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    • 11. 发明申请
    • Silica-reinforced rubber compounded with blocked mercaptosilanes and alkyl alkoxysilanes
    • 与封闭的巯基硅烷和烷基烷氧基硅烷配合的硅橡胶
    • US20060106143A1
    • 2006-05-18
    • US10987847
    • 2004-11-12
    • Chenchy LinWilliam Hergenrother
    • Chenchy LinWilliam Hergenrother
    • B60C1/00
    • C08K5/548B60C1/0016C08K3/013C08L21/00
    • The invention provides a sulfur vulcanizable silica-reinforced elastomeric compound having improved tensile mechanical and dynamic viscoelastic properties. The compounds are formed by mixing an elastomer optionally having an alkoxysilane terminal group, with silica in the presence of an alkyl alkoxysilane and a blocked mercaptosilane. In particular, the mercaptosilane moiety of the blocked mercaptosilane and the alkyl alkoxysilane are present in a weight ratio of about 0.001:1 to about 0.20:1. Preferably, the blocked mercaptosilane and the alkyl alkoxysilane are compounded with the elastomer and the silica at high temperature to facilitate the silica-silane reaction. A deblocking agent is added at any desired mixing stage, optionally with the cure package, to allow binding of the mercaptosilane to the polymer.
    • 本发明提供具有改进的拉伸机械和动态粘弹性质的可硫化硫化二氧化硅增强的弹性体化合物。 通过在烷基烷氧基硅烷和封端巯基硅烷的存在下将任选具有烷氧基硅烷端基的弹性体与二氧化硅混合来形成化合物。 特别地,封端巯基硅烷的巯基硅烷部分和烷基烷氧基硅烷以约0.001:1至约0.20:1的重量比存在。 优选地,封端的巯基硅烷和烷基烷氧基硅烷在高温下与弹性体和二氧化硅混合以促进二氧化硅 - 硅烷反应。 在任何所需的混合阶段加入去封闭剂,任选地与固化包装一起,以使巯基硅烷与聚合物结合。