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11. 发明授权

US5427714A Ferroelectric liquid crystal composition 失效
标题翻译：铁电液晶组成
公开(公告)号：US5427714A
公开(公告)日：1995-06-27
申请号：US096848
申请日：1993-07-26
申请人： Katsuyuki Murashiro , Makoto Kikuchi , Kanetsugu Terashima
发明人： Katsuyuki Murashiro , Makoto Kikuchi , Kanetsugu Terashima
IPC分类号： G02F1/13 , C07D239/26 , C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46
CPC分类号： C07D239/26 , C09K19/3463
摘要： A ferroelectric liquid crystal composition having a SC* phase and a light-switching element using the composition are provided, which composition comprises the following components, A, B and C, each in a specified proportion: Component A has the formula ##STR1## wherein ##STR2## R.sup.1 and R.sup.2 are same or different linear or branched alkyl, alkoxy or alkanoyloxy of 1-18C, X is H, halogen or CN, l, m and n are 0 or 1 and (l+m+n) is 1 or 2, and has smectic C phase;Component B has the formula ##STR3## wherein ##STR4## Y is H, halogen or CN, k is 0 or 1, R.sup.3 is linear or branched alkyl or alkoxy of 1-18C, and * is asymmetric C, and consists of optically active compounds having the same senses of Ps in SC* phase induced when dissolved in smectic C liquid crystal, to one another; andComponent C has the formula ##STR5## wherein ##STR6## Z is H, halogen or CN, R.sup.5 and R.sup.6 are same or different linear or branched alkyl or alkoxy of 1-18C R.sup.4 is 12-18C alkyl or 1-18C linear or branched alkoxy, and * is asymmetric C, and is an optically active compound having the same sense of Ps in SC* phase induced when dissolved in smectic C liquid crystal as that of the compound of component B.
摘要翻译：提供具有SC *相的铁电液晶组合物和使用该组合物的光开关元件，该组成包含以下组分，A，B和C各自为特定比例：组分A具有式“IMAGE”（ A）其中R1和R2是1-18C的相同或不同的直链或支链烷基，烷氧基或烷酰氧基，X是H，卤素或CN，l，m和n是0或1，并且（1+ m + n）为1或2，具有近晶C相; 组分B具有式（B）其中或CN，k为0或1，R3为1-18C的直链或支链烷基或烷氧基，*为不对称C，并由具有在溶解在近晶C液晶中时，在SC *相中诱导的Ps的相同感觉; 并且组分C具有其中的公式（C）

12. 发明授权

US5240638A Ferroelectric liquid crystal composition 失效
标题翻译：铁电液晶组成
公开(公告)号：US5240638A
公开(公告)日：1993-08-31
申请号：US908854
申请日：1992-07-01
申请人： Makoto Kikuchi , Kanetsugu Terashima , Katsuyuki Murashiro
发明人： Makoto Kikuchi , Kanetsugu Terashima , Katsuyuki Murashiro
IPC分类号： C09K19/02 , C09K19/34 , C09K19/46
CPC分类号： C09K19/46 , C09K19/0225 , C09K19/3441
摘要： A ferroelectric liquid crystal composition comprising smectic liquid crystal composition(s) and optically active compounds and having a spontaneous polarization value of 20 nC cm.sup.-2 or less and nevertheless having high rate response properties, and a light-switching element are provided, which composition comprises the following components (A), (B), (C) and (D), in 76-95, 2-10, 1-6 and 2-8 wt.%, respectively, based on the total quantity of the 4 components:(A): at least one compound of the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different, being 1-18C alkyl, or the formula ##STR2## wherein R.sup.3 and R.sup.4 are the same or different, being 1-18C alkyl or alkoxy and having smectic C phase:(B): an optically active compound of the formula ##STR3## wherein R.sup.5 is 1-18C alkyl or alkoxy, X is ##STR4## Y is halogen or H and * is asymmetric C atom; (C): at least one optically active compound of the formulas ##STR5## wherein R.sup.6 and R.sup.8 are 1-18C alkyl or alkoxy, R.sup.7 and R.sup.9 are 2-18C alkyl or alkoxy and * is an asymmetric C atom; and(D): at least on optically active compound formula ##STR6## wherein R.sup.10 is 1-18 C alkyl or alkoxy, Z is H or halogen and * is an asymmetric C atom.
摘要翻译：提供了包含近晶型液晶组合物和光学活性化合物并且具有20nC cm -2以下的自发极化值并且具有高速率响应特性的铁电液晶组合物和光开关元件，该组成包括以下组分（A），（B），（C）和（D），分别为76-95，2-10,1-6和2-8重量％，基于4 组分：（A）：至少一种式（I）的化合物，其中R 1和R 2相同或不同，为1-18C烷基或式（II），其中R 3和R 4为相同或不同的是1-18C烷基或烷氧基并具有近晶C相：（B）：下式的光学活性化合物其中R5是1-18C烷基或烷氧基，X是Y 是卤素或H，*是不对称C原子; （IV）2a或图像（IV）中的至少一种光学活性化合物（IV-1a）图像（IV-1b）（IV-2b）其中R6和R8为1-18C烷基或烷氧基，R7和R9为2-18C烷基或烷氧基，*为不对称C原子; 和（D）：至少在光学活性化合物式“IMAGE”，1CHC2H5 + RE（V）其中R10为1-18C烷基或烷氧基，Z为H或卤素，*为不对称C原子。

13. 发明授权

US5106531A Ferroelectric liquid crystal composition 失效
标题翻译：电磁液晶组合物
公开(公告)号：US5106531A
公开(公告)日：1992-04-21
申请号：US476878
申请日：1990-02-07
申请人： Katsuyuki Murashiro , Makoto Kikuchi , Mitsuyoshi Ichihashi , Kanetsugu Terashima , Masaharu Seki
发明人： Katsuyuki Murashiro , Makoto Kikuchi , Mitsuyoshi Ichihashi , Kanetsugu Terashima , Masaharu Seki
IPC分类号： G02F1/137 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/141
CPC分类号： C09K19/3458
摘要： The present invention provides a ferroelectric liquid crystal composition which can exhibit an S.sub.C * phase in an extensive temperature range inclusive of room temperature and which has quick response properties and a large tilt angle, and it also provides a switching element containing the above-mentioned ferroelectric liquid crystal composition and having excellent response properties.The present invention is connected with a ferroelectric liquid crystal composition comprising at least one component A and at least one component B described hereinafter, the content of said component A being from 30 to 95% by weight, the content of said component B being from 5 to 50% by weight,said component A being a compound represented by the formula (I) ##STR1## wherein R.sup.1 is an alkoxy group having 3 to 14 carbon atoms, k is an integer of 1 and R.sup.2 is an optically active group,said component B being a ferroelectric liquid crystal compound having a spontaneous polarization of 10 nCcm.sup.-2 or more.

14. 发明授权

US08629225B2 Poly (N-alkylcarbazole) columnar structure and method for producing the same 有权
标题翻译：聚（N-烷基咔唑）柱状结构及其制造方法
公开(公告)号：US08629225B2
公开(公告)日：2014-01-14
申请号：US13040875
申请日：2011-03-04
申请人： Katsuyoshi Hoshino , Kazuki Takizawa , Katsuyuki Murashiro , Toshiki Komatsu
发明人： Katsuyoshi Hoshino , Kazuki Takizawa , Katsuyuki Murashiro , Toshiki Komatsu
IPC分类号： C08F26/06
CPC分类号： C08G61/124 , C08G2261/3241 , C08G2261/44
摘要： A poly(N-alkylcarbazole) columnar structure having electroconductivity is provided. The poly(N-alkylcarbazole) columnar structure having electroconductivity may be produced by electrolytically polymerizing an N-alkylcarbazole in a particular solvent.
摘要翻译：提供具有导电性的聚（N-烷基咔唑）柱状结构。具有导电性的聚（N-烷基咔唑）柱状结构可以通过在特定溶剂中电解聚合N-烷基咔唑来制备。

15. 发明授权

US08462419B2 Composition for electrochromic devices and electrochromic display device using the same 有权
标题翻译：用于电致变色装置的组合物和使用其的电致变色显示装置
公开(公告)号：US08462419B2
公开(公告)日：2013-06-11
申请号：US13283242
申请日：2011-10-27
申请人： Katsuyoshi Hoshino , Yosuke Oikawa , Mai Ando , Ryota Nakajima , Katsuyuki Murashiro , Toshiki Komatsu
发明人： Katsuyoshi Hoshino , Yosuke Oikawa , Mai Ando , Ryota Nakajima , Katsuyuki Murashiro , Toshiki Komatsu
IPC分类号： G02F1/155 , G02F1/361 , G02F1/00
CPC分类号： C09K9/02 , G02F1/1506 , G02F2202/04
摘要： There is provided a composition for electrochromic devices which clearly present only two states, a white-colored state and a decolored state. The composition for electrochromic devices contains (A) a specific quaternary ammonium salt, (B) a supporting electrolyte containing bromide ion, and (C) a solvent containing water as an essential component, and (A) is soluble in (C).
摘要翻译：提供了一种用于电致变色装置的组合物，其清楚地仅呈现出两种状态，即白色状态和脱色状态。用于电致变色装置的组合物含有（A）特定的季铵盐，（B）含有溴离子的支持电解质，（C）以水为主要成分的溶剂，（A）可溶于（C）。

16. 发明申请

US20120105933A1 COMPOSITION FOR ELECTROCHROMIC DEVICES AND ELECTROCHROMIC DISPLAY DEVICE USING THE SAME 有权
标题翻译：用于电致发光器件的组合物和使用该组合物的电致发光显示器件
公开(公告)号：US20120105933A1
公开(公告)日：2012-05-03
申请号：US13283242
申请日：2011-10-27
申请人： Katsuyoshi HOSHINO , Yosuke Oikawa , Mai Ando , Ryota Nakajima , Katsuyuki Murashiro , Toshiki Komatsu
发明人： Katsuyoshi HOSHINO , Yosuke Oikawa , Mai Ando , Ryota Nakajima , Katsuyuki Murashiro , Toshiki Komatsu
IPC分类号： G02F1/153 , H01B1/12
CPC分类号： C09K9/02 , G02F1/1506 , G02F2202/04
摘要： There is provided a composition for electrochromic devices which clearly present only two states, a white-colored state and a decolored state. The composition for electrochromic devices contains (A) a specific quaternary ammonium salt, (B) a supporting electrolyte containing bromide ion, and (C) a solvent containing water as an essential component, and (A) is soluble in (C).
摘要翻译：提供了一种用于电致变色装置的组合物，其清楚地仅呈现出两种状态，即白色状态和脱色状态。用于电致变色装置的组合物含有（A）特定的季铵盐，（B）含有溴离子的支持电解质，（C）以水为主要成分的溶剂，（A）可溶于（C）。

17. 发明授权

US5102576A Ferroelectric liquid crystal composition 失效
公开(公告)号：US5102576A
公开(公告)日：1992-04-07
申请号：US608739
申请日：1990-11-05
申请人： Kanetsugu Terashima , Makoto Kikuchi , Katsuyuki Murashiro
发明人： Kanetsugu Terashima , Makoto Kikuchi , Katsuyuki Murashiro
IPC分类号： G02F1/13 , C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46
CPC分类号： C09K19/46 , C09K19/3441 , C09K19/42 , C09K19/44
摘要： A ferroelectric liquid crystal composition comprising achiral smectic liquid crystal compounds(s) and optically active compounds and, which composition comprises the following components A, B and C in 50-91%, 4-30% and 5-20%, each by weight, respectively:Component A: at least one of compounds of the formula (A) having smectic C phase ##STR1## R.sup.1 and R.sup.2 each are same or different, linear or branched alkyl, alkoxy or alkanoyloxy each of 1-18 C, X is H, halogen or CN, l, m and n each one 1 or 2 and the sum of l, m and n is 1 or 2,component B: at least one of optically active compounds of the formula (B): ##STR2## and component C: at least one of optically active compounds of the formula ##STR3## wherein each R.sup.3 and R.sup.5 is a linear or branched alkyl or alkoxy of 1-18C, each R.sup.4 and R.sup.6 is a linear or branched alkyl of 2-18C or a linear or branched alkoxy of 1-18C, each Y and Z is H, halogen or CN k is 0 or 1 and * is asymmetric C, the compounds having the same sense of Ps in chiral smectic C phase, induced when dissolved in smectic C liquid crystal.

18. 发明授权

US06759102B2 Liquid crystal compositions and liquid crystal display devices 有权
标题翻译：液晶组合物和液晶显示装置
公开(公告)号：US06759102B2
公开(公告)日：2004-07-06
申请号：US10132854
申请日：2002-04-26
申请人： Katsuyuki Murashiro , Yasuhiro Kubo
发明人： Katsuyuki Murashiro , Yasuhiro Kubo
IPC分类号： C09K1930
CPC分类号： C09K19/46 , C09K19/42 , C09K19/44 , Y10T428/10 , Y10T428/1036
摘要： Liquid crystal compositions which comprise as a first component at least one compound selected from the group of compounds represented by the formula (I) and as a second component at least one compound selected from the group of compounds represented by the formula (II), the content of the first component being not less than 30% by weight based on the total weight of the composition wherein R1 and R3 are independently an alkyl of 1 to 10 carbon atoms and any —CH2— in the alkyl may be replaced by —O— or —CH═CH—; R2 is an alkyl of 1 to 10 carbon atoms, —F or —Cl; X1, X2, X3, X4, X5, X6, X7, X8 and X10 are independently —F or —H; X9 is —F, —Cl, —CF3, —OCF3 or —OCF2H; A1 and A2 are independently 1,4-cyclohexylene, pyrimidine-2,5-diyl or 1,4-phenylene in which any —H may be replaced by —F; Z1 and Z3 are independently a single bond, —(CH2)2— or —(CH2)4—; Z2 is a single bond or —CF2O—; and Z4 is a single bond, —COO— or —CF2O—. These compositions have reduced response time and low threshold voltage, and are used in a liquid crystal display device, especially that of an OCB mode.
摘要翻译：作为第一成分含有选自式（I）所示化合物的化合物和作为第二成分的至少一种选自式（II）所示的化合物的化合物的化合物的第一成分的液晶组合物，基于组合物的总重量，第一组分的含量不小于30重量％，其中R 1和R 3独立地是1至10个碳原子的烷基，并且烷基中的任何-CH 2 - 可以是被-O - 或-CH = CH-取代; R 2是1-10个碳原子的烷基，-F或-Cl; X 1，X 2，X 3，X 4，X 5，X 6，X 7，X 8和X 10独立地为-F或 - H; X 9是-F，-Cl，-CF 3，-OCF 3或-OCF 2 H; A 1和A 2独立地是1,4-亚环己基，嘧啶-2,5-二基或1,4-亚苯基，其中任何-H可被-F代替; Z 1和Z 3独立地是单键， - （CH 2）2 - 或 - （CH 2）4 - ; Z 2是单键或-CF 2 O-; 且Z 4为单键-COO-或-CF 2 O-。这些组合物具有降低的响应时间和低阈值电压，并且用于液晶显示装置，特别是OCB模式的液晶显示装置中。

19. 发明授权

US5529717A Smectic C liquid crystal composition and a liquid crystal display element 失效
标题翻译：液晶C液晶组合物和液晶显示元件
公开(公告)号：US5529717A
公开(公告)日：1996-06-25
申请号：US269017
申请日：1994-06-30
申请人： Katsuyuki Murashiro , Eiji Okabe , Makoto Kikuchi , Mayumi Tanabe , Masatoshi Fukushima , Shinichi Saito , Hitoshi Takeda , Makoto Shiomi , Takashi Kaneko , Motonari Matsuki , Mitsuhiro Koden
发明人： Katsuyuki Murashiro , Eiji Okabe , Makoto Kikuchi , Mayumi Tanabe , Masatoshi Fukushima , Shinichi Saito , Hitoshi Takeda , Makoto Shiomi , Takashi Kaneko , Motonari Matsuki , Mitsuhiro Koden
IPC分类号： C07D213/26 , C07D213/30 , C07D285/12 , C09K19/02 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/141 , G09G3/36
CPC分类号： C09K19/0225 , C09K19/34 , G09G3/3629 , G02F1/1416 , G09G2310/06
摘要： A composition containing a smectic C compound, having a .DELTA..epsilon. of negative value and enabling to effect a high speed response; a ferroelectric chiral smectic C liquid crystal composition using the same; and a ferroelectric liquid crystal display device using the ferroelectric chiral smectic C liquid crystal composition are provided,which composition containing a smectic C compound comprises at least one compound expressed by the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represent different linear alkyl groups of 1 to 9 C, andat least one compound expressed by the formula (II) ##STR2## wherein R.sup.3 and R.sup.4 each represent the same or different linear alkyl groups of 1 to 18 C and X is H or F.
摘要翻译：含有层状C化合物的组合物，其具有负值的DELTAε并能够实现高速响应; 使用其的铁电手性近晶C液晶组合物; 提供了使用铁电手性近晶C液晶组合物的铁电液晶显示装置，含有近晶C化合物的组合物包含至少一种式（I）表示的化合物，其中R1和R2各自表示 1至9个C的不同直链烷基和至少一种由式（II）表示的化合物（II），其中R 3和R 4各自表示相同或不同的直链烷基为1至18个碳原子并且X为H 或F.

20. 发明授权

US5378392A Antiferroelectric liquid crystal composition 失效
标题翻译：反铁电液晶组合物
公开(公告)号：US5378392A
公开(公告)日：1995-01-03
申请号：US917346
申请日：1992-07-23
申请人： Katsuyuki Murashiro , Kikuchi Makoto , Terashima Kanetsugu
发明人： Katsuyuki Murashiro , Kikuchi Makoto , Terashima Kanetsugu
IPC分类号： C09K19/02 , C09K19/20 , C09K19/46 , G02F1/13 , C09K19/52 , C09K19/12
CPC分类号： C09K19/0266 , C09K19/2021 , C09K19/46
摘要： An antiferroelectric mixture comprising first and second components is provided, the mixing proportions of the first and second components being 60-97 wt. % and 3-40 wt. % based upon the total weight of the two components, respectively, the first component being selected from the group consisting of compounds expressed by the formula (I) and the second component being selected from the group consisting of compounds expressed by the formula (II): ##STR1## wherein R.sup.1 and R.sup.3 are C.sub.1-18 alkyl or alkoxy, R.sup.2 and R.sup.4 are C.sub.2-18 alkyl or alkoxy, X and Y are --CH.sub.3, --CF.sub.3 or --C.sub.2 F.sub.5, rings A, B, C, D and E are 1,4-cyclohexylene, 1,4-phenylene an H atom of which may be replaced by a halogen atom or a cyano group, pyridine-2,5-diyl, pyrimidine-2,5-diyl, pyrazine-2,5-diyl or pyridazine-3,6-diyl, Z is --COO--, --CH.sub.2 O-- or --OCH.sub.2 --, m and n each are 1 or 2, (m+n) is 3, and Z is 0 or 1.Using the above antiferroelectric liquid crystal composition, a light-switching element having improved the temperature-dependency of threshold electric field and capable of effecting a tristable switching at a high is obtained.
摘要翻译：提供了包含第一和第二组分的反铁电混合物，第一和第二组分的混合比例为60-97wt。％和3-40wt。分别基于两种组分的总重量，第一组分选自由式（I）表示的化合物和第二组分选自由式（II）表示的化合物组成的组，：C1-18烷基或烷氧基，R2和R4是C2-18烷基或烷氧基，X和Y是-CH3，-CF3或-C2F5，A，B，C，D和E环是1,4-亚环己基，吡啶-2,5-二基，嘧啶-2,5-二基，吡嗪-2,5-二基或哒嗪-3的1,4-亚苯基，其中H原子可以被卤素原子或氰基取代， Z为-COO - ， - CH 2 O-或-OCH 2 - ，m和n各自为1或2，（m + n）为3，Z为0或1.使用上述反铁电液晶组合物，获得了提高阈值电场的温度依赖性且能够实现高的三态切换的光开关元件。

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