubber ingredient.
摘要翻译：通过将共轭二烯化合物与由组分（a） - （c）组成的特定催化剂聚合，然后与至少一种选自组分（d） - （I））的特定化合物反应获得新的改性共轭二烯聚合物），并且具有不小于85％的顺式-1,4-键含量，重均分子量与数均分子量之比不大于4.另外，橡胶组合物包含改性共轭二烯聚合橡胶成分。

16. 发明授权

US06747085B2 Conjugated diene polymer and rubber composition 有权
标题翻译：共轭二烯聚合物和橡胶组合物
公开(公告)号：US06747085B2
公开(公告)日：2004-06-08
申请号：US10253933
申请日：2002-09-25
申请人： Takuo Sone , Daisuke Yamazaki , Katsutoshi Nonaka , Iwakazu Hattori
发明人： Takuo Sone , Daisuke Yamazaki , Katsutoshi Nonaka , Iwakazu Hattori
IPC分类号： C08K336
CPC分类号： C08L19/006 , C08C19/00 , C08C19/44 , C08K3/36 , C08K5/0091 , C08K5/54 , C08L7/00 , C08L9/00 , C08L2666/08
摘要： A conjugated diene polymer is produced by continuously polymerizing a conjugated diene monomer with a catalyst consisting essentially of specified components (a) to (c) and reacting with at least one of specified components (d) and (e) and has a content of cis-1,4-bond of not less than 85%, a content of 1,2-vinyl bond of not more than 2.0% and a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) of not more than 5, and contains at least one functional group selected from epoxy group and hydroxyl group in its molecule. And also, a rubber composition comprises 10-200 parts by weight of silica based on 100 parts by weight of rubber ingredient consisting of 10-100% by weight of the above conjugated diene polymer and 90-0% by weight of the other diene polymer or natural rubber.
摘要翻译：共轭二烯聚合物通过使共轭二烯单体与基本上由特定组分（a）至（c）组成的催化剂连续聚合并与特定组分（d）和（e）中的至少一种反应并且具有顺式 -1,4-键不小于85％，1,2-乙烯基键含量不大于2.0％，重均分子量（Mw）与数均分子量（Mn）之比不大于并且在其分子中含有至少一个选自环氧基和羟基的官能团。此外，橡胶组合物包含10-200重量份的二氧化硅，基于100重量份的由10-100重量％的上述共轭二烯聚合物组成的橡胶组分和90重量％的其它二烯聚合物或天然橡胶。

17. 发明授权

US06255416B1 Method of producing conjugated diene polymers 有权
标题翻译：共轭二烯聚合物的制备方法
公开(公告)号：US06255416B1
公开(公告)日：2001-07-03
申请号：US09305260
申请日：1999-05-04
申请人： Takuo Sone , Katsutoshi Nonaka , Akio Takashima , Iwakazu Hattori
发明人： Takuo Sone , Katsutoshi Nonaka , Akio Takashima , Iwakazu Hattori
IPC分类号： C08F462
CPC分类号： C08F4/545 , C08F36/04
摘要： A conjugated diene polymer is obtained by using a specified catalyst system consisting of components (a)-(d) and indicating a high polymerization activity to a conjugated diene compound. Further, a modified conjugated diene polymer is obtained by reacting with at least one specified compound selected from the group consisting of components (e)-(j).
摘要翻译：通过使用由组分（a） - （d）组成的特定催化剂体系并且表示对共轭二烯化合物具有高聚合活性的共轭二烯聚合物。此外，通过与至少一种选自组分（e） - （j）的指定化合物反应获得改性共轭二烯聚合物。

18. 发明授权

US07294680B2 Method of producing conjugated diene polymers with narrow molecular weight distribution and polymer produced 有权
标题翻译：生产具有窄分子量分布的共轭二烯聚合物和聚合物的方法
公开(公告)号：US07294680B2
公开(公告)日：2007-11-13
申请号：US10759299
申请日：2004-01-20
申请人： Takuo Sone , Katsutoshi Nonaka , Iwakazu Hattori , Akio Takashima
发明人： Takuo Sone , Katsutoshi Nonaka , Iwakazu Hattori , Akio Takashima
IPC分类号： C08F4/52 , C08F8/42 , C08F136/02 , C08F236/02
CPC分类号： C08C19/00 , C08F36/04 , C08F4/545
摘要： Conjugated diene polymers having good wear resistance, mechanical properties, storage stability, processability and a reduced cold flow are produced by polymerizing a conjugated diene compound with a catalyst of rare earth element compound, a compound containing at least one halogen atom, an aluminoxane, and an organoaluminum compound in an organic solvent and reacting the resulting polymer just after the polymerization with at least one compound selected from the group consisting of a halogenated organometallic compound, a halogenated metal compound, an organometallic compound, a heterocumulene compound, a hetero three-membered-ring containing compound, a halogenated isocyano compound, a carboxylic acid, an acid halide, an ester compound, a carbonic ester compound, an acid anhydride and a metal salt of a carboxylic acid as a modifying agent.
摘要翻译：通过使共轭二烯化合物与稀土元素化合物的催化剂，含有至少一个卤素原子的化合物，铝氧烷和/或其混合物共聚而形成具有良好的耐磨性，机械性能，储存稳定性，加工性和降低的冷流的共轭二烯聚合物在有机溶剂中的有机铝化合物，使刚刚聚合后的所得聚合物与选自卤代有机金属化合物，卤化金属化合物，有机金属化合物，异葎草烯化合物，杂三元醇的至少一种化合物反应卤化异氰化合物，羧酸，酰卤，酯化合物，碳酸酯化合物，酸酐和作为改性剂的羧酸金属盐。

19. 发明授权

US06194505B1 Rubber composition for solid golf ball and solid golf ball 有权
标题翻译：固体高尔夫球和固体高尔夫球的橡胶组合物
公开(公告)号：US06194505B1
公开(公告)日：2001-02-27
申请号：US09201653
申请日：1998-12-01
申请人： Takuo Sone , Iwakazu Hattori
发明人： Takuo Sone , Iwakazu Hattori
IPC分类号： A63B3706
CPC分类号： C08L9/00 , A63B37/0003 , A63B37/0051 , A63B37/0073 , A63B37/0074 , A63B37/0075 , A63B37/0076 , A63B37/008 , A63B37/0084 , A63B37/0091 , C08C19/44 , C08F136/06 , C08F4/545
摘要： A rubber composition for solid golf balls comprising: (a) 50 to 100 parts by weight of a polybutadiene rubber with a 1,4-cis bond content of 80% or more, a 1,2-vinyl bond content of 2.0% or less, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn) of 3.5 or less, (b) 0 to 50 parts by weight of a diene-type rubber other than the component(a), provided that the total amount of the component (a) and component (b) is 100 parts by weight, (c) 10 to 50 parts by weight of a cross-linking monomer, (d) 20 to 80 part by weight of inorganic filler, and (e) an effective amount of an organic peroxide. The solid golf balls prepared from the rubber composition provide a good shot feeling, run a long distance, and exhibit superior durability.
摘要翻译：一种固体高尔夫球用橡胶组合物，其特征在于，包括：（a）50〜100重量份的1,4-顺式键合含量为80％以上的聚丁二烯橡胶，2.0％以下的1,2-乙烯基键含量，重均分子量（Mw）和数均分子量（Mn）的比（Mw / Mn）为3.5以下，（b）0〜50重量份除二烯类橡胶以外的二烯系橡胶组分（a），条件是组分（a）和组分（b）的总量为100重量份，（c）10至50重量份的交联单体，（d）20至80份的无机填料，和（e）有效量的有机过氧化物。由橡胶组合物制成的固体高尔夫球提供良好的拍摄感觉，运行长距离并且表现出优异的耐久性。

20. 发明授权

US6130299A Method for preparing conjugated diene polymer 失效
标题翻译：共轭二烯聚合物的制备方法
公开(公告)号：US6130299A
公开(公告)日：2000-10-10
申请号：US974922
申请日：1997-11-20
申请人： Takuo Sone , Akio Takashima , Katsutoshi Nonaka , Iwakazu Hattori
发明人： Takuo Sone , Akio Takashima , Katsutoshi Nonaka , Iwakazu Hattori
IPC分类号： C08F2/34 , C08F2/44 , C08F4/54 , C08F36/04 , C08F4/52
CPC分类号： C08F36/04
摘要： A method for preparing a conjugated diene polymer characterized by polymerizing a conjugated diene in vapor phase in the presence of an inorganic filler used as a rubber reinforcement agent and a catalyst which comprises (a) a compound containing a rare earth element of an atomic number of from 57 to 71 in the Periodic Table or a compound obtained by the reaction of this rare earth element-containing compound and a Lewis base, (b) an organic aluminum compound of the formula AlR.sup.1 R.sup.2 R.sup.3 or an almoxane, and (c) a halogen-containing compound. The vapor phase polymerization ensures easy control of the molecular weight of the polymer better dispersion of a rubber enforcement agent, and provides a rubber composition with improved rupture characteristics and abrasion resistance.
摘要翻译：一种制备共轭二烯聚合物的方法，其特征在于在用作橡胶增强剂的无机填料和催化剂存在下，气相中共轭二烯的聚合，所述催化剂包含（a）含有原子序数的稀土元素的化合物周期表中的57至71或通过该含稀土元素的化合物与路易斯碱的反应获得的化合物，（b）式AlR 1 R 2 R 3的有机铝化合物或阿莫氧烷，和（c）含有化合物。气相聚合确保了聚合物的分子量更容易控制橡胶强化剂的分散性，并提供了具有改进的断裂特性和耐磨性的橡胶组合物。

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