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    • 12. 发明授权
    • Electrochemical sensor
    • 电化学传感器
    • US5662786A
    • 1997-09-02
    • US807163
    • 1991-12-13
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • G01N27/407G01N27/409
    • G01N27/4075
    • The electrochemical sensor for determination of an oxygen content of exhaust gases, includes a probe element including a tube made from a raw material mixture consisting essentially of an ionically conductive solid electrolyte; an outer electrode located on the outer surface of the tube; a substantially pore-free conductor strip layer located on the outer surface, connected to the outer electrode, and extending toward the open end, the conductor strip layer having a portion in close proximity to the tube open end; and a substantially pore-free cover layer hermetically covering at least the portion of the pore-free conductor strip layer in close proximity to the open end of the tube, the cover layer being made from a cover layer material including the ionically conductive solid electrolyte. The cover layer material advantageously a sintering activity which is at least equal to that of the raw material mixture from which the tube is made. The conductor strip layer consists essentially of a ceramic supporting framework and an electron-conducting material. The ceramic ceramic binder has at least the same sintering activity as the cover layer material.
    • 用于确定废气氧含量的电化学传感器包括探针元件,其包括由基本上由离子导电固体电解质组成的原料混合物制成的管; 位于所述管的外表面上的外电极; 位于所述外表面上的基本上无孔的导体条带层,其连接到所述外电极并且朝向所述开口端延伸,所述导体带层具有紧邻所述管开口端的部分; 以及基本无孔的覆盖层,其至少密封地覆盖无孔导体带层的靠近管的开口端的部分,覆盖层由包括离子导电固体电解质的覆盖层材料制成。 覆盖层材料有利地是至少等于制造管的原料混合物的烧结活性。 导体带层基本上由陶瓷支撑框架和电子传导材料组成。 陶瓷陶瓷粘合剂具有与覆盖层材料至少相同的烧结活性。
    • 14. 发明授权
    • Sensor element seal for a detector
    • 检测器的传感器元件密封
    • US06223583B1
    • 2001-05-01
    • US09171687
    • 1999-04-19
    • Karl-Hermann FrieseHelmut Weyl
    • Karl-Hermann FrieseHelmut Weyl
    • G01N2712
    • G01N27/407
    • A sensor for determining an oxygen content of an exhaust gas of an internal combustion engine includes a flat-plate sensing element that is inserted in a gas-tight fashion via a hybrid seal in a ceramic shaped element that is arranged in a metal housing. The seal includes a powdered sealing packing, both placed around the sensing element in a recess at one end of the ceramic shaped element and a fusible glass seal located above the powdered sealing packing. The seal achieves gas-tight and gasoline-resistant isolation or immobilization of the sensing element in the ceramic shaped element.
    • 用于确定内燃机的排气的氧含量的传感器包括平板传感元件,该平板感测元件通过布置在金属外壳中的陶瓷元件中的混合密封件以气密方式插入。 密封件包括粉末密封填料,两个放置在陶瓷成形元件的一端的凹部中的感测元件周围,以及位于粉末密封填料上方的可熔玻璃密封件。 该密封件可实现气密和耐汽油隔离或固定在陶瓷成形元件中的传感元件。
    • 15. 发明授权
    • Electro-chemical measuring sensor with a potential-free sensor element
and method for producing it
    • 具有无电位传感器元件的电化学测量传感器及其制造方法
    • US5670032A
    • 1997-09-23
    • US592381
    • 1996-01-25
    • Karl-Hermann FrieseHelmut WeylSiegfried NeesHans-Martin Wiedenmann
    • Karl-Hermann FrieseHelmut WeylSiegfried NeesHans-Martin Wiedenmann
    • G01N27/409G01N27/407G01N27/26
    • G01N27/407G01N27/4078
    • An electro-chemical measuring sensor (10) for determining the oxygen content of gases, in particular for determining the oxygen content in exhaust gases of internal combustion engines, with a potential-free disposed sensor element (14). The sensor element (14) has an oxygen-ion-conducting solid electrolyte body (23), preferably in the shape of a pipe or tube closed at one end, which has an exterior electrode (25) disposed on the exterior surface with a strip conductor (27) on the side toward the contact and also extending on the exterior surface, and which is inserted by means of a sealing ring (20) in a metal housing (11). The sensor element (14) has an electrically insulating layer (21) at least in the area of the sealing ring (20), which covers at least the strip conductor (27) in the direction toward the housing (11). The insulating layer (21) is formed from a mixture of a crystalline, non-metallic material and a glass-forming material. In the course of production the insulating layer (21) is subjected to a thermal treatment above the melting temperature of the glass-forming material, in the course of which the insulating layer (21) forms a glaze filled with the crystalline, non-metallic material.
    • PCT No.PCT / DE94 / 00791 Sec。 371日期:1996年1月25日 102(e)日期1996年1月25日PCT 1994年7月9日PCT公布。 公开号WO95 / 04273 日期1995年2月9日,一种用于确定气体氧含量的电化学测量传感器(10),特别是用于确定内燃机排气中氧含量的电化学测量传感器(10)。 传感器元件(14)具有氧离子传导固体电解质体(23),优选地为在一端封闭的管或管的形状,其具有设置在外表面上的外部电极(25) 导体(27),并且还在外表面上延伸,并且通过密封环(20)插入到金属外壳(11)中。 传感器元件(14)至少在密封环(20)的区域中具有电绝缘层(21),其至少在朝向壳体(11)的方向上覆盖带状导体(27)。 绝缘层(21)由结晶,非金属材料和玻璃形成材料的混合物形成。 在制造过程中,将绝缘层(21)进行高于玻璃形成材料的熔化温度的热处理,其中绝缘层(21)形成填充有结晶非金属的釉料 材料。
    • 17. 发明授权
    • Exhaust gas sensor and method of producing the same
    • 废气传感器及其制造方法
    • US5423973A
    • 1995-06-13
    • US211083
    • 1994-06-20
    • Karl-Hermann FrieseHans-Martin WiedenmannHelmut Weyl
    • Karl-Hermann FrieseHans-Martin WiedenmannHelmut Weyl
    • G01N27/12G01N27/407G01N27/409G01N27/41G01N27/26
    • G01N27/4075
    • An exhaust gas sensor which is exposed to exhaust gas, includes a measuring electrode; and a porous ceramic coating provided on the measuring electrode and comprised of at least two layers, a first porous ceramic layer which is provided on the measuring electrode and at least a second porous ceramic layer which is provided on the first porous ceramic layer and which is directly exposed to the exhaust gas, wherein the first porous ceramic layer contains getter substances for removal of substances that are harmful to the measuring electrode, and wherein the second porous ceramic layer is provided with one of a diffusion resistance or a catalytic effect relative to exhaust gas constituents such that, at the boundary of the first and second porous ceramic layers, a gas composition is present in use which is comprised of one of oxidizable or reducible gas constituents and which sets a control position for the exhaust gas sensor.
    • PCT No.PCT / DE92 / 00714 Sec。 371日期:1994年6月20日 102(e)日期1994年6月20日PCT提交1992年8月27日PCT公布。 公开号WO93 / 06472 日本1997年4月1日。一种暴露于废气的排气传感器,包括测量电极; 以及设置在所述测量电极上并且包括至少两层的多孔陶瓷涂层,设置在所述测量电极上的第一多孔陶瓷层和设置在所述第一多孔陶瓷层上的至少第二多孔陶瓷层, 直接暴露于废气中,其中第一多孔陶瓷层含有用于除去对测量电极有害的物质的吸气剂物质,并且其中第二多孔陶瓷层具有相对于排气的扩散阻力或催化作用之一 气体成分,使得在第一和第二多孔陶瓷层的边界处,存在使用中的气体组合物,其由可氧化或可还原的气体成分之一组成,并且设置用于排气传感器的控制位置。
    • 19. 发明授权
    • Device for electrochemically measuring the concentration of oxygen in
combustion gases
    • 用于电化学测量燃烧气体中氧浓度的装置
    • US4057477A
    • 1977-11-08
    • US654918
    • 1976-02-03
    • Helmut WeylLeo Steinke
    • Helmut WeylLeo Steinke
    • G01N27/403G01N27/407G01N27/46
    • G01N27/407G01N27/4062G01N27/4078
    • A housing of the device has a passage formed with two spaced open ends and with an inner circumferential shoulder. A tubular member of ion-conducting solid electrolyte material has a first closed-ended portion projecting from one of the open ends, and a second portion extending through the passage and being formed with an outer circumferential flange an axial end face of which faces the one open end and is supported by the shoulder. The interior of the tubular member is in communication with the ambient atmosphere, and an electron-conductive inner electrode is provided on an inner surface of the tubular member and conductively connected with an outside terminal portion. An electron-conductive outer electrode is provided on an outer surface of the tubular member and conductively connected with the housing. A compensating arrangement is provided on the housing fixed with reference thereto and engages the second portion of the tubular member in such a way as to compensate for differential coefficience of thermal expansion and contraction of the material of the housing and of the tubular member, respectively. This prevents relative movements of the housing and tubular member when such differential expansion or contraction occurs.
    • 装置的壳体具有形成有两个间隔开的开口端和内周肩部的通道。 离子导电固体电解质材料的管状构件具有从一个开口端突出的第一封闭端部分和延伸穿过通道的第二部分,并且形成有外周凸缘,其轴向端面面向一个 开放式,并由肩膀支撑。 管状构件的内部与环境大气连通,并且在管状构件的内表面上设置电子导电内部电极,并与外部端子部分导电连接。 电子导电外电极设置在管状构件的外表面上并与壳体导电连接。 在相对于其固定的壳体上提供补偿装置,并且以这样一种方式接合管状构件的第二部分,以分别补偿壳体和管状构件的材料的热膨胀和收缩的差异系数。 这样可以防止在出现这种不同的膨胀或收缩时壳体和管状构件的相对运动。
    • 20. 发明授权
    • Electrochemical exhaust gas oxygen sensor construction
    • 电化学废气氧传感器构造
    • US4187163A
    • 1980-02-05
    • US863612
    • 1977-12-23
    • Leo SteinkeHelmut Weyl
    • Leo SteinkeHelmut Weyl
    • G01N27/409F02D41/14G01N27/403G01N27/407G01N27/46
    • G01N27/407F02D41/1454G01N27/4062
    • To prevent ingress of moisture, water, dirt, or other contamination into the interior of an exhaust gas sensor having an opening to provide for communication with ambient air to establish an oxygen reference level, a cover cap, preferably of metal, but which may be of plastic if extreme heat resistance is not required, is placed over the sensor, the cover cap being formed with a labyrinth which provides for communication between ambient air and the interior of the sensor, the labyrinth preferably being formed as a groove, especially a spiral groove, in the interior of the cap and having access to outside ambient air, the cap preferably being secured by means other than friction, such as a spot weld, an engagement catch or the like to the sensor housing.
    • 为了防止湿气,水,污垢或其他污染物进入具有开口的废气传感器的内部,以提供与环境空气的连通以建立氧参考水平,优选为金属的盖帽,但可以是 的塑料,如果不需要极高的耐热性,则放置在传感器上方,盖帽形成有迷宫,该迷宫用于环境空气和传感器内部之间的连通,迷宫优选地形成为凹槽,特别是螺旋形 凹槽,在盖的内部并且能够进入外部环境空气的情况下,盖优选地通过除摩擦之外的装置(例如点焊,接合卡爪等)固定到传感器壳体。